Lubricant composition for initial break-in, sliding member, and sliding member manufacturing method
Provided is an initial break-in lubricant composition capable of easily and economically reducing the coefficient of friction of a sliding portion. The initial break-in lubricant composition includes an organic dispersion medium and nanocarbon particles in a quantity from 0.1 to 2000 ppm by mass. The nanocarbon particles are preferably particles of one or more nanocarbon material(s) selected from the group consisting of: nanodiamonds, fullerenes, graphene oxide, nanographite, carbon nanotubes, carbon nanofilaments, onion-like carbon, diamond-like carbon, amorphous carbon, carbon black, carbon nanohorns, and carbon nanocoils.
1. An initial break-in lubricant composition comprising an organic dispersion medium, and a nanocarbon particle in a quantity from 0.1 to 500 ppm by mass, wherein the nanocarbon particle is a surface-modified nanodiamond particle, the surface of which is modified by at least one selected from a group consisting of silane compounds, a phosphonate ion, phosphonic acid residue, a surface-modifying group having a vinyl group at a terminal, a cation of a cationic surfactant, a group containing a polyglycerin chain, and a group containing a polyethylene glycol chain.
2. The initial break-in lubricant composition according to claim 1 , wherein the organic dispersion medium is one or more selected from the group consisting of: a polyol ester, a poly-α-olefin, a mineral oil, an alkylbenzene, and a polyalkylene glycol.
3. The initial break-in lubricant composition according to claim 1 , wherein an average dispersed particle size D50 of the nanocarbon particle is from 4 to 80 nm.
4. The initial break-in lubricant composition according to claim 1 , having a coefficient of friction of 0.14 or less after 200 m sliding when used as an initial break-in lubricant on an SUJ2 sliding surface, the friction coefficient as measured by Friction Test 1 as follows:
Friction Test 1: Using a ball-on-disk sliding friction testing apparatus including a disk having an SUJ2 sliding surface on its surface and a ball having an SUJ2 sliding surface on its surface, a coefficient of friction between the disk and the ball is measured when the ball is sliding 200 m under a load of 10 N at a speed of 50 mm/s with 1 mL of the initial break-in lubricant composition being applied dropwise.
5. The initial break-in lubricant composition according to claim 1 , having 0.90 to 1.10 as a ratio between a coefficient of friction after 400 m sliding when the initial break-in lubricant composition is used as an initial break-in lubricant on an SUJ2 sliding surface and a coefficient of friction after 750 m sliding when another lubricant is used, the ratio being [the former coefficient of friction]/[the latter coefficient of friction] as measured by Friction Test 2 as follows:
Friction Test 2: Using a ball-on-disk sliding friction testing apparatus including a disk having an SUJ2 sliding surface on its surface and a ball having an SUJ2 sliding surface on its surface, a coefficient of friction between the disk and the ball is measured when the ball is sliding 400 m under a load of 10 N at a speed of 50 mm/s with 1 mL of the initial break-in lubricant composition being applied dropwise, and after the initial break-in lubricant composition is removed, a coefficient of friction between the disk and the ball is measured when the ball is further sliding 750 m, a total of 1150 m, under a load of 10 N at a speed of 50 mm/s with 1 mL of a polyol ester being applied dropwise.
6. The initial break-in lubricant composition according to claim 1 , which has a haze value of 5 or less.
7. The initial break-in lubricant composition according to claim 1 , wherein an average dispersed particle size D50 of the nanocarbon particle is from 10 to 100 nm.