IP Library Granted Patent US 11,618,055
Granted Patent B2
US 11,618,055 · App. 17/978,370 · Granted Apr 4, 2023

Methods for providing flexible and/or elastic coatings on oilfield operational components

Inventors: Greg Andrews (Wilmington, DE); George D. Andrews (Wilmington, DE); Jeff Capell (Wilmington, DE)
Assignee: S+S INDUSTRIES TECHNOLOGY LLC
B05D7/586B05D1/02B05D1/18B05D1/38B05D3/12B05D5/00B05D7/14B05D7/16B05D7/22B05D7/222B05D7/225B05D7/26B05D7/544B05D7/546B05D7/584C08K5/5425C09D5/002C09D5/082C09D5/084C09D7/20C09D7/61C09D7/62C09D7/63C09D159/00C09D163/04C09D183/04C09D183/06C23F11/18E21B33/03E21B34/04E21B34/06E21B41/00E21B43/2607B05D2202/00B05D2202/10B05D2254/00B05D2350/60B05D2401/10B05D2504/00C08G59/022C08G59/063C08K3/11C08K3/36C08K5/541C08K5/544C08K5/5415C08K5/5435C09D163/00E21B17/02E21B43/26
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Quick Facts
Patent No.
US 11,618,055
App. No.
17/978,370
Granted
Apr 4, 2023
Kind
B2
Abstract

Coating compositions for coating an oilfield operational component, and related methods, may include in some aspects a coating composition having a trifunctional silane, a silanol, and a filler. The coating composition may be applied to a surface of the oilfield operational component that is configured to be exposed to a fluid. The coating composition may be applied to at least partially cover or coat the surface. The coating composition may be configured to chemically bond with a cured primer composition that includes an epoxy.

Claims (54)

1. A method for providing a flexible coating on a surface of a component, the method comprising:

applying a primer composition to a surface of a component configured to be exposed to a flow of fluid, the primer composition comprising epoxy;

at least partially curing the primer composition to obtain a primer layer having a dry film thickness ranging from about 20 micrometers to about 100 micrometers;

applying a first coating composition to the primer layer, the first coating composition comprising titanium dioxide and at least one of trifunctional silane, silanol, or filler;

at least partially curing the first coating composition to obtain a first coating layer having a dry film thickness ranging from about 100 micrometers to about 250 micrometers;

applying a second coating composition to the first coating layer, the second coating composition comprising at least one of trifunctional silane, silanol, or filler; and

at least partially curing the second coating composition to obtain a second coating layer having a dry film thickness ranging from about 100 micrometers to about 250 micrometers, at least one of the primer layer, the first coating layer, or the second coating layer being configured to reduce damage to the component from the flow of the fluid, such that the component exhibits a comparison factor indicative of an increased resistance to wear greater than about 2.

2. The method of claim 1 , wherein the comparison factor is indicative of a first amount of time during which a portion of the flexible coating wears to a first depth divided by a second amount of time during which a portion of the component without the flexible coating wears to a second depth equal to the first depth.

3. The method of claim 1 , wherein the comparison factor ranges from about 5 to about 30.

4. The method of claim 1 , wherein the comparison factor ranges from about 3 to about 12.

5. The method of claim 1 , wherein the comparison factor ranges from about 2 to about 20.

6. The method of claim 1 , wherein the first coating composition and the second coating composition are substantially the same.

7. The method of claim 1 , further comprising:

applying at least one an additional coating composition to the second coating layer, the at least one additional coating composition comprising at least one of trifunctional silane, silanol, filler, or titanium dioxide; and

at least partially curing the at least one additional coating composition to obtain at least one additional coating layer, such that the component exhibits a comparison factor indicative of an increased resistance to wear ranging from about 2 to about 30, and

wherein the total dry film thickness of the first coating layer, the second coating layer, and the at least one additional coating layer ranges from about 500 micrometers to about 1000 micrometers.

8. The method of claim 7 , wherein at least two of the first coating composition, the second coating composition, or the at least one additional coating composition are substantially the same.

9. The method of claim 7 , wherein applying the at least one additional coating composition comprises applying a third coating composition, and wherein at least partially curing the at least one additional coating composition comprises at least partially curing the third coating composition to obtain a third coating layer having a dry film thickness ranging from about 100 micrometers to about 250 micrometers, such that the component exhibits a comparison factor indicative of an increased resistance to wear ranging from about 2 to about 30.

10. The method of claim 1 , wherein the primer composition comprises at least one of an aliphatic amine, epichlorohydrin, bisphenol, silane adhesion promoter, trimethoxysilane, triethoxysilane, or 3-glycidoxypropyltrimethoxysilane.

11. The method of claim 1 , wherein at least one of the first coating composition or the second coating composition comprises trifunctional silane comprising at least one of an acetoxy silane, a ketoximino silane, an enoxy silane, an amine silane, an alkoxy silane, or alkenyl silane, ethyl triacetoxysilane, vinyl triacetoxysilane, methyl tris (methyl-ethyl-ketoximino) silane, or vinyl tris (methyl-ethyl-ketoximino) silane.

12. The method of claim 1 , wherein at least one of the first coating composition or the second coating composition comprises filler comprising at least one of fumed silica, glass fiber, mica, wollastonite, kaolin, or phylosilicates.

13. The method of claim 1 , wherein at least one of the first coating composition or the second coating composition further comprises at least one of a catalyst or a solvent.

14. The method of claim 1 , wherein the fluid comprises at least one of water, proppants, thickening agents, or mixtures thereof.

15. The method of claim 1 , wherein:

at least one of the first coating composition or the second coating composition comprises trifunctional silane, silanol, and filler,

the trifunctional silane comprises from about 0.01 wt. % to about 20 wt. % of the at least one of the first coating composition or the second coating composition on the basis of non-solvent components,

the silanol comprises from about 40 wt. % to about 99 wt. % of the at least one of the first coating composition or the second coating composition on the basis of non-solvent components;

the filler comprises from about 0.01 wt. % to about 25 wt. % of the at least one of the first coating composition or the second coating composition on the basis of non-solvent components, and

one or more of the trifunctional silane, the silanol, or the filler are configured to cure and form ethyl T-resin units, each of the ethyl T-resin units forming two or more bonds with one or more of other ethyl T-resin units, silanol fluid, fillers, or pigments.

16. A method for providing an elastic coating on a surface of an operational component configured to be exposed to a flow of fluid, the method comprising:

applying a primer composition to an interior surface of an operational component configured to be exposed to a flow of a fluid when in operation, the primer composition comprising epoxy;

at least partially curing the primer composition to obtain a primer layer having a dry film thickness ranging from about 20 micrometers to about 100 micrometers;

applying a first coating composition to the primer layer, the first coating composition comprising titanium dioxide and at least one of trifunctional silane, silanol, or filler;

at least partially curing the first coating composition to obtain a first coating layer having a dry film thickness ranging from about 100 micrometers to about 250 micrometers;

applying at least one additional coating composition to the first coating layer, the at least one additional coating composition comprising at least one of trifunctional silane, silanol, filler, or titanium dioxide; and

at least partially curing the at least one additional coating composition to obtain at least additional coating layer, the total dry film thickness of the first coating layer and the at least one additional coating layer ranging from about 500 micrometers to about 1000 micrometers, and at least one of the primer layer, the first coating layer, or the at least one additional coating layer being configured to reduce damage to the operational component from the flow of the fluid, such that the operational component exhibits a comparison factor indicative of an increased resistance to wear greater than about 2.

17. The method of claim 16 , wherein the first coating composition and the at least one additional coating composition are substantially the same.

18. The method of claim 16 , wherein applying the at least one additional coating composition comprises applying a second coating composition, and wherein at least partially curing the at least one additional coating composition comprises at least partially curing the second coating composition to obtain a second coating layer having a dry film thickness ranging from about 100 micrometers to about 250 micrometers, such that the operational component exhibits a comparison factor indicative of an increased resistance to wear ranging from about 2 to about 30.

19. The method of claim 18 , wherein applying the at least one additional coating composition further comprises applying a third coating composition, and wherein at least partially curing the at least one additional coating composition further comprises at least partially curing the third coating composition to obtain a third coating layer having a dry film thickness ranging from about 100 micrometers to about 250 micrometers, such that the operational component exhibits a comparison factor indicative of an increased resistance to wear ranging from about 2 to about 30.

20. The method of claim 19 , wherein at least two of the first coating composition, the second coating composition, or the third coating composition are substantially the same.

21. The method of claim 16 , wherein the primer composition comprises at least one of an aliphatic amine, epichlorohydrin, bisphenol, silane adhesion promoter, trimethoxysilane, triethoxysilane, or 3-glycidoxypropyltrimethoxysilane.

22. The method of claim 16 , wherein at least one of the first coating composition or the at least one additional coating composition comprises trifunctional silane comprising at least one of an acetoxy silane, a ketoximino silane, an enoxy silane, an amine silane, an alkoxy silane, or alkenyl silane, ethyl triacetoxysilane, vinyl triacetoxysilane, methyl tris (methyl-ethylketoximino) silane, or vinyl tris (methyl-ethyl-ketoximino) silane.

23. The method of claim 16 , wherein at least one of the first coating composition or the at least one additional coating composition comprises filler comprising at least one of fumed silica, glass fiber, mica, wollastonite, kaolin, or phylosilicates.

24. The method of claim 16 , wherein at least one of the first coating composition or the at least one additional coating composition further comprises at least one of a catalyst or a solvent.

25. The method of claim 16 , wherein the fluid comprises an oilfield fluid, and wherein the oilfield fluid comprises at least one of water, proppants, thickening agents, or mixtures thereof.

26. The method of claim 16 , wherein:

at least one of the first coating composition or the at least one additional coating composition comprises trifunctional silane, silanol, filler, and titanium dioxide,

the trifunctional silane comprises from about 0.01 wt. % to about 20 wt. % of the at least one of the first coating composition or the at least one additional coating composition on the basis of non-solvent components,

the silanol comprises from about 40 wt. % to about 99 wt. % of the at least one of the first coating composition or the at least one additional coating composition on the basis of non-solvent components, and

the filler comprises from about 0.01 wt. % to about 25 wt. % of the at least one of the first coating composition or the at least one additional coating composition on the basis of non-solvent components.

27. The method of claim 16 , wherein: one or more of the first coating composition or the at least one additional coating composition comprises trifunctional silane, silanol, filler, and titanium dioxide; and one or more of the trifunctional silane, the silanol, or the filler are configured to cure and form ethyl T-resin units, each of the ethyl T-resin units forming two or more bonds with one or more of other ethyl T-resin units, silanol, fillers, or pigments.

28. The method of claim 27 , wherein the one or more of the first coating composition or the at least one additional coating composition comprises an amount of ethyl T-resin units ranging from about 1.5 wt. % to about 5.0 wt. % of the one or more of the first coating composition or the at least one additional coating composition on the basis of non-solvent components.

29. The method of claim 16 , wherein one or more of the first coating composition or the at least one additional coating composition comprises trifunctional silane, silanol, filler, and blue pigment, the blue pigment in an amount ranging from about 1.0 wt. % to about 5.0 wt. % of the one or more of the first coating composition or the at least one additional coating composition on the basis of non-solvent components.

30. The method of claim 16 , wherein one or more of the first coating composition or the at least one additional coating composition comprises trifunctional silane, silanol, filler, and titanium dioxide, the titanium dioxide in an amount ranging from about 0.50 wt. % to about 0.90 wt. % of the one or more of the first coating composition or the at least one additional coating composition on the basis of non-solvent components.

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 1, 2022
From: ANDREWS, GREG; ANDREWS, GEORGE D.; CAPELL, JEFF
To: FORMULA NO. 37, LLC
Reel/Frame 061609/0449 →
CHANGE OF NAME Recorded Nov 1, 2022
From: S+S INDUSTRIES LLC
To: S+S INDUSTRIES TECHNOLOGY LLC
Reel/Frame 061828/0667 →
CHANGE OF NAME Recorded Nov 1, 2022
From: FORMULA NO. 37, LLC
To: S+S INDUSTRIES LLC
Reel/Frame 061828/0692 →
Continuity (13)
Continuation 17225743 · Apr 8, 2021
Provisional Application 63008035 · Apr 10, 2020
Provisional Application 63008038 · Apr 10, 2020
Provisional Application 63008042 · Apr 10, 2020
Provisional Application 63008046 · Apr 10, 2020
Provisional Application 63008049 · Apr 10, 2020
Provisional Application 63065542 · Aug 14, 2020
Provisional Application 63065545 · Aug 14, 2020
Provisional Application 63065565 · Aug 14, 2020
Provisional Application 63065577 · Aug 14, 2020
Provisional Application 63065591 · Aug 14, 2020
Provisional Application 63198044 · Sep 25, 2020
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