Method for manufacturing photoacoustic ultrasound generator with high laser-induced damage threshold and high-amplitude ultrasound generator manufactured using the method
A method for manufacturing a photoacoustic ultrasound generator includes forming an uncured prepolymer polydimethylsiloxane (PDMS) film on a substrate, spraying a solution of light-absorbing nano-particles onto a surface of the uncured PDMS film, and then permeating and diffusing the light-absorbing nano-particles into the uncured PDMS film; and curing the uncured PDMS film containing the light-absorbing nano-particles distributed therein to form a composite film of nano-particles and PDMS.
1. A method for manufacturing a photoacoustic ultrasound generator, the method comprising:
forming an uncured prepolymer polydimethylsiloxane (PDMS) film on a substrate;
spraying a solution of light-absorbing nano-particles onto a surface of the uncured PDMS film, and then permeating and diffusing the light-absorbing nano-particles into the uncured PDMS film; and
curing the uncured PDMS film containing the light-absorbing nano-particles distributed therein to form a composite film of nano-particles and PDMS.
2. The method of claim 1 , wherein the light-absorbing nano-particles permeated and diffused into the uncured PDMS film are dispersed such that a mean distance between the light-absorbing nano-particles in the uncured PDMS film is substantially equal to or larger than a thermal diffusion length during the temporal width of an irradiation laser pulse.
3. The method of claim 2 , wherein the PDMS composite film is obtained by dispersing the light-absorbing nano-particles in the uncured PDMS film such that the mean distance between the nano-particles is substantially equal to or larger than the thermal diffusion length, and the PDMS composite film has a laser-induced damage threshold that is higher than non-particle-PDMS composite films in which light-absorbing nano-particles are densely packed with a mean distance smaller than the thermal diffusion length.
4. The method of claim 2 , wherein the PDMS composite film is obtained by dispersing the light-absorbing nano-particles in the uncured PDMS film such that the mean distance between the nano-particles is substantially equal to or larger than the thermal diffusion length, and the PDMS composite film, in response to being irradiated with a laser pulse width of 5 to 20 ns, has a laser-induced damage threshold that exceeds 300 mJ/cm 2 .
5. The method of claim 1 , wherein the formation of the uncured PDMS film includes the application procedure of a solution of PDMS dissolved in a solvent onto the substrate using drop-casting or spin-coating methods.
6. The method of claim 1 , wherein the light-absorbing nano-particles comprise at least one nano-particle selected from the a-group consisting of metallic nano-particles, graphene flake, carbon nanotube (CNT), carbon nanofiber, and carbon nanosoot.
7. The method of claim 1 , wherein the method further comprises:
forming an additional PDMS coating layer by applying a PDMS solution on top of the PDMS composite film; and
curing the PDMS coating layer.