Build compositions
View Patent ↗The present disclosure relates to a build composition for a 3-dimensional printing process. The build composition comprises thermoplastic polymer particles, a first photoluminescent agent and a second photoluminescent agent. The build composition has a spectral signature characteristic of the presence of the first photoluminescent agent and the second photoluminescent agent in combination.
1. A build composition for a 3-dimensional printing process, the build composition comprising thermoplastic polymer particles, solid particles of a first photoluminescent agent and solid particles of a second photoluminescent agent, wherein the build composition has a spectral signature characteristic of the presence of the first photoluminescent agent and the second photoluminescent agent in combination, wherein the thermoplastic polymer particles are in the form of a powder, wherein the first photoluminescent agent and the second photoluminescent agent are in the form of a powder mixed with the thermoplastic polymer particles, and wherein the thermoplastic polymer particles are nylon 6 powder, nylon 9 powder, nylon 11 powder, nylon 12 powder, nylon 66 powder, nylon 612 powder, polyethylene powder, thermoplastic polyurethane powder, polypropylene powder, polyester powder, polyether ketone powder, polyacrylate powder, polystyrene powder, or a combination thereof.
2. A composition as claimed in claim 1 , wherein the first photoluminescent agent and/or the second photoluminescent agent are UV fluorescent pigments.
3. A composition as claimed in claim 1 , wherein the first photoluminescent agent and/or the second photoluminescent agent have a particle size of 10 μm to 100 μm.
4. A composition as claimed in claim 1 , wherein the total amount of photoluminescent agent in the composition is 0.1 to 3 weight % based on the total weight of the composition.
5. A composition as claimed in claim 1 , wherein the weight ratio of the first photoluminescent agent to the second photoluminescent agent is 20:1 to 1:20.
6. A composition as claimed in claim 1 , wherein the emission spectrum of the first photoluminescent agent overlaps with the emission spectrum of the second photoluminescent agent at least at a wavelength of 400 nm to 700 nm.
7. A composition as claimed in claim 1 , wherein the spectral signature of the build composition cannot be detected by visual inspection under visible light.
8. A composition as claimed in claim 1 , wherein the first photoluminescent agent and/or the second photoluminescent agent has both fluorescent and phosphorescent properties.
9. A composition as claimed in claim 1 , wherein the first photoluminescent agent and/or the second photoluminescent agent absorbs electromagnetic radiation at a wavelength less than 400 nm to generate a photoluminescent emission at least at a wavelength of from 400 nm to 700 nm.
10. A composition as claimed in claim 1 , which further comprises a third photoluminescent agent, wherein the build composition has a spectral signature characteristic of the presence of the first, second and third photoluminescent agents in combination.
11. The composition as claimed in claim 1 , wherein the first photoluminescent agent or the second photoluminescent agent comprises quantum dots having a particle size from 2 nm to 20 nm.
12. The composition as claimed in claim 1 , wherein the first photoluminescent agent is a green-emitting photoluminescent pigment, and wherein the second photoluminescent agent is an orange-emitting photoluminescent pigment.
13. The composition as claimed in claim 1 , wherein the first photoluminescent agent is present in an amount from 0.05 wt % to 1 wt % based on the total weight of the composition, and wherein the second photoluminescent agent is present in an amount from 0.05 wt % to 1 wt % based on the total weight of the composition.
14. The composition as claimed in claim 1 , wherein the first photoluminescent agent and the second photoluminescent agent are both excited by UV light and emit visible light.
15. The composition as claimed in claim 1 , wherein the thermoplastic polymer particles have an average particle size from 10 μm to 100 μm.
16. The composition as claimed in claim 1 , wherein the thermoplastic polymer particles are nylon 6 powder, nylon 9 powder, nylon 11 powder, nylon 12 powder, nylon 66 powder, nylon 612 powder, or a combination thereof.
17. The composition as claimed in claim 1 , wherein the thermoplastic polymer particles are blended with a filler.