Electrochemical devices including porous layers
Electrochemical devices that include porous layers, and associated methods, are generally described. In certain cases, the electrochemical device includes a first layer (e.g., a porous coating containing nanoparticles) between an anode and a separator, and a second layer (e.g., another porous coating containing nanoparticles) between a cathode and the separator. The first layer and/or the second layer may have a relatively high porosity, even after the application of an applied pressure to the electrochemical device. The presence of the first layer and the second layer in the electrochemical device may mitigate the occurrence of certain problematic phenomena during cycling of the electrochemical device.
1. An electrochemical device, comprising:
an anode;
a cathode;
a separator between the anode and the cathode;
a first layer between the anode and the separator, the first layer comprising a first plurality of nanoparticles; and
a second layer between the cathode and the separator, the second layer comprising a second plurality of nanoparticles;
wherein:
at least some of the nanoparticles of the first plurality of nanoparticles are in the form of a branched or chain-like structure,
at least some of the nanoparticles of the second plurality of nanoparticles are in the form of a branched or chain-like structure, and
the first plurality of nanoparticles and/or the second plurality of nanoparticles comprise fumed metal oxide particles and/or fumed metalloid oxide particles.
2. The electrochemical device of claim 1 , wherein the first layer and/or the second layer has a porosity of at least 40% after experiencing an applied pressure of at least 12 kg/cm 2 for a period of 14 hours.
3. The electrochemical device of claim 1 , wherein the first layer and the second layer each have a porosity of at least 40%.
4. The electrochemical device of claim 1 , wherein the first layer and the second layer each have a porosity of at least 60%.
5. The electrochemical device of claim 1 , wherein the first layer and the second layer each have a porosity of at least 80%.
6. The electrochemical device of claim 1 , wherein the branched or chain-like structures of the first plurality of nanoparticles comprise aggregates and/or agglomerates of the nanoparticles of the first plurality of nanoparticles and/or wherein the branched or chain-like structures of the second plurality of nanoparticles comprise aggregates and/or agglomerates of the nanoparticles of the second plurality of nanoparticles.
7. The electrochemical device of claim 1 , wherein the branched or chain-like structures of the first plurality of nanoparticles and/or second plurality of nanoparticles have an average length of at least 200 nm and less than or equal to 20 μm.
8. The electrochemical device of claim 1 , wherein the branched or chain-like structures of the first plurality of nanoparticles and/or second plurality of nanoparticles have an aspect ratio of at least 2 and less than or equal to 20.
9. The electrochemical device of claim 1 , wherein the first plurality of nanoparticles and/or second plurality of nanoparticles comprise Si, Al, Ti, Bi, Zn, Cr, Fe, Ge, Ni, Mo, Sn, Zr, V, W, Cu, Mn, Ce, Sb, or a combination thereof.
10. The electrochemical device of claim 1 , wherein the first plurality of nanoparticles and/or the second plurality of nanoparticles comprise SiO 2 .
11. The electrochemical device of claim 1 , wherein the first plurality of nanoparticles and/or the second plurality of nanoparticles comprise aluminum metal.
12. The electrochemical device of claim 1 , wherein the first plurality of nanoparticles and/or the second plurality of nanoparticles comprise a mixture of fumed metal oxide particles and/or fumed metalloid oxide particles and metallic nanoparticles.
13. The electrochemical device of claim 1 , wherein the first plurality of nanoparticles and/or the second plurality of nanoparticles comprise a mixture of fumed silica particles and aluminum nanoparticles.
14. The electrochemical device of claim 1 , wherein the thickness of the first layer and/or the second layer is greater than or equal to 100 nm and less than or equal to 20 μm.
15. The electrochemical device of claim 1 , wherein the first plurality of nanoparticles and/or the second plurality of nanoparticles have a mean maximum cross-sectional dimension of greater than or equal to 20 nm and less than or equal to 1,000 nm.
16. The electrochemical device of claim 1 , wherein the first plurality of nanoparticles and the second plurality of nanoparticles comprise fumed metal oxide particles and/or fumed metalloid oxide particles.
17. An electrochemical device, comprising:
an anode;
a cathode;
a separator between the anode and the cathode;
a first layer between the anode and the separator, the first layer comprising a first plurality of nanoparticles; and
a second layer between the cathode and the separator, the second layer comprising a second plurality of nanoparticles;
wherein:
the first layer and the second layer are porous,
at least some of the nanoparticles of the first plurality of nanoparticles are in the form of a branched or chain-like structure,
at least some of the nanoparticles of the second plurality of nanoparticles are in the form of a branched or chain-like structure, and
the first plurality of nanoparticles and/or the second plurality of nanoparticles are metallic.