Fuel cell cathode catalyst
A fuel cell catalyst for oxygen reduction reactions including Pt—Ni—Cu nanoparticles supported on nitrogen-doped mesoporous carbon (MPC) having enhanced activity and durability, and method of making said catalyst. The catalyst is synthesized by employing a solid state chemistry method, which involves thermally pretreating a N-doped MPC to remove moisture from the surface; impregnation of metal precursors on the N-doped MPC under vacuum condition; and reducing the metal precursors in a stream of CO and H 2 gas mixture.
1. A method of making a catalyst comprising platinum alloy nanoparticles supported on nitrogen-doped mesoporous carbon (MPC), said method comprising:
thermally pretreating a nitrogen-doped MPC support material to remove moisture;
evacuating the pretreated nitrogen-doped MPC support to further remove air from pores in the support;
impregnating metal precursors comprising platinum, nickel, and copper onto the pretreated nitrogen-doped MPC under vacuum condition to obtain a precursor-impregnated nitrogen-doped MPC support material;
heating the precursor-impregnated nitrogen-doped MPC support material to a functional temperature in the range of from 150° C. to 300° C.; and
delivering a functional gas comprising a gas mixture which comprises H 2 and CO to the precursor-impregnated nitrogen-doped MPC support material, the metal precursors reacting with the functional gas to form shaped platinum alloy nanoparticles supported on nitrogen-doped MPC.
2. The method according to claim 1 , wherein thermally pretreating comprises heating the mesoporous carbon material to a first temperature in an atmosphere comprising air, Ar, N 2 , O 2 or combinations thereof.
3. The method according to claim 1 , wherein the thermally pretreating comprises heating the mesoporous carbon material in air.
4. The method according to claim 1 , comprising delivering the functional gas at a partial pressure ratio of from 0:100 to 1:1 of H 2 to CO, and a volumetric flow rate of from 10 sccm to 1000 sccm.
5. The method according to claim 1 , further comprising maintaining the functional temperature for a period of from 0 hours to 5 hours in the presence of a functional gas.
6. The method according to claim 1 , wherein said nanoparticles have an octahedral or rhombic shape and a particle size from about 8-10 nm.
7. The method according to claim 1 , wherein the catalyst comprising platinum alloy nanoparticles supported on a nitrogen-doped mesoporous carbon material has enhanced ORR activity and durability.
8. A method for forming platinum alloy particles into nitrogen-doped mesoporous carbon, comprising:
in a chamber removing moisture from a nitrogen-doped mesoporous carbon material, the nitrogen-doped mesoporous carbon material having one or more pores;
evacuating the nitrogen-doped mesoporous carbon material to further remove air from the pores
applying a vacuum to the chamber;
delivering precursors comprising platinum, nickel, and copper to obtain a precursor-impregnated nitrogen-doped mesoporous carbon material;
purging the chamber using a purge gas;
heating the precursor-impregnated nitrogen-doped mesoporous carbon material to a functional temperature in the range of from 150° C. to 300° C.; and
delivering a functional gas comprising a gas mixture which comprises H 2 and CO to the precursor-impregnated nitrogen-doped mesoporous carbon material, the precursors reacting with the functional gas to form shaped platinum alloy nanoparticles within the one or more pores of the nitrogen-doped mesoporous carbon material.
9. The method according to claim 8 , wherein heating of the precursor-impregnated nitrogen-doped mesoporous carbon material is at a ramping rate of 15° C./min. to 200° C.
10. The method according to claim 9 , further comprising maintaining at 200° C. for 1 hour in H 2 /CO (5/120 cm 3 /min).