IP Library › Granted Patent US 11,637,263
Granted Patent B2
US 11,637,263 · App. 16/758,999 · Granted Apr 25, 2023

Light-emitting element, display device, electronic device, and lighting device each including TADF organic compound

Inventors: Nobuharu Ohsawa (Kanagawa, JP); Satoshi Seo (Kanagawa, JP)
H01L51/5028C09K11/02C09K11/06H01L51/5072C09K2211/1007C09K2211/1044C09K2211/185H01L27/323H01L27/3244H01L51/005H01L51/0052H01L51/0054H01L51/0058H01L51/0061H01L51/0067H01L51/0071H01L51/0072H01L51/0074H01L51/0085H01L51/5044H01L51/5278H01L2251/5376H01L2251/552
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Quick Facts
Patent No.
US 11,637,263
App. No.
16/758,999
Granted
Apr 25, 2023
Kind
B2
Abstract

A light-emitting element having high emission efficiency is provided. The light-emitting element includes a first organic compound, a second organic compound, and a third organic compound. The first organic compound has a function of converting triplet excitation energy into light emission. The second organic compound is preferably a TADF material. The third organic compound is a fluorescent compound. Light emitted from the light-emitting element is obtained from the third organic compound. Triplet excitation energy in a light-emitting layer is transferred to the third organic compound by reverse intersystem crossing caused by the second organic compound or through the first organic compound.

Claims (56)

1. A light-emitting device comprising:

a first electrode;

a light-emitting layer over the first electrode, the light-emitting layer comprising:

a first organic compound configured to convert triplet excitation energy into light emission;

a second organic compound; and

a third organic compound configured to convert singlet excitation energy into light emission; and

a second electrode over the light-emitting layer,

wherein a difference between the lowest singlet excitation energy level of the second organic compound and the lowest triplet excitation energy level of the second organic compound is greater than or equal to 0 eV and less than or equal to 0.2 eV,

wherein light emission from the light-emitting layer comprises light emission from the third organic compound, and

wherein the lowest triplet excitation energy level of the first organic compound is higher than or equal to the lowest triplet excitation energy of the third organic compound.

2. The light-emitting device according to claim 1 , wherein the first organic compound and the second organic compound are capable of forming an exciplex.

3. The light-emitting device according to claim 2 , wherein an emission spectrum of the exciplex comprises a region overlapping with an absorption band on a longest wavelength side in an absorption spectrum of the third organic compound.

4. The light-emitting device according to claim 2 , wherein the exciplex is configured to supply excitation energy to the third organic compound.

5. The light-emitting device according to claim 1 , wherein the first organic compound is configured to supply excitation energy to the third organic compound.

6. The light-emitting device according to claim 1 , wherein the lowest triplet excitation energy level of the first organic compound is higher than or equal to the lowest singlet excitation energy level of the third organic compound.

7. The light-emitting device according to claim 1 , wherein the lowest triplet excitation energy level of the first organic compound is lower than or equal to the lowest triplet excitation energy level of the second organic compound.

8. The light-emitting device according to claim 1 , wherein the first organic compound comprises one of Ru, Rh, Pd, Os, Ir and Pt.

9. The light-emitting device according to claim 1 , wherein the first organic compound is capable of emitting phosphorescence.

10. The light-emitting device according to claim 1 , wherein the first organic compound has an emission quantum yield higher than or equal to 0% and lower than or equal to 40% at room temperature.

11. The light-emitting device according to claim 1 , wherein the third organic compound is capable of emitting fluorescence.

12. A display device comprising:

the light-emitting device according to claim 1 ; and

at least one of a color filter and a transistor.

13. An electronic device comprising:

the display device according to claim 12 ; and

at least one of a housing and a touch sensor.

14. A lighting device comprising:

the light-emitting device according to claim 1 ; and

at least one of a housing and a touch sensor.

15. A light-emitting device comprising:

a first electrode;

a light-emitting layer over the first electrode, the light-emitting layer comprising:

a first organic compound configured to convert triplet excitation energy into light emission;

a second organic compound comprising a 7 c -electron rich skeleton and a 7 C-electron deficient skeleton; and

a third organic compound configured to convert singlet excitation energy into light emission; and

a second electrode over the light-emitting layer,

wherein light emission from the light-emitting layer comprises light emission from the third organic compound, and

wherein the lowest triplet excitation energy level of the first organic compound is higher than or equal to the lowest triplet excitation energy of the third organic compound.

16. The light-emitting device according to claim 15 , wherein the first organic compound and the second organic compound are capable of forming an exciplex.

17. The light-emitting device according to claim 16 , wherein an emission spectrum of the exciplex comprises a region overlapping with an absorption band on a longest wavelength side in an absorption spectrum of the third organic compound.

18. The light-emitting device according to claim 16 , wherein the exciplex is configured to supply excitation energy to the third organic compound.

19. The light-emitting device according to claim 15 , wherein the first organic compound is configured to supply excitation energy to the third organic compound.

20. The light-emitting device according to claim 15 , wherein the 7 c -electron rich skeleton and the 7 c -electron deficient skeleton are directly bonded to each other.

21. The light-emitting device according to claim 15 , wherein the first organic compound comprises one of Ru, Rh, Pd, Os, Ir and Pt.

22. The light-emitting device according to claim 15 , wherein the first organic compound is capable of emitting phosphorescence.

23. The light-emitting device according to claim 15 , wherein the first organic compound has an emission quantum yield higher than or equal to 0% and lower than or equal to 40% at room temperature.

24. The light-emitting device according to claim 15 , wherein the third organic compound is capable of emitting fluorescence.

25. A display device comprising:

the light-emitting device according to claim 15 ; and

at least one of a color filter and a transistor.

26. An electronic device comprising:

the display device according to claim 25 ; and

at least one of a housing and a touch sensor.

27. A lighting device comprising:

the light-emitting device according to claim 15 ; and

at least one of a housing and a touch sensor.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 24, 2020
From: OHSAWA, NOBUHARU; SEO, SATOSHI
To: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
Reel/Frame 052487/0415 →
Priority Claims (1)
JP JP2017-213080 · Nov 2, 2017 · national
Continuity (1)
Related Publication 20200343469A1 · Oct 29, 2020