Binder aqueous solution including copolymer of (meth)acrylamide and alkoxyalkyl (meth)acrylate, slurry including the same, negative electrode, and lithium-ion battery
Provided are a binder aqueous solution for a lithium-ion battery, a slurry for a lithium-ion battery negative electrode, a negative electrode for a lithium-ion battery, and a lithium-ion battery. The binder aqueous solution for a lithium-ion battery contains a water-soluble poly(meth)acrylamide (A). The water-soluble poly(meth)acrylamide (A) is a polymer of a monomer group containing, with respect to 100 mol % of the monomer group, 30 mol % to 95 mol % of a (meth)acrylamide group-containing compound (a), and 5 mol % to 40 mol % of an alkoxyalkyl (meth)acrylate (b) represented by the following general formula (1), CH 2 ═C(R 1 )—CO—O—R 2 —O—R 3 (1) (in which R 1 is a hydrogen atom or a methyl group, R 2 is an alkylene group having 1 to 4 carbon atoms, R 3 is an alkyl group having 1 to 4 carbon atoms, and a total number of carbon atoms of the groups R 1 , R 2 and R 3 is 5 or less.)
1. A binder aqueous solution for a lithium-ion battery, containing:
a water-soluble poly(meth)acrylamide (A) being a polymer of a monomer group containing with respect to 100 mol % of the monomer group,
0.05 mol % to 0.10 mol % of (meth)allylsulfonic acid or a salt thereof,
30 mol % to 95 mol % of a (meth)acrylamide group-containing compound (a), and
an alkoxyalkyl (meth)acrylate (b) represented by general formula (1),
CH 2 ═C(R 1 )—CO—O—R 2 —O—R 3 (1)
wherein R 1 is a hydrogen atom or a methyl group, R 2 is an ethylene group, R 3 is a methyl group, and
wherein a content of the alkoxyalkyl (meth)acrylate (b) represented by general formula (1) is 20% by mass to 60% by mass with respect to 100% by mass of the monomer group.
2. A slurry for a lithium-ion battery negative electrode, containing the binder aqueous solution for a lithium-ion battery according to claim 1 and a negative electrode active material.
3. A negative electrode for a lithium-ion battery, obtained by applying the slurry for a lithium-ion battery negative electrode according to claim 2 to a current collector, and drying and curing the slurry.
4. A lithium-ion battery, comprising the negative electrode for a lithium-ion battery according to claim 3 .