Iron-based alloy powder and molded article using same
Disclosed are a composition for an Fe-based alloy and an Fe-based amorphous alloy powder, whereby a high-purity amorphous structure is maintained even after coating by thermal spraying or the like, but also various physical properties are improved. The composition for the Fe-based alloy includes iron, chromium, and molybdenum, wherein per 100 parts by weight of the iron, the chromium is contained in an amount of 25.4 to 55.3 parts by weight, the molybdenum is contained in an amount of 35.6 to 84.2 parts by weight, and at least one of carbon and boron is further contained.
1. A composition for an Fe-based alloy, the composition comprising:
iron;
chromium; and
molybdenum,
wherein per 100 parts by weight of the iron,
the chromium is contained in an amount of 25.4 to 55.3 parts by weight,
the molybdenum is contained in an amount of 35.6 to 84.2 parts by weight,
at least one of carbon and boron is contained in an amount of 3.4 to 23.7 parts by weight, and
at least one of additional components selected from the group consisting of tungsten, cobalt, yttrium, manganese, silicon, aluminum, niobium, zirconium, phosphorus, nickel, scandium, and a mixture thereof is contained in an amount of less than 1.125 parts by weight.
2. The composition of claim 1 , wherein an alloy that is formed by melting the composition and then cooling the melted composition from a melting point to a glass transition temperature at a cooling rate of 101 to 104 (degree/sec) has an amorphous phase in a proportion of 90 to 100%.
3. The composition of claim 1 , wherein the alloy prepared from the composition is one selected from the group consisting of powder, ribbon, sheet, wire, and three-dimensional shaped body.
4. An Fe-based amorphous alloy powder, comprising:
iron;
chromium; and
molybdenum,
wherein per 100 parts by weight of the iron,
the chromium is contained in an amount of 25.4 to 55.3 parts by weight,
the molybdenum is contained in an amount of 35.6 to 84.2 parts by weight,
at least one of carbon and boron is contained in an amount of 3.4 to 23.7 parts by weight, and
at least one of additional components selected from the group consisting of tungsten, cobalt, yttrium, manganese, silicon, aluminum, niobium, zirconium, phosphorus, nickel, scandium, and a mixture thereof is contained in an amount of less than 1.125 parts by weight.
5. The Fe-based amorphous alloy powder of claim 4 , wherein the alloy powder has an amorphous phase in a proportion of 90 to 100% by volume.
6. The Fe-based amorphous alloy powder of claim 5 , wherein the alloy powder is prepared by cooling a composition for an alloy from a melting point to a glass transition temperature at a cooling rate of 101 to 104 (degree/sec).
7. The Fe-based amorphous alloy powder of claim 6 , wherein the alloy powder has an average particle size of 10 to 100 μm.
8. The Fe-based amorphous alloy powder of claim 7 , wherein the alloy powder is prepared by atomizing.
9. The Fe-based amorphous alloy powder of claim 4 , wherein the alloy powder is used as a material in at least one process selected from the group consisting of a coating forming process, a metal powder injection molding (MIM) process, a three-dimensional (3D) printing process, and a powder metallurgy (P/M) process.
10. The Fe-based amorphous alloy powder of claim 4 , wherein when a shaped body is manufactured by thermal spraying using the alloy powder, a proportion of an amorphous phase in the shaped body is 90 to 100% by volume.
11. The Fe-based amorphous alloy powder of claim 10 , wherein when the thermal spraying is performed using a high velocity oxygen fuel (HVOF) device under the following spraying conditions, the proportion of the amorphous phase in the manufactured shaped body is 95 to 100% by volume,
[Condition]
Gun type: Hybrid, Air cap: 2701, LPG flow: 160 SCFH, LPG pressure: 90 PSI, Oxygen flow: 550 SCFH, Oxygen pressure: 150 PSI, Air flow: 900 SCFH, Air pressure: 100 PSI, Nitrogen flow: 28 SCFH, Nitrogen pressure: 150 PSI, Gun speed: 100 m/min, Gun pitch: 3.0 mm, Feeder rate 45 g/min, Stand-off distance: 250 mm.
12. The Fe-based amorphous alloy powder of claim 11 , wherein the shaped body has a Vickers hardness of 700 to 1,200 Hv (0.2), and a friction coefficient of 0.001 to 0.08 μm at a load of 100 N, or 0.06 to 0.12 μm at a load of 1,000 N.
13. The Fe-based amorphous alloy powder of claim 4 , wherein proportion (a) of an amorphous phase in an alloy powder and proportion (b) of the amorphous phase in an alloy fulfill an equation of 0.9≤b/a≤1, the alloy powder being prepared by melting a composition for an alloy containing iron, chromium, and molybdenum and further containing at least one of carbon and boron and then cooling the melted composition from a melting point to a glass transition temperature at a cooling rate of 101 to 104 (degree/sec), and the alloy being prepared by re-melting the alloy powder and cooling the re-melted alloy powder from a melting point to a glass transition temperature at the cooling rate of 101 to 104 (degree/sec).
14. An Fe-based alloy shaped body that is manufactured by 3D printing using the alloy powder of claim 4 ,
wherein a portion of an amorphous phase of an alloy in the shaped body is 90 to 100%.
15. A shaped body that is manufactured by sintering using the alloy powder of claim 4 ,
wherein the shaped body contains boride or carbide, or both the boride and carbide, and the boride and carbide are contained in a total amount of 3 to 8 parts by weight per 100 parts by weight of the iron.