Battery module with filler-containing cured resin layers
A battery module and a method of manufacturing the same are disclosed herein. In some embodiments, a battery module includes a module case having an internal space formed by a top plate, a bottom plate and sidewalls of the module case, a plurality of battery cells disposed in the internal space, a first filler-containing cured resin layer in contact with both the top plate and the plurality of battery cells, and a second filler-containing cured resin layer in contact with both the bottom plate and the plurality of battery cells. The battery module can have excellent power relative to volume, while being manufactured in a simple process and at a low cost.
1. A battery module, comprising:
a module case having an internal space formed by a top plate, a bottom plate and sidewalls of the module case;
a plurality of battery cells disposed in the internal space;
a first filler-containing cured resin layer in contact with both the top plate and the plurality of battery cells; and
a second filler-containing cured resin layer in contact with both the bottom plate and the plurality of battery cells,
wherein thermal conductivities of the first and second filler-containing cured resin layers are different from each other,
wherein the first filler-containing cured resin layer is an adhesive layer attached to both the top plate and the plurality of battery cells, and
wherein the second filler-containing cured resin layer is an adhesive layer attached to both the bottom plate and the plurality of battery cells,
wherein the first or the second filler-containing cured resin layer comprises an urethane resin, the urethane resin comprising an polyol-derived unit and a polyisocyanate-derived unit and
wherein the polyol-derived unit is an amorphous polyol or a polyol having a melting point (Tm) of 20° C. or lower and has a molecular weight in a range from 300 to 2,000.
2. The battery module according to claim 1 , wherein the thermal conductivity of the first filler-containing cured resin layer is 1.0 W/mK or less, and the thermal conductivity of the second filler-containing resin layer is 1.5 W/mK or more.
3. The battery module according to claim 1 , wherein the first and second filler-containing cured resin layers have an insulation breakdown voltage of 10 kV/mm or more.
4. The battery module according to claim 1 , wherein the first and second filler-containing cured resin layers have adhesive force of 200 gf/10 mm or more.
5. The battery module according to claim 1 , wherein the first and second filler-containing cured resin layers comprise urethane resins.
6. The battery module according to claim 5 , wherein the polyol is an ester-based polyol.
7. The battery module according to claim 6 , wherein the ester-based polyol is represented by Formula 1 or 2 below.
wherein, X is a dicarboxylic acid-derived unit, Y is a polyol-derived unit, n is a number in a range of 2 to 10 and m is a number in a range of 1 to 10.
8. The battery module according to claim 7 , wherein the dicarboxylic acid-derived unit is one or more units selected from the group consisting of a phthalic acid-derived unit, an isophthalic acid-derived unit, a terephthalic acid-derived unit, a trimellitic acid-derived unit, a tetrahydrophthalic acid-derived unit, a hexahydrophthalic acid-derived unit, a tetrachlorophthalic acid-derived unit, an oxalic acid-derived unit, an adipic acid-derived unit, an azelaic acid-derived unit, a sebacic acid-derived unit, a succinic acid-derived unit, a malic acid-derived unit, a glutaric acid-derived unit, a malonic acid-derived unit, a pimelic acid-derived unit, a suberic acid-derived unit, a 2,2-dimethylsuccinic acid-derived unit, a 3,3-dimethylglutaric acid-derived unit, a 2,2-dimethylglutaric acid-derived unit, a maleic acid-derived unit, a fumaric acid-derived unit, an itaconic acid-derived unit and a fatty acid-derived unit.
9. The battery module according to according to claim 7 , wherein the polyol-derived unit Y is any one or two or more units selected from the group consisting of an ethylene glycol-derived unit, a propylene glycol-derived unit, a 1,2-butylene glycol-derived unit, a 2,3-butylene glycol-derived unit, a 1,3-propanediol-derived unit, a 1,3-butanediol-derived unit, a 1,4-butanediol unit, a 1,6-hexanediol-derived unit, a neopentyl glycol-derived unit, a 1,2-ethylhexyldiol-derived unit, a 1,5-pentanediol-derived unit, a 1,10-decanediol-derived unit, a 1,3-cyclohexanedimethanol-derived unit, a 1,4-cyclohexanedimethanol-derived unit, a glycerin-derived unit and a trimethylol propane-derived unit.
10. The battery module according to claim 1 , wherein the polyisocyanate-derived unit is an alicyclic polyisocyanate-derived unit, a carbodiimide-modified alicyclic polyisocyanate-derived unit, or an isocyanurate-modified alicyclic polyisocyanate-derived unit.
11. The battery module according to claim 1 , wherein the first filler-containing cured resin layer comprises fumed silica, clay, calcium carbonate, alumina, aluminum nitride (AlN), boron nitride (BN), silicon nitride, silicon carbide (SiC), beryllium oxide (BeO), or a carbon filler.
12. The battery module according to claim 11 , wherein the first filler-containing cured resin layer comprises the filler in an amount of 100 to 300 parts by weight relative to 100 parts by weight of a resin component of the first filler-containing cured resin layer.
13. The battery module according to claim 1 , wherein the second filler-containing cured resin layer comprises a thermally conductive filler which is ceramic particles or a carbon-based filler.
14. The battery module according to claim 13 , wherein the second filler-containing cured resin layer comprises the filler in an amount of 500 to 2,000 parts by weight relative to 100 parts by weight of a resin component of the second filler-containing cured resin layer.
15. The battery module according to claim 1 , wherein the first or second filler-containing cured resin layer comprises a thixotropic agent, a diluent, a dispersant, a surface treatment agent, a flame retardant or a coupling agent.
16. The battery module according to claim 1 , wherein the first or second filler-containing resin layer has a thickness in a range of 100 μm to 5 mm.
17. A method for manufacturing the battery module of claim 1 , comprising:
injecting a first resin composition through one or more injection holes in the top plate of the module case, the first resin composition for forming the first filler-containing resin layer;
injecting a second resin composition through one or more injection holes in the bottom plate of the module case, wherein the second resin composition for forming the second filler-containing resin layer; and
curing the first and second resin compositions to form first and second filler-containing cured resin layers, respectively.
18. A battery pack, comprising:
two or more battery modules of claim 1 electrically connected to each other.
19. An automobile, comprising:
one or more battery modules of claim 1 .