Method for producing a surface layer on a ceramic matrix composite
A method is provided in which a resin coating is applied to a surface of a preform. The resin coating includes a carbonaceous resin and a particulate. The preform is added to a tooling. The preform, which is positioned in the tooling, is cured. The tooling is removed. The resin coating on the surface of the preform is pyrolyzed to form a resin carbon-char layer on the surface of the preform. The preform and the resin carbon-char layer are infiltrated with silicon to form a ceramic matrix composite (CMC) component including a layer of silicon carbide. During the infiltration, the silicon reacts with carbon in the resin carbon-char layer to form the layer of silicon carbide on the preform.
1. A method comprising:
applying a resin coating comprising a carbonaceous resin and a particulate to a surface of a preform;
controlling a viscosity of the carbonaceous resin, such that the resin coating does not infiltrate the preform;
adding the preform to a tooling;
curing the preform positioned in the tooling;
removing the tooling;
pyrolyzing the resin coating on the surface of the preform to yield a resin carbon-char layer on the surface of the preform; and
infiltrating the preform and the resin carbon-char layer with silicon to form a ceramic matrix composite (CMC) component including a layer of silicon carbide, wherein during the infiltration the silicon reacts with carbon in the resin carbon-char layer to form the layer of silicon carbide on the preform.
2. The method of claim 1 , wherein the viscosity is in a range of 600-1200 cP, inclusively.
3. The method of claim 1 , wherein the particulate comprises silicon carbide.
4. The method of claim 1 , wherein the pyrolyzing and the infiltrating are carried out simultaneously.
5. The method of claim 1 , wherein the layer of silicon carbide has a thickness between 50-250 microns.
6. The method of claim 1 , wherein the carbonaceous resin includes furfuryl alcohol.
7. The method of claim 1 , wherein the carbonaceous resin includes phenol formaldehyde.
8. The method of claim 1 , wherein the infiltrating the preform and the resin carbon-char layer includes melt infiltration.
9. The method of claim 8 , further comprising cooling the CMC component and the layer of silicon carbide after melt infiltration by introducing nitrogen or ammonia.
10. The method of claim 1 , wherein the layer of silicon carbide includes an outer layer of the CMC component comprising at least 90% silicon carbide by volume.
11. The method of claim 1 , wherein the layer of silicon carbide comprises less than 10% unreacted silicon by volume.
12. The method of claim 1 , wherein the CMC component is at least a portion of a component for a gas turbine engine.
13. The method of claim 1 , wherein the applying the resin coating further comprises injecting the resin coating into the tooling after the preform is added to the tooling.
14. A method for forming a silicon carbide-rich outer layer on a CMC component, the method comprising:
applying a resin coating comprising a carbonaceous resin and a particulate to a surface of a preform;
controlling a viscosity of the carbonaceous resin, such that the resin coating does not infiltrate the preform;
adding the preform to a tooling after applying the resin coating to the preform, wherein in the tooling is in a shape of at least a portion of a component of a gas turbine engine;
curing the preform;
removing the tooling;
pyrolyzing the resin coating on the surface of the preform to yield a resin carbon-char layer on the surface of the preform; and
after the pyrolyzing, immersing the preform into a molten material, the molten material being infiltrated into the preform.
15. The method of claim 14 , wherein the molten material includes silicon.
16. The method of claim 15 , wherein the molten material reacts with carbon in the resin carbon-char layer to form an outer layer including silicon carbide.
17. The method of claim 16 , wherein the outer layer includes less than 10% silicon by volume.
18. A CMC component for a gas turbine engine, the CMC component produced by the method of claim 1 comprising:
a CMC body comprising a matrix reinforced with silicon carbide fibers, the matrix comprising silicon carbide; and
an outer layer surrounding the CMC body and defining a periphery of the CMC component, wherein the outer layer, wherein the outer layer includes at least 90% silicon carbide and/or silicon boride by volume,
wherein the CMC component is a blade, a vane, or a casing.
19. The CMC component of claim 18 , wherein the outer layer has less than 2% residual porosity.
20. The CMC component of claim 18 , wherein the outer layer has a thickness between 50 microns and 250 microns.