IP Library › Granted Patent US 11,757,008
Granted Patent B2
US 11,757,008 · App. 16/969,794 · Granted Sep 12, 2023

Electronic device with 2-dimensional electron gas between polar-oriented rare-earth oxide layer grown over a semiconductor

Inventors: Rytis Dargis (Greensboro, NC); Andrew Clark (Mountain View, CA); Richard Hammond (Newport, GB); Rodney Pelzel (Bethlehem, PA); Michael Lebby (Apache Junction, AZ)
Assignee: IQE plc
H01L29/267H01L29/408H01L29/7787
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Quick Facts
Patent No.
US 11,757,008
App. No.
16/969,794
Granted
Sep 12, 2023
Kind
B2
Abstract

Layered structures described herein include electronic devices with 2-dimensional electron gas between polar-oriented cubic rare-earth oxide layers on a non-polar semiconductor. Layered structure includes a semiconductor device, comprising a III-N layer or rare-earth layer, a polar rare-earth oxide layer grown over the III-N layer or rare-earth layer, a gate terminal deposited or grown over the polar rare-earth oxide layer, a source terminal that is deposited or epitaxially grown over the layer, and a drain terminal that is deposited or grown over the layer.

Claims (65)

1. A layered structure, comprising:

a group III-nitride (III-N) layer, wherein the III-N layer has an orientation that is not polar; and

a polar rare-earth oxide layer grown over the III-N layer,

wherein the orientation of the III-N layer comprises an atomic arrangement such that a portion of rare-earth metal atoms of the polar rare-earth oxide layer are vertically aligned with nitrogen atoms of the III-N layer, and

wherein the orientation of the III-N layer comprises a <1-100> orientation or a <11-20> orientation.

2. The layered structure of claim 1 , wherein the orientation of the III-N layer is non-polar.

3. The layered structure of claim 1 , wherein the orientation of the III-N layer is semi-polar.

4. The layered structure of claim 1 , further comprising:

a rare-earth silicide layer grown over the polar rare-earth oxide layer.

5. The layered structure of claim 1 , further comprising:

an epitaxial metal layer epitaxially grown over the polar rare-earth oxide layer.

6. The layered structure of claim 1 , wherein the polar rare-earth oxide layer has at least a first portion of electrons that diffuse to an interface between the polar rare-earth oxide layer and the III-N layer or are transferred to the III-N layer to form an n-type 2-dimensional electron gas (2DEG) on the III-N layer.

7. The layered structure of claim 6 , wherein the III-N layer and the polar rare-earth oxide layer are selected to yield a conduction band offset between the III-N layer and the polar rare-earth oxide layer that is sufficient for electrons to diffuse from the polar rare-earth oxide layer into the III-N layer.

8. The layered structure of claim 1 , further comprising:

a group IV substrate; and

an epi-twist rare-earth oxide layer over the group IV substrate,

wherein the III-N layer is over the epi-twist rare-earth oxide layer.

9. The layered structure of claim 8 , further comprising:

an epitaxial metal layer between the epi-twist rare-earth oxide layer and the III-N layer.

10. The layered structure of claim 1 , wherein the III-N layer comprises gallium nitride.

11. A semiconductor device, comprising:

a group III-nitride (III-N) layer, wherein the III-N layer has an orientation that is not polar;

a polar rare-earth oxide layer grown over the III-N layer;

a gate terminal deposited or grown over the polar rare-earth oxide layer;

a source terminal that is deposited or epitaxially grown over the layer; and

a drain terminal that is deposited or grown over the layer,

wherein the orientation of the III-N layer comprises an atomic arrangement such that a portion of rare-earth metal atoms of the polar rare-earth oxide layer are vertically aligned with nitrogen atoms of the III-N layer, and

wherein the orientation of the III-N layer comprises a <1-100> orientation or a <11-20> orientation.

12. The semiconductor device of claim 11 , wherein the gate terminal comprises a rare-earth silicide or an epitaxial metal element.

13. The semiconductor device of claim 11 , further comprising:

a silicon dioxide layer between the polar rare-earth oxide layer and the gate terminal.

14. The semiconductor device of claim 11 , further comprising:

a silicon substrate; and

an epi-twist rare-earth oxide layer over the silicon substrate,

wherein the III-N layer is over the epi-twist rare-earth oxide layer.

15. The semiconductor device of claim 14 , wherein the III-N layer aligns with a first region on the epi-twist rare-earth oxide layer, and the layered structure further comprises:

a second III-N layer over a second region on the epi-twist rare-earth oxide layer, wherein the first region and the second region are non-overlapping;

a transparent electrode over a first sub-region of the second III-N layer; and

an electrode over a second sub-region of the III-N layer,

wherein the second III-N layer, the transparent electrode, and the electrode form a photonic device.

16. The semiconductor device of claim 15 , wherein the first region of the epi-twist rare-earth oxide layer and the second region of the epi-twist rare-earth oxide layer are discontinuous.

17. The semiconductor device of claim 16 , further comprising:

a silicon device integrated into the silicon substrate at a third region between the first region of the epi-twist rare-earth oxide layer and the second region of the epi-twist rare-earth oxide layer.

18. The semiconductor device of claim 17 , further comprising:

an element that comprises a rare-earth pnictide over the silicon substrate at the third region between the first region of the epi-twist rare-earth oxide layer and the second region of the epi-twist rare-earth oxide layer; and

a III-N device over the rare-earth pnictide element.

19. A layered structure, comprising:

a rare-earth-nitride (RE-N) layer, wherein the RE-N layer has an orientation that is not polar; and

a polar rare-earth oxide layer grown over the RE-N layer,

wherein the orientation of the RE-N layer comprises an atomic arrangement such that a portion of rare-earth metal atoms of the polar rare-earth oxide layer are vertically aligned with nitrogen atoms of the RE-N layer, and

wherein the orientation of the RE-N layer comprises a <1-100> orientation or a <11-20> orientation.

20. The layered structure of claim 19 , wherein the orientation of the RE-N layer is non-polar.

21. The layered structure of claim 19 , wherein the orientation of the RE-N layer is semi-polar.

22. The layered structure of claim 19 , further comprising:

a rare-earth silicide layer grown over the polar rare-earth oxide layer.

23. The layered structure of claim 19 , further comprising:

an epitaxial metal layer epitaxially grown over the polar rare-earth oxide layer.

24. The layered structure of claim 19 , wherein the polar rare-earth oxide layer has at least a first portion of electrons that diffuse to an interface between the polar rare-earth oxide layer and the RE-N layer or are transferred to the RE-N layer to form an n-type 2-dimensional electron gas (DEG) on the RE-N layer.

25. The layered structure of claim 24 , wherein the RE-N layer and the polar rare-earth oxide layer are selected to yield a conduction band offset between the RE-N layer and the polar rare-earth oxide layer that is sufficient for electrons to diffuse from the polar rare-earth oxide layer into the RE-N layer.

26. The layered structure of claim 19 , further comprising:

a group IV substrate; and

an epi-twist rare-earth oxide layer over the group IV substrate,

wherein the RE-N layer is over the epi-twist rare-earth oxide layer.

27. The layered structure of claim 26 , further comprising:

an epitaxial metal layer between the epi-twist rare-earth oxide layer and the RE-N layer.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 13, 2020
From: DARGIS, RYTIS; CLARK, ANDREW; HAMMOND, RICHARD; PELZEL, RODNEY; LEBBY, MICHAEL
To: IQE PLC
Reel/Frame 053491/0674 →
Continuity (2)
Provisional Application 62631163 · Feb 15, 2018
Related Publication 20210005720A1 · Jan 7, 2021