IP Library › Granted Patent US 11,733,435
Granted Patent B2
US 11,733,435 · App. 16/822,367 · Granted Aug 22, 2023

Polarizing plate protective film, polarizing plate, and liquid crystal display device

Inventors: Nobutaka Fukagawa (Kanagawa, JP); Yu Naito (Kanagawa, JP); Hiroki Kuwahara (Kanagawa, JP); Daisuke Sasaki (Kanagawa, JP); Hidetomo Furuyama (Kanagawa, JP); Natsuru Chikushi (Kanagawa, JP)
Assignee: FUJIFILM Corporation
G02B1/14C08J5/18C08K5/3445G02F1/133528C08J2325/06C08J2345/00C09K2323/031
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Quick Facts
Patent No.
US 11,733,435
App. No.
16/822,367
Granted
Aug 22, 2023
Kind
B2
Abstract

Provided are a polarizing plate protective film including a resin and a coloring agent having an absorption maximum wavelength in a range of 560 to 620 nm or 460 to 520 nm in an amount of 0.1 parts by mass or more with respect to 100 parts by mass of the resin, in which a film thickness is 1 to 18 μm, and a moisture content is 0.5% by mass or less, a polarizing plate in which the protective film is used, and a liquid crystal display device in which the polarizing plate is used.

Claims (32)

1. A polarizing plate protective film comprising:

a resin; and

a coloring agent having an absorption maximum wavelength in a range of 560 to 620 nm or 460 to 520 nm in an amount of 0.1 parts by mass or more with respect to 100 parts by mass of the resin,

wherein a film thickness is 2 to 8 μm, and a moisture content is 0.5% by mass or less, and

wherein the coloring agent is a squarine-based coloring agent represented by General Formula (3)

wherein in General Formula (3), R 1 and R 2 each independently represent a hydrogen atom or a substituent, B 1 to B 4 each independently represent a carbon atom or a nitrogen atom, and R 3 and R 4 each independently represent a hydrogen atom or a substituent.

2. The polarizing plate protective film according to claim 1 ,

wherein the polarizing plate protective film contains an electron-donating quencher, and a HOMO energy level of the coloring agent and a HOMO energy level of the electron-donating quencher satisfy a relational expression [A-1] below,

E Hq −E Hd ≤0.40 eV  relational expression [A-1]:

here, E Hd and E Hq each represent values below,

E Hd : HOMO energy level of coloring agent

E Hq : HOMO energy level of electron-donating quencher.

3. The polarizing plate protective film according to claim 1 ,

wherein the polarizing plate protective film contains an electron-accepting quencher, and a LUMO energy level of the coloring agent and a LUMO energy level of the electron-accepting quencher satisfy a relational expression [B-1] below,

E Ld −E Lq ≤0 eV  relational expression [B-1]:

here, E Ld and E Lq each represent values below,

E Ld : LUMO energy level of coloring agent

E Lq : LUMO energy level of electron-accepting quencher.

4. The polarizing plate protective film according to claim 1 ,

wherein the resin satisfies a relational expression [C] below,

0.80 ≤fd ≤0.95  relational expression [C]:

here, an fd value is defined by a relational expression I below,

fd=δd /(δ d+δp+δh )  relational expression I:

in the relational expression I, δd, δp, and δh each represent a term corresponding to the London dispersion force, a term corresponding to the dipole-dipole force, and a term corresponding to the hydrogen bond force relative to a solubility parameter δt computed by the Hoy method.

5. The polarizing plate protective film according to claim 1 , wherein the resin includes a polystyrene resin.

6. The polarizing plate protective film according to claim 1 , wherein the resin includes a cyclic polyolefin resin.

7. A polarizing plate comprising:

the polarizing plate protective film according to claim 1 .

8. A liquid crystal display device comprising:

the polarizing plate according to claim 7 .

9. The liquid crystal display device according to claim 8 ,

wherein the polarizing plate protective film in the polarizing plate is disposed between a liquid crystal cell and a polarizer.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 18, 2020
From: FUKAGAWA, NOBUTAKA; NAITO, YU; KUWAHARA, HIROKI; SASAKI, DAISUKE; FURUYAMA, HIDETOMO; CHIKUSHI, NATSURU
To: FUJIFILM CORPORATION
Reel/Frame 052153/0194 →
Priority Claims (5)
JP 2017-192085 · Sep 29, 2017 · national
JP 2017-247933 · Dec 25, 2017 · national
JP 2018-035024 · Feb 28, 2018 · national
JP 2018-104900 · May 31, 2018 · national
JP 2018-122094 · Jun 27, 2018 · national
Continuity (2)
Continuation PCTJP2018036494 · Sep 28, 2018
Related Publication 20200217993A1 · Jul 9, 2020
Cited By (1)
US 12,571,950