Method for producing thermally conductive thin film using synthetic graphite powder
Disclosed is a method for producing a thermally conductive thin film for protecting elements and the like integrated inside an electronic device such as a smartphone from heat. A method for using synthetic graphite powder to produce a thin film that has excellent thermal conductivity compared to existing natural graphite thin films or metal thin films and can be produced at lower cost than existing synthetic graphite thin films obtained from polyimide or the like may be provided.
1. A process for preparing a thermally conductive thin film, which comprises:
(1) pretreating synthetic graphite powder under a pressurized or decompressed condition wherein the pretreatment is conducted as thermal treatment of the synthetic graphite powder at 500 to 3,000° C. under a pressurized condition of 100 to 2,000 bar or as thermal treatment of the synthetic graphite powder at 500 to 3,000° C. under a decompressed condition of 10 −2 to 10 −5 Torr;
(2) adding an intercalant to the pretreated synthetic graphite powder obtained in step (1);
(3) thermally treating the synthetic graphite powder to which the intercalant has been added; and
(4) rolling the thermally treated synthetic graphite powder obtained in step (3) to produce the thermally conductive thin film.
2. The process for preparing a thermally conductive thin film of claim 1 , wherein the synthetic graphite powder in step (1) are graphitized cokes powder, kish graphite powder, or mixed powder thereof.
3. The process for preparing a thermally conductive thin film of claim 1 , wherein the synthetic graphite powder in step (1) have a particle diameter of 50 to 200 μm.
4. The process for preparing a thermally conductive thin film of claim 1 , wherein the intercalant in step (2) comprises a first oxidizing agent selected from the group consisting of sulfuric acid, nitric acid, potassium chlorate, potassium nitrate, and a mixture thereof at a concentration of 40 to 60%.
5. The process for preparing a thermally conductive thin film of claim 4 , wherein the intercalant in step (2) further comprises a second oxidizing agent selected from the group consisting of perchloric acid, hydrogen peroxide, chromic acid, boric acid, and a mixture thereof, and the first oxidizing agent and the second oxidizing agent are comprised at a weight ratio of 1:100 to 50:100.
6. The process for preparing a thermally conductive thin film of claim 1 , wherein the thermal treatment of step (3) is carried out at a temperature of about 1,500 to 3,000° C.
7. The process for preparing a thermally conductive thin film of claim 1 , wherein the synthetic graphite powder thermally treated have a degree of expansion of 150 to 300%, and
the degree of expansion is defined as a percentage of the c-axis value after expansion with reference to the c-axis value before expansion in the graphite crystal structure.
8. The process for preparing a thermally conductive thin film of claim 1 , wherein the synthetic graphite powder in step (1) have a particle diameter of 50 to 200 μm;
the pretreatment of step (1) is carried out as the thermal treatment of the synthetic graphite powder at 500 to 3,000° C. under a decompressed condition of 10 −2 to 10 −5 Torr;
the intercalant in step (2) comprises a first oxidizing agent selected from the group consisting of sulfuric acid, nitric acid, potassium chlorate, potassium nitrate, and a mixture thereof at a concentration of 40 to 60%;
the thermal treatment of step (3) is carried out at a temperature of about 1,500 to 3,000° C.; and
the thermally conductive thin film has a thickness of 50 to 1,000 μm, a density of 1.5 to 2.0 g/cm 3 , and a thermal conductivity in the horizontal direction of 300 to 700 W/mK.