Metal supported powder catalyst matrix and processes for multiphase chemical reactions
A catalytic membrane composite that includes porous supported catalyst particles durably enmeshed in a porous fibrillated polymer membrane is provided. The porous fibrillated polymer membrane may be manipulated to take the form of a tube, disc, or diced tape and used in multiphase reaction systems. The supported catalyst particles are composed of at least one finely divided metal catalyst dispersed on a porous support substrate. High catalytic activity is gained by the effective fine dispersion of the finely divided metal catalyst such that the metal catalyst covers the support substrate and/or is interspersed in the pores of the support substrate. In some embodiments, the catalytic membrane composite may be introduced to a stirred tank autoclave reactor system, a continuous flow reactor system, or a Parr Shaker reaction system and used to effect the catalytic reaction.
1. A reaction system comprising:
a catalytic article comprising a porous fibrillated polymer membrane that includes supported catalyst particles durably enmeshed within the porous fibrillated polymer membrane;
a reaction mixture including:
a liquid phase comprising at least one liquid phase reactant; and
a gas phase comprising at least one gas phase reactant; and
a reaction vessel containing the catalytic article, the liquid phase, and the gas phase,
wherein the reaction mixture has free access to move through and around the catalytic particles, and
wherein the catalytic article is in the form of diced tape.
2. The reaction system of claim 1 , wherein the reaction system is configured for hydrogenation.
3. The reaction system of claim 1 , wherein the porous fibrillated polymer membrane is insoluble to reactants and products in the multiphase chemical reaction.
4. The reaction system of claim 1 , wherein the porous fibrillated polymer membrane comprises polytetrafluorethylene (PTFE), poly(ethylene-co-tetrafluoroethylene) (ETFE), ultra high molecular weight polyethylene (UHMWPE), polyparaxylylene (PPX), polylactic acid and any combination or blend thereof.
5. The reaction system of claim 1 , wherein the porous fibrillated polymer membrane comprises polytetrafluoroethylene (PTFE), expanded polytetrafluoroethylene (ePTFE), modified PTFE, or a PTFE copolymer.
6. The reaction system of claim 1 , wherein the porous fibrillated polymer membrane comprises expanded polytetrafluoroethylene (ePTFE).
7. The reaction system of claim 1 , wherein the porous fibrillated polymer membrane has a porosity from about 30% to about 95%.
8. The reaction system of claim 1 , wherein the reaction system is a continuous loop reactor.
9. The reaction system of claim 1 , wherein the reaction system is configured for hydrogenation.
10. The reaction system of claim 1 , comprising a reaction vessel in the form of a continuous loop configured for continuous flow of the liquid phase reactant and the gas phase reactant across and through the catalytic article.
11. The reaction system of claim 1 , comprising a stirred tank reaction vessel comprising a rotatable impeller shaft having thereon at least one impeller blade.
12. The reaction system of claim 11 , wherein the impeller blade is pitched.