IP Library › Granted Patent US 11,614,574
Granted Patent B2
US 11,614,574 · App. 16/581,783 · Granted Mar 28, 2023

Coloring composition for solid-state imaging element

Inventors: Tomotaka Chuko (Tokyo, JP); Kenji Hiki (Tokyo, JP); Ryuji Doi (Tokyo, JP); Kazushige Kitazawa (Tokyo, JP); Shinichi Okamoto (Tokyo, JP); Tetsuya Hirota (Tokyo, JP); Tadatoshi Maeda (Tokyo, JP); Hiroyuki Chinone (Tokyo, JP)
Assignee: TOPPAN PRINTING CO., LTD.
G02B5/223C09D4/06C09D5/32C09D7/41C09D7/63C09D133/14H01L27/14621
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Quick Facts
Patent No.
US 11,614,574
App. No.
16/581,783
Granted
Mar 28, 2023
Kind
B2
Abstract

A photosensitive green composition for a color filter of a solid-state imaging element, contains a colorant (A), a binder resin (B), a photopolymerization initiator (C), a photopolymerizable monomer (D), an ultraviolet absorber (E), and a monofunctional thiol (F), wherein the colorant (A) contains C.I. Pigment Green 36 and/or C.I. Pigment Green 58.

Claims (26)

1. A photosensitive green composition for a color filter of a solid-state imaging element, comprising:

a colorant (A);

a binder resin (B);

a photopolymerization initiator (C);

a photopolymerizable monomer (D);

an ultraviolet absorber (E); and

a monofunctional thiol (F),

wherein the colorant (A) comprises C.I. Pigment Green 36, C.I. Pigment Green 58, and/or C.I. Pigment Yellow 150, and

the monofunctional thiol (F) comprises 2-mercapto-5-methylthio-1,3,4-thiadiazole or triphenylmethanethiol, and

a content of the monofunctional thiol (F) is 0.05 to 3.00% by weight in a total solid content of the photosensitive green composition.

2. The photosensitive green composition for a color filter of a solid-state imaging element according to claim 1 , wherein the photopolymerizable monomer (D) comprises a urethane acrylate, and the urethane acrylate is a compound obtained by reacting a compound represented by a general formula (1) with a polyfunctional isocyanate represented by a general formula (2),

the general formula (1) being

wherein R 1 , R 2 , R 3 independently represent an acryloyl group or a methacryloyl group, and

the general formula (2) being

o=C=N−X−N=C=O

wherein X represents a divalent alkylene group or an arylene group.

3. The photosensitive green composition for a color filter of a solid-state imaging element according to claim 1 , wherein a content of the ultraviolet absorber (E) is 0.05 to 3.00% by weight in a total solid content of the photosensitive green coloring composition.

4. The photosensitive green composition for a color filter of a solid-state imaging element according to claim 1 , wherein the ultraviolet absorber (E) comprises an ultraviolet absorber having an absorbance at a wavelength of 365 nm of 0.4 or more measured when dissolved in chloroform to be diluted to 10 mg/L.

5. The photosensitive green composition for a color filter of a solid-state imaging element according to claim 1 , wherein the ultraviolet absorber (E) comprises at least one selected from benzotriazole-based compounds, benzophenone-based compounds, and triazine-based compounds.

6. The photosensitive green composition for a color filter of a solid-state imaging element according to claim 1 , wherein a content of the colorant (A) is 40 to 70% by weight in a total solid content of the photosensitive green composition.

7. The photosensitive green composition for a color filter of a solid-state imaging element according to claim 1 , wherein a content of the photopolymerization initiator (C) is 0.3 to 5.0% by weight in a total solid content of the photosensitive green composition.

8. The photosensitive green composition for a color filter of a solid-state imaging element according to claim 1 , wherein the photopolymerization initiator (C) comprises an oxime ester-based photopolymerization initiator.

9. A color filter for a solid-state imaging element, comprising a filter segment made from the photosensitive green composition for a color filter of a solid-state imaging element as defined in claim 1 on a base material.

10. A solid-state imaging element comprising the color filter for a solid-state imaging element as defined in claim 9 .

11. The photosensitive green composition for a color filter of a solid-state imaging element according to claim 1 , wherein the photopolymerizable monomer (D) comprises urethane acrylate and/or penta- or higher functional acrylate excluding urethane acrylate.

12. The photosensitive green composition for a color filter of a solid-state imaging element according to claim 11 , wherein a content of the photopolymerizable monomer (D) is 15 to 30% by weight with respect to a total solid content of the photosensitive green coloring composition, and a total content of the urethane acrylate and the penta- or higher functional acrylate excluding urethane acrylate is 50 to 90% by weight in a total solid content of the photopolymerizable monomer (D).

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 6, 2022
From: TOYO INK SC HOLDINGS CO., LTD.; TOYOCOLOR CO., LTD.
To: TOPPAN PRINTING CO.,LTD.
Reel/Frame 060104/0355 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 25, 2019
From: CHUKO, TOMOTAKA; HIKI, KENJI; DOI, RYUJI; KITAZAWA, KAZUSHIGE; OKAMOTO, SHINICHI; HIROTA, TETSUYA; MAEDA, TADATOSHI; CHINONE, HIROYUKI
To: TOYO INK SC HOLDINGS CO., LTD.; TOYOCOLOR CO., LTD.; TOPPAN PRINTING CO., LTD.
Reel/Frame 050492/0687 →
Priority Claims (2)
JP 2017-065341 · Mar 29, 2017 · national
JP 2017-195892 · Oct 6, 2017 · national
Continuity (2)
Continuation PCTJP2018013150 · Mar 29, 2018
Related Publication 20200018878A1 · Jan 16, 2020