IP Library › Granted Patent US 11,683,943
Granted Patent B2
US 11,683,943 · App. 17/125,126 · Granted Jun 20, 2023

Memory device with a plurality of metal chalcogenide layers

Inventors: Tsunehiro Ino (Fujisawa Kanagawa, JP); Yukihiro Nomura (Taito Tokyo, JP); Kazuhiko Yamamoto (Fujisawa Kanagawa, JP); Koji Usuda (Yokohama Kanagawa, JP)
Assignee: Kioxia Corporation
H10B63/80G11C13/0004G11C13/0007H10N70/231H10N70/8822H10N70/8825H10N70/8828G11C2213/76
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Quick Facts
Patent No.
US 11,683,943
App. No.
17/125,126
Granted
Jun 20, 2023
Kind
B2
Abstract

A memory device including a first conductive layer; a second conductive layer; a resistance change region provided between the first conductive layer and the second conductive layer; a first region provided between the resistance change region and the first conductive layer, the first region including a first element selected from the group consisting of niobium, vanadium, tantalum, and titanium, and a second element selected from the group consisting of oxygen, sulfur, selenium, and tellurium, the first region having a first atomic ratio of the first element to the second element; and a second region provided between the first region and the resistance change region, the second region including the first element and the second element, the second region having a second atomic ratio of the first element to the second element, the second atomic ratio being smaller than the first atomic ratio.

Claims (47)

1. A memory device comprising:

a first conductive layer;

a second conductive layer;

a resistance change region provided between the first conductive layer and the second conductive layer;

a first region provided between the resistance change region and the first conductive layer, the first region including a first element selected from the group consisting of niobium (Nb), vanadium (V), tantalum (Ta), and titanium (Ti), and a second element selected from the group consisting of oxygen (O), sulfur (S), selenium (Se), and tellurium (Te), the first region having a first atomic ratio of the first element to the second element; and

a second region provided between the first region and the resistance change region, the second region including the first element and the second element, the second region having a second atomic ratio of the first element to the second element, the second atomic ratio being smaller than the first atomic ratio.

2. The memory device according to claim 1 , further comprising a third region provided between the second region and the resistance change region, the third region including the first element and the second element, the third region having a third atomic ratio of the first element to the second element, the third atomic ratio being larger than the second atomic ratio.

3. The memory device according to claim 1 , wherein the second atomic ratio is equal to or less than 80% of the first atomic ratio.

4. The memory device according to claim 1 , further comprising a third conductive layer provided between the second region and the resistance change region.

5. The memory device according to claim 1 , wherein

the first region has a thickness equal to or less than 1 nm in a direction from the first conductive layer to the second conductive layer, and

the second region has a thickness equal to or less than 1 nm in the direction.

6. The memory device according to claim 1 , wherein the first conductive layer has an oriented structure.

7. A memory device comprising:

a first conductive layer;

a second conductive layer;

a resistance change region provided between the first conductive layer and the second conductive layer;

a first region provided between the resistance change region and the first conductive layer, the first region including a first substance selected from the group consisting of carbon, niobium sulfide, tantalum sulfide, titanium sulfide, niobium selenide, tantalum selenide, tantalum telluride, bismuth selenide, indium selenide, and gallium telluride;

a second region provided between the first region and the resistance change region, the second region including a second substance selected from the group consisting of molybdenum sulfide, tungsten sulfide, molybdenum selenide, tungsten selenide, molybdenum telluride, tungsten telluride, zirconium sulfide, zirconium selenide, hafnium sulfide, and hafnium selenide; and

a third region provided between the second region and the resistance change region, the third region including the first substance.

8. The memory device according to claim 7 , wherein

the first region has a thickness equal to or less than 1 nm in a direction from the first conductive layer to the second conductive layer, and

the second region has a thickness equal to or less than 1 nm in the direction.

9. The memory device according to claim 7 , wherein the first conductive layer has an oriented structure.

10. A memory device comprising:

a plurality of first wires;

a plurality of second wires intersecting with the first wires; and

a memory cell disposed in at least one of regions where the first wires intersect with the second wires, wherein

the memory cell includes:

a resistance change region provided between the first wire and the second wire;

a first region provided between the resistance change region and the first wire, the first region including a first element selected from the group consisting of niobium (Nb), vanadium (V), tantalum (Ta), and titanium (Ti), and a second element selected from the group consisting of oxygen (O), sulfur (S), selenium (Se), and tellurium (Te), the first region having a first atomic ratio of the first element to the second element; and

a second region provided between the first region and the resistance change region, the second region including the first element and the second element, the second region having a second atomic ratio of the first element to the second element, the second atomic ratio being smaller than the first atomic ratio.

11. The memory device according to claim 10 , wherein the memory cell includes a third region provided between the second region and the resistance change region, the third region including the first element and the second element, the third region having a third atomic ratio of the first element to the second element, the third atomic ratio being larger than the second atomic ratio.

12. The memory device according to claim 10 , wherein the second atomic ratio is equal to or less than 80% of the first atomic ratio.

13. The memory device according to claim 10 , wherein the memory cell further includes a conductive layer between the second region and the resistance change region.

14. The memory device according to claim 10 , wherein the first region has a thickness equal to or less than 1 nm in a direction from the first wire to the second wire, and

the second region has a thickness equal to or less than 1 nm in the direction.

15. A memory device comprising:

a first conductive layer;

a second conductive layer;

a resistance change region provided between the first conductive layer and the second conductive layer;

a first region provided between the resistance change region and the first conductive layer, the first region including a first substance selected from the group consisting of carbon, niobium sulfide, tantalum sulfide, titanium sulfide, niobium selenide, tantalum selenide, tantalum telluride, bismuth selenide, indium selenide, and gallium telluride;

a second region provided between the first region and the resistance change region, the second region including a second substance selected from the group consisting of molybdenum sulfide, tungsten sulfide, molybdenum selenide, tungsten selenide, molybdenum telluride, tungsten telluride, zirconium sulfide, zirconium selenide, hafnium sulfide, and hafnium selenide; and

a third conductive layer provided between the second region and the resistance change region,

wherein

the first region has a thickness equal to or less than 1 nm in a direction from the first conductive layer to the second conductive layer, and

the second region has a thickness equal to or less than 1 nm in the direction.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 11, 2021
From: INO, TSUNEHIRO; NOMURA, YUKIHIRO; YAMAMOTO, KAZUHIKO; USUDA, KOJI
To: KIOXIA CORPORATION
Reel/Frame 056205/0273 →
Priority Claims (1)
JP JP2020-049899 · Mar 19, 2020 · national
Continuity (1)
Related Publication 20210296400A1 · Sep 23, 2021