Chemically strengthened glass and production method therefor
The purpose of the present invention is to provide a chemically strengthened glass having excellent transparency and strength and being scratch resistant. The present invention pertains to a chemically strengthened glass that: has a compressive stress layer on the surface thereof; has a visible light transmittance of at least 70% when the thickness thereof is converted to 0.8 mm; has a surface compressive stress of at least 600 MPa; has a compressive stress depth of at least 80 μm; and contains a β-spodumene.
1. A chemically strengthened glass, comprising by mass % on an oxide basis:
58 to 70% of SiO 2 ;
15 to 30% of Al 2 O 3 ;
2 to 10% of Li 2 O;
0 to 5% of Na 2 O;
0 to 2% of K 2 O;
1 to 6% of SnO 2 ;
0.5 to 6% of ZrO 2 ; and
0 to 6% of P 2 O 5 ,
wherein
a total content of Na 2 O and K 2 O is from 2% to 5%:
a total content of SnO 2 and ZrO 2 is 7% or higher and 12% or lower; and
a content ratio of SnO 2 /(SnO 2 +ZrO 2 ) is 0.45 or more and 0.7 or less,
wherein
the chemically strengthened glass does not comprise As 2 O 3 ,
the chemically strengthened glass has a compressive stress layer in a surface thereof,
wherein:
the chemically strengthened glass is a crystallized glass having precipitated crystals of β-spodumene as a main crystal; and
the surface of the chemically strengthened glass has an X-ray diffraction pattern different from an X-ray diffraction pattern of a crystal of an inside of the chemically strengthened glass.
2. The chemically strengthened glass according to claim 1 , wherein the surface of the chemically strengthened glass has a position of an X-ray diffraction peak shifted to a lower angle side with respect to a position of an X-ray diffraction peak of the crystal of the inside of the chemically strengthened glass.
3. The chemically strengthened glass according to claim 1 , wherein the surface of the chemically strengthened glass has the X-ray diffraction peak lower than the X-ray diffraction peak of the crystal of the inside of the chemically strengthened glass.
4. The chemically strengthened glass according to claim 1 , wherein:
a visible light transmittance of the glass having a thickness of 0.8 mm is 70% or higher;
a surface compressive stress is 600 MPa or more and a depth of the compressive stress layer is 80 μm or more.
5. The chemically strengthened glass according to claim 1 , wherein the content of SnO 2 is from 1.5 to 6%.
6. The chemically strengthened glass according to claim 1 , wherein a haze value of the glass having a thickness of 0.8 mm is 1.5% or lower.
7. The chemically strengthened glass according to claim 1 , having a maximum depth of 80 μm or more where a compressive stress value is 50 MPa or more.
8. The chemically strengthened glass according to claim 1 , having an average thermal expansion coefficient at 50° C. to 350° C. of 30×10 −7 /° C. or less.
9. The chemically strengthened glass according to claim 1 , having a Vickers hardness of 720 or more.
10. A method for manufacturing a chemically strengthened glass, the method comprising:
crystallizing an amorphous glass to form a crystallized glass having precipitated crystals of β-spodumene as a main crystal; and
causing an ion exchange between metal ions in a crystal of the crystallized glass and metal ions in a molten salt, which have larger ionic radii than ionic radii of the metal ions in the crystal, to obtain a chemically strengthened glass;
wherein the chemically strengthened glass, comprises by mass % on an oxide basis:
58 to 70% of SiO 2 ;
15 to 30% of Al 2 O 3 ;
2 to 10% of Li 2 O;
0 to 5% of Na 2 O;
0 to 2% of K 2 O;
1 to 6% of SnO 2 ;
0.5 to 6% of ZrO 2 ; and
0 to 6% of P 2 O 5 ,
wherein
a total content of Na 2 O and K 2 O is from 2% to 5%;
a total content of SnO 2 , and ZrO 2 is 7% or higher and 12% or lower; and
a content ratio of SnO 2 /(SnO 2 +ZrO 2 ) is 0.45 or more and 0.7 or less,
wherein the chemically strengthened glass does not comprise As 2 O 3 .
11. The method for manufacturing a chemically strengthened glass according to claim 10 , wherein:
the content of SnO 2 is from 1.5 to 6% of SnO 2 .
12. The chemically strengthened glass according is claim 1 , wherein an average particle size of the precipitated crystals is 300 nm or less.