Organic electroluminescent materials and devices
A compound having the formula: Formula I is disclosed. The compound is useful as emitters in OLEDs.
1. A compound having the formula [L A ] 3-n Ir[L B ] n , having the structure:
wherein R 1 , R 2 , R 3 , R 4 , and R 5 each independently represents mono, to a maximum possible number of substitutions, or no substitution;
wherein X is selected from the group consisting of BR′, NR′, PR′, O, S, Se, C═O, S═O, SO 2 , CR′R″, SiR′R″, and GeR′R″;
wherein R′, R″, R 1 , R 2 , R 3 , R 4 , and R 5 are independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof;
wherein any substitutions are optionally joined or fused into a ring;
wherein n is 1 or 2;
wherein R is selected from the group consisting of alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, partially or fully fluorinated variants thereof, partially or fully deuterated variants thereof, and combination thereof; and
wherein R has at least five carbon atoms.
2. The compound of claim 1 , wherein R has at least six carbon atoms.
3. The compound of claim 1 , wherein R has at least seven carbon atoms.
4. The compound of claim 1 , wherein n is 2.
5. The compound of claim 1 , wherein X is O.
6. The compound of claim 1 , wherein R comprises a cycloalkyl or heterocycloalkyl.
7. The compound of claim 1 , wherein R 1 , R 2 , R 3 , R 4 and R 5 are each independently selected from the group consisting of hydrogen, deuterium, alkyl, cycloalkyl, aryl, and combinations thereof.
8. The compound of claim 1 , wherein R is selected from the group consisting of:
9. The compound of claim 1 , wherein the compound is selected from the group consisting of:
wherein R 6 is selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof.
10. The compound of claim 8 , wherein L A is selected from the group consisting of L A1 to L A371 having a structure according to
in which R, R 1 , R A , R B , R C , R D , and R E are defined as provided below:
L Ai ,
where i is
R 1
R
R A
R B
R C
R D
R E
1.
H
R A1
H
H
H
H
H
2.
H
R A2
H
H
H
H
H
3.
H
R A3
H
H
H
H
H
4.
H
R A4
H
H
H
H
H
5.
H
R A5
H
H
H
H
H
6.
H
R A6
H
H
H
H
H
7.
H
R A7
H
H
H
H
H
8.
H
R A8
H
H
H
H
H
9.
H
R A9
H
H
H
H
H
10.
H
R A10
H
H
H
H
H
11.
H
R A11
H
H
H
H
H
12.
H
R A12
H
H
H
H
H
13.
H
R A13
H
H
H
H
H
14.
H
R A14
H
H
H
H
H
15.
H
R A15
H
H
H
H
H
16.
H
R A16
H
H
H
H
H
17.
H
R A17
H
H
H
H
H
18.
H
R A18
H
H
H
H
H
19.
H
R A19
H
H
H
H
H
20.
H
R A20
H
H
H
H
H
21.
H
R A21
H
H
H
H
H
22.
H
R A22
H
H
H
H
H
23.
H
R A23
H
H
H
H
H
24.
H
R A24
H
H
H
H
H
25.
H
R A25
H
H
H
H
H
26.
H
R A26
H
H
H
H
H
27.
H
R A27
H
H
H
H
H
28.
H
R A28
H
H
H
H
H
29.
H
R A29
H
H
H
H
H
30.
H
R A30
H
H
H
H
H
31.
H
R A31
H
H
H
H
H
32.
H
R A32
H
H
H
H
H
33.
H
R A33
H
H
H
H
H
34.
H
R A34
H
H
H
H
H
35.
H
R A35
H
H
H
H
H
36.
H
R A36
H
H
H
H
H
37.
H
R A37
H
H
H
H
H
38.
H
R A38
H
H
H
H
H
39.
H
R A39
H
H
H
H
H
40.
H
R A40
H
H
H
H
H
41.
H
R A41
H
H
H
H
H
42.
H
R A42
H
H
H
H
H
43.
H
R A43
H
H
H
H
H
44.
H
R A44
H
H
H
H
H
45.
H
R A45
H
H
H
H
H
46.
H
R A46
H
H
H
H
H
47.
H
R A47
H
H
H
H
H
48.
H
R A48
H
H
H
H
H
49.
H
R A49
H
H
H
H
H
50.
H
R A50
H
H
H
H
H
51.
H
R A51
H
H
H
H
H
52.
H
R A52
H
H
H
H
H
53.
H
R A53
H
H
H
H
H
54.
H
R A54
H
H
H
H
H
55.
H
R A55
H
H
H
H
H
56.
H
R A56
H
H
H
H
H
57.
H
R A57
H
H
H
H
H
58.
H
R A58
H
H
H
H
H
59.
H
R A59
H
H
H
H
H
60.
H
R A60
H
H
H
H
H
61.
H
R A61
H
H
H
H
H
62.
H
R A62
H
H
H
H
H
63.
H
R A63
H
H
H
H
H
64.
H
R A64
H
H
H
H
H
65.
H
R A65
H
H
H
H
H
66.
H
R A66
H
H
H
H
H
67.
H
R A67
H
H
H
H
H
68.
H
R A68
H
H
H
H
H
69.
H
R A69
H
H
H
H
H
70.
H
R A70
H
H
H
H
H
71.
H
R A71
H
H
H
H
H
72.
H
R A72
H
H
H
H
H
73.
H
R A73
H
H
H
H
H
74.
H
R A74
H
H
H
H
H
75.
H
R A75
H
H
H
H
H
76.
H
R A76
H
H
H
H
H
77.
H
R A77
H
H
H
H
H
78.
H
R A78
H
H
H
H
H
79.
H
R A79
H
H
H
H
H
80.
H
R A80
H
H
H
H
H
81.
H
R A81
H
H
H
H
H
82.
H
R A82
H
H
H
H
H
83.
H
R A83
H
H
H
H
H
84.
H
R A84
H
H
H
H
H
85.
H
R A85
H
H
H
H
H
86.
H
R A86
H
H
H
H
H
87.
H
R A87
H
H
H
H
H
88.
H
R A88
H
H
H
H
H
89.
H
R A89
H
H
H
H
H
90.
H
R A90
H
H
H
H
H
91.
H
R A91
H
H
H
H
H
92.
H
R A92
H
H
H
H
H
93.
H
R A93
H
H
H
H
H
94.
CD 3
R A1
H
H
H
H
H
95.
CD 3
R A2
H
H
H
H
H
96.
CD 3
R A3
H
H
H
H
H
97.
CD 3
R A4
H
H
H
H
H
98.
CD 3
R A5
H
H
H
H
H
99.
CD 3
R A6
H
H
H
H
H
100.
CD 3
R A7
H
H
H
H
H
101.
CD 3
R A8
H
H
H
H
H
102.
CD 3
R A9
H
H
H
H
H
103.
CD 3
R A10
H
H
H
H
H
104.
CD 3
R A11
H
H
H
H
H
105.
CD 3
R A12
H
H
H
H
H
106.
CD 3
R A13
H
H
H
H
H
107.
CD 3
R A14
H
H
H
H
H
108.
CD 3
R A15
H
H
H
H
H
109.
CD 3
R A16
H
H
H
H
H
110.
CD 3
R A17
H
H
H
H
H
111.
CD 3
R A18
H
H
H
H
H
112.
CD 3
R A19
H
H
H
H
H
113.
CD 3
R A20
H
H
H
H
H
114.
CD 3
R A21
H
H
H
H
H
115.
CD 3
R A22
H
H
H
H
H
116.
CD 3
R A23
H
H
H
H
H
117.
CD 3
R A24
H
H
H
H
H
118.
CD 3
R A25
H
H
H
H
H
119.
CD 3
R A26
H
H
H
H
H
120.
CD 3
R A27
H
H
H
H
H
121.
CD 3
R A28
H
H
H
H
H
122.
CD 3
R A29
H
H
H
H
H
123.
CD 3
R A30
H
H
H
H
H
124.
CD 3
R A31
H
H
H
H
H
125.
CD 3
R A32
H
H
H
H
H
126.
CD 3
R A33
H
H
H
H
H
127.
CD 3
R A34
H
H
H
H
H
128.
CD 3
R A35
H
H
H
H
H
129.
CD 3
R A36
H
H
H
H
H
130.
CD 3
R A37
H
H
H
H
H
131.
CD 3
R A38
H
H
H
H
H
132.
CD 3
R A39
H
H
H
H
H
133.
CD 3
R A40
H
H
H
H
H
134.
CD 3
R A41
H
H
H
H
H
135.
CD 3
R A42
H
H
H
H
H
136.
CD 3
R A43
H
H
H
H
H
137.
CD 3
R A44
H
H
H
H
H
138.
CD 3
R A45
H
H
H
H
H
139.
CD 3
R A46
H
H
H
H
H
140.
CD 3
R A47
H
H
H
H
H
141.
CD 3
R A48
H
H
H
H
H
142.
CD 3
R A49
H
H
H
H
H
143.
CD 3
R A50
H
H
H
H
H
144.
CD 3
R A51
H
H
H
H
H
145.
CD 3
R A52
H
H
H
H
H
146.
CD 3
R A53
H
H
H
H
H
147.
CD 3
R A54
H
H
H
H
H
148.
CD 3
R A55
H
H
H
H
H
149.
CD 3
R A56
H
H
H
H
H
150.
CD 3
R A57
H
H
H
H
H
151.
CD 3
R A58
H
H
H
H
H
152.
CD 3
R A59
H
H
H
H
H
153.
CD 3
R A60
H
H
H
H
H
154.
CD 3
R A61
H
H
H
H
H
155.
CD 3
R A62
H
H
H
H
H
156.
CD 3
R A63
H
H
H
H
H
157.
CD 3
R A64
H
H
H
H
H
158.
CD 3
R A65
H
H
H
H
H
159.
CD 3
R A66
H
H
H
H
H
160.
CD 3
R A67
H
H
H
H
H
161.
CD 3
R A68
H
H
H
H
H
162.
CD 3
R A69
H
H
H
H
H
163.
CD 3
R A70
H
H
H
H
H
164.
CD 3
R A71
H
H
H
H
H
165.
CD 3
R A72
H
H
H
H
H
166.
CD 3
R A73
H
H
H
H
H
167.
CD 3
R A74
H
H
H
H
H
168.
CD 3
R A75
H
H
H
H
H
169.
CD 3
R A76
H
H
H
H
H
170.
CD 3
R A77
H
H
H
H
H
171.
CD 3
R A78
H
H
H
H
H
172.
CD 3
R A79
H
H
H
H
H
173.
CD 3
R A80
H
H
H
H
H
174.
CD 3
R A81
H
H
H
H
H
175.
CD 3
R A82
H
H
H
H
H
176.
CD 3
R A83
H
H
H
H
H
177.
CD 3
R A84
H
H
H
H
H
178.
CD 3
R A85
H
H
H
H
H
179.
CD 3
R A86
H
H
H
H
H
180.
CD 3
R A87
H
H
H
H
H
181.
CD 3
R A88
H
H
H
H
H
182.
CD 3
R A89
H
H
H
H
H
183.
CD 3
R A90
H
H
H
H
H
184.
CD 3
R A91
H
H
H
H
H
185.
CD 3
R A92
H
H
H
H
H
186.
CD 3
R A93
H
H
H
H
H
187.
H
R A1
H
CD 3
H
H
H
188.
H
R A2
H
CD 3
H
H
H
189.
H
R A3
H
CD 3
H
H
H
190.
H
R A4
H
CD 3
H
H
H
191.
H
R A5
H
CD 3
H
H
H
192.
H
R A6
H
CD 3
H
H
H
193.
H
R A7
H
CD 3
H
H
H
194.
H
R A8
H
CD 3
H
H
H
195.
H
R A10
H
CD 3
H
H
H
196.
H
R A11
H
CD 3
H
H
H
197.
H
R A12
H
CD 3
H
H
H
198.
H
R A13
H
CD 3
H
H
H
199.
H
R A14
H
CD 3
H
H
H
200.
H
R A15
H
CD 3
H
H
H
201.
H
R A16
H
CD 3
H
H
H
202.
H
R A17
H
CD 3
H
H
H
203.
H
R A18
H
CD 3
H
H
H
204.
H
R A19
H
CD 3
H
H
H
205.
H
R A20
H
CD 3
H
H
H
206.
H
R A21
H
CD 3
H
H
H
207.
H
R A22
H
CD 3
H
H
H
208.
H
R A23
H
CD 3
H
H
H
209.
H
R A24
H
CD 3
H
H
H
210.
H
R A25
H
CD 3
H
H
H
211.
H
R A26
H
CD 3
H
H
H
212.
H
R A27
H
CD 3
H
H
H
213.
H
R A28
H
CD 3
H
H
H
214.
H
R A29
H
CD 3
H
H
H
215.
H
R A30
H
CD 3
H
H
H
216.
H
R A31
H
CD 3
H
H
H
217.
H
R A32
H
CD 3
H
H
H
218.
H
R A33
H
CD 3
H
H
H
219.
H
R A34
H
CD 3
H
H
H
220.
H
R A35
H
CD 3
H
H
H
221.
H
R A36
H
CD 3
H
H
H
222.
H
R A37
H
CD 3
H
H
H
223.
H
R A38
H
CD 3
H
H
H
224.
H
R A39
H
CD 3
H
H
H
225.
H
R A40
H
CD 3
H
H
H
226.
H
R A41
H
CD 3
H
H
H
227.
H
R A42
H
CD 3
H
H
H
228.
H
R A43
H
CD 3
H
H
H
229.
H
R A44
H
CD 3
H
H
H
230.
H
R A45
H
CD 3
H
H
H
231.
H
R A46
H
CD 3
H
H
H
232.
H
R A47
H
CD 3
H
H
H
233.
H
R A48
H
CD 3
H
H
H
234.
H
R A49
H
CD 3
H
H
H
235.
H
R A50
H
CD 3
H
H
H
236.
H
R A51
H
CD 3
H
H
H
237.
H
R A52
H
CD 3
H
H
H
238.
H
R A53
H
CD 3
H
H
H
239.
H
R A54
H
CD 3
H
H
H
240.
H
R A55
H
CD 3
H
H
H
241.
H
R A56
H
CD 3
H
H
H
242.
H
R A57
H
CD 3
H
H
H
243.
H
R A58
H
CD 3
H
H
H
244.
H
R A59
H
CD 3
H
H
H
245.
H
R A60
H
CD 3
H
H
H
246.
H
R A61
H
CD 3
H
H
H
247.
H
R A62
H
CD 3
H
H
H
248.
H
R A63
H
CD 3
H
H
H
249.
H
R A64
H
CD 3
H
H
H
250.
H
R A65
H
CD 3
H
H
H
251.
H
R A66
H
CD 3
H
H
H
252.
H
R A67
H
CD 3
H
H
H
253.
H
R A68
H
CD 3
H
H
H
254.
H
R A69
H
CD 3
H
H
H
255.
H
R A70
H
CD 3
H
H
H
256.
H
R A71
H
CD 3
H
H
H
257.
H
R A72
H
CD 3
H
H
H
258.
H
R A73
H
CD 3
H
H
H
259.
H
R A74
H
CD 3
H
H
H
260.
H
R A75
H
CD 3
H
H
H
261.
H
R A76
H
CD 3
H
H
H
262.
H
R A77
H
CD 3
H
H
H
263.
H
R A78
H
CD 3
H
H
H
264.
H
R A79
H
CD 3
H
H
H
265.
H
R A80
H
CD 3
H
H
H
266.
H
R A81
H
CD 3
H
H
H
267.
H
R A82
H
CD 3
H
H
H
268.
H
R A83
H
CD 3
H
H
H
269.
H
R A84
H
CD 3
H
H
H
270.
H
R A85
H
CD 3
H
H
H
271.
H
R A86
H
CD 3
H
H
H
272.
H
R A87
H
CD 3
H
H
H
273.
H
R A88
H
CD 3
H
H
H
274.
H
R A89
H
CD 3
H
H
H
275.
H
R A90
H
CD 3
H
H
H
276.
H
R A91
H
CD 3
H
H
H
277.
H
R A92
H
CD 3
H
H
H
278.
H
R A93
H
CD 3
H
H
H
279.
CD 3
R A1
H
CD 3
H
H
H
280.
CD 3
R A2
H
CD 3
H
H
H
281.
CD 3
R A3
H
CD 3
H
H
H
282.
CD 3
R A4
H
CD 3
H
H
H
283.
CD 3
R A5
H
CD 3
H
H
H
284.
CD 3
R A6
H
CD 3
H
H
H
285.
CD 3
R A7
H
CD 3
H
H
H
286.
CD 3
R A8
H
CD 3
H
H
H
287.
CD 3
R A9
H
CD 3
H
H
H
288.
CD 3
R A10
H
CD 3
H
H
H
289.
CD 3
R A11
H
CD 3
H
H
H
290.
CD 3
R A12
H
CD 3
H
H
H
291.
CD 3
R A13
H
CD 3
H
H
H
292.
CD 3
R A14
H
CD 3
H
H
H
293.
CD 3
R A15
H
CD 3
H
H
H
294.
CD 3
R A16
H
CD 3
H
H
H
295.
CD 3
R A17
H
CD 3
H
H
H
296.
CD 3
R A18
H
CD 3
H
H
H
297.
CD 3
R A19
H
CD 3
H
H
H
298.
CD 3
R A20
H
CD 3
H
H
H
299.
CD 3
R A21
H
CD 3
H
H
H
300.
CD 3
R A22
H
CD 3
H
H
H
301.
CD 3
R A23
H
CD 3
H
H
H
302.
CD 3
R A24
H
CD 3
H
H
H
303.
CD 3
R A25
H
CD 3
H
H
H
304.
CD 3
R A26
H
CD 3
H
H
H
305.
CD 3
R A27
H
CD 3
H
H
H
306.
CD 3
R A28
H
CD 3
H
H
H
307.
CD 3
R A29
H
CD 3
H
H
H
308.
CD 3
R A30
H
CD 3
H
H
H
309.
CD 3
R A31
H
CD 3
H
H
H
310.
CD 3
R A32
H
CD 3
H
H
H
311.
CD 3
R A33
H
CD 3
H
H
H
312.
CD 3
R A34
H
CD 3
H
H
H
313.
CD 3
R A35
H
CD 3
H
H
H
314.
CD 3
R A36
H
CD 3
H
H
H
315.
CD 3
R A37
H
CD 3
H
H
H
316.
CD 3
R A38
H
CD 3
H
H
H
317.
CD 3
R A39
H
CD 3
H
H
H
318.
CD 3
R A40
H
CD 3
H
H
H
319.
CD 3
R A41
H
CD 3
H
H
H
320.
CD 3
R A42
H
CD 3
H
H
H
321.
CD 3
R A43
H
CD 3
H
H
H
322.
CD 3
R A44
H
CD 3
H
H
H
323.
CD 3
R A45
H
CD 3
H
H
H
324.
CD 3
R A46
H
CD 3
H
H
H
325.
CD 3
R A47
H
CD 3
H
H
H
326.
CD 3
R A48
H
CD 3
H
H
H
327.
CD 3
R A49
H
CD 3
H
H
H
328.
CD 3
R A50
H
CD 3
H
H
H
329.
CD 3
R A51
H
CD 3
H
H
H
330.
CD 3
R A52
H
CD 3
H
H
H
331.
CD 3
R A53
H
CD 3
H
H
H
332.
CD 3
R A54
H
CD 3
H
H
H
333.
CD 3
R A55
H
CD 3
H
H
H
334.
CD 3
R A56
H
CD 3
H
H
H
335.
CD 3
R A57
H
CD 3
H
H
H
336.
CD 3
R A58
H
CD 3
H
H
H
337.
CD 3
R A59
H
CD 3
H
H
H
338.
CD 3
R A60
H
CD 3
H
H
H
339.
CD 3
R A61
H
CD 3
H
H
H
340.
CD 3
R A62
H
CD 3
H
H
H
341.
CD 3
R A63
H
CD 3
H
H
H
342.
CD 3
R A64
H
CD 3
H
H
H
343.
CD 3
R A65
H
CD 3
H
H
H
344.
CD 3
R A66
H
CD 3
H
H
H
345.
CD 3
R A67
H
CD 3
H
H
H
346.
CD 3
R A68
H
CD 3
H
H
H
347.
CD 3
R A69
H
CD 3
H
H
H
348.
CD 3
R A70
H
CD 3
H
H
H
349.
CD 3
R A71
H
CD 3
H
H
H
350.
CD 3
R A72
H
CD 3
H
H
H
351.
CD 3
R A73
H
CD 3
H
H
H
352.
CD 3
R A74
H
CD 3
H
H
H
353.
CD 3
R A75
H
CD 3
H
H
H
354.
CD 3
R A76
H
CD 3
H
H
H
355.
CD 3
R A77
H
CD 3
H
H
H
356.
CD 3
R A78
H
CD 3
H
H
H
357.
CD 3
R A79
H
CD 3
H
H
H
358.
CD 3
R A80
H
CD 3
H
H
H
359.
CD 3
R A81
H
CD 3
H
H
H
360.
CD 3
R A82
H
CD 3
H
H
H
361.
CD 3
R A83
H
CD 3
H
H
H
362.
CD 3
R A84
H
CD 3
H
H
H
363.
CD 3
R A85
H
CD 3
H
H
H
364.
CD 3
R A86
H
CD 3
H
H
H
365.
CD 3
R A87
H
CD 3
H
H
H
366.
CD 3
R A88
H
CD 3
H
H
H
367.
CD 3
R A89
H
CD 3
H
H
H
368.
CD 3
R A90
H
CD 3
H
H
H
369.
CD 3
R A91
H
CD 3
H
H
H
370.
CD 3
R A92
H
CD 3
H
H
H
371.
CD 3
R A93
H
CD 3
H
H
H.
11. The compound of claim 1 , wherein L B is selected from the group consisting of L B1 to L B1471 having a structure according to
wherein R B1 , R B2 , R B3 , and R B4 are defined as provided below:
L Bi , where i is
R B1
R B2
R B3
R B4
1.
H
H
H
H
2.
CH 3
H
H
H
3.
H
CH 3
H
H
4.
H
H
CH 3
H
5.
CH 3
CH 3
H
CH 3
6.
CH 3
H
CH 3
H
7.
CH 3
H
H
CH 3
8.
H
CH 3
CH 3
H
9.
H
CH 3
H
CH 3
10.
H
H
CH 3
CH 3
11.
CH 3
CH 3
CH 3
H
12.
CH 3
CH 3
H
CH 3
13.
CH 3
H
CH 3
CH 3
14.
H
CH 3
CH 3
CH 3
15.
CH 3
CH 3
CH 3
CH 3
16.
CH 2 CH 3
H
H
H
17.
CH 2 CH 3
CH 3
H
CH 3
18.
CH 2 CH 3
H
CH 3
H
19.
CH 2 CH 3
H
H
CH 3
20.
CH 2 CH 3
CH 3
CH 3
H
21.
CH 2 CH 3
CH 3
H
CH 3
22.
CH 2 CH 3
H
CH 3
CH 3
23.
CH 2 CH 3
CH 3
CH 3
CH 3
24.
H
CH 2 CH 3
H
H
25.
CH 3
CH 2 CH 3
H
CH 3
26.
H
CH 2 CH 3
CH 3
H
27.
H
CH 2 CH 3
H
CH 3
28.
CH 3
CH 2 CH 3
CH 3
H
29.
CH 3
CH 2 CH 3
H
CH 3
30.
H
CH 2 CH 3
CH 3
CH 3
31.
CH 3
CH 2 CH 3
CH 3
CH 3
32.
H
H
CH 2 CH 3
H
33.
CH 3
H
CH 2 CH 3
H
34.
H
CH 3
CH 2 CH 3
H
35.
H
H
CH 2 CH 3
CH 3
36.
CH 3
CH 3
CH 2 CH 3
H
37.
CH 3
H
CH 2 CH 3
CH 3
38.
H
CH 3
CH 2 CH 3
CH 3
39.
CH 3
CH 3
CH 2 CH 3
CH 3
40.
CH(CH 3 ) 2
H
H
H
41.
CH(CH 3 ) 2
CH 3
H
CH 3
42.
CH(CH 3 ) 2
H
CH 3
H
43.
CH(CH 3 ) 2
H
H
CH 3
44.
CH(CH 3 ) 2
CH 3
CH 3
H
45.
CH(CH 3 ) 2
CH 3
H
CH 3
46.
CH(CH 3 ) 2
H
CH 3
CH 3
47.
CH(CH 3 ) 2
CH 3
CH 3
CH 3
48.
H
CH(CH 3 ) 2
H
H
49.
CH 3
CH(CH 3 ) 2
H
CH 3
50.
H
CH(CH 3 ) 2
CH 3
H
51.
H
CH(CH 3 ) 2
H
CH 3
52.
CH 3
CH(CH 3 ) 2
CH 3
H
53.
CH 3
CH(CH 3 ) 2
H
CH 3
54.
H
CH(CH 3 ) 2
CH 3
CH 3
55.
CH 3
CH(CH 3 ) 2
CH 3
CH 3
56.
H
H
CH(CH 3 ) 2
H
57.
CH 3
H
CH(CH 3 ) 2
H
58.
H
CH 3
CH(CH 3 ) 2
H
59.
H
H
CH(CH 3 ) 2
CH 3
60.
CH 3
CH 3
CH(CH 3 ) 2
H
61.
CH 3
H
CH(CH 3 ) 2
CH 3
62.
H
CH 3
CH(CH 3 ) 2
CH 3
63.
CH 3
CH 3
CH(CH 3 ) 2
CH 3
64.
CH 2 CH(CH 3 ) 2
H
H
H
65.
CH 2 CH(CH 3 ) 2
CH 3
H
CH 3
66.
CH 2 CH(CH 3 ) 2
H
CH 3
H
67.
CH 2 CH(CH 3 ) 2
H
H
CH 3
68.
CH 2 CH(CH 3 ) 2
CH 3
CH 3
H
69.
CH 2 CH(CH 3 ) 2
CH 3
H
CH 3
70.
CH 2 CH(CH 3 ) 2
H
CH 3
CH 3
71.
CH 2 CH(CH 3 ) 2
CH 3
CH 3
CH 3
72.
H
CH 2 CH(CH 3 ) 2
H
H
73.
CH 3
CH 2 CH(CH 3 ) 2
H
CH 3
74.
H
CH 2 CH(CH 3 ) 2
CH 3
H
75.
H
CH 2 CH(CH 3 ) 2
H
CH 3
76.
CH 3
CH 2 CH(CH 3 ) 2
CH 3
H
77.
CH 3
CH 2 CH(CH 3 ) 2
H
CH 3
78.
H
CH 2 CH(CH 3 ) 2
CH 3
CH 3
79.
CH 3
CH 2 CH(CH 3 ) 2
CH 3
CH 3
80.
H
H
CH 2 CH(CH 3 ) 2
H
81.
CH 3
H
CH 2 CH(CH 3 ) 2
H
82.
H
CH 3
CH 2 CH(CH 3 ) 2
H
83.
H
H
CH 2 CH(CH 3 ) 2
CH 3
84.
CH 3
CH 3
CH 2 CH(CH 3 ) 2
H
85.
CH 3
H
CH 2 CH(CH 3 ) 2
CH 3
86.
H
CH 3
CH 2 CH(CH 3 ) 2
CH 3
87.
CH 3
CH 3
CH 2 CH(CH 3 ) 2
CH 3
88.
C(CH 3 ) 3
H
H
H
89.
C(CH 3 ) 3
CH 3
H
CH 3
90.
C(CH 3 ) 3
H
CH 3
H
91.
C(CH 3 ) 3
H
H
C(CH 3 ) 3
92.
C(CH 3 ) 3
CH 3
CH 3
H
93.
C(CH 3 ) 3
CH 3
H
CH 3
94.
C(CH 3 ) 3
H
CH 3
CH 3
95.
C(CH 3 ) 3
CH 3
CH 3
CH 3
96.
H
C(CH 3 ) 3
H
H
97.
CH 3
C(CH 3 ) 3
H
CH 3
98.
H
C(CH 3 ) 3
CH 3
H
99.
H
C(CH 3 ) 3
H
CH 3
100.
CH 3
C(CH 3 ) 3
CH 3
H
101.
CH 3
C(CH 3 ) 3
H
CH 3
102.
H
C(CH 3 ) 3
CH 3
CH 3
103.
CH 3
C(CH 3 ) 3
CH 3
CH 3
104.
H
H
C(CH 3 ) 3
H
105.
CH 3
H
C(CH 3 ) 3
H
106.
H
CH 3
C(CH 3 ) 3
H
107.
H
H
C(CH 3 ) 3
CH 3
108.
CH 3
CH 3
C(CH 3 ) 3
H
109.
CH 3
H
C(CH 3 ) 3
CH 3
110.
H
CH 3
C(CH 3 ) 3
CH 3
111.
CH 3
CH 3
C(CH 3 ) 3
CH 3
112.
CH 2 (CH 3 ) 3
H
H
H
113.
CH 2 (CH 3 ) 3
CH 3
H
CH 3
114.
CH 2 (CH 3 ) 3
H
CH 3
H
115.
CH 2 (CH 3 ) 3
H
H
CH 3
116.
CH 2 (CH 3 ) 3
CH 3
CH 3
H
117.
CH 2 (CH 3 ) 3
CH 3
H
CH 3
118.
CH 2 (CH 3 ) 3
H
CH 3
CH 3
119.
CH 2 (CH 3 ) 3
CH 3
CH 3
CH 3
120.
H
CH 2 (CH 3 ) 3
H
H
121.
CH 3
CH 2 (CH 3 ) 3
H
CH 3
122.
H
CH 2 (CH 3 ) 3
CH 3
H
123.
H
CH 2 (CH 3 ) 3
H
CH 3
124.
CH 3
CH 2 (CH 3 ) 3
CH 3
H
125.
CH 3
CH 2 (CH 3 ) 3
H
CH 3
126.
H
CH 2 (CH 3 ) 3
CH 3
CH 3
127.
CH 3
CH 2 (CH 3 ) 3
CH 3
CH 3
128.
H
H
CH 2 (CH 3 ) 3
H
129.
CH 3
H
CH 2 (CH 3 ) 3
H
130.
H
CH 3
CH 2 (CH 3 ) 3
H
131.
H
H
CH 2 (CH 3 ) 3
CH 3
132.
CH 3
CH 3
CH 2 (CH 3 ) 3
H
133.
CH 3
H
CH 2 (CH 3 ) 3
CH 3
134.
H
CH 3
CH 2 (CH 3 ) 3
CH 3
135.
CH 3
CH 3
CH 2 (CH 3 ) 3
CH 3
136.
H
H
H
137.
CH 3
H
CH 3
138.
H
CH 3
H
139.
H
H
CH 3
140.
CH 3
CH 3
H
141.
CH 3
H
CH 3
142.
H
CH 3
CH 3
143.
CH 3
CH 3
CH 3
144.
H
H
H
145.
CH 3
H
CH 3
146.
H
CH 3
H
147.
H
H
CH 3
148.
CH 3
CH 3
H
149.
CH 3
H
CH 3
150.
H
CH 3
CH 3
151.
CH 3
CH 3
CH 3
152.
H
H
H
153.
CH 3
H
H
154.
H
CH 3
H
155.
H
H
CH 3
156.
CH 3
CH 3
H
157.
CH 3
H
CH 3
158.
H
CH 3
CH 3
159.
CH 3
CH 3
CH 3
160.
H
H
H
161.
H
CH 3
H
162.
H
CH 3
H
163.
H
H
CH 3
164.
CH 3
CH 3
H
165.
CH 3
H
CH 3
166.
H
CH 3
CH 3
167.
CH 3
CH 3
CH 3
168.
H
H
H
169.
CH 3
H
CH 3
170.
H
CH 3
H
171.
H
H
CH 3
172.
CH 3
CH 3
H
173.
CH 3
H
CH 3
174.
H
CH 3
CH 3
175.
CH 3
CH 3
CH 3
176.
H
H
H
177.
CH 3
H
H
178.
H
CH 3
H
179.
H
H
CH 3
180.
CH 3
CH 3
H
181.
CH 3
H
CH 3
182.
H
CH 3
CH 3
183.
CH 3
CH 3
CH 3
184.
H
H
H
185.
CH 3
H
CH 3
186.
H
CH 3
H
187.
H
H
CH 3
188.
CH 3
CH 3
H
189.
CH 3
H
CH 3
190.
H
CH 3
CH 3
191.
CH 3
CH 3
CH 3
192.
H
H
H
193.
CH 3
H
CH 3
194.
H
CH 3
H
195.
H
H
CH 3
196.
CH 3
CH 3
H
197.
CH 3
H
CH 3
198.
H
CH 3
CH 3
199.
CH 3
CH 3
CH 3
200.
H
H
H
201.
CH 3
H
H
202.
H
CH 3
H
203.
H
H
CH 3
204.
CH 3
CH 3
H
205.
CH 3
H
CH 3
206.
H
CH 3
CH 3
207.
CH 3
CH 3
CH 3
208.
H
H
H
209.
CH 3
H
CH 3
210.
H
CH 3
H
211.
H
H
CH 3
212.
CH 3
CH 3
H
213.
CH 3
H
CH 3
214.
H
CH 3
CH 3
215.
CH 3
CH 3
CH 3
216.
H
H
H
217.
CH 3
H
CH 3
218.
H
CH 3
H
219.
H
H
CH 3
220.
CH 3
CH 3
H
221.
CH 3
H
CH 3
222.
H
CH 3
CH 3
223.
CH 3
CH 3
CH 3
224.
H
H
H
225.
CH 3
H
H
226.
H
CH 3
H
227.
H
H
CH 3
228.
CH 3
CH 3
H
229.
CH 3
H
CH 3
230.
H
CH 3
CH 3
231.
CH 3
CH 3
CH 3
232.
H
H
H
233.
CH 3
H
CH 3
234.
H
CH 3
H
235.
H
H
CH 3
236.
CH 3
CH 3
H
237.
CH 3
H
CH 3
238.
H
CH 3
CH 3
239.
CH 3
CH 3
CH 3
240.
H
H
H
241.
CH 3
H
CH 3
242.
H
CH 3
H
243.
H
H
CH 3
244.
CH 3
CH 3
H
245.
CH 3
H
CH 3
246.
H
CH 3
CH 3
247.
CH 3
CH 3
CH 3
248.
H
H
H
249.
CH 3
H
H
250.
H
CH 3
H
251.
H
H
CH 3
252.
CH 3
CH 3
H
253.
CH 3
H
CH 3
254.
H
CH 3
CH 3
255.
CH 3
CH 3
CH 3
256.
H
H
H
257.
CH 3
H
CH 3
258.
H
CH 3
H
259.
H
H
CH 3
260.
CH 3
CH 3
H
261.
CH 3
H
CH 3
262.
H
CH 3
CH 3
263.
CH 3
CH 3
CH 3
264.
H
H
H
265.
CH 3
H
CH 3
266.
H
CH 3
H
267.
H
H
CH 3
268.
CH 3
CH 3
H
269.
CH 3
H
CH 3
270.
H
CH 3
CH 3
271.
CH 3
CH 3
CH 3
272.
H
H
H
273.
CH 3
H
H
274.
H
CH 3
H
275.
H
H
CH 3
276.
CH 3
CH 3
H
277.
CH 3
H
CH 3
278.
H
CH 3
CH 3
279.
CH 3
CH 3
CH 3
280.
CH(CH 3 ) 2
H
CH 2 CH 3
H
281.
CH(CH 3 ) 2
H
CH(CH 3 ) 2
H
282.
CH(CH 3 ) 2
H
CH 2 CH(CH 3 ) 2
H
283.
CH(CH 3 ) 2
H
C(CH 3 ) 3
H
284.
CH(CH 3 ) 2
H
CH 2 C(CH 3 ) 2
H
285.
CH(CH 3 ) 2
H
H
286.
CH(CH 3 ) 2
H
H
287.
CH(CH 3 ) 2
H
H
288.
CH(CH 3 ) 2
H
H
289.
CH(CH 3 ) 2
H
H
290.
CH(CH 3 ) 2
H
H
291.
C(CH 3 ) 3
H
CH 2 CH 3
H
292.
C(CH 3 ) 3
H
CH(CH 3 ) 2
H
293.
C(CH 3 ) 3
H
CH 2 CH(CH 3 ) 2
H
294.
C(CH 3 ) 3
H
C(CH 3 ) 3
H
295.
C(CH 3 ) 3
H
CH 2 C(CH 3 ) 3
H
296.
C(CH 3 ) 3
H
H
297.
C(CH 3 ) 3
H
H
298.
C(CH 3 ) 3
H
H
299.
C(CH 3 ) 3
H
H
300.
C(CH 3 ) 3
H
H
301.
C(CH 3 ) 3
H
H
302.
CH 2 C(CH 3 ) 3
H
CH 2 CH 3
H
303.
CH 2 C(CH 3 ) 3
H
CH(CH 3 ) 2
H
304.
CH 2 C(CH 3 ) 3
H
CH 2 CH(CH 3 ) 2
H
305.
CH 2 C(CH 3 ) 3
H
C(CH 3 ) 3
H
306.
CH 2 C(CH 3 ) 3
H
CH 2 C(CH 3 ) 3
H
307.
CH 2 C(CH 3 ) 3
H
H
308.
CH 2 C(CH 3 ) 3
H
H
309.
CH 2 C(CH 3 ) 3
H
H
310.
CH 2 C(CH 3 ) 3
H
H
311.
CH 2 C(CH 3 ) 3
H
H
312.
CH 2 C(CH 3 ) 3
H
H
313.
H
CH 2 CH 3
H
314.
H
CH(CH 3 ) 2
H
315.
H
CH 2 CH(CH 3 ) 2
H
316.
H
C(CH 3 ) 3
H
317.
H
CH 2 C(CH 3 ) 3
H
318.
H
H
319.
H
H
320.
H
H
321.
H
H
322.
H
H
323.
H
H
324.
H
CH 2 CH 3
H
325.
H
CH(CH 3 ) 2
H
326.
H
CH 2 CH(CH 3 ) 2
H
327.
H
C(CH 3 ) 3
H
328.
H
CH 2 C(CH 3 ) 3
H
329.
H
H
330.
H
H
331.
H
H
332.
H
H
333.
H
H
334.
H
H
335.
H
CH 2 CH(CH 3 ) 2
H
336.
H
C(CH 3 ) 3
H
337.
H
CH 2 C(CH 3 ) 3
H
338.
H
CH 2 CH 2 CF 3
H
339.
H
CH 2 C(CH 3 ) 2 CF 3
H
340.
H
H
341.
H
H
342.
H
H
343.
H
H
344.
H
H
345.
H
H
346.
H
CH 2 CH(CH 3 ) 2
H
347.
H
C(CH 3 ) 3
H
348.
H
CH 2 C(CH 3 ) 3
H
349.
H
H
350.
H
H
351.
H
H
352.
H
H
353.
H
H
354.
H
H
355.
H
CH 2 CH(CH 3 ) 2
H
356.
H
C(CH 3 ) 3
H
357.
H
CH 2 C(CH 3 ) 3
H
358.
H
H
359.
H
H
360.
H
H
361.
H
H
362.
H
H
363.
H
H
364.
H
H
H
H
365.
CD 3
H
H
H
366.
H
CD 3
H
H
367.
H
H
CD 3
H
368.
CD 3
CD 3
H
CD 3
369.
CD 3
H
CD 3
H
370.
CD 3
H
H
CD 3
371.
H
CD 3
CH 3
H
372.
H
CD 3
H
CD 3
373.
H
H
CD 3
CD 3
374.
CD 3
CD 3
CD 3
H
375.
CD 3
CD 3
H
CD 3
376.
CD 3
H
CD 3
CD 3
377.
H
CD 3
CD 3
CD 3
378.
CD 3
CD 3
CD 3
CD 3
379.
CD 2 CH 3
H
H
H
380.
CD 2 CH 3
CD 3
H
CD 3
381.
CD 2 CH 3
H
CD 3
H
382.
CD 2 CH 3
H
H
CD 3
383.
CD 2 CH 3
CD 3
CD 3
H
384.
CD 2 CH 3
CD 3
H
CD 3
385.
CD 2 CH 3
H
CD 3
CD 3
386.
CD 2 CH 3
CD 3
CD 3
CD 3
387.
H
CD 2 CH 3
H
H
388.
CH 3
CD 2 CH 3
H
CD 3
389.
H
CD 2 CH 3
CD 3
H
390.
H
CD 2 CH 3
H
CD 3
391.
CD 3
CD 2 CH 3
CD 3
H
392.
CD 3
CD 2 CH 3
H
CD 3
393.
H
CD 2 CH 3
CD 3
CD 3
394.
CD 3
CD 2 CH 3
CD 3
CD 3
395.
H
H
CD 2 CH 3
H
396.
CD 3
H
CD 2 CH 3
H
397.
H
CD 3
CD 2 CH 3
H
398.
H
H
CD 2 CH 3
CD 3
399.
CD 3
CD 3
CD 2 CH 3
H
400.
CD 3
H
CD 2 CH 3
CD 3
401.
H
CD 3
CD 2 CH 3
CD 3
402.
CD 3
CD 3
CD 2 CH 3
CD 3
403.
CD(CH 3 ) 2
H
H
H
404.
CD(CH 3 ) 2
CD 3
H
CD 3
405.
CD(CH 3 ) 2
H
CD 3
H
406.
CD(CH 3 ) 2
H
H
CD 3
407.
CD(CH 3 ) 2
CD 3
CD 3
H
408.
CD(CH 3 ) 2
CD 3
H
CD 3
409.
CD(CH 3 ) 2
H
CD 3
CD 3
410.
CD(CH 3 ) 2
CD 3
CD 3
CD 3
411.
H
CD(CH 3 ) 2
H
H
412.
CD 3
CD(CH 3 ) 2
H
CD 3
413.
H
CD(CH 3 ) 2
CD 3
H
414.
H
CD(CH 3 ) 2
H
CD 3
415.
CD 3
CD(CH 3 ) 2
CD 3
H
416.
CD 3
CD(CH 3 ) 2
H
CD 3
417.
H
CD(CH 3 ) 2
CD 3
CD 3
418.
CD 3
CD(CH 3 ) 2
CD 3
CD 3
419.
H
H
CD(CH 3 ) 2
H
420.
CD 3
H
CD(CH 3 ) 2
H
421.
H
CD 3
CD(CH 3 ) 2
H
422.
H
H
CD(CH 3 ) 2
CD 3
423.
CD 3
CD 3
CD(CH 3 ) 2
H
424.
CD 3
H
CD(CH 3 ) 2
CD 3
425.
H
CD 3
CD(CH 3 ) 2
CD 3
426.
CD 3
CD 3
CD(CH 3 ) 2
CD 3
427.
CD(CD 3 ) 2
H
H
H
428.
CD(CD 3 ) 2
CD 3
H
CD 3
429.
CD(CD 3 ) 2
H
CD 3
H
430.
CD(CD 3 ) 2
H
H
CD 3
431.
CD(CD 3 ) 2
CD 3
CD 3
H
432.
CD(CD 3 ) 2
CD 3
H
CD 3
433.
CD(CD 3 ) 2
H
CD 3
CD 3
434.
CD(CD 3 ) 2
CD 3
CD 3
CD 3
435.
H
CD(CD 3 ) 2
H
H
436.
CH 3
CD(CD 3 ) 2
H
CD 3
437.
H
CD(CD 3 ) 2
CD 3
H
438.
H
CD(CD 3 ) 2
H
CD 3
439.
CD 3
CD(CD 3 ) 2
CD 3
H
440.
CD 3
CD(CD 3 ) 2
H
CD 3
441.
H
CD(CD 3 ) 2
CD 3
CD 3
442.
CD 3
CD(CD 3 ) 2
CD 3
CD 3
443.
H
H
CD(CD 3 ) 2
H
444.
CD 3
H
CD(CD 3 ) 2
H
445.
H
CD 3
CD(CD 3 ) 2
H
446.
H
H
CD(CD 3 ) 2
CD 3
447.
CD 3
CD 3
CD(CD 3 ) 2
H
448.
CD 3
H
CD(CD 3 ) 2
CD 3
449.
H
CD 3
CD(CD 3 ) 2
CD 3
450.
CD 3
CD 3
CD(CD 3 ) 2
CD 3
451.
CD 2 CH(CH 3 ) 2
H
H
H
452.
CD 2 CH(CH 3 ) 2
CD 3
H
CD 3
453.
CD 2 CH(CH 3 ) 2
H
CD 3
H
454.
CD 2 CH(CH 3 ) 2
H
H
CD 3
455.
CD 2 CH(CH 3 ) 2
CD 3
CD 3
H
456.
CD 2 CH(CH 3 ) 2
CD 3
H
CD 3
457.
CD 2 CH(CH 3 ) 2
H
CD 3
CD 3
458.
CD 2 CH(CH 3 ) 2
CD 3
CD 3
CD 3
459.
H
CD 2 CH(CH 3 ) 2
H
H
460.
CD 3
CD 2 CH(CH 3 ) 2
H
CD 3
461
H
CD 2 CH(CH 3 ) 2
CD 3
H
462.
H
CD 2 CH(CH 3 ) 2
H
CD 3
463.
CD 3
CD 2 CH(CH 3 ) 2
CD 3
H
464.
CD 3
CD 2 CH(CH 3 ) 2
H
CD 3
465.
H
CD 2 CH(CH 3 ) 2
CD 3
CD 3
466.
CD 3
CD 2 CH(CH 3 ) 2
CD 3
CD 3
467.
H
H
CD 2 CH(CH 3 ) 2
H
468.
CD 3
H
CD 2 CH(CH 3 ) 2
H
469.
H
CD 3
CD 2 CH(CH 3 ) 2
H
470.
H
H
CD 2 CH(CH 3 ) 2
CD 3
471.
CD 3
CD 3
CD 2 CH(CH 3 ) 2
H
472.
CD 3
H
CD 2 CH(CH 3 ) 2
CD 3
473.
H
CD 3
CD 2 CH(CH 3 ) 2
CD 3
474.
CD 3
CD 3
CD 2 CH(CH 3 ) 2
CD 3
475.
CD 2 C(CH 3 ) 3
H
H
H
476.
CD 2 C(CH 3 ) 3
CD 3
H
CD 3
477.
CD 2 C(CH 3 ) 3
H
CD 3
H
478.
CD 2 C(CH 3 ) 3
H
H
CD 3
479.
CD 2 C(CH 3 ) 3
CD 3
CD 3
H
480.
CD 2 C(CH 3 ) 3
CD 3
H
CD 3
481.
CD 2 C(CH 3 ) 3
H
CD 3
CD 3
482.
CD 2 C(CH 3 ) 3
CH 3
CD 3
CD 3
483.
H
CD 2 C(CH 3 ) 3
H
H
484.
CD 3
CD 2 C(CH 3 ) 3
H
CD 3
485.
H
CD 2 C(CH 3 ) 3
CD 3
H
486.
H
CD 2 C(CH 3 ) 3
H
CD 3
487.
CD 3
CD 2 C(CH 3 ) 3
CD 3
H
488.
CD 3
CD 2 C(CH 3 ) 3
H
CD 3
489.
H
CD 2 C(CH 3 ) 3
CD 3
CD 3
490.
CD 3
CD 2 C(CH 3 ) 3
CD 3
CD 3
491.
H
H
CD 2 C(CH 3 ) 3
H
492.
CD 3
H
CD 2 C(CH 3 ) 3
H
493.
H
CD 3
CD 2 C(CH 3 ) 3
H
494.
H
H
CD 2 C(CH 3 ) 3
CD 3
495.
CD 3
CD 3
CD 2 C(CH 3 ) 3
H
496.
CD 3
H
CD 2 C(CH 3 ) 3
CD 3
497.
H
CD 3
CD 2 C(CH 3 ) 3
CD 3
498.
CD 3
CD 3
CD 2 C(CH 3 ) 3
CD 3
499.
H
H
H
500.
CD 3
H
CD 3
501.
H
CD 3
H
502.
H
H
CD 3
503.
CD 3
CD 3
H
504.
CD 3
H
CD 3
505.
H
CD 3
CD 3
506.
CD 3
CD 3
CD 3
507.
H
H
H
508.
CD 3
H
CD 3
509.
H
CD 3
H
510.
H
H
CD 3
511.
CD 3
CD 3
H
512.
CD 3
H
CD 3
513.
H
CD 3
CD 3
514.
CD 3
CD 3
CD 3
515.
H
H
H
516.
CD 3
H
H
517.
H
CD 3
H
518.
H
H
CD 3
519.
CD 3
CD 3
H
520.
CD 3
H
CD 3
521.
H
CD 3
CD 3
522.
CD 3
CD 3
CD 3
523.
H
H
H
524.
CD 3
H
CD 3
525.
H
CD 3
H
526.
H
H
CD 3
527.
CD 3
CD 3
H
528.
CD 3
H
CD 3
529.
H
CD 3
CD 3
530.
CD 3
CD 3
CD 3
531.
H
H
H
532.
CH 3
H
CD 3
533.
H
CD 3
H
534.
H
H
CD 3
535.
CD 3
CD 3
H
536.
CD 3
H
CD 3
537.
H
CD 3
CD 3
538.
CH 3
CD 3
CD 3
539.
H
H
H
540.
CD 3
H
H
541.
H
CD 3
H
542.
H
H
CD 3
543.
CD 3
CD 3
H
544.
CD 3
H
CD 3
545.
H
CD 3
CD 3
546.
CD 3
CD 3
CD 3
547.
H
H
H
548.
CD 3
H
CD 3
549.
H
CD 3
H
550.
H
H
CD 3
551.
CD 3
CD 3
H
552.
CD 3
H
CD 3
553.
H
CD 3
CD 3
554.
CD 3
CD 3
CD 3
555.
H
H
H
556.
CD 3
H
CD 3
557.
H
CD 3
H
558.
H
H
CD 3
559.
CD 3
CD 3
H
560.
CD 3
H
CD 3
561.
H
CD 3
CD 3
562.
CD 3
CD 3
CD 3
563.
H
H
H
564.
CD 3
H
H
565.
H
CD 3
H
566.
H
H
CD 3
567.
CD 3
CD 3
H
568.
CD 3
H
CD 3
569.
H
CD 3
CD 3
570.
CD 3
CD 3
CD 3
571.
H
H
H
572.
CD 3
H
CD 3
573.
H
CD 3
H
574.
H
H
CD 3
575.
CD 3
CD 3
H
576.
CD 3
H
CD 3
577.
H
CD 3
CD 3
578.
CD 3
CD 3
CD 3
579.
H
H
H
580.
CD 3
H
CD 3
581.
H
CD 3
H
582.
H
H
CD 3
583.
CD 3
CD 3
H
584.
CD 3
H
CD 3
585.
H
CD 3
CD 3
586.
CD 3
CD 3
CD 3
587.
H
H
H
588.
CD 3
H
H
589.
H
CD 3
H
590.
H
H
CD 3
591.
CD 3
CD 3
H
592.
CD 3
H
H
593.
H
CD 3
CD 3
594.
CD 3
CD 3
CD 3
595.
H
H
H
596.
CD 3
H
CD 3
597.
H
CD 3
H
598.
H
H
CD 3
599.
CD 3
CD 3
H
600.
CD 3
H
CD 3
601.
H
CD 3
CD 3
602.
CD 3
CD 3
CD 3
603.
H
H
H
604.
CD 3
H
CD 3
605.
H
CD 3
H
606.
H
H
CD 3
607.
CD 3
CD 3
H
608.
CD 3
H
CD 3
609.
H
CD 3
CD 3
610.
CD 3
CD 3
CD 3
611.
H
H
H
612.
CD 3
H
H
613.
H
CD 3
H
614.
H
H
CD 3
615.
CD 3
CD 3
H
616.
CD 3
H
CD 3
617.
H
CD 3
CD 3
618.
CD 3
CD 3
CD 3
619.
H
H
H
620.
CD 3
H
CD 3
621.
H
CD 3
H
622.
H
H
CD 3
623.
CH 3
CH 3
H
624.
CD 3
H
CD 3
625.
H
CD 3
CD 3
626.
CD 3
CD 3
CD 3
627.
H
H
H
628.
CD 3
H
CD 3
629.
H
CD 3
H
630.
H
H
CD 3
631.
CD 3
CD 3
H
632.
CD 3
H
CD 3
633.
H
CD 3
CD 3
634.
CD 3
CD 3
CD 3
635.
H
H
H
636.
CD 3
H
H
637.
H
CD 3
H
638.
H
H
CH 3
639.
CD 3
CD 3
H
640.
CD 3
H
CD 3
641.
H
CD 3
CD 3
642.
CD 3
CD 3
CD 3
643.
CD(CH 3 ) 2
H
CD 2 CH 3
H
644.
CD(CH 3 ) 2
H
CD(CH 3 ) 2
H
645.
CD(CH 3 ) 2
H
CD 2 CH(CH 3 ) 2
H
646.
CD(CH 3 ) 2
H
C(CH 3 ) 3
H
647.
CD(CH 3 ) 2
H
CD 2 C(CH 3 ) 3
H
648.
CD(CH 3 ) 2
H
H
649.
CD(CH 3 ) 2
H
H
650.
CD(CH 3 ) 2
H
H
651.
CD(CH 3 ) 2
H
H
652.
CD(CH 3 ) 2
H
H
653.
CD(CH 3 ) 2
H
H
654.
C(CH 3 ) 3
H
CD 2 CH 3
H
655.
C(CH 3 ) 3
H
CD(CH 3 ) 2
H
656.
C(CH 3 ) 3
H
CD 2 CH(CH 3 ) 2
H
657.
C(CH 3 ) 3
H
C(CH 3 ) 3
H
658.
C(CH 3 ) 3
H
CD 2 C(CH 3 ) 3
H
659.
C(CH 3 ) 3
H
H
660.
C(CH 3 ) 3
H
H
661.
C(CH 3 ) 3
H
H
662.
C(CH 3 ) 3
H
H
663.
C(CH 3 ) 3
H
H
664.
C(CH 3 ) 3
H
H
665.
CD 2 C(CH 3 ) 3
H
CD 2 CH 3
H
666.
CD 2 C(CH 3 ) 3
H
CD(CH 3 ) 2
H
667.
CD 2 C(CH 3 ) 3
H
CD 2 CH(CH 3 ) 2
H
668.
CD 2 C(CH 3 ) 3
H
C(CH 3 ) 3
H
669.
CD 2 C(CH 3 ) 3
H
CD 2 C(CH 3 ) 3
H
670.
CD 2 C(CH 3 ) 3
H
H
671.
CD 2 C(CH 3 ) 3
H
H
672.
CD 2 C(CH 3 ) 3
H
H
673.
CD 2 C(CH 3 ) 3
H
H
674.
CD 2 C(CH 3 ) 3
H
H
675.
CD 2 C(CH 3 ) 3
H
H
676.
H
CD 2 CH 3
H
677.
H
CD(CH 3 ) 2
H
678.
H
CD 2 CH(CH 3 ) 2
H
679.
H
C(CH 3 ) 3
H
680.
H
CD 2 C(CH 3 ) 3
H
681.
H
682.
H
H
683.
H
H
684.
H
H
685.
H
H
686.
H
H
687.
H
CD 2 CH 3
H
688.
H
CD(CH 3 ) 2
H
689.
H
CD 2 CH(CH 3 ) 2
H
690.
H
C(CH 3 ) 3
H
691.
H
CD 2 C(CH 3 ) 3
H
692.
H
CD 2 CH 2 CF 3
H
693.
H
CD 2 C(CH 3 ) 2 CF 3
H
694.
H
H
695.
H
H
696.
H
H
697.
H
H
698.
H
H
699.
H
H
700.
H
CD 2 CH 3
H
701.
H
CD(CH 3 ) 2
H
702.
H
CD 2 CH(CH 3 ) 2
H
703.
H
C(CH 3 ) 3
H
704.
H
CD 2 C(CH 3 ) 3
H
705.
H
CD 2 CH 2 CF 3
H
706.
H
CD 2 C(CH 3 ) 2 CF 3
H
707.
H
H
708.
H
H
709.
H
H
710.
H
H
711.
H
H
712.
H
H
713.
H
CD 2 CH 3
H
714.
H
CD(CH 3 ) 2
H
715.
H
CD 2 CH(CH 3 ) 2
H
716.
H
C(CH 3 ) 3
H
717.
H
CD 2 C(CH 3 ) 3
H
718.
H
CD 2 CH 2 CF 3
H
719.
H
CD 2 C(CH 3 ) 2 CF 3
H
720.
H
H
721.
H
H
722.
H
H
723.
H
H
724.
H
H
725.
H
H
726.
H
CD 2 CH 3
H
727.
H
CD(CH 3 ) 2
H
728.
H
CD 2 CH(CH 3 ) 2
H
729.
H
C(CH 3 ) 3
H
730.
H
CD 2 C(CH 3 ) 3
H
731.
H
CD 2 CH 2 CF 3
H
732.
H
CD 2 C(CH 3 ) 2 CF 3
H
733.
H
H
734.
H
H
735.
H
H
736.
H
H
737.
H
H
738.
H
H
H
H
739.
CH 3
Ph
H
H
740.
H
Ph
H
H
741.
H
Ph
CH 3
H
742.
CH 3
Ph
H
CH 3
743.
CH 3
Ph
CH 3
H
744.
CH 3
Ph
H
CH 3
745.
H
Ph
CH 3
H
746.
H
Ph
H
CH 3
747.
H
Ph
CH 3
CH 3
748.
CH 3
Ph
CH 3
H
749.
CH 3
Ph
H
CH 3
750.
CH 3
Ph
CH 3
CH 3
751.
H
Ph
CH 3
CH 3
752.
CH 3
Ph
CH 3
CH 3
753.
CH 2 CH 3
Ph
H
H
754.
CH 2 CH 3
Ph
H
CH 3
755.
CH 2 CH 3
Ph
CH 3
H
756.
CH 2 CH 3
Ph
H
CH 3
757.
CH 2 CH 3
Ph
CH 3
H
758.
CH 2 CH 3
Ph
H
CH 3
759.
CH 2 CH 3
Ph
CH 3
CH 3
760.
CH 2 CH 3
Ph
CH 3
CH 3
761.
H
Ph
H
H
762.
CH 3
Ph
H
CH 3
763.
H
Ph
CH 3
H
764.
H
Ph
H
CH 3
765.
CH 3
Ph
CH 3
H
766.
CH 3
Ph
H
CH 3
767.
H
Ph
CH 3
CH 3
768.
CH 3
Ph
CH 3
CH 3
769.
H
Ph
CH 2 CH 3
H
770.
CH 3
Ph
CH 2 CH 3
H
771.
H
Ph
CH 2 CH 3
H
772.
H
Ph
CH 2 CH 3
CH 3
773.
CH 3
Ph
CH 2 CH 3
H
774.
CH 3
Ph
CH 2 CH 3
CH 3
775.
H
Ph
CH 2 CH 3
CH 3
776.
CH 3
Ph
CH 2 CH 3
CH 3
777.
CH(CH 3 ) 2
Ph
H
H
778.
CH(CH 3 ) 2
P
H
CH 3
779.
CH(CH 3 ) 2
Ph
CH 3
H
780.
CH(CH 3 ) 2
Ph
H
CH 3
781.
CH(CH 3 ) 2
Ph
CH 3
H
782.
CH(CH 3 ) 2
Ph
H
CH 3
783.
CH(CH 3 ) 2
Ph
CH 3
CH 3
784.
CH(CH 3 ) 2
Ph
CH 3
CH 3
785.
H
Ph
H
H
786.
CH 3
Ph
H
CH 3
787.
H
Ph
CH 3
H
788.
H
Ph
H
CH 3
789.
CH 3
Ph
CH 3
H
790.
CH 3
Ph
H
CH 3
791.
H
Ph
CH 3
CH 3
792.
CH 3
Ph
CH 3
CH 3
793.
H
Ph
CH(CH 3 ) 2
H
794.
CH 3
Ph
CH(CH 3 ) 2
H
795.
H
Ph
CH(CH 3 ) 2
H
796.
H
Ph
CH(CH 3 ) 2
CH 3
797.
CH 3
Ph
CH(CH 3 ) 2
H
798.
CH 3
Ph
CH(CH 3 ) 2
CH 3
799.
H
Ph
CH(CH 3 ) 2
CH 3
800.
CH 3
Ph
CH(CH 3 ) 2
CH 3
801.
CH 2 CH(CH 3 ) 2
Ph
H
H
802.
CH 2 CH(CH 3 ) 2
Ph
H
CH 3
803.
CH 2 CH(CH 3 ) 2
Ph
CH 3
H
804.
CH 2 CH(CH 3 ) 2
Ph
H
CH 3
805.
CH 2 CH(CH 3 ) 2
Ph
CH 3
H
806.
CH 2 CH(CH 3 ) 2
Ph
H
CH 3
807.
CH 2 CH(CH 3 ) 2
Ph
CH 3
CH 3
808.
CH 2 CH(CH 3 ) 2
Ph
CH 3
CH 3
809.
H
Ph
H
H
810.
CH 3
Ph
H
CH 3
811.
H
Ph
CH 3
H
812.
H
Ph
H
CH 3
813.
CH 3
Ph
CH 3
H
814.
CH 3
Ph
H
CH 3
815.
H
Ph
CH 3
CH 3
816.
CH 3
Ph
CH 3
CH 3
817.
H
Ph
CH 2 CH(CH 3 ) 2
H
818.
CH 3
Ph
CH 2 CH(CH 3 ) 2
H
819.
H
Ph
CH 2 CH(CH 3 ) 2
H
820.
H
Ph
CH 2 CH(CH 3 ) 2
CH 3
821.
CH 3
Ph
CH 2 CH(CH 3 ) 2
H
822.
CH 3
Ph
CH 2 CH(CH 3 ) 2
CH 3
823.
H
Ph
CH 2 CH(CH 3 ) 2
CH 3
824.
CH 3
Ph
CH 2 CH(CH 3 ) 2
CH 3
825.
C(CH 3 ) 3
Ph
H
H
826.
C(CH 3 ) 3
Ph
H
CH 3
827.
C(CH 3 ) 3
Ph
CH 3
H
828.
C(CH 3 ) 3
Ph
H
CH 3
829.
C(CH 3 ) 3
Ph
CH 3
H
830.
C(CH 3 ) 3
Ph
H
CH 3
831.
C(CH 3 ) 3
Ph
CH 3
CH 3
832.
C(CH 3 ) 3
Ph
CH 3
CH 3
833.
H
Ph
H
H
834.
CH 3
Ph
H
CH 3
835.
H
Ph
CH 3
H
836.
H
Ph
H
CH 3
837.
CH 3
Ph
CH 3
H
838.
CH 3
Ph
H
CH 3
839.
H
Ph
CH 3
CH 3
840.
CH 3
Ph
CH 3
CH 3
841.
H
Ph
C(CH 3 ) 3
H
842.
CH 3
Ph
C(CH 3 ) 3
H
843.
H
Ph
C(CH 3 ) 3
H
844.
H
Ph
C(CH 3 ) 3
CH 3
845.
CH 3
Ph
C(CH 3 ) 3
H
846.
CH 3
Ph
C(CH 3 ) 3
CH 3
847.
H
Ph
C(CH 3 ) 3
CH 3
848.
CH 3
Ph
C(CH 3 ) 3
CH 3
849.
CH 2 C(CH 3 ) 3
Ph
H
H
850.
CH 2 C(CH 3 ) 3
Ph
H
CH 3
851.
CH 2 C(CH 3 ) 3
Ph
CH 3
H
852.
CH 2 C(CH 3 ) 3
Ph
H
CH 3
853.
CH 2 C(CH 3 ) 3
Ph
CH 3
H
854.
CH 2 C(CH 3 ) 3
Ph
H
CH 3
855.
CH 2 C(CH 3 ) 3
Ph
CH 3
CH 3
856.
CH 2 C(CH 3 ) 3
Ph
CH 3
CH 3
857.
H
Ph
H
H
858.
CH 3
Ph
H
CH 3
859.
H
Ph
CH 3
H
860.
H
Ph
H
CH 3
861.
CH 3
Ph
CH 3
H
862.
CH 3
Ph
H
CH 3
863.
H
Ph
CH 3
CH 3
864.
CH 3
Ph
CH 3
CH 3
865.
H
Ph
CH 2 C(CH 3 ) 3
H
866.
CH 3
Ph
CH 2 C(CH 3 ) 3
H
867.
H
Ph
CH 2 C(CH 3 ) 3
H
868.
H
Ph
CH 2 C(CH 3 ) 3
CH 3
869.
CH 3
Ph
CH 2 C(CH 3 ) 3
H
870.
CH 3
Ph
CH 2 C(CH 3 ) 3
CH 3
871.
H
Ph
CH 2 C(CH 3 ) 3
CH 3
872.
CH 3
Ph
CH 2 C(CH 3 ) 3
CH 3
873.
Ph
H
H
874.
Ph
H
CH 3
875.
Ph
H
CH 3
876.
Ph
H
CH 3
877.
Ph
CH 3
H
878.
Ph
H
CH 3
879.
Ph
CH 3
CH 3
880.
Ph
CH 3
CH 3
881.
H
Ph
H
H
882.
CH 3
Ph
H
CH 3
883.
H
Ph
CH 3
H
884.
H
Ph
H
CH 3
885.
CH 3
Ph
CH 3
H
886.
CH 3
Ph
H
CH 3
887.
H
Ph
CH 3
CH 3
888.
CH 3
Ph
CH 3
CH 3
889.
H
Ph
H
890.
CH 3
Ph
H
891.
H
Ph
H
892.
H
Ph
CH 3
893.
CH 3
Ph
H
894.
CH 3
Ph
CH 3
895.
H
Ph
CH 3
896.
CH 3
Ph
CH 3
897.
Ph
H
H
898.
Ph
H
CH 3
899.
Ph
CH 3
H
900.
Ph
H
CH 3
901.
Ph
CH 3
H
902.
Ph
H
CH 3
903.
Ph
CH 3
CH 3
904.
Ph
CH 3
CH 3
905.
H
Ph
H
H
906.
CH 3
Ph
H
CH 3
907.
H
Ph
CH 3
H
908.
H
Ph
H
CH 3
909.
CH 3
Ph
CH 3
H
910.
CH 3
Ph
H
CH 3
911.
H
Ph
CH 3
CH 3
912.
CH 3
Ph
CH 3
CH 3
913.
H
Ph
H
914.
CH 3
Ph
H
915.
H
Ph
H
916.
H
Ph
CH 3
917.
CH 3
Ph
H
918.
CH 3
Ph
CH 3
919.
H
Ph
CH 3
920.
CH 3
Ph
CH 3
921.
Ph
H
H
922.
Ph
H
CH 3
923.
Ph
CH 3
H
924.
Ph
H
CH 3
925.
Ph
CH 3
H
926.
Ph
H
CH 3
927.
Ph
CH 3
CH 3
928.
Ph
CH 3
CH 3
929.
H
Ph
H
H
930.
CH 3
Ph
H
CH 3
931.
H
Ph
CH 3
H
932.
H
Ph
H
CH 3
933.
CH 3
Ph
CH 3
H
934.
CH 3
Ph
H
CH 3
935.
CH 3
Ph
CH 3
CH 3
936.
CH 3
Ph
CH 3
CH 3
937.
H
Ph
H
938.
CH 3
Ph
H
939.
H
Ph
H
940.
CH 3
Ph
CH 3
941.
CH 3
Ph
H
942.
CH 3
Ph
CH 3
943.
H
Ph
CH 3
944.
CH 3
Ph
CH 3
945.
Ph
H
H
946.
Ph
H
CH 3
947.
Ph
CH 3
H
948.
Ph
H
CH 3
949.
Ph
CH 3
H
950.
Ph
H
CH 3
951.
Ph
CH 3
CH 3
952.
Ph
CH 3
CH 3
953.
H
Ph
H
H
954.
CH 3
Ph
H
CH 3
955.
H
Ph
CH 3
H
956.
H
Ph
H
CH 3
957.
CH 3
Ph
CH 3
H
958.
CH 3
Ph
H
CH 3
959.
H
Ph
CH 3
CH 3
960.
CH 3
Ph
CH 3
CH 3
961.
H
Ph
H
962.
H
Ph
H
963.
H
Ph
H
964.
H
Ph
CH 3
965.
CH 3
Ph
H
966.
CH 3
Ph
CH 3
967.
H
Ph
CH 3
968.
CH 3
Ph
CH 3
969.
Ph
H
H
970.
Ph
H
CH 3
971.
Ph
CH 3
H
972.
Ph
H
CH 3
973.
Ph
CH 3
H
974.
Ph
H
CH 3
975.
Ph
CH 3
CH 3
976.
Ph
CH 3
CH 3
977.
H
Ph
H
H
978.
CH 3
Ph
H
CH 3
979.
H
Ph
CH 3
H
980.
H
Ph
H
CH 3
981.
CH 3
Ph
CH 3
H
982.
CH 3
Ph
H
CH 3
983.
H
Ph
CH 3
CH 3
984.
CH 3
Ph
CH 3
CH 3
985.
H
Ph
H
986.
CH 3
Ph
H
987.
H
Ph
H
988.
H
Ph
CH 3
989.
CH 3
Ph
H
990.
CH 3
Ph
CH 3
991.
H
Ph
CH 3
992.
CH 3
Ph
CH 3
993.
Ph
H
H
994.
Ph
H
CH 3
995.
Ph
CH 3
H
996.
Ph
H
CH 3
997.
Ph
CH 3
H
998.
Ph
H
CH 3
999.
Ph
CH 3
CH 3
1000.
Ph
CH 3
CH 3
1001.
H
Ph
H
H
1002.
CH 3
Ph
H
CH 3
1003.
H
Ph
CH 3
H
1004.
H
Ph
H
CH 3
1005.
CH 3
Ph
CH 3
H
1006.
CH 3
Ph
H
CH 3
1007.
H
Ph
CH 3
CH 3
1008.
CH 3
Ph
CH 3
CH 3
1009.
H
Ph
H
1010.
CH 3
Ph
H
1011.
H
Ph
H
1012.
H
Ph
CH 3
1013.
CH 3
Ph
CH 3
1014.
CH 3
Ph
CH 3
1015.
H
Ph
CH 3
1016.
CH 3
Ph
CH 3
1017.
CH(CH 3 ) 2
Ph
CH 2 CH 3
H
1018.
CH(CH 3 ) 2
Ph
CH(CH 3 ) 2
H
1019.
CH(CH 3 ) 2
Ph
CH 2 CH(CH 3 ) 2
H
1020.
CH(CH 3 ) 2
Ph
C(CH 3 ) 3
H
1021.
CH(CH 3 ) 2
Ph
CH 2 C(CH 3 ) 3
H
1022.
CH(CH 3 ) 2
Ph
H
1023.
CH(CH 3 ) 2
Ph
H
1024.
CH(CH 3 ) 2
Ph
H
1025.
CH(CH 3 ) 2
Ph
H
1026.
CH(CH 3 ) 2
Ph
H
1027.
CH(CH 3 ) 2
Ph
H
1028.
C(CH 3 ) 3
Ph
CH 2 CH 3
H
1029.
C(CH 3 ) 3
Ph
CH(CH 3 ) 2
H
1030.
C(CH 3 ) 3
Ph
CH 2 CH(CH 3 ) 2
H
1031.
C(CH 3 ) 3
Ph
C(CH 3 ) 3
H
1032.
C(CH 3 ) 3
Ph
CH 2 C(CH 3 ) 3
H
1033.
C(CH 3 ) 3
Ph
H
1034.
C(CH 3 ) 3
Ph
H
1035.
C(CH 3 ) 3
Ph
H
1036.
C(CH 3 ) 3
Ph
H
1037.
C(CH 3 ) 3
Ph
H
1038.
C(CH 3 ) 3
Ph
H
1039.
CH 2 C(CH 3 ) 3
Ph
CH 2 CH 3
H
1040.
CH 2 C(CH 3 ) 3
Ph
CH(CH 3 ) 2
H
1041.
CH 2 C(CH 3 ) 3
Ph
CH 2 CH(CH 3 ) 2
H
1042.
CH 2 C(CH 3 ) 3
Ph
C(CH 3 ) 3
H
1043.
CH 2 C(CH 3 ) 3
Ph
CH 2 C(CH 3 ) 3
H
1044.
CH 2 C(CH 3 ) 3
Ph
H
1045.
CH 2 C(CH 3 ) 3
Ph
H
1046.
CH 2 C(CH 3 ) 3
Ph
H
1047.
CH 2 C(CH 3 ) 3
Ph
H
1048.
CH 2 C(CH 3 ) 3
Ph
H
1049.
CH 2 C(CH 3 ) 3
Ph
H
1050.
Ph
CH 2 CH 3
H
1051.
Ph
CH(CH 3 ) 2
H
1052.
Ph
CH 2 CH(CH 3 ) 2
H
1053.
Ph
C(CH 3 ) 3
H
1054.
Ph
CH 2 C(CH 3 ) 3
H
1055.
Ph
H
1056.
Ph
H
1057.
Ph
H
1058.
Ph
H
1059.
Ph
H
1060.
Ph
H
1061.
Ph
CH 2 CH 3
H
1062.
Ph
CH(CH 3 ) 2
H
1063.
Ph
CH 2 CH(CH 3 ) 2
H
1064.
Ph
C(CH 3 ) 3
H
1065.
Ph
CH 2 C(CH 3 ) 3
H
1066.
Ph
H
1067.
Ph
H
1068.
Ph
H
1069.
Ph
H
1070.
Ph
H
1071.
Ph
H
1072.
Ph
CH 2 CH(CH 3 ) 2
H
1073.
Ph
C(CH 3 ) 3
H
1074.
Ph
CH 2 C(CH 3 ) 3
H
1075.
Ph
H
1076.
Ph
H
1077.
Ph
H
1078.
Ph
H
1079.
Ph
H
1080.
Ph
H
1081.
Ph
CH 2 CH(CH 3 ) 2
H
1082.
Ph
C(CH 3 ) 3
H
1083.
Ph
CH 2 C(CH 3 ) 3
H
1084.
Ph
H
1085.
Ph
H
1086.
Ph
H
1087.
Ph
H
1088.
Ph
H
1089.
Ph
H
1090.
Ph
CH 2 CH(CH 3 ) 2
H
1091.
Ph
C(CH 3 ) 3
H
1092.
Ph
CH 2 C(CH 3 ) 3
H
1093.
Ph
CH 2 CH 2 CF 3
H
1094.
Ph
CH 2 C(CH 3 ) 2 CF 3
H
1095.
Ph
H
1096.
Ph
H
1097.
Ph
H
1098.
Ph
H
1099.
Ph
H
1100.
Ph
H
1101.
H
Ph
H
H
1102.
CD 3
Ph
H
H
1103.
H
Ph
H
H
1104.
H
Ph
CD 3
H
1105.
CD 3
Ph
H
CD 3
1106.
CD 3
Ph
CD 3
H
1107.
CD 3
Ph
H
CD 3
1108.
H
Ph
CH 3
H
1109.
H
Ph
H
CD 3
1110.
H
Ph
CD 3
CD 3
1111.
CD 3
Ph
CD 3
H
1112.
CD 3
Ph
H
CD 3
1113.
CD 3
Ph
CD 3
CD 3
1114.
H
Ph
CD 3
CD 3
1115.
CD 3
Ph
CD 3
CD 3
1116.
CD 2 CH 3
Ph
H
1117.
CD 2 CH 3
Ph
H
CD 3
1118.
CD 2 CH 3
Ph
CD 3
H
1119.
CD 2 CH 3
Ph
H
CD 3
1120.
CD 2 CH 3
Ph
CD 3
H
1121.
CD 2 CH 3
Ph
H
CD 3
1122.
CD 2 CH 3
Ph
CD 3
CD 3
1123.
CD 2 CH 3
Ph
CD 3
CD 3
1124.
H
Ph
H
H
1125.
CH 3
Ph
H
CD 3
1126.
H
Ph
CD 3
H
1127.
H
Ph
H
CD 3
1128.
CD 3
Ph
CD 3
H
1129.
CD 3
Ph
H
CD 3
1130.
H
Ph
CD 3
CD 3
1131.
CD 3
Ph
CD 3
CD 3
1132.
H
Ph
CD 2 CH 3
H
1133.
CD 3
Ph
CD 2 CH 3
H
1134.
H
Ph
CD 2 CH 3
H
1135.
H
Ph
CD 2 CH 3
CD 3
1136.
CD 3
Ph
CD 2 CH 3
H
1137.
CD 3
Ph
CD 2 CH 3
CD 3
1138.
H
Ph
CD 2 CH 3
CD 3
1139.
CD 3
Ph
CD 2 CH 3
CD 3
1140.
CD(CH 3 ) 2
Ph
H
H
1141.
CD(CH 3 ) 2
Ph
H
CD 3
1142.
CD(CH 3 ) 2
Ph
CD 3
H
1143.
CD(CH 3 ) 2
Ph
H
CD 3
1144.
CD(CH 3 ) 2
Ph
CD 3
H
1145.
CD(CH 3 ) 2
Ph
H
CD 3
1146.
CD(CH 3 ) 2
Ph
CD 3
CD 3
1147.
CD(CH 3 ) 2
Ph
CD 3
CD 3
1148.
H
Ph
H
H
1149.
CD 3
Ph
H
CD 3
1150.
H
Ph
CD 3
H
1151.
H
Ph
H
CD 3
1152.
CD 3
Ph
CD 3
H
1153.
CD 3
Ph
H
CD 3
1154.
H
Ph
CD 3
CD 3
1155.
CD 3
Ph
CD 3
CD 3
1156.
H
Ph
CD(CH 3 ) 2
H
1157.
CD 3
Ph
CD(CH 3 ) 2
H
1158.
H
Ph
CD(CH 3 ) 2
H
1159.
H
Ph
CD(CH 3 ) 2
CD 3
1160.
CD 3
Ph
CD(CH 3 ) 2
H
1161.
CD 3
Ph
CD(CH 3 ) 2
CD 3
1162.
H
Ph
CD(CH 3 ) 2
CD 3
1163.
CD 3
Ph
CD(CH 3 ) 2
CD 3
1164.
CD(CH 3 ) 2
Ph
H
H
1165.
CD(CH 3 ) 2
Ph
H
CD 3
1166.
CD(CH 3 ) 2
Ph
CD 3
H
1167.
CD(CH 3 ) 2
Ph
H
CD 3
1168.
CD(CH 3 ) 2
Ph
CD 3
H
1169.
CD(CH 3 ) 2
Ph
H
CD 3
1170.
CD(CH 3 ) 2
Ph
CD 3
CD 3
1171.
CD(CH 3 ) 2
Ph
CD 3
CD 3
1172.
H
Ph
H
H
1173.
CH 3
Ph
H
CD 3
1174.
H
Ph
CD 3
H
1175.
H
Ph
H
CD 3
1176.
CD 3
Ph
CD 3
H
1177.
CD 3
Ph
H
CD 3
1178.
H
Ph
CD 3
CD 3
1179.
CD 3
Ph
CD 3
CD 3
1180.
H
Ph
CD(CD 3 ) 2
H
1181.
CD 3
Ph
CD(CD 3 ) 2
H
1182.
H
Ph
CD(CD 3 ) 2
H
1183.
H
Ph
CD(CD 3 ) 2
CD 3
1184.
CD 3
Ph
CD(CD 3 ) 2
H
1185.
CD 3
Ph
CD(CD 3 ) 2
CD 3
1186.
H
Ph
CD(CD 3 ) 2
CD 3
1187.
CD 3
Ph
CD(CD 3 ) 2
CD 3
1188.
CD 2 CH(CH 3 ) 2
Ph
H
H
1189.
CD 2 CH(CH 3 ) 2
Ph
H
CD 3
1190.
CD 2 CH(CH 3 ) 2
Ph
CD 3
H
1191.
CD 2 CH(CH 3 ) 2
Ph
H
CD 3
1192.
CD 2 CH(CH 3 ) 2
Ph
CD 3
H
1193.
CD 2 CH(CH 3 ) 2
Ph
H
CD 3
1194.
CD 2 CH(CH 3 ) 2
Ph
CD 3
CD 3
1195.
CD 2 CH(CH 3 ) 2
Ph
CD 3
CD 3
1196.
H
Ph
H
H
1197.
CD 3
Ph
H
CD 3
1198.
H
Ph
CD 3
H
1199.
H
Ph
H
CD 3
1200.
CD 3
Ph
CD 3
H
1201.
CD 3
Ph
H
CD 3
1202.
H
Ph
CD 3
CD 3
1203.
CD 3
Ph
CD 3
CD 3
1204.
H
Ph
CD 2 CH(CH 3 ) 2
H
1205.
CD 3
Ph
CD 2 CH(CH 3 ) 2
H
1206.
H
Ph
CD 2 CH(CH 3 ) 2
H
1207.
H
Ph
CD 2 CH(CH 3 ) 2
CD 3
1208.
CD 3
Ph
CD 2 CH(CH 3 ) 2
H
1209.
CD 3
Ph
CD 2 CH(CH 3 ) 2
CD 3
1210.
H
Ph
CD 2 CH(CH 3 ) 2
CD 3
1211.
CD 3
Ph
CD 2 CH(CH 3 ) 2
CD 3
1212.
CD 2 C(CH 3 ) 3
Ph
H
H
1213.
CD 2 C(CH 3 ) 3
Ph
H
CD 3
1214.
CD 2 C(CH 3 ) 3
Ph
CD 3
H
1215.
CD 2 C(CH 3 ) 3
Ph
H
CD 3
1216.
CD 2 C(CH 3 ) 3
Ph
CD 3
H
1217.
CD 2 C(CH 3 ) 3
Ph
H
CD 3
1218.
CD 2 C(CH 3 ) 3
Ph
CD 3
CD 3
1219.
CD 2 C(CH 3 ) 3
Ph
CD 3
CD 3
1220.
H
Ph
H
H
1221.
CD 3
Ph
H
CD 3
1222.
H
Ph
CD 3
H
1223.
H
Ph
H
CD 3
1224.
CD 3
Ph
CD 3
H
1225.
CD 3
Ph
H
CD 3
1226.
H
Ph
CD 3
CD 3
1227.
CD 3
Ph
CD 3
CD 3
1228.
H
Ph
CD 2 C(CH 3 ) 3
H
1229.
CD 3
Ph
CD 2 C(CH 3 ) 3
H
1230.
H
Ph
CD 2 C(CH 3 ) 3
H
1231.
H
Ph
CD 2 C(CH 3 ) 3
CD 3
1232.
CD 3
Ph
CD 2 C(CH 3 ) 3
H
1233.
CD 3
Ph
CD 2 C(CH 3 ) 3
CD 3
1234.
H
Ph
CD 2 C(CH 3 ) 3
CD 3
1235.
CD 3
Ph
CD 2 C(CH 3 ) 3
CD 3
1236.
Ph
H
H
1237.
Ph
H
CD 3
1238.
Ph
CD 3
H
1239.
Ph
H
CD 3
1240.
Ph
CD 3
H
1241.
Ph
H
CD 3
1242.
Ph
CD 3
CD 3
1243.
Ph
CD 3
CD 3
1244.
H
Ph
H
H
1245.
CD 3
Ph
H
CD 3
1246.
H
Ph
CD 3
H
1247.
H
Ph
H
CD 3
1248.
CD 3
Ph
CD 3
H
1249.
CD 3
Ph
H
CD 3
1250.
H
Ph
CD 3
CD 3
1251.
CD 3
Ph
CD 3
CD 3
1252.
H
Ph
H
1253.
CD 3
Ph
H
1254.
H
Ph
H
1255.
H
Ph
CD 3
1256.
CD 3
Ph
H
1257.
CD 3
Ph
CD 3
1258.
H
Ph
CD 3
1259.
CD 3
Ph
CD 3
1260.
Ph
H
H
1261.
Ph
H
CD 3
1262.
Ph
CD 3
H
1263.
Ph
H
CD 3
1264.
Ph
CD 3
H
1265.
Ph
H
CD 3
1266.
Ph
CD 3
CD 3
1267.
Ph
CD 3
CD 3
1268.
H
Ph
H
H
1269.
CH 3
Ph
H
CD 3
1270.
H
Ph
CD 3
H
1271.
H
Ph
H
CD 3
1272.
CD 3
Ph
CD 3
H
1273.
CD 3
Ph
H
CD 3
1274.
H
Ph
CD 3
CD 3
1275.
CH 3
Ph
CD 3
CD 3
1276.
H
Ph
H
1277.
CD 3
Ph
H
1278.
H
Ph
H
1279.
H
Ph
CD 3
1280.
CD 3
Ph
H
1281.
CD 3
Ph
CD 3
1282.
H
Ph
CD 3
1283.
CD 3
Ph
CD 3
1284.
Ph
H
H
1285.
Ph
H
CD 3
1286.
Ph
CD 3
H
1287.
Ph
H
CD 3
1288.
Ph
CD 3
H
1289.
Ph
H
CD 3
1290.
Ph
CD 3
CD 3
1291.
Ph
CD 3
CD 3
1292.
H
Ph
H
H
1293.
CD 3
Ph
H
CD 3
1294.
H
Ph
CD 3
H
1295.
H
Ph
H
CD 3
1296.
CD 3
Ph
CD 3
H
1297.
CD 3
Ph
H
CD 3
1298.
H
Ph
CD 3
CD 3
1299.
CD 3
Ph
CD 3
CD 3
1300.
H
Ph
H
1301.
CD 3
Ph
H
1302.
H
Ph
H
1303.
H
Ph
H
1304.
CD 3
Ph
H
1305.
CD 3
Ph
CD 3
1306.
H
Ph
CD 3
1307.
CD 3
Ph
CD 3
1308.
Ph
H
H
1309.
Ph
H
CD 3
1310.
Ph
CD 3
H
1311.
Ph
H
CD 3
1312.
Ph
CD 3
H
1313.
Ph
H
CD 3
1314.
Ph
CD 3
CD 3
1315.
Ph
CD 3
CD 3
1316.
H
Ph
H
H
1317.
CD 3
Ph
H
CD 3
1318.
H
Ph
CD 3
H
1319.
H
Ph
H
CD 3
1320.
CD 3
Ph
CD 3
H
1321.
CD 3
Ph
H
CD 3
1322.
H
Ph
CD 3
CD 3
1323.
CD 3
Ph
CD 3
CD 3
1324.
H
Ph
H
1325.
CD 3
Ph
H
1326.
H
Ph
H
1327.
H
Ph
CD 3
1328.
CD 3
Ph
H
1329.
CD 3
Ph
CD 3
1330.
H
Ph
CD 3
1331.
CD 3
Ph
CD 3
1332.
Ph
H
H
1333.
Ph
H
CD 3
1334.
Ph
CD 3
H
1335.
Ph
H
CD 3
1336.
Ph
CD 3
H
1337.
Ph
H
CD 3
1338.
Ph
CD 3
CD 3
1339.
Ph
CD 3
CD 3
1340.
H
Ph
H
H
1341.
CD 3
Ph
H
CD 3
1342.
H
Ph
CD 3
H
1343.
H
Ph
H
CD 3
1344.
CD 3
Ph
CD 3
H
1345.
CD 3
Ph
H
CD 3
1346.
H
Ph
CD 3
CD 3
1347.
CD 3
Ph
CD 3
CD 3
1348.
H
Ph
H
1349
CD 3
Ph
H
1350.
H
Ph
H
1351.
H
Ph
CD 3
1352.
CD 3
Ph
H
1353.
CD 3
Ph
CD 3
1354.
H
Ph
CD 3
1355.
CD 3
Ph
CD 3
1356.
Ph
H
H
1357.
Ph
H
CD 3
1358.
Ph
CD 3
H
1359.
Ph
H
CD 3
1360.
Ph
CH 3
H
1361.
Ph
H
CD 3
1362.
Ph
CD 3
CD 3
1363.
Ph
CD 3
CD 3
1364.
H
Ph
H
H
1365.
CD 3
Ph
H
CD 3
1366.
H
Ph
CD 3
H
1367.
H
Ph
H
CD 3
1368.
CD 3
Ph
CD 3
H
1369.
CD 3
Ph
H
CD 3
1370.
H
Ph
CD 3
CD 3
1371.
CD 3
Ph
CD 3
CD 3
1372.
H
Ph
H
1373.
CD 3
Ph
H
1374.
H
Ph
H
1375.
H
Ph
CH 3
1376.
CD 3
Ph
H
1377.
CD 3
Ph
CD 3
1378.
H
Ph
CD 3
1379.
CD 3
Ph
CD 3
1380.
CD(CH 3 ) 2
Ph
CD 2 CH 3
H
1381.
CD(CH 3 ) 2
Ph
CD(CH 3 ) 2
H
1382.
CD(CH 3 ) 2
Ph
CD 2 CH(CH 3 ) 2
H
1383.
CD(CH 3 ) 2
Ph
C(CH 3 ) 3
H
1384.
CD(CH 3 ) 2
Ph
CD 2 C(CH 3 ) 3
H
1385.
CD(CH 3 ) 2
Ph
CD 2 CH 2 CF 3
H
1386.
CD(CH 3 ) 2
Ph
CD 2 C(CH 3 ) 2 CF 3
H
1387.
CD(CH 3 ) 2
Ph
H
1388.
CD(CH 3 ) 2
Ph
H
1389.
CD(CH 3 ) 2
Ph
H
1390.
CD(CH 3 ) 2
Ph
H
1391.
CD(CH 3 ) 2
Ph
H
1392.
CD(CH 3 ) 2
Ph
H
1393.
C(CH 3 ) 3
Ph
CD 2 CH 3
H
1394.
C(CH 3 ) 3
Ph
CD(CH 3 ) 2
H
1395.
C(CH 3 ) 3
Ph
CD 2 CH(CH 3 ) 2
H
1396.
C(CH 3 ) 3
Ph
C(CH 3 ) 3
H
1397.
C(CH 3 ) 3
Ph
CD 2 C(CH 3 ) 3
H
1398.
C(CH 3 ) 3
Ph
H
1399.
C(CH 3 ) 3
Ph
H
1400.
C(CH 3 ) 3
Ph
H
1401.
C(CH 3 ) 3
Ph
H
1402.
C(CH 3 ) 3
Ph
H
1403.
C(CH 3 ) 3
Ph
H
1404.
CD 2 C(CH 3 ) 3
Ph
CD 2 CH 3
H
1405.
CD 2 C(CH 3 ) 3
Ph
CD(CH 3 ) 2
H
1406.
CD 2 C(CH 3 ) 3
Ph
CD 2 CH(CH 3 ) 2
H
1407.
CD 2 C(CH 3 ) 3
Ph
C(CH 3 ) 3
H
1408.
CD 2 C(CH 3 ) 3
Ph
CD 2 C(CH 3 ) 3
H
1409.
CD 2 C(CH 3 ) 3
Ph
CD 2 CH 2 CF 3
H
1410.
CD 2 C(CH 3 ) 3
Ph
CD 2 C(CH 3 ) 2 CF 3
H
1411.
CD 2 C(CH 3 ) 3
Ph
H
1412.
CD 2 C(CH 3 ) 3
Ph
H
1413.
CD 2 C(CH 3 ) 3
Ph
H
1414.
CD 2 C(CH 3 ) 3
Ph
H
1415.
CD 2 C(CH 3 ) 3
Ph
H
1416.
CD 2 C(CH 3 ) 3
Ph
H
1417.
Ph
CD 2 CH 3
H
1418.
Ph
CD(CH 3 ) 2
H
1419.
Ph
CD 2 (CH 3 ) 2
H
1420.
Ph
C(CH 3 ) 3
H
1421.
Ph
CD 2 C(CH 3 ) 3
H
1422.
Ph
H
1423.
Ph
H
1424.
Ph
H
1425.
Ph
H
1426.
Ph
H
1427.
Ph
H
1428.
Ph
CD 2 CH 3
H
1429.
Ph
CD(CH 3 ) 2
H
1430.
Ph
CD 2 CH(CH 3 ) 2
H
1431.
Ph
C(CH 3 ) 3
H
1432.
Ph
CD 2 C(CH 3 ) 3
H
1433.
Ph
H
1434.
Ph
H
1435.
Ph
H
1436.
Ph
H
1437.
Ph
H
1438.
Ph
H
1439.
Ph
CD 2 CH 3
H
1440.
Ph
CD(CH 3 ) 2
H
1441.
Ph
CD 2 CH(CH 3 ) 2
H
1442.
Ph
C(CH 3 ) 3
H
1443.
Ph
CD 2 C(CH 3 ) 3
H
1444.
Ph
H
1445.
Ph
H
1446.
Ph
H
1447.
Ph
H
1448.
Ph
H
1449.
Ph
H
1450.
Ph
CD 2 CH 3
H
1451.
Ph
CD(CH 3 ) 2
H
1452.
Ph
CD 2 CH(CH 3 ) 2
H
1453.
Ph
C(CH 3 ) 3
H
1454.
Ph
CD 2 C(CH 3 ) 3
H
1455.
Ph
H
1456.
Ph
H
1457.
Ph
H
1458.
Ph
H
1459.
Ph
H
1460.
Ph
H
1461.
Ph
CD 2 CH 3
H
1462.
Ph
CD(CH 3 ) 2
H
1463.
Ph
CD 2 CH(CH 3 ) 2
H
1464.
Ph
C(CH 3 ) 3
H
1465.
Ph
CD 2 C(CH 3 ) 3
H
1466.
Ph
H
1467.
Ph
H
1468.
Ph
H
1469.
Ph
H
1470.
Ph
H
1471.
Ph
H.
12. The compound of claim 11 , wherein the compound is selected from the group consisting of Compound A-x having the formula Ir(L Ai )(L Bj ) 2 or Compound B-x having the formula Ir(L Ai ) 2 (L Bj );
wherein x is an integer defined by x=1471i+j−1471, wherein i is an integer from 1 to 371, j is an integer from 1 to 1471, and
wherein L A1 to L A371 have the following formula:
wherein R, R 1 , R 2 , R 3 , R 4 , R 5 , and R 6 are defined as provided below:
L Ai ,
where i is
R 1
R
R 2
R 3
R 4
R 5
R 6
1.
H
R A1
H
H
H
H
H
2.
H
R A2
H
H
H
H
H
3.
H
R A3
H
H
H
H
H
4.
H
R A4
H
H
H
H
H
5.
H
R A5
H
H
H
H
H
6.
H
R A6
H
H
H
H
H
7.
H
R A7
H
H
H
H
H
8.
H
R A8
H
H
H
H
H
9.
H
R A9
H
H
H
H
H
10.
H
R A10
H
H
H
H
H
11.
H
R A11
H
H
H
H
H
12.
H
R A12
H
H
H
H
H
13.
H
R A13
H
H
H
H
H
14.
H
R A14
H
H
H
H
H
15.
H
R A15
H
H
H
H
H
16.
H
R A16
H
H
H
H
H
17.
H
R A17
H
H
H
H
H
18.
H
R A18
H
H
H
H
H
19.
H
R A19
H
H
H
H
H
20.
H
R A20
H
H
H
H
H
21.
H
R A21
H
H
H
H
H
22.
H
R A22
H
H
H
H
H
23.
H
R A23
H
H
H
H
H
24.
H
R A24
H
H
H
H
H
25.
H
R A25
H
H
H
H
H
26.
H
R A26
H
H
H
H
H
27.
H
R A27
H
H
H
H
H
28.
H
R A28
H
H
H
H
H
29.
H
R A29
H
H
H
H
H
30.
H
R A30
H
H
H
H
H
31.
H
R A31
H
H
H
H
H
32.
H
R A32
H
H
H
H
H
33.
H
R A33
H
H
H
H
H
34.
H
R A34
H
H
H
H
H
35.
H
R A35
H
H
H
H
H
36.
H
R A36
H
H
H
H
H
37.
H
R A37
H
H
H
H
H
38.
H
R A38
H
H
H
H
H
39.
H
R A39
H
H
H
H
H
40.
H
R A40
H
H
H
H
H
41.
H
R A41
H
H
H
H
H
42.
H
R A42
H
H
H
H
H
43.
H
R A43
H
H
H
H
H
44.
H
R A44
H
H
H
H
H
45.
H
R A45
H
H
H
H
H
46.
H
R A46
H
H
H
H
H
47.
H
R A47
H
H
H
H
H
48.
H
R A48
H
H
H
H
H
49.
H
R A49
H
H
H
H
H
50.
H
R A50
H
H
H
H
H
51.
H
R A51
H
H
H
H
H
52.
H
R A52
H
H
H
H
H
53.
H
R A53
H
H
H
H
H
54.
H
R A54
H
H
H
H
H
55.
H
R A55
H
H
H
H
H
56.
H
R A56
H
H
H
H
H
57.
H
R A57
H
H
H
H
H
58.
H
R A58
H
H
H
H
H
59.
H
R A59
H
H
H
H
H
60.
H
R A60
H
H
H
H
H
61.
H
R A61
H
H
H
H
H
62.
H
R A62
H
H
H
H
H
63.
H
R A63
H
H
H
H
H
64.
H
R A64
H
H
H
H
H
65.
H
R A65
H
H
H
H
H
66.
H
R A66
H
H
H
H
H
67.
H
R A67
H
H
H
H
H
68.
H
R A68
H
H
H
H
H
69.
H
R A69
H
H
H
H
H
70.
H
R A70
H
H
H
H
H
71.
H
R A71
H
H
H
H
H
72.
H
R A72
H
H
H
H
H
73.
H
R A73
H
H
H
H
H
74.
H
R A74
H
H
H
H
H
75.
H
R A75
H
H
H
H
H
76.
H
R A76
H
H
H
H
H
77.
H
R A77
H
H
H
H
H
78.
H
R A78
H
H
H
H
H
79.
H
R A79
H
H
H
H
H
80.
H
R A80
H
H
H
H
H
81.
H
R A81
H
H
H
H
H
82.
H
R A82
H
H
H
H
H
83.
H
R A83
H
H
H
H
H
84.
H
R A84
H
H
H
H
H
85.
H
R A85
H
H
H
H
H
86.
H
R A86
H
H
H
H
H
87.
H
R A87
H
H
H
H
H
88.
H
R A88
H
H
H
H
H
89.
H
R A89
H
H
H
H
H
90.
H
R A90
H
H
H
H
H
91.
H
R A91
H
H
H
H
H
92.
H
R A92
H
H
H
H
H
93.
H
R A93
H
H
H
H
H
94.
CD 3
R A1
H
H
H
H
H
95.
CD 3
R A2
H
H
H
H
H
96.
CD 3
R A3
H
H
H
H
H
97.
CD 3
R A4
H
H
H
H
H
98.
CD 3
R A5
H
H
H
H
H
99.
CD 3
R A6
H
H
H
H
H
100.
CD 3
R A7
H
H
H
H
H
101.
CD 3
R A8
H
H
H
H
H
102.
CD 3
R A9
H
H
H
H
H
103.
CD 3
R A10
H
H
H
H
H
104.
CD 3
R A11
H
H
H
H
H
105.
CD 3
R A12
H
H
H
H
H
106.
CD 3
R A13
H
H
H
H
H
107.
CD 3
R A14
H
H
H
H
H
108.
CD 3
R A15
H
H
H
H
H
109.
CD 3
R A16
H
H
H
H
H
110.
CD 3
R A17
H
H
H
H
H
111.
CD 3
R A18
H
H
H
H
H
112.
CD 3
R A19
H
H
H
H
H
113.
CD 3
R A20
H
H
H
H
H
114.
CD 3
R A21
H
H
H
H
H
115.
CD 3
R A22
H
H
H
H
H
116.
CD 3
R A23
H
H
H
H
H
117.
CD 3
R A24
H
H
H
H
H
118.
CD 3
R A25
H
H
H
H
H
119.
CD 3
R A26
H
H
H
H
H
120.
CD 3
R A27
H
H
H
H
H
121.
CD 3
R A28
H
H
H
H
H
122.
CD 3
R A29
H
H
H
H
H
123.
CD 3
R A30
H
H
H
H
H
124.
CD 3
R A31
H
H
H
H
H
125.
CD 3
R A32
H
H
H
H
H
126.
CD 3
R A33
H
H
H
H
H
127.
CD 3
R A34
H
H
H
H
H
128.
CD 3
R A35
H
H
H
H
H
129.
CD 3
R A36
H
H
H
H
H
130.
CD 3
R A37
H
H
H
H
H
131.
CD 3
R A38
H
H
H
H
H
132.
CD 3
R A39
H
H
H
H
H
133.
CD 3
R A40
H
H
H
H
H
134.
CD 3
R A41
H
H
H
H
H
135.
CD 3
R A42
H
H
H
H
H
136.
CD 3
R A43
H
H
H
H
H
137.
CD 3
R A44
H
H
H
H
H
138.
CD 3
R A45
H
H
H
H
H
139.
CD 3
R A46
H
H
H
H
H
140.
CD 3
R A47
H
H
H
H
H
141.
CD 3
R A48
H
H
H
H
H
142.
CD 3
R A49
H
H
H
H
H
143.
CD 3
R A50
H
H
H
H
H
144.
CD 3
R A51
H
H
H
H
H
145.
CD 3
R A52
H
H
H
H
H
146.
CD 3
R A53
H
H
H
H
H
147.
CD 3
R A54
H
H
H
H
H
148.
CD 3
R A55
H
H
H
H
H
149.
CD 3
R A56
H
H
H
H
H
150.
CD 3
R A57
H
H
H
H
H
151.
CD 3
R A58
H
H
H
H
H
152.
CD 3
R A59
H
H
H
H
H
153.
CD 3
R A60
H
H
H
H
H
154.
CD 3
R A61
H
H
H
H
H
155.
CD 3
R A62
H
H
H
H
H
156.
CD 3
R A63
H
H
H
H
H
157.
CD 3
R A64
H
H
H
H
H
158.
CD 3
R A65
H
H
H
H
H
159.
CD 3
R A66
H
H
H
H
H
160.
CD 3
R A67
H
H
H
H
H
161.
CD 3
R A68
H
H
H
H
H
162.
CD 3
R A69
H
H
H
H
H
163.
CD 3
R A70
H
H
H
H
H
164.
CD 3
R A71
H
H
H
H
H
165.
CD 3
R A72
H
H
H
H
H
166.
CD 3
R A73
H
H
H
H
H
167.
CD 3
R A74
H
H
H
H
H
168.
CD 3
R A75
H
H
H
H
H
169.
CD 3
R A76
H
H
H
H
H
170.
CD 3
R A77
H
H
H
H
H
171.
CD 3
R A78
H
H
H
H
H
172.
CD 3
R A79
H
H
H
H
H
173.
CD 3
R A80
H
H
H
H
H
174.
CD 3
R A81
H
H
H
H
H
175.
CD 3
R A82
H
H
H
H
H
176.
CD 3
R A83
H
H
H
H
H
177.
CD 3
R A84
H
H
H
H
H
178.
CD 3
R A85
H
H
H
H
H
179.
CD 3
R A86
H
H
H
H
H
180.
CD 3
R A87
H
H
H
H
H
181.
CD 3
R A88
H
H
H
H
H
182.
CD 3
R A89
H
H
H
H
H
183.
CD 3
R A90
H
H
H
H
H
184.
CD 3
R A91
H
H
H
H
H
185.
CD 3
R A92
H
H
H
H
H
186.
CD 3
R A93
H
H
H
H
H
187.
H
R A1
H
CD 3
H
H
H
188.
H
R A2
H
CD 3
H
H
H
189.
H
R A3
H
CD 3
H
H
H
190.
H
R A4
H
CD 3
H
H
H
191.
H
R A5
H
CD 3
H
H
H
192.
H
R A6
H
CD 3
H
H
H
193.
H
R A7
H
CD 3
H
H
H
194.
H
R A8
H
CD 3
H
H
H
195.
H
R A10
H
CD 3
H
H
H
196.
H
R A11
H
CD 3
H
H
H
197.
H
R A12
H
CD 3
H
H
H
198.
H
R A13
H
CD 3
H
H
H
199.
H
R A14
H
CD 3
H
H
H
200.
H
R A15
H
CD 3
H
H
H
201.
H
R A16
H
CD 3
H
H
H
202.
H
R A17
H
CD 3
H
H
H
203.
H
R A18
H
CD 3
H
H
H
204.
H
R A19
H
CD 3
H
H
H
205.
H
R A20
H
CD 3
H
H
H
206.
H
R A21
H
CD 3
H
H
H
207.
H
R A22
H
CD 3
H
H
H
208.
H
R A23
H
CD 3
H
H
H
209.
H
R A24
H
CD 3
H
H
H
210.
H
R A25
H
CD 3
H
H
H
211.
H
R A26
H
CD 3
H
H
H
212.
H
R A27
H
CD 3
H
H
H
213.
H
R A28
H
CD 3
H
H
H
214.
H
R A29
H
CD 3
H
H
H
215.
H
R A30
H
CD 3
H
H
H
216.
H
R A31
H
CD 3
H
H
H
217.
H
R A32
H
CD 3
H
H
H
218.
H
R A33
H
CD 3
H
H
H
219.
H
R A34
H
CD 3
H
H
H
220.
H
R A35
H
CD 3
H
H
H
221.
H
R A36
H
CD 3
H
H
H
222.
H
R A37
H
CD 3
H
H
H
223.
H
R A38
H
CD 3
H
H
H
224.
H
R A39
H
CD 3
H
H
H
225.
H
R A40
H
CD 3
H
H
H
226.
H
R A41
H
CD 3
H
H
H
227.
H
R A42
H
CD 3
H
H
H
228.
H
R A43
H
CD 3
H
H
H
229.
H
R A44
H
CD 3
H
H
H
230.
H
R A45
H
CD 3
H
H
H
231.
H
R A46
H
CD 3
H
H
H
232.
H
R A47
H
CD 3
H
H
H
233.
H
R A48
H
CD 3
H
H
H
234.
H
R A49
H
CD 3
H
H
H
235.
H
R A50
H
CD 3
H
H
H
236.
H
R A51
H
CD 3
H
H
H
237.
H
R A52
H
CD 3
H
H
H
238.
H
R A53
H
CD 3
H
H
H
239.
H
R A54
H
CD 3
H
H
H
240.
H
R A55
H
CD 3
H
H
H
241.
H
R A56
H
CD 3
H
H
H
242.
H
R A57
H
CD 3
H
H
H
243.
H
R A58
H
CD 3
H
H
H
244.
H
R A59
H
CD 3
H
H
H
245.
H
R A60
H
CD 3
H
H
H
246.
H
R A61
H
CD 3
H
H
H
247.
H
R A62
H
CD 3
H
H
H
248.
H
R A63
H
CD 3
H
H
H
249.
H
R A64
H
CD 3
H
H
H
250.
H
R A65
H
CD 3
H
H
H
251.
H
R A66
H
CD 3
H
H
H
252.
H
R A67
H
CD 3
H
H
H
253.
H
R A68
H
CD 3
H
H
H
254.
H
R A69
H
CD 3
H
H
H
255.
H
R A70
H
CD 3
H
H
H
256.
H
R A71
H
CD 3
H
H
H
257.
H
R A72
H
CD 3
H
H
H
258.
H
R A73
H
CD 3
H
H
H
259.
H
R A74
H
CD 3
H
H
H
260.
H
R A75
H
CD 3
H
H
H
261.
H
R A76
H
CD 3
H
H
H
262.
H
R A77
H
CD 3
H
H
H
263.
H
R A78
H
CD 3
H
H
H
264.
H
R A79
H
CD 3
H
H
H
265.
H
R A80
H
CD 3
H
H
H
266.
H
R A81
H
CD 3
H
H
H
267.
H
R A82
H
CD 3
H
H
H
268.
H
R A83
H
CD 3
H
H
H
269.
H
R A84
H
CD 3
H
H
H
270.
H
R A85
H
CD 3
H
H
H
271.
H
R A86
H
CD 3
H
H
H
272.
H
R A87
H
CD 3
H
H
H
273.
H
R A88
H
CD 3
H
H
H
274.
H
R A89
H
CD 3
H
H
H
275.
H
R A90
H
CD 3
H
H
H
276.
H
R A91
H
CD 3
H
H
H
277.
H
R A92
H
CD 3
H
H
H
278.
H
R A93
H
CD 3
H
H
H
279.
CD 3
R A1
H
CD 3
H
H
H
280.
CD 3
R A2
H
CD 3
H
H
H
281.
CD 3
R A3
H
CD 3
H
H
H
282.
CD 3
R A4
H
CD 3
H
H
H
283.
CD 3
R A5
H
CD 3
H
H
H
284.
CD 3
R A6
H
CD 3
H
H
H
285.
CD 3
R A7
H
CD 3
H
H
H
286.
CD 3
R A8
H
CD 3
H
H
H
287.
CD 3
R A9
H
CD 3
H
H
H
288.
CD 3
R A10
H
CD 3
H
H
H
289.
CD 3
R A11
H
CD 3
H
H
H
290.
CD 3
R A12
H
CD 3
H
H
H
291.
CD 3
R A13
H
CD 3
H
H
H
292.
CD 3
R A14
H
CD 3
H
H
H
293.
CD 3
R A15
H
CD 3
H
H
H
294.
CD 3
R A16
H
CD 3
H
H
H
295.
CD 3
R A17
H
CD 3
H
H
H
296.
CD 3
R A18
H
CD 3
H
H
H
297.
CD 3
R A19
H
CD 3
H
H
H
298.
CD 3
R A20
H
CD 3
H
H
H
299.
CD 3
R A21
H
CD 3
H
H
H
300.
CD 3
R A22
H
CD 3
H
H
H
301.
CD 3
R A23
H
CD 3
H
H
H
302.
CD 3
R A24
H
CD 3
H
H
H
303.
CD 3
R A25
H
CD 3
H
H
H
304.
CD 3
R A26
H
CD 3
H
H
H
305.
CD 3
R A27
H
CD 3
H
H
H
306.
CD 3
R A28
H
CD 3
H
H
H
307.
CD 3
R A29
H
CD 3
H
H
H
308.
CD 3
R A30
H
CD 3
H
H
H
309.
CD 3
R A31
H
CD 3
H
H
H
310.
CD 3
R A32
H
CD 3
H
H
H
311.
CD 3
R A33
H
CD 3
H
H
H
312.
CD 3
R A34
H
CD 3
H
H
H
313.
CD 3
R A35
H
CD 3
H
H
H
314.
CD 3
R A36
H
CD 3
H
H
H
315.
CD 3
R A37
H
CD 3
H
H
H
316.
CD 3
R A38
H
CD 3
H
H
H
317.
CD 3
R A39
H
CD 3
H
H
H
318.
CD 3
R A40
H
CD 3
H
H
H
319.
CD 3
R A41
H
CD 3
H
H
H
320.
CD 3
R A42
H
CD 3
H
H
H
321.
CD 3
R A43
H
CD 3
H
H
H
322.
CD 3
R A44
H
CD 3
H
H
H
323.
CD 3
R A45
H
CD 3
H
H
H
324.
CD 3
R A46
H
CD 3
H
H
H
325.
CD 3
R A47
H
CD 3
H
H
H
326.
CD 3
R A48
H
CD 3
H
H
H
327.
CD 3
R A49
H
CD 3
H
H
H
328.
CD 3
R A50
H
CD 3
H
H
H
329.
CD 3
R A51
H
CD 3
H
H
H
330.
CD 3
R A52
H
CD 3
H
H
H
331.
CD 3
R A53
H
CD 3
H
H
H
332.
CD 3
R A54
H
CD 3
H
H
H
333.
CD 3
R A55
H
CD 3
H
H
H
334.
CD 3
R A56
H
CD 3
H
H
H
335.
CD 3
R A57
H
CD 3
H
H
H
336.
CD 3
R A58
H
CD 3
H
H
H
337.
CD 3
R A59
H
CD 3
H
H
H
338.
CD 3
R A60
H
CD 3
H
H
H
339.
CD 3
R A61
H
CD 3
H
H
H
340.
CD 3
R A62
H
CD 3
H
H
H
341.
CD 3
R A63
H
CD 3
H
H
H
342.
CD 3
R A64
H
CD 3
H
H
H
343.
CD 3
R A65
H
CD 3
H
H
H
344.
CD 3
R A66
H
CD 3
H
H
H
345.
CD 3
R A67
H
CD 3
H
H
H
346.
CD 3
R A68
H
CD 3
H
H
H
347.
CD 3
R A69
H
CD 3
H
H
H
348.
CD 3
R A70
H
CD 3
H
H
H
349.
CD 3
R A71
H
CD 3
H
H
H
350.
CD 3
R A72
H
CD 3
H
H
H
351.
CD 3
R A73
H
CD 3
H
H
H
352.
CD 3
R A74
H
CD 3
H
H
H
353.
CD 3
R A75
H
CD 3
H
H
H
354.
CD 3
R A76
H
CD 3
H
H
H
355.
CD 3
R A77
H
CD 3
H
H
H
356.
CD 3
R A78
H
CD 3
H
H
H
357.
CD 3
R A79
H
CD 3
H
H
H
358.
CD 3
R A80
H
CD 3
H
H
H
359.
CD 3
R A81
H
CD 3
H
H
H
360.
CD 3
R A82
H
CD 3
H
H
H
361.
CD 3
R A83
H
CD 3
H
H
H
362.
CD 3
R A84
H
CD 3
H
H
H
363.
CD 3
R A85
H
CD 3
H
H
H
364.
CD 3
R A86
H
CD 3
H
H
H
365.
CD 3
R A87
H
CD 3
H
H
H
366.
CD 3
R A88
H
CD 3
H
H
H
367.
CD 3
R A89
H
CD 3
H
H
H
368.
CD 3
R A90
H
CD 3
H
H
H
369.
CD 3
R A91
H
CD 3
H
H
H
370.
CD 3
R A92
H
CD 3
H
H
H
371.
CD 3
R A93
H
CD 3
H
H
H.
13. An organic light emitting device (OLED) comprising:
an anode;
a cathode; and
an organic layer, disposed between the anode and the cathode, comprising a compound having the formula:
wherein R 1 , R 2 , R 3 , R 4 , and R 5 each independently represents mono, to a maximum possible number of substitutions, or no substitution;
wherein X is selected from the group consisting of BR′, NR′, PR′, O, S, Se, C═O, S═O, SO 2 , CR′R″, SiR′R″, and GeR′R″;
wherein R′, R″, R 1 , R 2 , R 3 , R 4 , and R 5 are independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof;
wherein any substitutions are optionally joined or fused into a ring;
wherein n is 1 or 2;
wherein R is selected from the group consisting of alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, partially or fully fluorinated variants thereof, partially or fully deuterated variants thereof, and combination thereof; and
wherein R has at least five carbon atoms.
14. The OLED of claim 13 , wherein R has at least six carbon atoms.
15. The OLED of claim 13 , wherein R has at least seven carbon atoms.
16. The OLED of claim 13 , wherein the organic layer further comprises a host, wherein host comprises at least one chemical group selected from the group consisting of triphenylene, carbazole, dibenzothiphene, dibenzofuran, dibenzoselenophene, azatriphenylene, azacarbazole, aza-dibenzothiophene, aza-dibenzofuran, and aza-dibenzoselenophene.
17. The OLED of claim 13 , wherein the organic layer further comprises a host, wherein the host is selected from the group consisting of:
and combinations thereof.
18. The OLED of claim 13 , wherein the organic layer further comprises a host, wherein the host comprises a metal complex.
19. A consumer product comprising an organic light-emitting device (OLED) comprising:
an anode;
a cathode; and
an organic layer, disposed between the anode and the cathode, comprising a compound having the formula:
wherein R 1 , R 2 , R 3 , R 4 , and R 5 each independently represents mono, to a maximum possible number of substitutions, or no substitution;
wherein X is selected from the group consisting of BR′, NR′, PR′, O, S, Se, C═O, S═O, SO 2 , CR′R″, SiR′R″, and GeR′R″;
wherein R′, R″, R 1 , R 2 , R 3 , R 4 , and R 5 are independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof;
wherein any substitutions are optionally joined or fused into a ring;
wherein n is 1 or 2;
wherein R is selected from the group consisting of alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, partially or fully fluorinated variants thereof, partially or fully deuterated variants thereof, and combination thereof; and
wherein R has at least five carbon atoms.
20. The consumer product of claim 19 , wherein the consumer product is one of a flat panel display, a curved display, a computer monitor, a medical monitor, OLEDs used in photodynamic therapy, near IR (NIR) OLEDs, a television, a billboard, a light for interior or exterior illumination and/or signaling, a heads-up display, a fully or partially transparent display, a flexible display, a rollable display, a foldable display, a stretchable display, a laser printer, a telephone, a cell phone, tablet, a phablet, a personal digital assistant (PDA), a wearable device, a laptop computer, a digital camera, a camcorder, a viewfinder, a micro-display that is less than 2 inches diagonal, a 3-D display, a virtual reality or augmented reality display, a vehicle, a video wall comprising multiple displays tiled together, a theater or stadium screen, or a sign.