IP Library › Granted Patent US 11,749,803
Granted Patent B2
US 11,749,803 · App. 16/931,113 · Granted Sep 5, 2023

Cathode material and battery

Inventors: Tadaaki Matsumura (Shiga, JP); Izuru Sasaki (Kyoto, JP); Yuta Sugimoto (Hyogo, JP)
Assignee: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.
H01M4/62H01M4/131H01M4/366H01M4/505H01M4/525H01M10/0525H01M10/0562H01M50/431H01M2300/008
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Quick Facts
Patent No.
US 11,749,803
App. No.
16/931,113
Granted
Sep 5, 2023
Kind
B2
Abstract

Provided is a cathode material including a cathode active material; a coating layer which coats at least a part of a surface of the cathode active material, and which includes a first solid electrolyte material; and a second solid electrolyte material. The first solid electrolyte material includes Li, M, and X; however, does not include sulfur. M includes at least one element selected from the group consisting of metalloid elements and metal elements other than Li. X includes at least one element selected from the group consisting of Cl and Br.

Claims (19)

1. A cathode material, comprising:

particles of a cathode active material comprising a lithium nickel-cobalt-manganese oxide;

a coating layer comprising a first solid electrolyte material forming a coating surrounding a surface of the particles of the cathode active material; and

particles of a second solid electrolyte material,

wherein the first solid electrolyte material is represented by Li 2 MgX 4 , Li 2 FeX 4 , Li(Al a Ga b In c )X 4 , Li 3 (Al a Ga b In c )X 6 , where 0≤a≤1, 0≤b≤1, 0≤c≤1, a+b+c=1, or the following composition formula (1):

Li α M β X 6   Formula (1)

where 2.5≤α≤3,

1≤β≤1.1,

M includes at least one element selected from the group consisting of Mg, Al, Ca, Sc, Ti, Zn, Ga, Sr, Y, Zr, Nb, Sn, Ba, Hf, Ta, Bi, B, Si, Ge, As, Sb, and Te, and

X includes at least one element selected from the group consisting of Cl and Br,

wherein the second solid electrolyte material is represented by Li 3 YX′ 6 , Li 2 MgX′ 4 , Li 2 FeX′ 4 , Li(Al a′ Ga b′ In c′ )X′ 4 , Li 3 (Al a′ Ga b′ In c′ )X′ 6 , where 0≤a′≤1, 0≤b′≤1, 0≤c′≤1, a′+b′+c′=1, and X′ includes I and at least one element selected from the group consisting of Cl and Br, and

wherein the particles of the cathode active material and the particles of the second solid electrolyte material are separated by the coating formed by the first solid electrolyte material and are not in direct contact with each other.

2. The cathode material according to claim 1 , wherein M includes yttrium.

3. The cathode material according to claim 1 , wherein X′ includes Cl and Br.

4. A battery, comprising:

a cathode including the cathode material according to claim 1 ;

an anode; and

an electrolyte layer provided between the cathode and the anode,

wherein the electrolyte layer comprises at least one sulfide solid electrolyte material selected from the group consisting of Li 2 S—P 2 S 5 , Li 2 S—SiS 2 , Li 2 S—B 2 S 3 , Li 2 S—GeS 2 , Li 3.25 Ge 0.25 P 0.75 S 4 , and Li 10 GeP 2 S 12 .

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 19, 2020
From: MATSUMURA, TADAAKI; SASAKI, IZURU; SUGIMOTO, YUTA
To: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.
Reel/Frame 054087/0700 →
Priority Claims (3)
JP 2018-011533 · Jan 26, 2018 · national
JP 2018-011534 · Jan 26, 2018 · national
JP 2018-173451 · Sep 18, 2018 · national
Continuity (2)
Continuation PCTJP2018043358 · Nov 26, 2018
Related Publication 20200350626A1 · Nov 5, 2020
Cited By (2)
US 12,266,759 US 12,431,500