Method for reducing carbon dioxide to manufacture multi-carbon hydrocarbon compound
A method for reducing carbon dioxide to manufacture a multi-carbon hydrocarbon compound includes steps as follows. A reduction reaction with separation and purification system is provided, which includes a carbon dioxide absorption tower, a reactor, a gas-liquid separation device, a liquid-phase purification device and a gas-phase purification device. An absorption step is performed, wherein a carbon dioxide gas is absorbed to form a mixed solution. A photocatalysis step is performed, wherein the mixed solution is reacted with a photocatalyst to form a carbon-based compound. A separation step is performed, wherein the carbon-based compound is separated to form a liquid-phase mixture and a gas-phase mixture. A liquid-phase purification step is performed, wherein the liquid-phase mixture is purified. A gas-phase purification step is performed, wherein the gas-phase mixture is separated and purified to form a multi-carbon hydrocarbon compound.
1. A method for reducing carbon dioxide to manufacture a multi-carbon hydrocarbon compound, comprising:
providing a reduction reaction with separation and purification system, comprising:
a carbon dioxide absorption tower having an absorbent;
a reactor communicated to a liquid outlet of the carbon dioxide absorption tower and having a photocatalyst;
a gas-liquid separation device communicated with the reactor, and the gas-liquid separation device connected with a liquid-phase tank and a gas-phase tank by a first flow path and a second flow path, respectively;
a liquid-phase purification device communicated with the liquid-phase tank; and
a gas-phase purification device comprising a washing tower and at least one separation column set, wherein the washing tower is communicated with the gas-phase tank, and the at least one separation column set is connected with the washing tower;
performing an absorption step, wherein a carbon dioxide gas is performed a carbon dioxide absorption treatment by the absorbent in the carbon dioxide absorption tower to form a mixed solution;
performing a photocatalysis step, wherein the mixed solution is reacted with the photocatalyst under an irradiation of a light source in the reactor to form a carbon-based compound;
performing a separation step, wherein the carbon-based compound is separated by the gas-liquid separation device to form a liquid-phase mixture and a gas-phase mixture, which are stored in the liquid-phase tank and the gas-phase tank, respectively;
performing a liquid-phase purification step, wherein the liquid-phase mixture is filtered and dried in the liquid-phase purification device to purify the liquid-phase mixture; and
performing a gas-phase purification step, wherein the gas-phase mixture is washed by the washing tower, and separated and purified the gas-phase mixture in the at least one separation column set by a pressure swing adsorption method in the gas-phase purification device to form a multi-carbon hydrocarbon compound.
2. The method for reducing carbon dioxide to manufacture the multi-carbon hydrocarbon compound of claim 1 , wherein the absorbent is a sodium hydroxide.
3. The method for reducing carbon dioxide to manufacture the multi-carbon hydrocarbon compound of claim 1 , wherein the photocatalyst comprises a selenium-based compound, a tellurium-based compound, an arsenic-based compound or a compound represented by formula (i), formula (ii), formula (iii), formula (iv) or formula (v):
M 1 A 1 X
formula (i),
M 2 BiO 2 X
formula (ii),
BiOX/BiOY
formula (iii),
BiOX/BiOY/BiOZ
formula (iv),
M 3 A 2 O
formula (v);
wherein M 1 is bismuth, antimony, gallium or indium, M 2 is lead, calcium, strontium, barium, copper or iron, and M 3 is lithium, sodium, or potassium;
wherein A 1 is oxygen, sulfur, selenium or tellurium, and A 2 is titanium, vanadium, chromium, manganese, iron, cobalt, nickel, zirconium, niobium, tantalum, molybdenum or tungsten;
wherein X, Y, Z are fluorine, chlorine, bromine or iodine.
4. The method for reducing carbon dioxide to manufacture the multi-carbon hydrocarbon compound of claim 3 , wherein the photocatalyst further comprises a composite of the selenium-based compound, the tellurium-based compound, the arsenic-based compound or the compound represented by formula (i), formula (ii), formula (iii), formula (iv) or formula (v) with a two-dimensional structural material.
5. The method for reducing carbon dioxide to manufacture the multi-carbon hydrocarbon compound of claim 4 , wherein the two-dimensional structure material is a graphitic carbon nitride, a graphene oxide, a bismuth oxyhalide-based compound, a sulfur-doped graphitic carbon nitride, a carbon nanotube or a graphene.
6. The method for reducing carbon dioxide to manufacture the multi-carbon hydrocarbon compound of claim 1 , wherein a number of the at least one separation column set is three.
7. The method for reducing carbon dioxide to manufacture the multi-carbon hydrocarbon compound of claim 1 , wherein an adsorbent material contained in the at least one separation column set is a zeolite, a silica gel, an activated carbon, an activated oxidation aluminum or a 4 Å molecular sieve.
8. The method for reducing carbon dioxide to manufacture the multi-carbon hydrocarbon compound of claim 1 , wherein the at least one separation column set comprises an adsorption column and a desorption column.
9. The method for reducing carbon dioxide to manufacture the multi-carbon hydrocarbon compound of claim 1 , further comprising a detection step, wherein a detection device is connected to the gas-phase purification device to measure a production of the multi-carbon hydrocarbon compound.
10. The method for reducing carbon dioxide to manufacture the multi-carbon hydrocarbon compound of claim 9 , wherein the detection device is a gas chromatography.