Radioactive chemical waste treatment apparatus
The present invention relates to a radioactive chemical waste treatment apparatus including an adsorption unit including an radioactive chemical waste adsorption member for adsorbing and separating radioactive chemical wastes from radioactive chemical waste-containing fluid, and a regeneration unit which is in fluidic communication with the adsorption unit and is for regenerating the radioactive chemical waste adsorption member by desorbing the radioactive chemical wastes from the adsorption member with the radioactive chemical wastes adsorbed thereonto, and to a radioactive chemical waste treatment method including (A) adsorbing radioactive chemical wastes onto a radioactive chemical waste adsorption member and separating the radioactive chemical wastes from a radioactive chemical waste-containing fluid, and (B) desorbing the radioactive chemical wastes from the radioactive chemical waste adsorption member with the radioactive chemical wastes adsorbed thereonto, and regenerating the radioactive chemical waste adsorption member.
1. A radioactive chemical waste treatment apparatus comprising:
an adsorption unit comprising a radioactive chemical waste adsorption member for adsorbing and separating radioactive chemical wastes from a radioactive chemical waste-containing fluid; and
a regeneration unit which is in fluidic communication with the adsorption unit and is for regenerating the radioactive chemical waste adsorption member by desorbing the radioactive chemical wastes from the adsorption member with the radioactive chemical wastes adsorbed thereonto,
wherein the radioactive chemical wastes comprise radioactive iodine,
the radioactive iodine comprises at least one selected from the group consisting of I − , I 2 and CH 3 I,
wherein the radioactive chemical waste adsorption member comprises a support and an adsorbent, and
wherein the adsorbent comprises at least one selected from platinum (Pt), palladium (Pd), ruthenium (Ru), osmium (Os), rhodium (Rh), iridium (Ir), and an alloy thereof.
2. The radioactive chemical waste treatment apparatus of claim 1 , wherein
the adsorbent is mixed or dispersed in the support, or contained in at least a portion of the surface of the support.
3. The radioactive chemical waste treatment apparatus of claim 2 , wherein
the support has at least one shape selected from a mesh shape and a nanoparticle shape, and
the support comprises at least one selected from iron, magnetite, nickel, cobalt, an alloy thereof, and an oxide thereof.
4. The radioactive chemical waste treatment apparatus of claim 1 , wherein the radioactive chemical wastes further comprise radioactive cesium, and the adsorbent further comprises Prussian blue.
5. The radioactive chemical waste treatment apparatus of claim 1 , wherein the radioactive chemical waste adsorption member is sintered at 50° C. to 900° C. and is then washed and dealloyed with at least one solution selected from a Piranha solution, nitric acid, sulfuric acid, and hydrochloric acid.
6. The radioactive chemical waste treatment apparatus of claim 1 , further comprising a magnetic substrate for fixing the radioactive chemical waste adsorption member inside the adsorption unit.
7. The radioactive chemical waste treatment apparatus of claim 1 , wherein the regeneration unit comprises a desorption member for desorbing the radioactive chemical wastes from the radioactive chemical waste adsorption member with the radioactive chemical wastes adsorbed thereonto while electrochemically reacting with the radioactive chemical wastes.
8. The radioactive chemical waste treatment apparatus of claim 7 , wherein the desorption member comprises a three-electrode system with the radioactive chemical waste adsorption member serving as a working electrode.
9. The radioactive chemical waste treatment apparatus of claim 1 , wherein the regeneration unit further comprises a first separation membrane unit for preventing inflow of the radioactive chemical wastes desorbed from the radioactive chemical waste adsorption member in the adsorption unit.
10. The radioactive chemical waste treatment apparatus of claim 1 , wherein the adsorption unit further comprises a second separation membrane unit for preventing inflow of contaminants in the radioactive chemical waste-containing fluid.