Electrode body, electrolytic capacitor provided with electrode body, and method for producing electrode body
Provided is an electrode body that exhibits a good cathode side capacitance, and an electrolytic capacitor provided with this electrode body. The electrode body used for a cathode of the electrolytic capacitor has a cathode foil and a carbon layer. The cathode foil is made of a valve acting metal, and an enlarged surface layer is formed on the surface thereof. The carbon layer is formed on the enlarged surface layer. The interface between the enlarged surface layer and the carbon layer has an uneven shape.
1. An electrode body used for a cathode of an electrolytic capacitor, comprising:
a cathode foil made of a valve acting metal, having an enlarged surface layer formed on a surface; and
a carbon layer formed on the enlarged surface layer,
wherein
an interface between the enlarged surface layer and the carbon layer has an uneven shape;
the enlarged surface layer is formed by digging a plurality of etching pits;
a diameter of the etching pit is 0.12 μm or more and 0.43 μm or less near a surface layer;
a depth of the etching pit is 1.5 μm or more and 5.0 μm or less;
in the uneven shape, a distance between both ends in a cross section obtained by cutting a convex region along a height direction is 1.5 μm or more and 8.0 μm or less; and
the uneven shape has the convex region height of 0.15 μm or more and 0.80 μm or less.
2. The electrode body according to claim 1 , wherein an unevenness depth of the uneven shape is 0.5 μm or more.
3. The electrode body according to claim 2 , wherein;
the carbon layer further enters the etching pit from an interface of the uneven shape.
4. The electrode body according to claim 2 , wherein
a ratio of an interface length Y to a range length X (Y/X×100) is 110% or more,
wherein the interface length Y is a length from an arbitrary start point to an arbitrary end point along the interface between the enlarged surface layer and the carbon layer, and is a length including the carbon layer entering the etching pit; and
the range length X is, among vectors connecting the start point and the end point at which the interface length Y is measured in a straight line, a length of a direction component orthogonal to the height direction of the uneven shape.
5. The electrode body according to claim 2 ,
wherein the uneven shape is compressed and deformed by pressing.
6. The electrode body according to claim 1 , wherein;
the carbon layer further enters the etching pit from an interface of the uneven shape.
7. The electrode body according to claim 6 ,
wherein the carbon layer penetrates the etching pit by an average of 0.5 μm or more in a depth direction.
8. The electrode body according to claim 7 ,
wherein the uneven shape is compressed and deformed by pressing.
9. The electrode body according to claim 6 ,
wherein the carbon layer penetrates the etching pit by an average of 0.7 μm or more in a depth direction.
10. The electrode body according to claim 6 , wherein
a ratio of an interface length Y to a range length X (Y/X×100) is 110% or more,
wherein the interface length Y is a length from an arbitrary start point to an arbitrary end point along the interface between the enlarged surface layer and the carbon layer, and is a length including the carbon layer entering the etching pit; and
the range length X is, among vectors connecting the start point and the end point at which the interface length Y is measured in a straight line, a length of a direction component orthogonal to the height direction of the uneven shape.
11. The electrode body according to claim 6 ,
wherein the uneven shape is compressed and deformed by pressing.
12. The electrode body according to claim 1 , wherein
a ratio of an interface length Y to a range length X (Y/X×100) is 110% or more,
wherein the interface length Y is a length from an arbitrary start point to an arbitrary end point along the interface between the enlarged surface layer and the carbon layer, and is a length including the carbon layer entering the etching pit; and
the range length X is, among vectors connecting the start point and the end point at which the interface length Y is measured in a straight line, a length of a direction component orthogonal to the height direction of the uneven shape.
13. The electrode body according to claim 12 ,
wherein the uneven shape is compressed and deformed by pressing.
14. The electrode body according to claim 1 ,
wherein the uneven shape is compressed and deformed by pressing.
15. The electrode body according to claim 1 ,
wherein the carbon layer contains a scaly carbon material and a spherical carbon material.
16. An electrolytic capacitor comprising the electrode body according to claim 1 on the cathode.
17. A method for manufacturing an electrode body used for a cathode of an electrolytic capacitor, comprising steps of:
forming a carbon layer on a cathode foil made of a valve acting metal and having an enlarged surface layer formed on a surface; and
pressing the cathode foil on which the carbon layer is formed;
wherein
an interface between the enlarged surface layer and the carbon layer has an uneven shape;
the enlarged surface layer is formed by digging a plurality of etching pits;
a diameter of the etching pit is 0.12 μm or more and 0.43 μm or less near a surface layer;
a depth of the etching pit is 1.5 μm or more and 5.0 μm or less;
in the uneven shape, a distance between both ends in a cross section obtained by cutting a convex region along a height direction is 1.5 μm or more and 8.0 μm or less; and
the uneven shape has the convex region height of 0.15 μm or more and 0.80 μm or less.
18. The method for manufacturing the electrode body according to claim 17 ,
wherein the cathode foil on which the carbon layer is formed is pressed with a press line pressure of 1.54 kNcm −1 or more.
19. The electrode body according to claim 17 ,
wherein the carbon layer is formed by applying a slurry containing scaly carbon and spherical carbon to a cathode foil and drying it.