Liquid solution concentration system comprising isolated subsystem and related methods
Liquid solution concentration systems, and related methods, are generally described. In some embodiments, the system is an osmotic system comprising a plurality of osmotic modules. For example, the osmotic system can comprise a feed osmotic module configured to produce an osmotic module retentate outlet stream having a higher concentration of solute than the retentate inlet stream transported to the feed osmotic module. The osmotic system can also comprise an isolation osmotic module fluidically connected to the feed osmotic module. The osmotic system can also optionally comprise a purification osmotic module fluidically connected to the feed osmotic module and/or the isolation osmotic module. Certain embodiments are related to altering the degree to which the feed osmotic module retentate outlet stream is recycled back to the retentate-side inlet of the feed osmotic module during operation. Additional embodiments are related to the manner in which the retentate-side effluent from the isolation osmotic module is distributed among the system modules during operation.
1. A method of operating an osmotic system, the osmotic system comprising:
a feed osmotic module comprising:
a retentate side,
a permeate side, and
at least one osmotic membrane between the retentate side and the permeate side; and an isolation osmotic module comprising:
a retentate side,
a permeate side, and
at least one osmotic membrane between the retentate side and the permeate side;
wherein the retentate side of the isolation osmotic module is fluidically connected to the permeate side of the feed osmotic module; and
wherein the method comprises:
during both a first period of time and a second period of time, transporting a feed solution comprising a solvent and a solute to the retentate side of the feed osmotic module such that the feed solution enters the retentate side of the feed osmotic module;
during both the first period of time and the second period of time, operating the feed osmotic module to produce:
a feed osmotic module retentate outlet stream exiting the retentate side of the feed osmotic module, the feed osmotic module retentate outlet stream having a solute concentration that is greater than a solute concentration of the feed solution entering the retentate side of the feed osmotic module, and
a feed osmotic module permeate outlet stream that exits the permeate side of the feed osmotic module, the feed osmotic module permeate outlet stream comprising at least a portion of the solvent from the feed osmotic module retentate inlet stream;
during both the first period of time and the second period of time, transporting an isolation osmotic module retentate inlet stream comprising at least a portion of the feed osmotic module permeate outlet stream to the retentate side of the isolation osmotic module such that the isolation osmotic module retentate inlet stream enters the retentate side of the isolation osmotic module; and
during both the first period of time and the second period of time, operating the isolation osmotic module to produce:
an isolation osmotic module retentate outlet stream exiting the retentate side of the isolation osmotic module, the isolation osmotic module retentate outlet stream having an osmotic pressure that is greater than an osmotic pressure of the isolation osmotic module retentate inlet stream, and
an isolation osmotic module permeate outlet stream that exits the permeate side of the isolation osmotic module, the isolation osmotic module permeate outlet stream comprising at least a portion of solvent from the isolation osmotic module retentate inlet stream;
wherein:
during the first period of time, the retentate side of the feed osmotic module receives at least a portion of the feed osmotic module retentate outlet stream; and
during the second period of time, the retentate side of the feed osmotic module no longer receives any portion of the feed osmotic module retentate outlet stream or receives an amount of the feed osmotic module retentate outlet stream that is less than the amount of the feed osmotic module retentate outlet stream received by the retentate side of the feed osmotic module during the first period of time.
2. The method of claim 1 , further comprising transferring a feed osmotic module permeate inlet stream to the permeate side of the feed osmotic module, wherein the feed osmotic module permeate inlet stream comprises at least a portion of the isolation osmotic module retentate outlet stream.
3. The method of claim 2 , wherein the retentate side of the isolation osmotic module is fluidically connected to the permeate side of the isolation osmotic module, and wherein the method further comprises transferring an isolation osmotic permeate inlet stream to the permeate side of the isolation osmotic module, wherein the isolation osmotic module permeate inlet stream comprises at least a portion of the isolation osmotic module retentate outlet stream.
4. The method of claim 3 , wherein:
the osmotic system further comprises a purification osmotic module comprising:
a retentate side fluidically connected to the retentate side of the isolation osmotic module,
a permeate side, and
at least one osmotic membrane between the retentate side and the permeate side, and
the method further comprises transporting a purification osmotic module retentate inlet stream to the retentate side of the purification osmotic module, and operating the purification osmotic module to produce a purification osmotic module retentate outlet stream that exits the retentate side of the purification osmotic module, wherein the isolation osmotic module retentate inlet stream comprises at least a portion of the purification osmotic module retentate outlet stream, and wherein the purification osmotic module retentate inlet stream comprises at least a portion of the feed osmotic module permeate outlet stream and/or at least a portion of the isolation osmotic module permeate outlet stream.
5. The method of claim 4 , wherein
at least a portion of the isolation osmotic module permeate outlet stream is transported to the retentate side of the purification osmotic module.
6. The method of claim 4 , wherein
at least a portion of the feed osmotic module permeate outlet stream is transported to the retentate side of the purification osmotic module.
7. The method of claim 6 , wherein
at least a portion of the isolation osmotic module permeate outlet stream is transported to the retentate side of the purification osmotic module.
8. The method of claim 1 , wherein the retentate side of the isolation osmotic module is fluidically connected to the permeate side of the isolation osmotic module, and wherein the method further comprises transferring an isolation osmotic permeate inlet stream to the permeate side of the isolation osmotic module, wherein the isolation osmotic module permeate inlet stream comprises at least a portion of the isolation osmotic module retentate outlet stream.
9. The method of claim 1 , wherein:
the osmotic system further comprises a purification osmotic module comprising:
a retentate side fluidically connected to the retentate side of the isolation osmotic module,
a permeate side, and
at least one osmotic membrane between the retentate side and the permeate side, and
the method further comprises transporting a purification osmotic module retentate inlet stream to the retentate side of the purification osmotic module, and operating the purification osmotic module to produce a purification osmotic module retentate outlet stream that exits the retentate side of the purification osmotic module, wherein the isolation osmotic module retentate inlet stream comprises at least a portion of the purification osmotic module retentate outlet stream, and wherein the purification osmotic module retentate inlet stream comprises at least a portion of the feed osmotic module permeate outlet stream and/or at least a portion of the isolation osmotic module permeate outlet stream.
10. The method of claim 1 , wherein:
the osmotic system further comprises a purification osmotic module comprising:
a retentate side fluidically connected to the permeate side of the feed osmotic module,
a permeate side, and
at least one osmotic membrane between the retentate side and the permeate side, and the method further comprises:
producing a feed osmotic module permeate outlet stream that exits the permeate side of the feed osmotic module,
transporting a purification osmotic module retentate inlet stream to the retentate side of the purification osmotic module, and
operating the purification osmotic module to produce a purification osmotic module retentate outlet stream that exits the retentate side of the purification osmotic module, wherein the purification osmotic module retentate inlet stream comprises at least a portion of the feed osmotic module permeate outlet stream.
11. The method of claim 1 , wherein:
the osmotic system further comprises a purification osmotic module comprising:
a retentate side fluidically connected to the permeate side of the isolation osmotic module,
a permeate side, and
at least one osmotic membrane between the retentate side and the permeate side, and the method further comprises:
producing an isolation osmotic module permeate outlet stream that exits the permeate side of the isolation osmotic module,
transporting a purification osmotic module retentate inlet stream to the retentate side of the purification osmotic module, and
operating the purification osmotic module to produce a purification osmotic module retentate outlet stream that exits the retentate side of the purification osmotic module, wherein the purification osmotic module retentate inlet stream comprises at least a portion of the isolation osmotic module permeate outlet stream.
12. The method of claim 1 , wherein, during the second period of time, less than or equal to 90 wt % of the feed osmotic module retentate outlet stream exiting the retentate side of the feed osmotic module is recycled back to the retentate side of the feed osmotic module.
13. The method of claim 1 , wherein, during the second period of time, none of the feed osmotic module retentate outlet stream exiting the retentate side of the feed osmotic module is recycled back to the retentate side of the feed osmotic module.
14. The method of claim 1 , wherein the feed osmotic module is operated as a reverse osmosis module.
15. The method of claim 1 , wherein:
the osmotic system further comprises a purification osmotic module comprising:
a retentate side fluidically connected to the permeate side of the feed osmotic module and/or the permeate side of the isolation osmotic module,
a permeate side, and
at least one osmotic membrane between the retentate side and the permeate side, and the method further comprises:
transporting a purification osmotic module retentate inlet stream to the retentate side of the purification osmotic module, and
operating the purification osmotic module to produce a purification osmotic module retentate outlet stream that exits the retentate side of the purification osmotic module, wherein the purification osmotic module is operated as a reverse osmosis module, and wherein the purification osmotic module retentate inlet stream comprises at least a portion of the feed osmotic module permeate outlet stream and/or at least a portion of the isolation osmotic module permeate outlet stream.
16. The method of claim 1 , wherein the isolation osmotic module is operated as a reverse osmosis module.
17. The method of claim 1 , wherein the feed osmotic module comprises a plurality of osmotic membranes.
18. The method of claim 1 , wherein the isolation osmotic module comprises a plurality of osmotic membranes.
19. The method of claim 1 , wherein the solute concentration in the feed osmotic module retentate outlet stream is at least 1% higher, on a mass basis, than the concentration of the solute in the feed solution.
20. The method of claim 1 , wherein:
the osmotic system further comprises a purification osmotic module comprising:
a retentate side fluidically connected to the permeate side of the feed osmotic module and/or the permeate side of the isolation osmotic module,
a permeate side, and
at least one osmotic membrane between the retentate side and the permeate side, and the method further comprises:
transporting a purification osmotic module retentate inlet stream to the retentate side of the purification osmotic module, and
operating the purification osmotic module to produce a purification osmotic module retentate outlet stream that exits the retentate side of the purification osmotic module, wherein, during the first period of time, the total amount of osmotic membrane surface area within the retentate side of the feed osmotic module is changed, the total amount of osmotic membrane surface area within the retentate side of the isolation osmotic module is changed, and/or the total amount of osmotic membrane surface area within a retentate side of the purification osmotic module is changed, and wherein the purification osmotic module retentate inlet stream comprises at least a portion of the feed osmotic module permeate outlet stream and/or at least a portion of the isolation osmotic module permeate outlet stream.
21. The method of claim 1 , wherein, during the first period of time, the total amount of osmotic membrane surface area within the retentate side of the feed osmotic module decreases, as a function of time, by at least 5%.
22. The method of claim 1 , wherein, during the first period of time, the total amount of osmotic membrane surface area within the retentate side of the isolation osmotic module increases, as a function of time, by at least 5%.
23. The method of claim 1 , wherein, during the first period of time, the retentate side of the isolation osmotic module receives at least a portion of the isolation osmotic module retentate outlet stream.