Organic electroluminescent materials and devices
A compound comprising a first ligand L A having a Formula selected from: is disclosed. In the Formulas rings B and C are 5-membered or 6-membered aromatic or heteroaromatic ring; Z 1 , Z 2 , X 1 , X 2 , X 3 , X 4 , X 5 , and X 6 are each C or N, but X 1 , X 2 , X 3 , or X 4 is C when it forms a direct bond to Z 2 ; Y is selected from CRR′, NR′, O, S, and Se; R, R′, R A , R B , R C , and R D are each selected from a variety of substituents; the ligand L A is coordinated to a metal M by the dashed lines, and optionally to other ligands. Organic light emitting devices and consumer products containing the compounds are also disclosed.
1. A compound comprising a first ligand L A having the Formula selected from the group consisting of:
wherein ring B and C are each independently a 5-membered or 6-membered aromatic or heteroaromatic ring;
wherein R A , R B , R C , and R D each independently represent mono to the maximum possible number of substituents, or no substituent;
wherein Z 1 and Z 2 are each independently selected from the group consisting of C and N;
wherein X 1 , X 2 , X 3 , X 4 , X 5 , and X 6 are each C;
wherein when the first ligand L A has the Formula of Formula IA, ring B is a 5-membered ring or ring B contains two nitrogen atoms;
wherein Y is selected from the group consisting of CRR′, NR′, O, S, SiRR′, and Se;
wherein when ring B is phenyl in Formula IB, Y is selected from the group consisting of NR′, S, SiRR′, and Se;
wherein R, R′, R A , R B , R C , and R D are each independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof;
wherein any two substituents are optionally joined or fused into a ring;
wherein the ligand L A is coordinated to a metal M by the dashed lines to form a 5-membered chelate ring;
wherein M does not form a direct bond to X 1 in Formula IB;
wherein M does not form a direct bond to X 4 in Formula IC;
wherein the metal M can be coordinated to other ligands; and
wherein the ligand L A is optionally linked with other ligands to comprise a tridentate, tetradentate, pentadentate or hexadentate ligand.
2. The compound of claim 1 , wherein M is selected from the group consisting of Ir, Rh, Re, Ru, Os, Pt, Pd, Au, and Cu.
3. The compound of claim 1 , wherein M is Ir or Pt.
4. The compound of claim 1 , wherein R, R′, R A , R B , R C , and R D are each independently selected from the group consisting of hydrogen, deuterium, fluorine, alkyl, cycloalkyl, heteroalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, aryl, heteroaryl, nitrile, isonitrile, sulfanyl, and combinations thereof.
5. The compound of claim 1 , wherein Y is O.
6. The compound of claim 1 , wherein ring C is a fused benzene ring.
7. The compound of claim 1 , wherein when the first ligand L A has the Formula of Formula IA, ring B is selected from the group consisting of pyrimidine, pyrazine, pyridazine, imidazole, pyrazole, triazole, pyrrole, oxazole, thiazole, and imidazole derived carbene; and
when the first ligand L A has the Formula of Formula IB or IC, ring B is selected from the group consisting of pyridine, pyrimidine, pyrazine, pyridazine, benzene, imidazole, pyrazole, triazole, pyrrole, oxazole, thiazole, and imidazole derived carbene.
8. The compound of claim 1 , wherein the first ligand L A is selected from the group consisting of:
and aza variants thereof; and
wherein Ra is selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof.
9. The compound of claim 1 , wherein the first ligand L A is selected from the group consisting of L A121 through L A456 , L A577 through L A2736 , L A2857 through L A4104 , and L A4225 through L A4780 , wherein L A121 through L A240 have a structure of Formula II:
wherein R 1 , R 2 , X, and Y are defined as:
Ligand
R 1
R 2
X
Y
L A121
H
H
N
S
L A122
R B1
H
N
S
L A123
R B3
H
N
S
L A124
R B4
H
N
S
L A125
R B7
H
N
S
L A126
R B10
H
N
S
L A127
R A3
H
N
S
L A128
R A34
H
N
S
L A129
H
H
N
O
L A130
R B1
H
N
O
L A131
R B3
H
N
O
L A132
R B4
H
N
O
L A133
R B7
H
N
O
L A134
R B10
H
N
O
L A135
R A3
H
N
O
L A136
R A34
H
N
O
L A137
H
H
N
NCH 3
L A138
R B1
H
N
NCH 3
L A139
R B3
H
N
NCH 3
L A140
R B4
H
N
NCH 3
L A141
R B7
H
N
NCH 3
L A142
R B10
H
N
NCH 3
L A143
R A3
H
N
NCH 3
L A144
R A34
H
N
NCH 3
L A145
H
H
N
C(CH 3 ) 2
L A146
R B1
H
N
C(CH 3 ) 2
L A147
R B3
H
N
C(CH 3 ) 2
L A148
R B4
H
N
C(CH 3 ) 2
L A149
R B7
H
N
C(CH 3 ) 2
L A150
R B10
H
N
C(CH 3 ) 2
L A151
R A3
H
N
C(CH 3 ) 2
L A152
R A34
H
N
C(CH 3 ) 2
L A153
H
H
N
Si(CH 3 ) 2
L A154
R B1
H
N
Si(CH 3 ) 2
L A155
R B3
H
N
Si(CH 3 ) 2
L A156
R B4
H
N
Si(CH 3 ) 2
L A157
R B7
H
N
Si(CH 3 ) 2
L A158
R B10
H
N
Si(CH 3 ) 2
L A159
R A3
H
N
Si(CH 3 ) 2
L A160
R A34
H
N
Si(CH 3 ) 2
L A161
H
R B1
N
S
L A162
R B1
R B1
N
S
L A163
R B3
R B1
N
S
L A164
R B4
R B1
N
S
L A165
R B7
R B1
N
S
L A166
R B10
R B1
N
S
L A167
R A3
R B1
N
S
L A168
R A34
R B1
N
S
L A169
H
R B1
N
O
L A170
R B1
R B1
N
O
L A171
R B3
R B1
N
O
L A172
R B4
R B1
N
O
L A173
R B7
R B1
N
O
L A174
R B10
R B1
N
O
L A175
R A3
R B1
N
O
L A176
R A34
R B1
N
O
L A177
H
R B1
N
NCH 3
L A178
R B1
R B1
N
NCH 3
L A179
R B3
R B1
N
NCH 3
L A180
R B4
R B1
N
NCH 3
L A181
R B7
R B1
N
NCH 3
L A182
R B10
R B1
N
NCH 3
L A183
R A3
R B1
N
NCH 3
L A184
R A34
R B1
N
NCH 3
L A185
H
R B1
N
C(CH 3 ) 2
L A186
R B1
R B1
N
C(CH 3 ) 2
L A187
R B3
R B1
N
C(CH 3 ) 2
L A188
R B4
R B1
N
C(CH 3 ) 2
L A189
R B7
R B1
N
C(CH 3 ) 2
L A190
R B10
R B1
N
C(CH 3 ) 2
L A191
R A3
R B1
N
C(CH 3 ) 2
L A192
R A34
R B1
N
C(CH 3 ) 2
L A193
H
R B1
N
Si(CH 3 ) 2
L A194
R B1
R B1
N
Si(CH 3 ) 2
L A195
R B3
R B1
N
Si(CH 3 ) 2
L A196
R B4
R B1
N
Si(CH 3 ) 2
L A197
R B7
R B1
N
Si(CH 3 ) 2
L A198
R B10
R B1
N
Si(CH 3 ) 2
L A199
R A3
R B1
N
Si(CH 3 ) 2
L A200
R A34
R B1
N
Si(CH 3 ) 2
L A201
H
R B2
N
S
L A202
R B1
R B2
N
S
L A203
R B3
R B2
N
S
L A204
R B4
R B2
N
S
L A205
R B7
R B2
N
S
L A206
R B10
R B2
N
S
L A207
R A3
R B2
N
S
L A208
R A34
R B2
N
S
L A209
H
R B2
N
O
L A210
R B1
R B2
N
O
L A211
R B3
R B2
N
O
L A212
R B4
R B2
N
O
L A213
R B7
R B2
N
O
L A214
R B10
R B2
N
O
L A215
R A3
R B2
N
O
L A216
R A34
R B2
N
O
L A217
H
R B2
N
NCH 3
L A218
R B1
R B2
N
NCH 3
L A219
R B3
R B2
N
NCH 3
L A220
R B4
R B2
N
NCH 3
L A221
R B7
R B2
N
NCH 3
L A222
R B10
R B2
N
NCH 3
L A223
R A3
R B2
N
NCH 3
L A224
R A34
R B2
N
NCH 3
L A225
H
R B2
N
C(CH 3 ) 2
L A226
R B1
R B2
N
C(CH 3 ) 2
L A227
R B3
R B2
N
C(CH 3 ) 2
L A228
R B4
R B2
N
C(CH 3 ) 2
L A229
R B7
R B2
N
C(CH 3 ) 2
L A230
R B10
R B2
N
C(CH 3 ) 2
L A231
R A3
R B2
N
C(CH 3 ) 2
L A232
R A34
R B2
N
C(CH 3 ) 2
L A233
H
R B2
N
Si(CH 3 ) 2
L A234
R B1
R B2
N
Si(CH 3 ) 2
L A235
R B3
R B2
N
Si(CH 3 ) 2
L A236
R B4
R B2
N
Si(CH 3 ) 2
L A237
R B7
R B2
N
Si(CH 3 ) 2
L A238
R B10
R B2
N
Si(CH 3 ) 2
L A239
R A3
R B2
N
Si(CH 3 ) 2
L A240
R A34
R B2
N
Si(CH 3 ) 2
wherein L A241 through L A360 have a structure of Formula III:
wherein R 2 , R 3 and Y are defined as provided below:
Ligand
R 2
R 3
Y
L A241
H
H
S
L A242
H
R B1
S
L A243
H
R B2
S
L A244
H
R B3
S
L A245
H
R B4
S
L A246
H
R B5
S
L A247
H
R A34
S
L A248
H
R A52
S
L A249
H
H
O
L A250
H
R B1
O
L A251
H
R B2
O
L A252
H
R B3
O
L A253
H
R B4
O
L A254
H
R B5
O
L A255
H
R A34
O
L A256
H
R A52
O
L A257
H
H
NCH 3
L A258
H
R B1
NCH 3
L A259
H
R B2
NCH 3
L A260
H
R B3
NCH 3
L A261
H
R B4
NCH 3
L A262
H
R B5
NCH 3
L A263
H
R A34
NCH 3
L A264
H
R A52
NCH 3
L A265
H
H
C(CH 3 ) 2
L A266
H
R B1
C(CH 3 ) 2
L A267
H
R B2
C(CH 3 ) 2
L A268
H
R B3
C(CH 3 ) 2
L A269
H
R B4
C(CH 3 ) 2
L A270
H
R B5
C(CH 3 ) 2
L A271
H
R A34
C(CH 3 ) 2
L A272
H
R A52
C(CH 3 ) 2
L A273
H
H
Si(CH 3 ) 2
L A274
H
R B1
Si(CH 3 ) 2
L A275
H
R B2
Si(CH 3 ) 2
L A276
H
R B3
Si(CH 3 ) 2
L A277
H
R B4
Si(CH 3 ) 2
L A278
H
R B5
Si(CH 3 ) 2
L A279
H
R A34
Si(CH 3 ) 2
L A280
H
R A52
Si(CH 3 ) 2
L A281
R B1
H
S
L A282
R B1
R B1
S
L A283
R B1
R B2
S
L A284
R B1
R B3
S
L A285
R B1
R B4
S
L A286
R B1
R B5
S
L A287
R B1
R A34
S
L A288
R B1
R A52
S
L A289
R B1
H
O
L A290
R B1
R B1
O
L A291
R B1
R B2
O
L A292
R B1
R B3
O
L A293
R B1
R B4
O
L A294
R B1
R B5
O
L A295
R B1
R A34
O
L A296
R B1
R A52
O
L A297
R B1
H
NCH 3
L A298
R B1
R B1
NCH 3
L A299
R B1
R B2
NCH 3
L A300
R B1
R B3
NCH 3
L A301
R B1
R B4
NCH 3
L A302
R B1
R B5
NCH 3
L A303
R B1
R A34
NCH 3
L A304
R B1
R A52
NCH 3
L A305
R B1
H
C(CH 3 ) 2
L A306
R B1
R B1
C(CH 3 ) 2
L A307
R B1
R B2
C(CH 3 ) 2
L A308
R B1
R B3
C(CH 3 ) 2
L A309
R B1
R B4
C(CH 3 ) 2
L A310
R B1
R B5
C(CH 3 ) 2
L A311
R B1
R A34
C(CH 3 ) 2
L A312
R B1
R A52
C(CH 3 ) 2
L A313
R B1
H
Si(CH 3 ) 2
L A314
R B1
R B1
Si(CH 3 ) 2
L A315
R B1
R B2
Si(CH 3 ) 2
L A316
R B1
R B3
Si(CH 3 ) 2
L A317
R B1
R B4
Si(CH 3 ) 2
L A318
R B1
R B5
Si(CH 3 ) 2
L A319
R B1
R A34
Si(CH 3 ) 2
L A320
R B1
R A52
Si(CH 3 ) 2
L A321
R B2
H
S
L A322
R B2
R B1
S
L A323
R B2
R B2
S
L A324
R B2
R B3
S
L A325
R B2
R B4
S
L A326
R B2
R B5
S
L A327
R B2
R A34
S
L A328
R B2
R A52
S
L A329
R B2
H
O
L A330
R B2
R B1
O
L A331
R B2
R B2
O
L A332
R B2
R B3
O
L A333
R B2
R B4
O
L A334
R B2
R B5
O
L A335
R B2
R A34
O
L A336
R B2
R A52
O
L A337
R B2
H
NCH 3
L A338
R B2
R B1
NCH 3
L A339
R B2
R B2
NCH 3
L A340
R B2
R B3
NCH 3
L A341
R B2
R B4
NCH 3
L A342
R B2
R B5
NCH 3
L A343
R B2
R A34
NCH 3
L A344
R B2
R A52
NCH 3
L A345
R B2
H
C(CH 3 ) 2
L A346
R B2
R B1
C(CH 3 ) 2
L A347
R B2
R B2
C(CH 3 ) 2
L A348
R B2
R B3
C(CH 3 ) 2
L A349
R B2
R B4
C(CH 3 ) 2
L A350
R B2
R B5
C(CH 3 ) 2
L A351
R B2
R A34
C(CH 3 ) 2
L A352
R B2
R A52
C(CH 3 ) 2
L A353
R B2
H
Si(CH 3 ) 2
L A354
R B2
R B1
Si(CH 3 ) 2
L A355
R B2
R B2
Si(CH 3 ) 2
L A356
R B2
R B3
Si(CH 3 ) 2
L A357
R B2
R B4
Si(CH 3 ) 2
L A358
R B2
R B5
Si(CH 3 ) 2
L A359
R B2
R A34
Si(CH 3 ) 2
L A360
R B2
R A52
Si(CH 3 ) 2
wherein L A361 through L A456 have a structure of Formula IV,
wherein R 2 , R 4 , Y, and X are defined as provided below:
Ligand
R 2
R 4
Y
Z
L A361
H
H
S
S
L A362
H
R B1
S
S
L A363
H
R B3
S
S
L A364
H
R B4
S
S
L A365
H
R B7
S
S
L A366
H
R B10
S
S
L A367
H
R A3
S
S
L A368
H
R A34
S
S
L A369
H
H
S
O
L A370
H
R B1
S
O
L A371
H
R B3
S
O
L A372
H
R B4
S
O
L A373
H
R B7
S
O
L A374
H
R B10
S
O
L A375
H
R A3
S
O
L A376
H
R A34
S
O
L A377
H
H
S
NCH 3
L A378
H
R B1
S
NCH 3
L A379
H
R B3
S
NCH 3
L A380
H
R B4
S
NCH 3
L A381
H
R B7
S
NCH 3
L A382
H
R B10
S
NCH 3
L A383
H
R A3
S
NCH 3
L A384
H
R A34
S
NCH 3
L A385
H
H
O
S
L A386
H
R B1
O
S
L A387
H
R B3
O
S
L A388
H
R B4
O
S
L A389
H
R B7
O
S
L A390
H
R B10
O
S
L A391
H
R A3
O
S
L A392
H
R A34
O
S
L A393
H
H
O
O
L A394
H
R B1
O
O
L A395
H
R B3
O
O
L A396
H
R B4
O
O
L A397
H
R B7
O
O
L A398
H
R B10
O
O
L A399
H
R A3
O
O
L A400
H
R A34
O
O
L A401
H
H
O
NCH 3
L A402
H
R B1
O
NCH 3
L A403
H
R B3
O
NCH 3
L A404
H
R B4
O
NCH 3
L A405
H
R B7
O
NCH 3
L A406
H
R B10
O
NCH 3
L A407
H
R A3
O
NCH 3
L A408
H
R A34
O
NCH 3
L A409
R B1
H
S
S
L A410
R B1
R B1
S
S
L A411
R B1
R B3
S
S
L A412
R B1
R B4
S
S
L A413
R B1
R B7
S
S
L A414
R B1
R B10
S
S
L A415
R B1
R A3
S
S
L A416
R B1
R A34
S
S
L A417
R B1
H
S
O
L A418
R B1
R B1
S
O
L A419
R B1
R B3
S
O
L A420
R B1
R B4
S
O
L A421
R B1
R B7
S
O
L A422
R B1
R B10
S
O
L A423
R B1
R A3
S
O
L A424
R B1
R A34
S
O
L A425
R B1
H
S
NCH 3
L A426
R B1
R B1
S
NCH 3
L A427
R B1
R B3
S
NCH 3
L A428
R B1
R B4
S
NCH 3
L A429
R B1
R B7
S
NCH 3
L A430
R B1
R B10
S
NCH 3
L A431
R B1
R A3
S
NCH 3
L A432
R B1
R A34
S
NCH 3
L A433
R B1
H
O
S
L A434
R B1
R B1
O
S
L A435
R B1
R B3
O
S
L A436
R B1
R B4
O
S
L A437
R B1
R B7
O
S
L A438
R B1
R B10
O
S
L A439
R B1
R A3
O
S
L A440
R B1
R A34
O
S
L A441
R B1
H
O
O
L A442
R B1
R B1
O
O
L A443
R B1
R B3
O
O
L A444
R B1
R B4
O
O
L A445
R B1
R B7
O
O
L A446
R B1
R B10
O
O
L A447
R B1
R A3
O
O
L A448
R B1
R A34
O
O
L A449
R B1
H
O
NCH 3
L A450
R B1
R B1
O
NCH 3
L A451
R B1
R B3
O
NCH 3
L A452
R B1
R B4
O
NCH 3
L A453
R B1
R B7
O
NCH 3
L A454
R B1
R B10
O
NCH 3
L A455
R B1
R A3
O
NCH 3
L A456
R B1
R A34
O
NCH 3
wherein L A577 through L A696 have a structure of Formula V:
wherein R 1 , R 2 , X, and Y are defined as provided below:
Ligand
R 1
R 2
X
Y
L A577
H
H
N
S
L A578
R B1
H
N
S
L A579
R B3
H
N
S
L A580
R B4
H
N
S
L A581
R B7
H
N
S
L A582
R B10
H
N
S
L A583
R A3
H
N
S
L A584
R A34
H
N
S
L A585
H
H
N
O
L A586
R B1
H
N
O
L A587
R B3
H
N
O
L A588
R B4
H
N
O
L A589
R B7
H
N
O
L A590
R B10
H
N
O
L A591
R A3
H
N
O
L A592
R A34
H
N
O
L A593
H
H
N
NCH 3
L A594
R B1
H
N
NCH 3
L A595
R B3
H
N
NCH 3
L A596
R B4
H
N
NCH 3
L A597
R B7
H
N
NCH 3
L A598
R B10
H
N
NCH 3
L A599
R A3
H
N
NCH 3
L A600
R A34
H
N
NCH 3
L A601
H
H
N
C(CH 3 ) 2
L A602
R B1
H
N
C(CH 3 ) 2
L A603
R B3
H
N
C(CH 3 ) 2
L A604
R B4
H
N
C(CH 3 ) 2
L A605
R B7
H
N
C(CH 3 ) 2
L A606
R B10
H
N
C(CH 3 ) 2
L A607
R A3
H
N
C(CH 3 ) 2
L A608
R A34
H
N
C(CH 3 ) 2
L A609
H
H
N
Si(CH 3 ) 2
L A610
R B1
H
N
Si(CH 3 ) 2
L A611
R B3
H
N
Si(CH 3 ) 2
L A612
R B4
H
N
Si(CH 3 ) 2
L A613
R B7
H
N
Si(CH 3 ) 2
L A614
R B10
H
N
Si(CH 3 ) 2
L A615
R A3
H
N
Si(CH 3 ) 2
L A616
R A34
H
N
Si(CH 3 ) 2
L A617
H
R B1
N
S
L A618
R B1
R B1
N
S
L A619
R B3
R B1
N
S
L A620
R B4
R B1
N
S
L A621
R B7
R B1
N
S
L A622
R B10
R B1
N
S
L A623
R A3
R B1
N
S
L A624
R A34
R B1
N
S
L A625
H
R B1
N
O
L A626
R B1
R B1
N
O
L A627
R B3
R B1
N
O
L A628
R B4
R B1
N
O
L A629
R B7
R B1
N
O
L A630
R B10
R B1
N
O
L A631
R A3
R B1
N
O
L A632
R A34
R B1
N
O
L A633
H
R B1
N
NCH 3
L A634
R B1
R B1
N
NCH 3
L A635
R B3
R B1
N
NCH 3
L A636
R B4
R B1
N
NCH 3
L A637
R B7
R B1
N
NCH 3
L A638
R B10
R B1
N
NCH 3
L A639
R A3
R B1
N
NCH 3
L A640
R A34
R B1
N
NCH 3
L A641
H
R B1
N
C(CH 3 ) 2
L A642
R B1
R B1
N
C(CH 3 ) 2
L A643
R B3
R B1
N
C(CH 3 ) 2
L A644
R B4
R B1
N
C(CH 3 ) 2
L A645
R B7
R B1
N
C(CH 3 ) 2
L A646
R B10
R B1
N
C(CH 3 ) 2
L A647
R A3
R B1
N
C(CH 3 ) 2
L A648
R A34
R B1
N
C(CH 3 ) 2
L A649
H
R B1
N
Si(CH 3 ) 2
L A650
R B1
R B1
N
Si(CH 3 ) 2
L A651
R B3
R B1
N
Si(CH 3 ) 2
L A652
R B4
R B1
N
Si(CH 3 ) 2
L A653
R B7
R B1
N
Si(CH 3 ) 2
L A654
R B10
R B1
N
Si(CH 3 ) 2
L A655
R A3
R B1
N
Si(CH 3 ) 2
L A656
R A34
R B1
N
Si(CH 3 ) 2
L A657
H
R B2
N
S
L A658
R B1
R B2
N
S
L A659
R B3
R B2
N
S
L A660
R B4
R B2
N
S
L A661
R B7
R B2
N
S
L A662
R B10
R B2
N
S
L A663
R A3
R B2
N
S
L A664
R A34
R B2
N
S
L A665
H
R B2
N
O
L A666
R B1
R B2
N
O
L A667
R B3
R B2
N
O
L A668
R B4
R B2
N
O
L A669
R B7
R B2
N
O
L A670
R B10
R B2
N
O
L A671
R A3
R B2
N
O
L A672
R A34
R B2
N
O
L A673
H
R B2
N
NCH 3
L A674
R B1
R B2
N
NCH 3
L A675
R B3
R B2
N
NCH 3
L A676
R B4
R B2
N
NCH 3
L A677
R B7
R B2
N
NCH 3
L A678
R B10
R B2
N
NCH 3
L A679
R A3
R B2
N
NCH 3
L A680
R A34
R B2
N
NCH 3
L A681
H
R B2
N
C(CH 3 ) 2
L A682
R B1
R B2
N
C(CH 3 ) 2
L A683
R B3
R B2
N
C(CH 3 ) 2
L A684
R B4
R B2
N
C(CH 3 ) 2
L A685
R B7
R B2
N
C(CH 3 ) 2
L A686
R B10
R B2
N
C(CH 3 ) 2
L A687
R A3
R B2
N
C(CH 3 ) 2
L A688
R A34
R B2
N
C(CH 3 ) 2
L A689
H
R B2
N
Si(CH 3 ) 2
L A690
R B1
R B2
N
Si(CH 3 ) 2
L A691
R B3
R B2
N
Si(CH 3 ) 2
L A692
R B4
R B2
N
Si(CH 3 ) 2
L A693
R B7
R B2
N
Si(CH 3 ) 2
L A694
R B10
R B2
N
Si(CH 3 ) 2
L A695
R A3
R B2
N
Si(CH 3 ) 2
L A696
R A34
R B2
N
Si(CH 3 ) 2
wherein L A697 through L A816 have a structure of Formula VI:
wherein R 2 , R 3 , and Y are defined as provided below:
Ligand
R 2
R 3
Y
Ligand
R 1
R 2
R 14
L A697
H
H
S
L A757
R B1
R B4
NCH 3
L A698
H
R B1
S
L A758
R B1
R B5
NCH 3
L A699
H
R B2
S
L A759
R B1
R A34
NCH 3
L A700
H
R B3
S
L A760
R B1
R A52
NCH 3
L A701
H
R B4
S
L A761
R B1
H
C(CH 3 ) 2
L A702
H
R B5
S
L A762
R B1
R B1
C(CH 3 ) 2
L A703
H
R A34
S
L A763
R B1
R B2
C(CH 3 ) 2
L A704
H
R A52
S
L A764
R B1
R B3
C(CH 3 ) 2
L A705
H
H
O
L A765
R B1
R B4
C(CH 3 ) 2
L A706
H
R B1
O
L A766
R B1
R B5
C(CH 3 ) 2
L A707
H
R B2
O
L A767
R B1
R A34
C(CH 3 ) 2
L A708
H
R B3
O
L A768
R B1
R A52
C(CH 3 ) 2
L A709
H
R B4
O
L A769
R B1
H
Si(CH 3 ) 2
L A710
H
R B5
O
L A770
R B1
R B1
Si(CH 3 ) 2
L A711
H
R A34
O
L A771
R B1
R B2
Si(CH 3 ) 2
L A712
H
R A52
O
L A772
R B1
R B3
Si(CH 3 ) 2
L A713
H
H
NCH 3
L A773
R B1
R B4
Si(CH 3 ) 2
L A714
H
R B1
NCH 3
L A774
R B1
R B5
Si(CH 3 ) 2
L A715
H
R B2
NCH 3
L A775
R B1
R A34
Si(CH 3 ) 2
L A716
H
R B3
NCH 3
L A776
R B1
R A52
Si(CH 3 ) 2
L A717
H
R B4
NCH 3
L A777
R B2
H
S
L A718
H
R B5
NCH 3
L A778
R B2
R B1
S
L A719
H
R A34
NCH 3
L A779
R B2
R B2
S
L A720
H
R A52
NCH 3
L A780
R B2
R B3
S
L A721
H
H
C(CH 3 ) 2
L A781
R B2
R B4
S
L A722
H
R B1
C(CH 3 ) 2
L A782
R B2
R B5
S
L A723
H
R B2
C(CH 3 ) 2
L A783
R B2
R A34
S
L A724
H
R B3
C(CH 3 ) 2
L A784
R B2
R A52
S
L A725
H
R B4
C(CH 3 ) 2
L A785
R B2
H
O
L A726
H
R B5
C(CH 3 ) 2
L A786
R B2
R B1
O
L A727
H
R A34
C(CH 3 ) 2
L A787
R B2
R B2
O
L A728
H
R A52
C(CH 3 ) 2
L A788
R B2
R B3
O
L A729
H
H
Si(CH 3 ) 2
L A789
R B2
R B4
O
L A730
H
R B1
Si(CH 3 ) 2
L A790
R B2
R B5
O
L A731
H
R B2
Si(CH 3 ) 2
L A791
R B2
R A34
O
L A732
H
R B3
Si(CH 3 ) 2
L A792
R B2
R A52
O
L A733
H
R B4
Si(CH 3 ) 2
L A793
R B2
H
NCH 3
L A734
H
R B5
Si(CH 3 ) 2
L A794
R B2
R B1
NCH 3
L A735
H
R A34
Si(CH 3 ) 2
L A795
R B2
R B2
NCH 3
L A736
H
R A52
Si(CH 3 ) 2
L A796
R B2
R B3
NCH 3
L A737
R B1
H
S
L A797
R B2
R B4
NCH 3
L A738
R B1
R B1
S
L A798
R B2
R B5
NCH 3
L A739
R B1
R B2
S
L A799
R B2
R A34
NCH 3
L A740
R B1
R B3
S
L A800
R B2
R A52
NCH 3
L A741
R B1
R B4
S
L A801
R B2
H
C(CH 3 ) 2
L A742
R B1
R B5
S
L A802
R B2
R B1
C(CH 3 ) 2
L A743
R B1
R A34
S
L A803
R B2
R B2
C(CH 3 ) 2
L A744
R B1
R A52
S
L A804
R B2
R B3
C(CH 3 ) 2
L A745
R B1
H
O
L A805
R B2
R B4
C(CH 3 ) 2
L A746
R B1
R B1
O
L A806
R B2
R B5
C(CH 3 ) 2
L A747
R B1
R B2
O
L A807
R B2
R A34
C(CH 3 ) 2
L A748
R B1
R B3
O
L A808
R B2
R A52
C(CH 3 ) 2
L A749
R B1
R B4
O
L A809
R B2
H
Si(CH 3 ) 2
L A750
R B1
R B5
O
L A810
R B2
R B1
Si(CH 3 ) 2
L A751
R B1
R A34
O
L A811
R B2
R B2
Si(CH 3 ) 2
L A752
R B1
R A52
O
L A812
R B2
R B3
Si(CH 3 ) 2
L A753
R B1
H
NCH 3
L A813
R B2
R B4
Si(CH 3 ) 2
L A754
R B1
R B1
NCH 3
L A814
R B2
R B5
Si(CH 3 ) 2
L A755
R B1
R B2
NCH 3
L A815
R B2
R A34
Si(CH 3 ) 2
L A756
R B1
R B3
NCH 3
L A816
R B2
R A52
Si(CH 3 ) 2
wherein L A817 through L A912 have a structure of Formula VII:
wherein R 2 , R 4 , and Y are defined as provided below:
Ligand
R 2
R 4
Y
Z
L A817
H
H
S
S
L A818
H
R B1
S
S
L A819
H
R B3
S
S
L A820
H
R B4
S
S
L A821
H
R B7
S
S
L A822
H
R B10
S
S
L A823
H
R A3
S
S
L A824
H
R A34
S
S
L A825
H
H
S
O
L A826
H
R B1
S
O
L A827
H
R B3
S
O
L A828
H
R B4
S
O
L A829
H
R B7
S
O
L A830
H
R B10
S
O
L A831
H
R A3
S
O
L A832
H
R A34
S
O
L A833
H
H
S
NCH 3
L A834
H
R B1
S
NCH 3
L A835
H
R B3
S
NCH 3
L A836
H
R B4
S
NCH 3
L A837
H
R B7
S
NCH 3
L A838
H
R B10
S
NCH 3
L A839
H
R A3
S
NCH 3
L A840
H
R A34
S
NCH 3
L A841
H
H
O
S
L A842
H
R B1
O
S
L A843
H
R B3
O
S
L A844
H
R B4
O
S
L A845
H
R B7
O
S
L A846
H
R B10
O
S
L A847
H
R A3
O
S
L A848
H
R A34
O
S
L A849
H
H
O
O
L A850
H
R B1
O
O
L A851
H
R B3
O
O
L A852
H
R B4
O
O
L A853
H
R B7
O
O
L A854
H
R B10
O
O
L A855
H
R A3
O
O
L A856
H
R A34
O
O
L A857
H
H
O
NCH 3
L A858
H
R B1
O
NCH 3
L A859
H
R B3
O
NCH 3
L A860
H
R B4
O
NCH 3
L A861
H
R B7
O
NCH 3
L A862
H
R B10
O
NCH 3
L A863
H
R A3
O
NCH 3
L A864
H
R A34
O
NCH 3
L A865
R B1
H
S
S
L A866
R B1
R B1
S
S
L A867
R B1
R B3
S
S
L A868
R B1
R B4
S
S
L A869
R B1
R B7
S
S
L A870
R B1
R B10
S
S
L A871
R B1
R A3
S
S
L A872
R B1
R A34
S
S
L A873
R B1
H
S
O
L A874
R B1
R B1
S
O
L A875
R B1
R B3
S
O
L A876
R B1
R B4
S
O
L A877
R B1
R B7
S
O
L A878
R B1
R B10
S
O
L A879
R B1
R A3
S
O
L A880
R B1
R A34
S
O
L A881
R B1
H
S
NCH 3
L A882
R B1
R B1
S
NCH 3
L A883
R B1
R B3
S
NCH 3
L A884
R B1
R B4
S
NCH 3
L A885
R B1
R B7
S
NCH 3
L A886
R B1
R B10
S
NCH 3
L A887
R B1
R A3
S
NCH 3
L A888
R B1
R A34
S
NCH 3
L A889
R B1
H
O
S
L A890
R B1
R B1
O
S
L A891
R B1
R B3
O
S
L A892
R B1
R B4
O
S
L A893
R B1
R B7
O
S
L A894
R B1
R B10
O
S
L A895
R B1
R A3
O
S
L A896
R B1
R A34
O
S
L A897
R B1
H
O
O
L A898
R B1
R B1
O
O
L A899
R B1
R B3
O
O
L A900
R B1
R B4
O
O
L A901
R B1
R B7
O
O
L A902
R B1
R B10
O
O
L A903
R B1
R A3
O
O
L A904
R B1
R A34
O
O
L A905
R B1
H
O
NCH 3
L A906
R B1
R B1
O
NCH 3
L A907
R B1
R B3
O
NCH 3
L A908
R B1
R B4
O
NCH 3
L A909
R B1
R B7
O
NCH 3
L A910
R B1
R B10
O
NCH 3
L A911
R B1
R A3
O
NCH 3
L A912
R B1
R A34
O
NCH 3
wherein L A913 through L A1152 have a structure of Formula VIII:
wherein R 1 , R 2 , Y, and X are defined as provided below:
Ligand
R 1
R 2
X
Y
L A913
H
H
C
S
L A914
R B1
H
C
S
L A915
R B3
H
C
S
L A916
R B4
H
C
S
L A917
R B7
H
C
S
L A918
R B10
H
C
S
L A919
R A3
H
C
S
L A920
R A34
H
C
S
L A921
H
H
C
O
L A922
R B1
H
C
O
L A923
R B3
H
C
O
L A924
R B4
H
C
O
L A925
R B7
H
C
O
L A926
R B10
H
C
O
L A927
R A3
H
C
O
L A928
R A34
H
C
O
L A929
H
H
C
NCH 3
L A930
R B1
H
C
NCH 3
L A931
R B3
H
C
NCH 3
L A932
R B4
H
C
NCH 3
L A933
R B7
H
C
NCH 3
L A934
R B10
H
C
NCH 3
L A935
R A3
H
C
NCH 3
L A936
R A34
H
C
NCH 3
L A937
H
H
C
C(CH 3 ) 2
L A938
R B1
H
C
C(CH 3 ) 2
L A939
R B3
H
C
C(CH 3 ) 2
L A940
R B4
H
C
C(CH 3 ) 2
L A941
R B7
H
C
C(CH 3 ) 2
L A942
R B10
H
C
C(CH 3 ) 2
L A943
R A3
H
C
C(CH 3 ) 2
L A944
R A34
H
C
C(CH 3 ) 2
L A945
H
H
C
Si(CH 3 ) 2
L A946
R B1
H
C
Si(CH 3 ) 2
L A947
R B3
H
C
Si(CH 3 ) 2
L A948
R B4
H
C
Si(CH 3 ) 2
L A949
R B7
H
C
Si(CH 3 ) 2
L A950
R B10
H
C
Si(CH 3 ) 2
L A951
R A3
H
C
Si(CH 3 ) 2
L A952
R A34
H
C
Si(CH 3 ) 2
L A953
H
R B1
C
S
L A954
R B1
R B1
C
S
L A955
R B3
R B1
C
S
L A956
R B4
R B1
C
S
L A957
R B7
R B1
C
S
L A958
R B10
R B1
C
S
L A959
R A3
R B1
C
S
L A960
R A34
R B1
C
S
L A961
H
R B1
C
O
L A962
R B1
R B1
C
O
L A963
R B3
R B1
C
O
L A964
R B4
R B1
C
O
L A965
R B7
R B1
C
O
L A966
R B10
R B1
C
O
L A967
R A3
R B1
C
O
L A968
R A34
R B1
C
O
L A969
H
R B1
C
NCH 3
L A970
R B1
R B1
C
NCH 3
L A971
R B3
R B1
C
NCH 3
L A972
R B4
R B1
C
NCH 3
L A973
R B7
R B1
C
NCH 3
L A974
R B10
R B1
C
NCH 3
L A975
R A3
R B1
C
NCH 3
L A976
R A34
R B1
C
NCH 3
L A977
H
R B1
C
C(CH 3 ) 2
L A978
R B1
R B1
C
C(CH 3 ) 2
L A979
R B3
R B1
C
C(CH 3 ) 2
L A980
R B4
R B1
C
C(CH 3 ) 2
L A981
R B7
R B1
C
C(CH 3 ) 2
L A982
R B10
R B1
C
C(CH 3 ) 2
L A983
R A3
R B1
C
C(CH 3 ) 2
L A984
R A34
R B1
C
C(CH 3 ) 2
L A985
H
R B1
C
Si(CH 3 ) 2
L A986
R B1
R B1
C
Si(CH 3 ) 2
L A987
R B3
R B1
C
Si(CH 3 ) 2
L A988
R B4
R B1
C
Si(CH 3 ) 2
L A989
R B7
R B1
C
Si(CH 3 ) 2
L A990
R B10
R B1
C
Si(CH 3 ) 2
L A991
R A3
R B1
C
Si(CH 3 ) 2
L A992
R A34
R B1
C
Si(CH 3 ) 2
L A993
H
R B2
C
S
L A994
R B1
R B2
C
S
L A995
R B3
R B2
C
S
L A996
R B4
R B2
C
S
L A997
R B7
R B2
C
S
L A998
R B10
R B2
C
S
L A999
R A3
R B2
C
S
L A1000
R A34
R B2
C
S
L A1001
H
R B2
C
O
L A1002
R B1
R B2
C
O
L A1003
R B3
R B2
C
O
L A1004
R B4
R B2
C
O
L A1005
R B7
R B2
C
O
L A1006
R B10
R B2
C
O
L A1007
R A3
R B2
C
O
L A1008
R A34
R B2
C
O
L A1009
H
R B2
C
NCH 3
L A1010
R B1
R B2
C
NCH 3
L A1011
R B3
R B2
C
NCH 3
L A1012
R B4
R B2
C
NCH 3
L A1013
R B7
R B2
C
NCH 3
L A1014
R B10
R B2
C
NCH 3
L A1015
R A3
R B2
C
NCH 3
L A1016
R A34
R B2
C
NCH 3
L A1017
H
R B2
C
C(CH 3 ) 2
L A1018
R B1
R B2
C
C(CH 3 ) 2
L A1019
R B3
R B2
C
C(CH 3 ) 2
L A1020
R B4
R B2
C
C(CH 3 ) 2
L A1021
R B7
R B2
C
C(CH 3 ) 2
L A1022
R B10
R B2
C
C(CH 3 ) 2
L A1023
R A3
R B2
C
C(CH 3 ) 2
L A1024
R A34
R B2
C
C(CH 3 ) 2
L A1025
H
R B2
C
Si(CH 3 ) 2
L A1026
R B1
R B2
C
Si(CH 3 ) 2
L A1027
R B3
R B2
C
Si(CH 3 ) 2
L A1028
R B4
R B2
C
Si(CH 3 ) 2
L A1029
R B7
R B2
C
Si(CH 3 ) 2
L A1030
R B10
R B2
C
Si(CH 3 ) 2
L A1031
R A3
R B2
C
Si(CH 3 ) 2
L A1032
R A34
R B2
C
Si(CH 3 ) 2
L A1033
H
H
N
S
L A1034
R B1
H
N
S
L A1035
R B3
H
N
S
L A1036
R B4
H
N
S
L A1037
R B7
H
N
S
L A1038
R B10
H
N
S
L A1039
R A3
H
N
S
L A1040
R A34
H
N
S
L A1041
H
H
N
O
L A1042
R B1
H
N
O
L A1043
R B3
H
N
O
L A1044
R B4
H
N
O
L A1045
R B7
H
N
O
L A1046
R B10
H
N
O
L A1047
R A3
H
N
O
L A1048
R A34
H
N
O
L A1049
H
H
N
NCH 3
L A1050
R B1
H
N
NCH 3
L A1051
R B3
H
N
NCH 3
L A1052
R B4
H
N
NCH 3
L A1053
R B7
H
N
NCH 3
L A1054
R B10
H
N
NCH 3
L A1055
R A3
H
N
NCH 3
L A1056
R A34
H
N
NCH 3
L A1057
H
H
N
C(CH 3 ) 2
L A1058
R B1
H
N
C(CH 3 ) 2
L A1059
R B3
H
N
C(CH 3 ) 2
L A1060
R B4
H
N
C(CH 3 ) 2
L A1061
R B7
H
N
C(CH 3 ) 2
L A1062
R B10
H
N
C(CH 3 ) 2
L A1063
R A3
H
N
C(CH 3 ) 2
L A1064
R A34
H
N
C(CH 3 ) 2
L A1065
H
H
N
Si(CH 3 ) 2
L A1066
R B1
H
N
Si(CH 3 ) 2
L A1067
R B3
H
N
Si(CH 3 ) 2
L A1068
R B4
H
N
Si(CH 3 ) 2
L A1069
R B7
H
N
Si(CH 3 ) 2
L A1070
R B10
H
N
Si(CH 3 ) 2
L A1071
R A3
H
N
Si(CH 3 ) 2
L A1072
R A34
H
N
Si(CH 3 ) 2
L A1073
H
R B1
N
S
L A1074
R B1
R B1
N
S
L A1075
R B3
R B1
N
S
L A1076
R B4
R B1
N
S
L A1077
R B7
R B1
N
S
L A1078
R B10
R B1
N
S
L A1079
R A3
R B1
N
S
L A1080
R A34
R B1
N
S
L A1081
H
R B1
N
O
L A1082
R B1
R B1
N
O
L A1083
R B3
R B1
N
O
L A1084
R B4
R B1
N
O
L A1085
R B7
R B1
N
O
L A1086
R B10
R B1
N
O
L A1087
R A3
R B1
N
O
L A1088
R A34
R B1
N
O
L A1089
H
R B1
N
NCH 3
L A1090
R B1
R B1
N
NCH 3
L A1091
R B3
R B1
N
NCH 3
L A1092
R B4
R B1
N
NCH 3
L A1093
R B7
R B1
N
NCH 3
L A1094
R B10
R B1
N
NCH 3
L A1095
R A3
R B1
N
NCH 3
L A1096
R A34
R B1
N
NCH 3
L A1097
H
R B1
N
C(CH 3 ) 2
L A1098
R B1
R B1
N
C(CH 3 ) 2
L A1099
R B3
R B1
N
C(CH 3 ) 2
L A1100
R B4
R B1
N
C(CH 3 ) 2
L A1101
R B7
R B1
N
C(CH 3 ) 2
L A1102
R B10
R B1
N
C(CH 3 ) 2
L A1103
R A3
R B1
N
C(CH 3 ) 2
L A1104
R A34
R B1
N
C(CH 3 ) 2
L A1105
H
R B1
N
Si(CH 3 ) 2
L A1106
R B1
R B1
N
Si(CH 3 ) 2
L A1107
R B3
R B1
N
Si(CH 3 ) 2
L A1108
R B4
R B1
N
Si(CH 3 ) 2
L A1109
R B7
R B1
N
Si(CH 3 ) 2
L A1110
R B10
R B1
N
Si(CH 3 ) 2
L A1111
R A3
R B1
N
Si(CH 3 ) 2
L A1112
R A34
R B1
N
Si(CH 3 ) 2
L A1113
H
R B2
N
S
L A1114
R B1
R B2
N
S
L A1115
R B3
R B2
N
S
L A1116
R B4
R B2
N
S
L A1117
R B7
R B2
N
S
L A1118
R B10
R B2
N
S
L A1119
R A3
R B2
N
S
L A1120
R A34
R B2
N
S
L A1121
H
R B2
N
O
L A1122
R B1
R B2
N
O
L A1123
R B3
R B2
N
O
L A1124
R B4
R B2
N
O
L A1125
R B7
R B2
N
O
L A1126
R B10
R B2
N
O
L A1127
R A3
R B2
N
O
L A1128
R A34
R B2
N
O
L A1129
H
R B2
N
NCH 3
L A1130
R B1
R B2
N
NCH 3
L A1131
R B3
R B2
N
NCH 3
L A1132
R B4
R B2
N
NCH 3
L A1133
R B7
R B2
N
NCH 3
L A1134
R B10
R B2
N
NCH 3
L A1135
R A3
R B2
N
NCH 3
L A1136
R A34
R B2
N
NCH 3
L A1137
H
R B2
N
C(CH 3 ) 2
L A1138
R B1
R B2
N
C(CH 3 ) 2
L A1139
R B3
R B2
N
C(CH 3 ) 2
L A1140
R B4
R B2
N
C(CH 3 ) 2
L A1141
R B7
R B2
N
C(CH 3 ) 2
L A1142
R B10
R B2
N
C(CH 3 ) 2
L A1143
R A3
R B2
N
C(CH 3 ) 2
L A1144
R A34
R B2
N
C(CH 3 ) 2
L A1145
H
R B2
N
Si(CH 3 ) 2
L A1146
R B1
R B2
N
Si(CH 3 ) 2
L A1147
R B3
R B2
N
Si(CH 3 ) 2
L A1148
R B4
R B2
N
Si(CH 3 ) 2
L A1149
R B7
R B2
N
Si(CH 3 ) 2
L A1150
R B10
R B2
N
Si(CH 3 ) 2
L A1151
R A3
R B2
N
Si(CH 3 ) 2
L A1152
R A34
R B2
N
Si(CH 3 ) 2
wherein L A1153 through L A1272 have a structure of Formula IX:
wherein R 2 , R 3 , and Y are defined as provided below:
Ligand
R 2
R 3
Y
Ligand
R 1
R 2
R 14
L A1153
H
H
S
L A1213
R B1
R B4
NCH 3
L A1154
H
R B1
S
L A1214
R B1
R B5
NCH 3
L A1155
H
R B2
S
L A1215
R B1
R A34
NCH 3
L A1156
H
R B3
S
L A1216
R B1
R A52
NCH 3
L A1157
H
R B4
S
L A1217
R B1
H
C(CH 3 ) 2
L A1158
H
R B5
S
L A1218
R B1
R B1
C(CH 3 ) 2
L A1159
H
R A34
S
L A1219
R B1
R B2
C(CH 3 ) 2
L A1160
H
R A52
S
L A1220
R B1
R B3
C(CH 3 ) 2
L A1161
H
H
O
L A1221
R B1
R B4
C(CH 3 ) 2
L A1162
H
R B1
O
L A1222
R B1
R B5
C(CH 3 ) 2
L A1163
H
R B2
O
L A1223
R B1
R A34
C(CH 3 ) 2
L A1164
H
R B3
O
L A1224
R B1
R A52
C(CH 3 ) 2
L A1165
H
R B4
O
L A1225
R B1
H
Si(CH 3 ) 2
L A1166
H
R B5
O
L A1226
R B1
R B1
Si(CH 3 ) 2
L A1167
H
R A34
O
L A1227
R B1
R B2
Si(CH 3 ) 2
L A1168
H
R A52
O
L A1228
R B1
R B3
Si(CH 3 ) 2
L A1169
H
H
NCH 3
L A1229
R B1
R B4
Si(CH 3 ) 2
L A1170
H
R B1
NCH 3
L A1230
R B1
R B5
Si(CH 3 ) 2
L A1171
H
R B2
NCH 3
L A1231
R B1
R A34
Si(CH 3 ) 2
L A1172
H
R B3
NCH 3
L A1232
R B1
R A52
Si(CH 3 ) 2
L A1173
H
R B4
NCH 3
L A1233
R B2
H
S
L A1174
H
R B5
NCH 3
L A1234
R B2
R B1
S
L A1175
H
R A34
NCH 3
L A1235
R B2
R B2
S
L A1176
H
R A52
NCH 3
L A1236
R B2
R B3
S
L A1177
H
H
C(CH 3 ) 2
L A1237
R B2
R B4
S
L A1178
H
R B1
C(CH 3 ) 2
L A1238
R B2
R B5
S
L A1179
H
R B2
C(CH 3 ) 2
L A1239
R B2
R A34
S
L A1180
H
R B3
C(CH 3 ) 2
L A1240
R B2
R A52
S
L A1181
H
R B4
C(CH 3 ) 2
L A1241
R B2
H
O
L A1182
H
R B5
C(CH 3 ) 2
L A1242
R B2
R B1
O
L A1183
H
R A34
C(CH 3 ) 2
L A1243
R B2
R B2
O
L A1184
H
R A52
C(CH 3 ) 2
L A1244
R B2
R B3
O
L A1185
H
H
Si(CH 3 ) 2
L A1245
R B2
R B4
O
L A1186
H
R B1
Si(CH 3 ) 2
L A1246
R B2
R B5
O
L A1187
H
R B2
Si(CH 3 ) 2
L A1247
R B2
R A34
O
L A1188
H
R B3
Si(CH 3 ) 2
L A1248
R B2
R A52
O
L A1189
H
R B4
Si(CH 3 ) 2
L A1249
R B2
H
NCH 3
L A1190
H
R B5
Si(CH 3 ) 2
L A1250
R B2
R B1
NCH 3
L A1191
H
R A34
Si(CH 3 ) 2
L A1251
R B2
R B2
NCH 3
L A1192
H
R A52
Si(CH 3 ) 2
L A1252
R B2
R B3
NCH 3
L A1193
R B1
H
S
L A1253
R B2
R B4
NCH 3
L A1194
R B1
R B1
S
L A1254
R B2
R B5
NCH 3
L A1195
R B1
R B2
S
L A1255
R B2
R A34
NCH 3
L A1196
R B1
R B3
S
L A1256
R B2
R A52
NCH 3
L A1197
R B1
R B4
S
L A1257
R B2
H
C(CH 3 ) 2
L A1198
R B1
R B5
S
L A1258
R B2
R B1
C(CH 3 ) 2
L A1199
R B1
R A34
S
L A1259
R B2
R B2
C(CH 3 ) 2
L A1200
R B1
R A52
S
L A1260
R B2
R B3
C(CH 3 ) 2
L A1201
R B1
H
O
L A1261
R B2
R B4
C(CH 3 ) 2
L A1202
R B1
R B1
O
L A1262
R B2
R B5
C(CH 3 ) 2
L A1203
R B1
R B2
O
L A1263
R B2
R A34
C(CH 3 ) 2
L A1204
R B1
R B3
O
L A1264
R B2
R A52
C(CH 3 ) 2
L A1205
R B1
R B4
O
L A1265
R B2
H
Si(CH 3 ) 2
L A1206
R B1
R B5
O
L A1266
R B2
R B1
Si(CH 3 ) 2
L A1207
R B1
R A34
O
L A1267
R B2
R B2
Si(CH 3 ) 2
L A1208
R B1
R A52
O
L A1268
R B2
R B3
Si(CH 3 ) 2
L A1209
R B1
H
NCH 3
L A1269
R B2
R B4
Si(CH 3 ) 2
L A1210
R B1
R B1
NCH 3
L A1270
R B2
R B5
Si(CH 3 ) 2
L A1211
R B1
R B2
NCH 3
L A1271
R B2
R A34
Si(CH 3 ) 2
L A1212
R B1
R B3
NCH 3
L A1272
R B2
R A52
Si(CH 3 ) 2
wherein L A1273 through L A1368 have a structure of Formula X:
wherein R 2 , R 4 , Y, and Z are defined as provided below:
Ligand
R 2
R 4
Y
Z
L A1273
H
H
S
S
L A1274
H
R B1
S
S
L A1275
H
R B3
S
S
L A1276
H
R B4
S
S
L A1277
H
R B7
S
S
L A1278
H
R B10
S
S
L A1279
H
R A3
S
S
L A1280
H
R A34
S
S
L A1281
H
H
S
O
L A1282
H
R B1
S
O
L A1283
H
R B3
S
O
L A1284
H
R B4
S
O
L A1285
H
R B7
S
O
L A1286
H
R B10
S
O
L A1287
H
R A3
S
O
L A1288
H
R A34
S
O
L A1289
H
H
S
NCH 3
L A1290
H
R B1
S
NCH 3
L A1291
H
R B3
S
NCH 3
L A1292
H
R B4
S
NCH 3
L A1293
H
R B7
S
NCH 3
L A1294
H
R B10
S
NCH 3
L A1295
H
R A3
S
NCH 3
L A1296
H
R A34
S
NCH 3
L A1297
H
H
O
S
L A1298
H
R B1
O
S
L A1299
H
R B3
O
S
L A1300
H
R B4
O
S
L A1301
H
R B7
O
S
L A1302
H
R B10
O
S
L A1303
H
R A3
O
S
L A1304
H
R A34
O
S
L A1305
H
H
O
O
L A1306
H
R B1
O
O
L A1307
H
R B3
O
O
L A1308
H
R B4
O
O
L A1309
H
R B7
O
O
L A1310
H
R B10
O
O
L A1311
H
R A3
O
O
L A1312
H
R A34
O
O
L A1313
H
H
O
NCH 3
L A1314
H
R B1
O
NCH 3
L A1315
H
R B3
O
NCH 3
L A1316
H
R B4
O
NCH 3
L A1317
H
R B7
O
NCH 3
L A1318
H
R B10
O
NCH 3
L A1319
H
R A3
O
NCH 3
L A1320
H
R A34
O
NCH 3
L A1321
R B1
H
S
S
L A1322
R B1
R B1
S
S
L A1323
R B1
R B3
S
S
L A1324
R B1
R B4
S
S
L A1325
R B1
R B7
S
S
L A1326
R B1
R B10
S
S
L A1327
R B1
R A3
S
S
L A1328
R B1
R A34
S
S
L A1329
R B1
H
S
O
L A1330
R B1
R B1
S
O
L A1331
R B1
R B3
S
O
L A1332
R B1
R B4
S
O
L A1333
R B1
R B7
S
O
L A1334
R B1
R B10
S
O
L A1335
R B1
R A3
S
O
L A1336
R B1
R A34
S
O
L A1337
R B1
H
S
NCH 3
L A1338
R B1
R B1
S
NCH 3
L A1339
R B1
R B3
S
NCH 3
L A1340
R B1
R B4
S
NCH 3
L A1341
R B1
R B7
S
NCH 3
L A1342
R B1
R B10
S
NCH 3
L A1343
R B1
R A3
S
NCH 3
L A1344
R B1
R A34
S
NCH 3
L A1345
R B1
H
O
S
L A1346
R B1
R B1
O
S
L A1347
R B1
R B3
O
S
L A1348
R B1
R B4
O
S
L A1349
R B1
R B7
O
S
L A1350
R B1
R B10
O
S
L A1351
R B1
R A3
O
S
L A1352
R B1
R A34
O
S
L A1353
R B1
H
O
O
L A1354
R B1
R B1
O
O
L A1355
R B1
R B3
O
O
L A1356
R B1
R B4
O
O
L A1357
R B1
R B7
O
O
L A1358
R B1
R B10
O
O
L A1359
R B1
R A3
O
O
L A1360
R B1
R A34
O
O
L A1361
R B1
H
O
NCH 3
L A1362
R B1
R B1
O
NCH 3
L A1363
R B1
R B3
O
NCH 3
L A1364
R B1
R B4
O
NCH 3
L A1365
R B1
R B7
O
NCH 3
L A1366
R B1
R B10
O
NCH 3
L A1367
R B1
R A3
O
NCH 3
L A1368
R B1
R A34
O
NCH 3
wherein L A1369 through L A1608 have a structure of Formula XI:
wherein R 1 , R 2 , X, and Y are defined as provided below:
Ligand
R 1
R 2
X
Y
L A1369
H
H
C
S
L A1370
R B1
H
C
S
L A1371
R B3
H
C
S
L A1372
R B4
H
C
S
L A1373
R B7
H
C
S
L A1374
R B10
H
C
S
L A1375
R A3
H
C
S
L A1376
R A34
H
C
S
L A1377
H
H
C
O
L A1378
R B1
H
C
O
L A1379
R B3
H
C
O
L A1380
R B4
H
C
O
L A1381
R B7
H
C
O
L A1382
R B10
H
C
O
L A1383
R A3
H
C
O
L A1384
R A34
H
C
O
L A1385
H
H
C
NCH 3
L A1386
R B1
H
C
NCH 3
L A1387
R B3
H
C
NCH 3
L A1388
R B4
H
C
NCH 3
L A1389
R B7
H
C
NCH 3
L A1390
R B10
H
C
NCH 3
L A1391
R A3
H
C
NCH 3
L A1392
R A34
H
C
NCH 3
L A1393
H
H
C
C(CH 3 ) 2
L A1394
R B1
H
C
C(CH 3 ) 2
L A1395
R B3
H
C
C(CH 3 ) 2
L A1396
R B4
H
C
C(CH 3 ) 2
L A1397
R B7
H
C
C(CH 3 ) 2
L A1398
R B10
H
C
C(CH 3 ) 2
L A1399
R A3
H
C
C(CH 3 ) 2
L A1400
R A34
H
C
C(CH 3 ) 2
L A1401
H
H
C
Si(CH 3 ) 2
L A1402
R B1
H
C
Si(CH 3 ) 2
L A1403
R B3
H
C
Si(CH 3 ) 2
L A1404
R B4
H
C
Si(CH 3 ) 2
L A1405
R B7
H
C
Si(CH 3 ) 2
L A1406
R B10
H
C
Si(CH 3 ) 2
L A1407
R A3
H
C
Si(CH 3 ) 2
L A1408
R A34
H
C
Si(CH 3 ) 2
L A1409
H
R B1
C
S
L A1410
R B1
R B1
C
S
L A1411
R B3
R B1
C
S
L A1412
R B4
R B1
C
S
L A1413
R B7
R B1
C
S
L A1414
R B10
R B1
C
S
L A1415
R A3
R B1
C
S
L A1416
R A34
R B1
C
S
L A1417
H
R B1
C
O
L A1418
R B1
R B1
C
O
L A1419
R B3
R B1
C
O
L A1420
R B4
R B1
C
O
L A1421
R B7
R B1
C
O
L A1422
R B10
R B1
C
O
L A1423
R A3
R B1
C
O
L A1424
R A34
R B1
C
O
L A1425
H
R B1
C
NCH 3
L A1426
R B1
R B1
C
NCH 3
L A1427
R B3
R B1
C
NCH 3
L A1428
R B4
R B1
C
NCH 3
L A1429
R B7
R B1
C
NCH 3
L A1430
R B10
R B1
C
NCH 3
L A1431
R A3
R B1
C
NCH 3
L A1432
R A34
R B1
C
NCH 3
L A1433
H
R B1
C
C(CH 3 ) 2
L A1434
R B1
R B1
C
C(CH 3 ) 2
L A1435
R B3
R B1
C
C(CH 3 ) 2
L A1436
R B4
R B1
C
C(CH 3 ) 2
L A1437
R B7
R B1
C
C(CH 3 ) 2
L A1438
R B10
R B1
C
C(CH 3 ) 2
L A1439
R A3
R B1
C
C(CH 3 ) 2
L A1440
R A34
R B1
C
C(CH 3 ) 2
L A1441
H
R B1
C
Si(CH 3 ) 2
L A1442
R B1
R B1
C
Si(CH 3 ) 2
L A1443
R B3
R B1
C
Si(CH 3 ) 2
L A1444
R B4
R B1
C
Si(CH 3 ) 2
L A1445
R B7
R B1
C
Si(CH 3 ) 2
L A1446
R B10
R B1
C
Si(CH 3 ) 2
L A1447
R A3
R B1
C
Si(CH 3 ) 2
L A1448
R A34
R B1
C
Si(CH 3 ) 2
L A1449
H
R B2
C
S
L A1450
R B1
R B2
C
S
L A1451
R B3
R B2
C
S
L A1452
R B4
R B2
C
S
L A1453
R B7
R B2
C
S
L A1454
R B10
R B2
C
S
L A1455
R A3
R B2
C
S
L A1456
R A34
R B2
C
S
L A1457
H
R B2
C
O
L A1458
R B1
R B2
C
O
L A1459
R B3
R B2
C
O
L A1460
R B4
R B2
C
O
L A1461
R B7
R B2
C
O
L A1462
R B10
R B2
C
O
L A1463
R A3
R B2
C
O
L A1464
R A34
R B2
C
O
L A1465
H
R B2
C
NCH 3
L A1466
R B1
R B2
C
NCH 3
L A1467
R B3
R B2
C
NCH 3
L A1468
R B4
R B2
C
NCH 3
L A1469
R B7
R B2
C
NCH 3
L A1470
R B10
R B2
C
NCH 3
L A1471
R A3
R B2
C
NCH 3
L A1472
R A34
R B2
C
NCH 3
L A1473
H
R B2
C
C(CH 3 ) 2
L A1474
R B1
R B2
C
C(CH 3 ) 2
L A1475
R B3
R B2
C
C(CH 3 ) 2
L A1476
R B4
R B2
C
C(CH 3 ) 2
L A1477
R B7
R B2
C
C(CH 3 ) 2
L A1478
R B10
R B2
C
C(CH 3 ) 2
L A1479
R A3
R B2
C
C(CH 3 ) 2
L A1480
R A34
R B2
C
C(CH 3 ) 2
L A1481
H
R B2
C
Si(CH 3 ) 2
L A1482
R B1
R B2
C
Si(CH 3 ) 2
L A1483
R B3
R B2
C
Si(CH 3 ) 2
L A1484
R B4
R B2
C
Si(CH 3 ) 2
L A1485
R B7
R B2
C
Si(CH 3 ) 2
L A1486
R B10
R B2
C
Si(CH 3 ) 2
L A1487
R A3
R B2
C
Si(CH 3 ) 2
L A1488
R A34
R B2
C
Si(CH 3 ) 2
L A1489
H
H
N
S
L A1490
R B1
H
N
S
L A1491
R B3
H
N
S
L A1492
R B4
H
N
S
L A1493
R B7
H
N
S
L A1494
R B10
H
N
S
L A1495
R A3
H
N
S
L A1496
R A34
H
N
S
L A1497
H
H
N
O
L A1498
R B1
H
N
O
L A1499
R B3
H
N
O
L A1500
R B4
H
N
O
L A1501
R B7
H
N
O
L A1502
R B10
H
N
O
L A1503
R A3
H
N
O
L A1504
R A34
H
N
O
L A1505
H
H
N
NCH 3
L A1506
R B1
H
N
NCH 3
L A1507
R B3
H
N
NCH 3
L A1508
R B4
H
N
NCH 3
L A1509
R B7
H
N
NCH 3
L A1510
R B10
H
N
NCH 3
L A1511
R A3
H
N
NCH 3
L A1512
R A34
H
N
NCH 3
L A1513
H
H
N
C(CH 3 ) 2
L A1514
R B1
H
N
C(CH 3 ) 2
L A1515
R B3
H
N
C(CH 3 ) 2
L A1516
R B4
H
N
C(CH 3 ) 2
L A1517
R B7
H
N
C(CH 3 ) 2
L A1518
R B10
H
N
C(CH 3 ) 2
L A1519
R A3
H
N
C(CH 3 ) 2
L A1520
R A34
H
N
C(CH 3 ) 2
L A1521
H
H
N
Si(CH 3 ) 2
L A1522
R B1
H
N
Si(CH 3 ) 2
L A1523
R B3
H
N
Si(CH 3 ) 2
L A1524
R B4
H
N
Si(CH 3 ) 2
L A1525
R B7
H
N
Si(CH 3 ) 2
L A1526
R B10
H
N
Si(CH 3 ) 2
L A1527
R A3
H
N
Si(CH 3 ) 2
L A1528
R A34
H
N
Si(CH 3 ) 2
L A1529
H
R B1
N
S
L A1530
R B1
R B1
N
S
L A1531
R B3
R B1
N
S
L A1532
R B4
R B1
N
S
L A1533
R B7
R B1
N
S
L A1534
R B10
R B1
N
S
L A1535
R A3
R B1
N
S
L A1536
R A34
R B1
N
S
L A1537
H
R B1
N
O
L A1538
R B1
R B1
N
O
L A1539
R B3
R B1
N
O
L A1540
R B4
R B1
N
O
L A1541
R B7
R B1
N
O
L A1542
R B10
R B1
N
O
L A1543
R A3
R B1
N
O
L A1544
R A34
R B1
N
O
L A1545
H
R B1
N
NCH 3
L A1546
R B1
R B1
N
NCH 3
L A1547
R B3
R B1
N
NCH 3
L A1548
R B4
R B1
N
NCH 3
L A1549
R B7
R B1
N
NCH 3
L A1550
R B10
R B1
N
NCH 3
L A1551
R A3
R B1
N
NCH 3
L A1552
R A34
R B1
N
NCH 3
L A1553
H
R B1
N
C(CH 3 ) 2
L A1554
R B1
R B1
N
C(CH 3 ) 2
L A1555
R B3
R B1
N
C(CH 3 ) 2
L A1556
R B4
R B1
N
C(CH 3 ) 2
L A1557
R B7
R B1
N
C(CH 3 ) 2
L A1558
R B10
R B1
N
C(CH 3 ) 2
L A1559
R A3
R B1
N
C(CH 3 ) 2
L A1560
R A34
R B1
N
C(CH 3 ) 2
L A1561
H
R B1
N
Si(CH 3 ) 2
L A1562
R B1
R B1
N
Si(CH 3 ) 2
L A1563
R B3
R B1
N
Si(CH 3 ) 2
L A1564
R B4
R B1
N
Si(CH 3 ) 2
L A1565
R B7
R B1
N
Si(CH 3 ) 2
L A1566
R B10
R B1
N
Si(CH 3 ) 2
L A1567
R A3
R B1
N
Si(CH 3 ) 2
L A1568
R A34
R B1
N
Si(CH 3 ) 2
L A1569
H
R B2
N
S
L A1570
R B1
R B2
N
S
L A1571
R B3
R B2
N
S
L A1572
R B4
R B2
N
S
L A1573
R B7
R B2
N
S
L A1574
R B10
R B2
N
S
L A1575
R A3
R B2
N
S
L A1576
R A34
R B2
N
S
L A1577
H
R B2
N
O
L A1578
R B1
R B2
N
O
L A1579
R B3
R B2
N
O
L A1580
R B4
R B2
N
O
L A1581
R B7
R B2
N
O
L A1582
R B10
R B2
N
O
L A1583
R A3
R B2
N
O
L A1584
R A34
R B2
N
O
L A1585
H
R B2
N
NCH 3
L A1586
R B1
R B2
N
NCH 3
L A1587
R B3
R B2
N
NCH 3
L A1588
R B4
R B2
N
NCH 3
L A1589
R B7
R B2
N
NCH 3
L A1590
R B10
R B2
N
NCH 3
L A1591
R A3
R B2
N
NCH 3
L A1592
R A34
R B2
N
NCH 3
L A1593
H
R B2
N
C(CH 3 ) 2
L A1594
R B1
R B2
N
C(CH 3 ) 2
L A1595
R B3
R B2
N
C(CH 3 ) 2
L A1596
R B4
R B2
N
C(CH 3 ) 2
L A1597
R B7
R B2
N
C(CH 3 ) 2
L A1598
R B10
R B2
N
C(CH 3 ) 2
L A1599
R A3
R B2
N
C(CH 3 ) 2
L A1600
R A34
R B2
N
C(CH 3 ) 2
L A1601
H
R B2
N
Si(CH 3 ) 2
L A1602
R B1
R B2
N
Si(CH 3 ) 2
L A1603
R B3
R B2
N
Si(CH 3 ) 2
L A1604
R B4
R B2
N
Si(CH 3 ) 2
L A1605
R B7
R B2
N
Si(CH 3 ) 2
L A1606
R B10
R B2
N
Si(CH 3 ) 2
L A1607
R A3
R B2
N
Si(CH 3 ) 2
L A1608
R A34
R B2
N
Si(CH 3 ) 2
wherein L A1609 through L A1728 have a structure of Formula XII:
wherein R 2 , R 3 , and Y are defined as provided below:
Ligand
R 2
R 3
Y
L A1609
H
H
S
L A1610
H
R B1
S
L A1611
H
R B2
S
L A1612
H
R B3
S
L A1613
H
R B4
S
L A1614
H
R B5
S
L A1615
H
R A34
S
L A1616
H
R A52
S
L A1617
H
H
O
L A1618
H
R B1
O
L A1619
H
R B2
O
L A1620
H
R B3
O
L A1621
H
R B4
O
L A1622
H
R B5
O
L A1623
H
R A34
O
L A1624
H
R A52
O
L A1625
H
H
NCH 3
L A1626
H
R B1
NCH 3
L A1627
H
R B2
NCH 3
L A1628
H
R B3
NCH 3
L A1629
H
R B4
NCH 3
L A1630
H
R B5
NCH 3
L A1631
H
R A34
NCH 3
L A1632
H
R A52
NCH 3
L A1633
H
H
C(CH 3 ) 2
L A1634
H
R B1
C(CH 3 ) 2
L A1635
H
R B2
C(CH 3 ) 2
L A1636
H
R B3
C(CH 3 ) 2
L A1637
H
R B4
C(CH 3 ) 2
L A1638
H
R B5
C(CH 3 ) 2
L A1639
H
R A34
C(CH 3 ) 2
L A1640
H
R A52
C(CH 3 ) 2
L A1641
H
H
Si(CH 3 ) 2
L A1642
H
R B1
Si(CH 3 ) 2
L A1643
H
R B2
Si(CH 3 ) 2
L A1644
H
R B3
Si(CH 3 ) 2
L A1645
H
R B4
Si(CH 3 ) 2
L A1646
H
R B5
Si(CH 3 ) 2
L A1647
H
R A34
Si(CH 3 ) 2
L A1648
H
R A52
Si(CH 3 ) 2
L A1649
R B1
H
S
L A1650
R B1
R B1
S
L A1651
R B1
R B2
S
L A1652
R B1
R B3
S
L A1653
R B1
R B4
S
L A1654
R B1
R B5
S
L A1655
R B1
R A34
S
L A1656
R B1
R A52
S
L A1657
R B1
H
O
L A1658
R B1
R B1
O
L A1659
R B1
R B2
O
L A1660
R B1
R B3
O
L A1661
R B1
R B4
O
L A1662
R B1
R B5
O
L A1663
R B1
R A34
O
L A1664
R B1
R A52
O
L A1665
R B1
H
NCH 3
L A1666
R B1
R B1
NCH 3
L A1667
R B1
R B2
NCH 3
L A1668
R B1
R B3
NCH 3
L A1669
R B1
R B4
NCH 3
L A1670
R B1
R B5
NCH 3
L A1671
R B1
R A34
NCH 3
L A1672
R B1
R A52
NCH 3
L A1673
R B1
H
C(CH 3 ) 2
L A1674
R B1
R B1
C(CH 3 ) 2
L A1675
R B1
R B2
C(CH 3 ) 2
L A1676
R B1
R B3
C(CH 3 ) 2
L A1677
R B1
R B4
C(CH 3 ) 2
L A1678
R B1
R B5
C(CH 3 ) 2
L A1679
R B1
R A34
C(CH 3 ) 2
L A1680
R B1
R A52
C(CH 3 ) 2
L A1681
R B1
H
Si(CH 3 ) 2
L A1682
R B1
R B1
Si(CH 3 ) 2
L A1683
R B1
R B2
Si(CH 3 ) 2
L A1684
R B1
R B3
Si(CH 3 ) 2
L A1685
R B1
R B4
Si(CH 3 ) 2
L A1686
R B1
R B5
Si(CH 3 ) 2
L A1687
R B1
R A34
Si(CH 3 ) 2
L A1688
R B1
R A52
Si(CH 3 ) 2
L A1689
R B2
H
S
L A1690
R B2
R B1
S
L A1691
R B2
R B2
S
L A1692
R B2
R B3
S
L A1693
R B2
R B4
S
L A1694
R B2
R B5
S
L A1695
R B2
R A34
S
L A1696
R B2
R A52
S
L A1697
R B2
H
O
L A1698
R B2
R B1
O
L A1699
R B2
R B2
O
L A1700
R B2
R B3
O
L A1701
R B2
R B4
O
L A1702
R B2
R B5
O
L A1703
R B2
R A34
O
L A1704
R B2
R A52
O
L A1705
R B2
H
NCH 3
L A1706
R B2
R B1
NCH 3
L A1707
R B2
R B2
NCH 3
L A1708
R B2
R B3
NCH 3
L A1709
R B2
R B4
NCH 3
L A1710
R B2
R B5
NCH 3
L A1711
R B2
R A34
NCH 3
L A1712
R B2
R A52
NCH 3
L A1713
R B2
H
C(CH 3 ) 2
L A1714
R B2
R B1
C(CH 3 ) 2
L A1715
R B2
R B2
C(CH 3 ) 2
L A1716
R B2
R B3
C(CH 3 ) 2
L A1717
R B2
R B4
C(CH 3 ) 2
L A1718
R B2
R B5
C(CH 3 ) 2
L A1719
R B2
R A34
C(CH 3 ) 2
L A1720
R B2
R A52
C(CH 3 ) 2
L A1721
R B2
H
Si(CH 3 ) 2
L A1722
R B2
R B1
Si(CH 3 ) 2
L A1723
R B2
R B2
Si(CH 3 ) 2
L A1724
R B2
R B3
Si(CH 3 ) 2
L A1725
R B2
R B4
Si(CH 3 ) 2
L A1726
R B2
R B5
Si(CH 3 ) 2
L A1727
R B2
R A34
Si(CH 3 ) 2
L A1728
R B2
R A52
Si(CH 3 ) 2
wherein L A1729 through L A1824 have a structure of Formula XIII:
wherein R 2 , R 4 , Y, and Z are defined as provided below:
Ligand
R 2
R 4
Y
Z
L A1729
H
H
S
S
L A1730
H
R B1
S
S
L A1731
H
R B3
S
S
L A1732
H
R B4
S
S
L A1733
H
R B7
S
S
L A1734
H
R B10
S
S
L A1735
H
R A3
S
S
L A1736
H
R A34
S
S
L A1737
H
H
S
O
L A1738
H
R B1
S
O
L A1739
H
R B3
S
O
L A1740
H
R B4
S
O
L A1741
H
R B7
S
O
L A1742
H
R B10
S
O
L A1743
H
R A3
S
O
L A1744
H
R A34
S
O
L A1745
H
H
S
NCH 3
L A1746
H
R B1
S
NCH 3
L A1747
H
R B3
S
NCH 3
L A1748
H
R B4
S
NCH 3
L A1749
H
R B7
S
NCH 3
L A1750
H
R B10
S
NCH 3
L A1751
H
R A3
S
NCH 3
L A1752
H
R A34
S
NCH 3
L A1753
H
H
O
S
L A1754
H
R B1
O
S
L A1755
H
R B3
O
S
L A1756
H
R B4
O
S
L A1757
H
R B7
O
S
L A1758
H
R B10
O
S
L A1759
H
R A3
O
S
L A1760
H
R A34
O
S
L A1761
H
H
O
O
L A1762
H
R B1
O
O
L A1763
H
R B3
O
O
L A1764
H
R B4
O
O
L A1765
H
R B7
O
O
L A1766
H
R B10
O
O
L A1767
H
R A3
O
O
L A1768
H
R A34
O
O
L A1769
H
H
O
NCH 3
L A1770
H
R B1
O
NCH 3
L A1771
H
R B3
O
NCH 3
L A1772
H
R B4
O
NCH 3
L A1773
H
R B7
O
NCH 3
L A1774
H
R B10
O
NCH 3
L A1775
H
R A3
O
NCH 3
L A1776
H
R A34
O
NCH 3
L A1777
R B1
H
S
S
L A1778
R B1
R B1
S
S
L A1779
R B1
R B3
S
S
L A1780
R B1
R B4
S
S
L A1781
R B1
R B7
S
S
L A1782
R B1
R B10
S
S
L A1783
R B1
R A3
S
S
L A1784
R B1
R A34
S
S
L A1785
R B1
H
S
O
L A1786
R B1
R B1
S
O
L A1787
R B1
R B3
S
O
L A1788
R B1
R B4
S
O
L A1789
R B1
R B7
S
O
L A1790
R B1
R B10
S
O
L A1791
R B1
R A3
S
O
L A1792
R B1
R A34
S
O
L A1793
R B1
H
S
NCH 3
L A1794
R B1
R B1
S
NCH 3
L A1795
R B1
R B3
S
NCH 3
L A1796
R B1
R B4
S
NCH 3
L A1797
R B1
R B7
S
NCH 3
L A1798
R B1
R B10
S
NCH 3
L A1799
R B1
R A3
S
NCH 3
L A1800
R B1
R A34
S
NCH 3
L A1801
R B1
H
O
S
L A1802
R B1
R B1
O
S
L A1803
R B1
R B3
O
S
L A1804
R B1
R B4
O
S
L A1805
R B1
R B7
O
S
L A1806
R B1
R B10
O
S
L A1807
R B1
R A3
O
S
L A1808
R B1
R A34
O
S
L A1809
R B1
H
O
O
L A1810
R B1
R B1
O
O
L A1811
R B1
R B3
O
O
L A1812
R B1
R B4
O
O
L A1813
R B1
R B7
O
O
L A1814
R B1
R B10
O
O
L A1815
R B1
R A3
O
O
L A1816
R B1
R A34
O
O
L A1817
R B1
H
O
NCH 3
L A1818
R B1
R B1
O
NCH 3
L A1819
R B1
R B3
O
NCH 3
L A1820
R B1
R B4
O
NCH 3
L A1821
R B1
R B7
O
NCH 3
L A1822
R B1
R B10
O
NCH 3
L A1823
R B1
R A3
O
NCH 3
L A1824
R B1
R A34
O
NCH 3
wherein L A1825 through L A2064 have a structure of Formula XIV:
wherein R 1 , R 5 , X, and Y are defined as provided below:
Ligand
R 1
R 5
X
Y
L A1825
H
H
C
S
L A1826
R B1
H
C
S
L A1827
R B3
H
C
S
L A1828
R B4
H
C
S
L A1829
R B7
H
C
S
L A1830
R B10
H
C
S
L A1831
R A3
H
C
S
L A1832
R A34
H
C
S
L A1833
H
H
C
O
L A1834
R B1
H
C
O
L A1835
R B3
H
C
O
L A1836
R B4
H
C
O
L A1837
R B7
H
C
O
L A1838
R B10
H
C
O
L A1839
R A3
H
C
O
L A1840
R A34
H
C
O
L A1841
H
H
C
NCH 3
L A1842
R B1
H
C
NCH 3
L A1843
R B3
H
C
NCH 3
L A1844
R B4
H
C
NCH 3
L A1845
R B7
H
C
NCH 3
L A1846
R B10
H
C
NCH 3
L A1847
R A3
H
C
NCH 3
L A1848
R A34
H
C
NCH 3
L A1849
H
H
C
C(CH 3 ) 2
L A1850
R B1
H
C
C(CH 3 ) 2
L A1851
R B3
H
C
C(CH 3 ) 2
L A1852
R B4
H
C
C(CH 3 ) 2
L A1853
R B7
H
C
C(CH 3 ) 2
L A1854
R B10
H
C
C(CH 3 ) 2
L A1855
R A3
H
C
C(CH 3 ) 2
L A1856
R A34
H
C
C(CH 3 ) 2
L A1857
H
H
C
Si(CH 3 ) 2
L A1858
R B1
H
C
Si(CH 3 ) 2
L A1859
R B3
H
C
Si(CH 3 ) 2
L A1860
R B4
H
C
Si(CH 3 ) 2
L A1861
R B7
H
C
Si(CH 3 ) 2
L A1862
R B10
H
C
Si(CH 3 ) 2
L A1863
R A3
H
C
Si(CH 3 ) 2
L A1864
R A34
H
C
Si(CH 3 ) 2
L A1865
H
R B1
C
S
L A1866
R B1
R B1
C
S
L A1867
R B3
R B1
C
S
L A1868
R B4
R B1
C
S
L A1869
R B7
R B1
C
S
L A1870
R B10
R B1
C
S
L A1871
R A3
R B1
C
S
L A1872
R A34
R B1
C
S
L A1873
H
R B1
C
O
L A1874
R B1
R B1
C
O
L A1875
R B3
R B1
C
O
L A1876
R B4
R B1
C
O
L A1877
R B7
R B1
C
O
L A1878
R B10
R B1
C
O
L A1879
R A3
R B1
C
O
L A1880
R A34
R B1
C
O
L A1881
H
R B1
C
NCH 3
L A1882
R B1
R B1
C
NCH 3
L A1883
R B3
R B1
C
NCH 3
L A1884
R B4
R B1
C
NCH 3
L A1885
R B7
R B1
C
NCH 3
L A1886
R B10
R B1
C
NCH 3
L A1887
R A3
R B1
C
NCH 3
L A1888
R A34
R B1
C
NCH 3
L A1889
H
R B1
C
C(CH 3 ) 2
L A1890
R B1
R B1
C
C(CH 3 ) 2
L A1891
R B3
R B1
C
C(CH 3 ) 2
L A1892
R B4
R B1
C
C(CH 3 ) 2
L A1893
R B7
R B1
C
C(CH 3 ) 2
L A1894
R B10
R B1
C
C(CH 3 ) 2
L A1895
R A3
R B1
C
C(CH 3 ) 2
L A1896
R A34
R B1
C
C(CH 3 ) 2
L A1897
H
R B1
C
Si(CH 3 ) 2
L A1898
R B1
R B1
C
Si(CH 3 ) 2
L A1899
R B3
R B1
C
Si(CH 3 ) 2
L A1900
R B4
R B1
C
Si(CH 3 ) 2
L A1901
R B7
R B1
C
Si(CH 3 ) 2
L A1902
R B10
R B1
C
Si(CH 3 ) 2
L A1903
R A3
R B1
C
Si(CH 3 ) 2
L A1904
R A34
R B1
C
Si(CH 3 ) 2
L A1905
H
R B6
C
S
L A1906
R B1
R B6
C
S
L A1907
R B3
R B6
C
S
L A1908
R B4
R B6
C
S
L A1909
R B7
R B6
C
S
L A1910
R B10
R B6
C
S
L A1911
R A3
R B6
C
S
L A1912
R A34
R B6
C
S
L A1913
H
R B6
C
O
L A1914
R B1
R B6
C
O
L A1915
R B3
R B6
C
O
L A1916
R B4
R B6
C
O
L A1917
R B7
R B6
C
O
L A1918
R B10
R B6
C
O
L A1919
R A3
R B6
C
O
L A1920
R A34
R B6
C
O
L A1921
H
R B6
C
NCH 3
L A1922
R B1
R B6
C
NCH 3
L A1923
R B3
R B6
C
NCH 3
L A1924
R B4
R B6
C
NCH 3
L A1925
R B7
R B6
C
NCH 3
L A1926
R B10
R B6
C
NCH 3
L A1927
R A3
R B6
C
NCH 3
L A1928
R A34
R B6
C
NCH 3
L A1929
H
R B6
C
C(CH 3 ) 2
L A1930
R B1
R B6
C
C(CH 3 ) 2
L A1931
R B3
R B6
C
C(CH 3 ) 2
L A1932
R B4
R B6
C
C(CH 3 ) 2
L A1933
R B7
R B6
C
C(CH 3 ) 2
L A1934
R B10
R B6
C
C(CH 3 ) 2
L A1935
R A3
R B6
C
C(CH 3 ) 2
L A1936
R A34
R B6
C
C(CH 3 ) 2
L A1937
H
R B6
C
Si(CH 3 ) 2
L A1938
R B1
R B6
C
Si(CH 3 ) 2
L A1939
R B3
R B6
C
Si(CH 3 ) 2
L A1940
R B4
R B6
C
Si(CH 3 ) 2
L A1941
R B7
R B6
C
Si(CH 3 ) 2
L A1942
R B10
R B6
C
Si(CH 3 ) 2
L A1943
R A3
R B6
C
Si(CH 3 ) 2
L A1944
R A34
R B6
C
Si(CH 3 ) 2
L A1945
H
H
N
S
L A1946
R B1
H
N
S
L A1947
R B3
H
N
S
L A1948
R B4
H
N
S
L A1949
R B7
H
N
S
L A1950
R B10
H
N
S
L A1951
R A3
H
N
S
L A1952
R A34
H
N
S
L A1953
H
H
N
O
L A1954
R B1
H
N
O
L A1955
R B3
H
N
O
L A1956
R B4
H
N
O
L A1957
R B7
H
N
O
L A1958
R B10
H
N
O
L A1959
R A3
H
N
O
L A1960
R A34
H
N
O
L A1961
H
H
N
NCH 3
L A1962
R B1
H
N
NCH 3
L A1963
R B3
H
N
NCH 3
L A1964
R B4
H
N
NCH 3
L A1965
R B7
H
N
NCH 3
L A1966
R B10
H
N
NCH 3
L A1967
R A3
H
N
NCH 3
L A1968
R A34
H
N
NCH 3
L A1969
H
H
N
C(CH 3 ) 2
L A1970
R B1
H
N
C(CH 3 ) 2
L A1971
R B3
H
N
C(CH 3 ) 2
L A1972
R B4
H
N
C(CH 3 ) 2
L A1973
R B7
H
N
C(CH 3 ) 2
L A1974
R B10
H
N
C(CH 3 ) 2
L A1975
R A3
H
N
C(CH 3 ) 2
L A1976
R A34
H
N
C(CH 3 ) 2
L A1977
H
H
N
Si(CH 3 ) 2
L A1978
R B1
H
N
Si(CH 3 ) 2
L A1979
R B3
H
N
Si(CH 3 ) 2
L A1980
R B4
H
N
Si(CH 3 ) 2
L A1981
R B7
H
N
Si(CH 3 ) 2
L A1982
R B10
H
N
Si(CH 3 ) 2
L A1983
R A3
H
N
Si(CH 3 ) 2
L A1984
R A34
H
N
Si(CH 3 ) 2
L A1985
H
R B1
N
S
L A1986
R B1
R B1
N
S
L A1987
R B3
R B1
N
S
L A1988
R B4
R B1
N
S
L A1989
R B7
R B1
N
S
L A1990
R B10
R B1
N
S
L A1991
R A3
R B1
N
S
L A1992
R A34
R B1
N
S
L A1993
H
R B1
N
O
L A1994
R B1
R B1
N
O
L A1995
R B3
R B1
N
O
L A1996
R B4
R B1
N
O
L A1997
R B7
R B1
N
O
L A1998
R B10
R B1
N
O
L A1999
R A3
R B1
N
O
L A2000
R A34
R B1
N
O
L A2001
H
R B1
N
NCH 3
L A2002
R B1
R B1
N
NCH 3
L A2003
R B3
R B1
N
NCH 3
L A2004
R B4
R B1
N
NCH 3
L A2005
R B7
R B1
N
NCH 3
L A2006
R B10
R B1
N
NCH 3
L A2007
R A3
R B1
N
NCH 3
L A2008
R A34
R B1
N
NCH 3
L A2009
H
R B1
N
C(CH 3 ) 2
L A2010
R B1
R B1
N
C(CH 3 ) 2
L A2011
R B3
R B1
N
C(CH 3 ) 2
L A2012
R B4
R B1
N
C(CH 3 ) 2
L A2013
R B7
R B1
N
C(CH 3 ) 2
L A2014
R B10
R B1
N
C(CH 3 ) 2
L A2015
R A3
R B1
N
C(CH 3 ) 2
L A2016
R A34
R B1
N
C(CH 3 ) 2
L A2017
H
R B1
N
Si(CH 3 ) 2
L A2018
R B1
R B1
N
Si(CH 3 ) 2
L A2019
R B3
R B1
N
Si(CH 3 ) 2
L A2020
R B4
R B1
N
Si(CH 3 ) 2
L A2021
R B7
R B1
N
Si(CH 3 ) 2
L A2022
R B10
R B1
N
Si(CH 3 ) 2
L A2023
R A3
R B1
N
Si(CH 3 ) 2
L A2024
R A34
R B1
N
Si(CH 3 ) 2
L A2025
H
R B6
N
S
L A2026
R B1
R B6
N
S
L A2027
R B3
R B6
N
S
L A2028
R B4
R B6
N
S
L A2029
R B7
R B6
N
S
L A2030
R B10
R B6
N
S
L A2031
R A3
R B6
N
S
L A2032
R A34
R B6
N
S
L A2033
H
R B6
N
O
L A2034
R B1
R B6
N
O
L A2035
R B3
R B6
N
O
L A2036
R B4
R B6
N
O
L A2037
R B7
R B6
N
O
L A2038
R B10
R B6
N
O
L A2039
R A3
R B6
N
O
L A2040
R A34
R B6
N
O
L A2041
H
R B6
N
NCH 3
L A2042
R B1
R B6
N
NCH 3
L A2043
R B3
R B6
N
NCH 3
L A2044
R B4
R B6
N
NCH 3
L A2045
R B7
R B6
N
NCH 3
L A2046
R B10
R B6
N
NCH 3
L A2047
R A3
R B6
N
NCH 3
L A2048
R A34
R B6
N
NCH 3
L A2049
H
R B6
N
C(CH 3 ) 2
L A2050
R B1
R B6
N
C(CH 3 ) 2
L A2051
R B3
R B6
N
C(CH 3 ) 2
L A2052
R B4
R B6
N
C(CH 3 ) 2
L A2053
R B7
R B6
N
C(CH 3 ) 2
L A2054
R B10
R B6
N
C(CH 3 ) 2
L A2055
R A3
R B6
N
C(CH 3 ) 2
L A2056
R A34
R B6
N
C(CH 3 ) 2
L A2057
H
R B6
N
Si(CH 3 ) 2
L A2058
R B1
R B6
N
Si(CH 3 ) 2
L A2059
R B3
R B6
N
Si(CH 3 ) 2
L A2060
R B4
R B6
N
Si(CH 3 ) 2
L A2061
R B7
R B6
N
Si(CH 3 ) 2
L A2062
R B10
R B6
N
Si(CH 3 ) 2
L A2063
R A3
R B6
N
Si(CH 3 ) 2
L A2064
R A34
R B6
N
Si(CH 3 ) 2
wherein L A2065 through L A2184 have a structure of Formula XV:
wherein R 3 , R 5 , and Y are defined as provided below:
Ligand
R 5
R 3
Y
Ligand
R 5
R 3
R 14
L A2065
H
H
S
L A2125
R B1
R B4
NCH 3
L A2066
H
R B1
S
L A2126
R B1
R B5
NCH 3
L A2067
H
R B2
S
L A2127
R B1
R A34
NCH 3
L A2068
H
R B3
S
L A2128
R B1
R A52
NCH 3
L A2069
H
R B4
S
L A2129
R B1
H
C(CH 3 ) 2
L A2070
H
R B5
S
L A2130
R B1
R B1
C(CH 3 ) 2
L A2071
H
R A34
S
L A2131
R B1
R B2
C(CH 3 ) 2
L A2072
H
R A52
S
L A2132
R B1
R B3
C(CH 3 ) 2
L A2073
H
H
O
L A2133
R B1
R B4
C(CH 3 ) 2
L A2074
H
R B1
O
L A2134
R B1
R B5
C(CH 3 ) 2
L A2075
H
R B2
O
L A2135
R B1
R A34
C(CH 3 ) 2
L A2076
H
R B3
O
L A2136
R B1
R A52
C(CH 3 ) 2
L A2077
H
R B4
O
L A2137
R B1
H
Si(CH 3 ) 2
L A2078
H
R B5
O
L A2138
R B1
R B1
Si(CH 3 ) 2
L A2079
H
R A34
O
L A2139
R B1
R B2
Si(CH 3 ) 2
L A2080
H
R A52
O
L A2140
R B1
R B3
Si(CH 3 ) 2
L A2081
H
H
NCH 3
L A2141
R B1
R B4
Si(CH 3 ) 2
L A2082
H
R B1
NCH 3
L A2142
R B1
R B5
Si(CH 3 ) 2
L A2083
H
R B2
NCH 3
L A2143
R B1
R A34
Si(CH 3 ) 2
L A2084
H
R B3
NCH 3
L A2144
R B1
R A52
Si(CH 3 ) 2
L A2085
H
R B4
NCH 3
L A2145
R B6
H
S
L A2086
H
R B5
NCH 3
L A2146
R B6
R B1
S
L A2087
H
R A34
NCH 3
L A2147
R B6
R B2
S
L A2088
H
R A52
NCH 3
L A2148
R B6
R B3
S
L A2089
H
H
C(CH 3 ) 2
L A2149
R B6
R B4
S
L A2090
H
R B1
C(CH 3 ) 2
L A2150
R B6
R B5
S
L A2091
H
R B2
C(CH 3 ) 2
L A2151
R B6
R A34
S
L A2092
H
R B3
C(CH 3 ) 2
L A2152
R B6
R A52
S
L A2093
H
R B4
C(CH 3 ) 2
L A2153
R B6
H
O
L A2094
H
R B5
C(CH 3 ) 2
L A2154
R B6
R B1
O
L A2095
H
R A34
C(CH 3 ) 2
L A2155
R B6
R B2
O
L A2096
H
R A52
C(CH 3 ) 2
L A2156
R B6
R B3
O
L A2097
H
H
Si(CH 3 ) 2
L A2157
R B6
R B4
O
L A2098
H
R B1
Si(CH 3 ) 2
L A2158
R B6
R B5
O
L A2099
H
R B2
Si(CH 3 ) 2
L A2159
R B6
R A34
O
L A2100
H
R B3
Si(CH 3 ) 2
L A2160
R B6
R A52
O
L A2101
H
R B4
Si(CH 3 ) 2
L A2161
R B6
H
NCH 3
L A2102
H
R B5
Si(CH 3 ) 2
L A2162
R B6
R B1
NCH 3
L A2103
H
R A34
Si(CH 3 ) 2
L A2163
R B6
R B2
NCH 3
L A2104
H
R A52
Si(CH 3 ) 2
L A2164
R B6
R B3
NCH 3
L A2105
R B1
H
S
L A2165
R B6
R B4
NCH 3
L A2106
R B1
R B1
S
L A2166
R B6
R B5
NCH 3
L A2107
R B1
R B2
S
L A2167
R B6
R A34
NCH 3
L A2108
R B1
R B3
S
L A2168
R B6
R A52
NCH 3
L A2109
R B1
R B4
S
L A2169
R B6
H
C(CH 3 ) 2
L A2110
R B1
R B5
S
L A2170
R B6
R B1
C(CH 3 ) 2
L A2111
R B1
R A34
S
L A2171
R B6
R B2
C(CH 3 ) 2
L A2112
R B1
R A52
S
L A2172
R B6
R B3
C(CH 3 ) 2
L A2113
R B1
H
O
L A2173
R B6
R B4
C(CH 3 ) 2
L A2114
R B1
R B1
O
L A2174
R B6
R B5
C(CH 3 ) 2
L A2115
R B1
R B2
O
L A2175
R B6
R A34
C(CH 3 ) 2
L A2116
R B1
R B3
O
L A2176
R B6
R A52
C(CH 3 ) 2
L A2117
R B1
R B4
O
L A2177
R B6
H
Si(CH 3 ) 2
L A2118
R B1
R B5
O
L A2178
R B6
R B1
Si(CH 3 ) 2
L A2119
R B1
R A34
O
L A2179
R B6
R B2
Si(CH 3 ) 2
L A2120
R B1
R A52
O
L A2180
R B6
R B3
Si(CH 3 ) 2
L A2121
R B1
H
NCH 3
L A2181
R B6
R B4
Si(CH 3 ) 2
L A2122
R B1
R B1
NCH 3
L A2182
R B6
R B5
Si(CH 3 ) 2
L A2123
R B1
R B2
NCH 3
L A2183
R B6
R A34
Si(CH 3 ) 2
L A2124
R B1
R B3
NCH 3
L A2184
R B6
R A52
Si(CH 3 ) 2
wherein L A2185 through L A2280 have a structure of Formula XVI:
wherein R 4 , R 5 , Y, and Z are defined as provided below:
Ligand
R 5
R 4
Y
Z
L A2185
H
H
S
S
L A2186
H
R B1
S
S
L A2187
H
R B3
S
S
L A2188
H
R B4
S
S
L A2189
H
R B7
S
S
L A2190
H
R B10
S
S
L A2191
H
R A3
S
S
L A2192
H
R A34
S
S
L A2193
H
H
S
O
L A2194
H
R B1
S
O
L A2195
H
R B3
S
O
L A2196
H
R B4
S
O
L A2197
H
R B7
S
O
L A2198
H
R B10
S
O
L A2199
H
R A3
S
O
L A2200
H
R A34
5
O
L A2201
H
H
S
NCH 3
L A2202
H
R B1
S
NCH 3
L A2203
H
R B3
S
NCH 3
L A2204
H
R B4
S
NCH 3
L A2205
H
R B7
S
NCH 3
L A2206
H
R B10
S
NCH 3
L A2207
H
R A3
S
NCH 3
L A2208
H
R A34
S
NCH 3
L A2209
H
H
O
S
L A2210
H
R B1
O
S
L A2211
H
R B3
O
S
L A2212
H
R B4
O
S
L A2213
H
R B7
O
S
L A2214
H
R B10
O
S
L A2215
H
R A3
O
S
L A2216
H
R A34
O
S
L A2217
H
H
O
O
L A2218
H
R B1
O
O
L A2219
H
R B3
O
O
L A2220
H
R B4
O
O
L A2221
H
R B7
O
O
L A2222
H
R B10
O
O
L A2223
H
R A3
O
O
L A2224
H
R A34
O
O
L A2225
H
H
O
NCH 3
L A2226
H
R B1
O
NCH 3
L A2227
H
R B3
O
NCH 3
L A2228
H
R B4
O
NCH 3
L A2229
H
R B7
O
NCH 3
L A2230
H
R B10
O
NCH 3
L A2231
H
R A3
O
NCH 3
L A2232
H
R A34
O
NCH 3
L A2233
R B6
H
S
S
L A2234
R B6
R B1
S
S
L A2235
R B6
R B3
S
S
L A2236
R B6
R B4
S
S
L A2237
R B6
R B7
S
S
L A2238
R B6
R B10
S
S
L A2239
R B6
R A3
S
S
L A2240
R B6
R A34
S
S
L A2241
R B6
H
S
O
L A2242
R B6
R B1
S
O
L A2243
R B6
R B3
S
O
L A2244
R B6
R B4
S
O
L A2245
R B6
R B7
S
O
L A2246
R B6
R B10
S
O
L A2247
R B6
R A3
S
O
L A2248
R B6
R A34
5
O
L A2249
R B6
H
S
NCH 3
L A2250
R B6
R B1
S
NCH 3
L A2251
R B6
R B3
S
NCH 3
L A2252
R B6
R B4
S
NCH 3
L A2253
R B6
R B7
S
NCH 3
L A2254
R B6
R B10
S
NCH 3
L A2255
R B6
R A3
S
NCH 3
L A2256
R B6
R A34
S
NCH 3
L A2257
R B6
H
O
S
L A2258
R B6
R B1
O
S
L A2259
R B6
R B3
O
S
L A2260
R B6
R B4
O
S
L A2261
R B6
R B7
O
S
L A2262
R B6
R B10
O
S
L A2263
R B6
R A3
O
S
L A2264
R B6
R A34
O
S
L A2265
R B6
H
O
O
L A2266
R B6
R B1
O
O
L A2267
R B6
R B3
O
O
L A2268
R B6
R B4
O
O
L A2269
R B6
R B7
O
O
L A2270
R B6
R B10
O
O
L A2271
R B6
R A3
O
O
L A2272
R B6
R A34
O
O
L A2273
R B6
H
O
NCH 3
L A2274
R B6
R B1
O
NCH 3
L A2275
R B6
R B3
O
NCH 3
L A2276
R B6
R B4
O
NCH 3
L A2277
R B6
R B7
O
NCH 3
L A2278
R B6
R B10
O
NCH 3
L A2279
R B6
R A3
O
NCH 3
L A2280
R B6
R A34
O
NCH 3
wherein L A2281 through L A2520 have a structure of Formula XVII:
wherein R 1 , R 5 , X, and Y are defined as provided below:
Ligand
R 1
R 5
X
Y
L A2281
H
H
C
S
L A2282
R B1
H
C
S
L A2283
R B3
H
C
S
L A2284
R B4
H
C
S
L A2285
R B7
H
C
S
L A2286
R B10
H
C
S
L A2287
R A3
H
C
S
L A2288
R A34
H
C
S
L A2289
H
H
C
O
L A2290
R B1
H
C
O
L A2291
R B3
H
C
O
L A2292
R B4
H
C
O
L A2293
R B7
H
C
O
L A2294
R B10
H
C
O
L A2295
R A3
H
C
O
L A2296
R A34
H
C
O
L A2297
H
H
C
NCH 3
L A2298
R B1
H
C
NCH 3
L A2299
R B3
H
C
NCH 3
L A2300
R B4
H
C
NCH 3
L A2301
R B7
H
C
NCH 3
L A2302
R B10
H
C
NCH 3
L A2303
R A3
H
C
NCH 3
L A2304
R A34
H
C
NCH 3
L A2305
H
H
C
C(CH 3 ) 2
L A2306
R B1
H
C
C(CH 3 ) 2
L A2307
R B3
H
C
C(CH 3 ) 2
L A2308
R B4
H
C
C(CH 3 ) 2
L A2309
R B7
H
C
C(CH 3 ) 2
L A2310
R B10
H
C
C(CH 3 ) 2
L A2311
R A3
H
C
C(CH 3 ) 2
L A2312
R A34
H
C
C(CH 3 ) 2
L A2313
H
H
C
Si(CH 3 ) 2
L A2314
R B1
H
C
Si(CH 3 ) 2
L A2315
R B3
H
C
Si(CH 3 ) 2
L A2316
R B4
H
C
Si(CH 3 ) 2
L A2317
R B7
H
C
Si(CH 3 ) 2
L A2318
R B10
H
C
Si(CH 3 ) 2
L A2319
R A3
H
C
Si(CH 3 ) 2
L A2320
R A34
H
C
Si(CH 3 ) 2
L A2321
H
R B1
C
S
L A2322
R B1
R B1
C
S
L A2323
R B3
R B1
C
S
L A2324
R B4
R B1
C
S
L A2325
R B7
R B1
C
S
L A2326
R B10
R B1
C
S
L A2327
R A3
R B1
C
S
L A2328
R A34
R B1
C
S
L A2329
H
R B1
C
O
L A2330
R B1
R B1
C
O
L A2331
R B3
R B1
C
O
L A2332
R B4
R B1
C
O
L A2333
R B7
R B1
C
O
L A2334
R B10
R B1
C
O
L A2335
R A3
R B1
C
O
L A2336
R A34
R B1
C
O
L A2337
H
R B1
C
NCH 3
L A2338
R B1
R B1
C
NCH 3
L A2339
R B3
R B1
C
NCH 3
L A2340
R B4
R B1
C
NCH 3
L A2341
R B7
R B1
C
NCH 3
L A2342
R B10
R B1
C
NCH 3
L A2343
R A3
R B1
C
NCH 3
L A2344
R A34
R B1
C
NCH 3
L A2345
H
R B1
C
C(CH 3 ) 2
L A2346
R B1
R B1
C
C(CH 3 ) 2
L A2347
R B3
R B1
C
C(CH 3 ) 2
L A2348
R B4
R B1
C
C(CH 3 ) 2
L A2349
R B7
R B1
C
C(CH 3 ) 2
L A2350
R B10
R B1
C
C(CH 3 ) 2
L A2351
R A3
R B1
C
C(CH 3 ) 2
L A2352
R A34
R B1
C
C(CH 3 ) 2
L A2353
H
R B1
C
Si(CH 3 ) 2
L A2354
R B1
R B1
C
Si(CH 3 ) 2
L A2355
R B3
R B1
C
Si(CH 3 ) 2
L A2356
R B4
R B1
C
Si(CH 3 ) 2
L A2357
R B7
R B1
C
Si(CH 3 ) 2
L A2358
R B10
R B1
C
Si(CH 3 ) 2
L A2359
R A3
R B1
C
Si(CH 3 ) 2
L A2360
R A34
R B1
C
Si(CH 3 ) 2
L A2361
H
R B6
C
S
L A2362
R B1
R B6
C
S
L A2363
R B3
R B6
C
S
L A2364
R B4
R B6
C
S
L A2365
R B7
R B6
C
S
L A2366
R B10
R B6
C
S
L A2367
R A3
R B6
C
S
L A2368
R A34
R B6
C
S
L A2369
H
R B6
C
O
L A2370
R B1
R B6
C
O
L A2371
R B3
R B6
C
O
L A2372
R B4
R B6
C
O
L A2373
R B7
R B6
C
O
L A2374
R B10
R B6
C
O
L A2375
R A3
R B6
C
O
L A2376
R A34
R B6
C
O
L A2377
H
R B6
C
NCH 3
L A2378
R B1
R B6
C
NCH 3
L A2379
R B3
R B6
C
NCH 3
L A2380
R B4
R B6
C
NCH 3
L A2381
R B7
R B6
C
NCH 3
L A2382
R B10
R B6
C
NCH 3
L A2383
R A3
R B6
C
NCH 3
L A2384
R A34
R B6
C
NCH 3
L A2385
H
R B6
C
C(CH 3 ) 2
L A2386
R B1
R B6
C
C(CH 3 ) 2
L A2387
R B3
R B6
C
C(CH 3 ) 2
L A2388
R B4
R B6
C
C(CH 3 ) 2
L A2389
R B7
R B6
C
C(CH 3 ) 2
L A2390
R B10
R B6
C
C(CH 3 ) 2
L A2391
R A3
R B6
C
C(CH 3 ) 2
L A2392
R A34
R B6
C
C(CH 3 ) 2
L A2393
H
R B6
C
Si(CH 3 ) 2
L A2394
R B1
R B6
C
Si(CH 3 ) 2
L A2395
R B3
R B6
C
Si(CH 3 ) 2
L A2396
R B4
R B6
C
Si(CH 3 ) 2
L A2397
R B7
R B6
C
Si(CH 3 ) 2
L A2398
R B10
R B6
C
Si(CH 3 ) 2
L A2399
R A3
R B6
C
Si(CH 3 ) 2
L A2400
R A34
R B6
C
Si(CH 3 ) 2
L A2401
H
H
N
S
L A2402
R B1
H
N
S
L A2403
R B3
H
N
S
L A2404
R B4
H
N
S
L A2405
R B7
H
N
S
L A2406
R B10
H
N
S
L A2407
R A3
H
N
S
L A2408
R A34
H
N
S
L A2409
H
H
N
O
L A2410
R B1
H
N
O
L A2411
R B3
H
N
O
L A2412
R B4
H
N
O
L A2413
R B7
H
N
O
L A2414
R B10
H
N
O
L A2415
R A3
H
N
O
L A2416
R A34
H
N
O
L A2417
H
H
N
NCH 3
L A2418
R B1
H
N
NCH 3
L A2419
R B3
H
N
NCH 3
L A2420
R B4
H
N
NCH 3
L A2421
R B7
H
N
NCH 3
L A2422
R B10
H
N
NCH 3
L A2423
R A3
H
N
NCH 3
L A2424
R A34
H
N
NCH 3
L A2425
H
H
N
C(CH 3 ) 2
L A2426
R B1
H
N
C(CH 3 ) 2
L A2427
R B3
H
N
C(CH 3 ) 2
L A2428
R B4
H
N
C(CH 3 ) 2
L A2429
R B7
H
N
C(CH 3 ) 2
L A2430
R B10
H
N
C(CH 3 ) 2
L A2431
R A3
H
N
C(CH 3 ) 2
L A2432
R A34
H
N
C(CH 3 ) 2
L A2433
H
H
N
Si(CH 3 ) 2
L A2434
R B1
H
N
Si(CH 3 ) 2
L A2435
R B3
H
N
Si(CH 3 ) 2
L A2436
R B4
H
N
Si(CH 3 ) 2
L A2437
R B7
H
N
Si(CH 3 ) 2
L A2438
R B10
H
N
Si(CH 3 ) 2
L A2439
R A3
H
N
Si(CH 3 ) 2
L A2440
R A34
H
N
Si(CH 3 ) 2
L A2441
H
R B1
N
S
L A2442
R B1
R B1
N
S
L A2443
R B3
R B1
N
S
L A2444
R B4
R B1
N
S
L A2445
R B7
R B1
N
S
L A2446
R B10
R B1
N
S
L A2447
R A3
R B1
N
S
L A2448
R A34
R B1
N
S
L A2449
H
R B1
N
O
L A2450
R B1
R B1
N
O
L A2451
R B3
R B1
N
O
L A2452
R B4
R B1
N
O
L A2453
R B7
R B1
N
O
L A2454
R B10
R B1
N
O
L A2455
R A3
R B1
N
O
L A2456
R A34
R B1
N
O
L A2457
H
R B1
N
NCH 3
L A2458
R B1
R B1
N
NCH 3
L A2459
R B3
R B1
N
NCH 3
L A2460
R B4
R B1
N
NCH 3
L A2461
R B7
R B1
N
NCH 3
L A2462
R B10
R B1
N
NCH 3
L A2463
R A3
R B1
N
NCH 3
L A2464
R A34
R B1
N
NCH 3
L A2465
H
R B1
N
C(CH 3 ) 2
L A2466
R B1
R B1
N
C(CH 3 ) 2
L A2467
R B3
R B1
N
C(CH 3 ) 2
L A2468
R B4
R B1
N
C(CH 3 ) 2
L A2469
R B7
R B1
N
C(CH 3 ) 2
L A2470
R B10
R B1
N
C(CH 3 ) 2
L A2471
R A3
R B1
N
C(CH 3 ) 2
L A2472
R A34
R B1
N
C(CH 3 ) 2
L A2473
H
R B1
N
Si(CH 3 ) 2
L A2474
R B1
R B1
N
Si(CH 3 ) 2
L A2475
R B3
R B1
N
Si(CH 3 ) 2
L A2476
R B4
R B1
N
Si(CH 3 ) 2
L A2477
R B7
R B1
N
Si(CH 3 ) 2
L A2478
R B10
R B1
N
Si(CH 3 ) 2
L A2479
R A3
R B1
N
Si(CH 3 ) 2
L A2480
R A34
R B1
N
Si(CH 3 ) 2
L A2481
H
R B6
N
S
L A2482
R B1
R B6
N
S
L A2483
R B3
R B6
N
S
L A2484
R B4
R B6
N
S
L A2485
R B7
R B6
N
S
L A2486
R B10
R B6
N
S
L A2487
R A3
R B6
N
S
L A2488
R A34
R B6
N
S
L A2489
H
R B6
N
O
L A2490
R B1
R B6
N
O
L A2491
R B3
R B6
N
O
L A2492
R B4
R B6
N
O
L A2493
R B7
R B6
N
O
L A2494
R B10
R B6
N
O
L A2495
R A3
R B6
N
O
L A2496
R A34
R B6
N
O
L A2497
H
R B6
N
NCH 3
L A2498
R B1
R B6
N
NCH 3
L A2499
R B3
R B6
N
NCH 3
L A2500
R B4
R B6
N
NCH 3
L A2501
R B7
R B6
N
NCH 3
L A2502
R B10
R B6
N
NCH 3
L A2503
R A3
R B6
N
NCH 3
L A2504
R A34
R B6
N
NCH 3
L A2505
H
R B6
N
C(CH 3 ) 2
L A2506
R B1
R B6
N
C(CH 3 ) 2
L A2507
R B3
R B6
N
C(CH 3 ) 2
L A2508
R B4
R B6
N
C(CH 3 ) 2
L A2509
R B7
R B6
N
C(CH 3 ) 2
L A2510
R B10
R B6
N
C(CH 3 ) 2
L A2511
R A3
R B6
N
C(CH 3 ) 2
L A2512
R A34
R B6
N
C(CH 3 ) 2
L A2513
H
R B6
N
Si(CH 3 ) 2
L A2514
R B1
R B6
N
Si(CH 3 ) 2
L A2515
R B3
R B6
N
Si(CH 3 ) 2
L A2516
R B4
R B6
N
Si(CH 3 ) 2
L A2517
R B7
R B6
N
Si(CH 3 ) 2
L A2518
R B10
R B6
N
Si(CH 3 ) 2
L A2519
R A3
R B6
N
Si(CH 3 ) 2
L A2520
R A34
R B6
N
Si(CH 3 ) 2
wherein L A2521 through L A2640 have a structure of Formula XVIII:
wherein R 3 , R 5 , and Y are defined as provided below:
Ligand
R 5
R 3
Y
Ligand
R 5
R 3
Y
L A2521
H
H
S
L A2581
R B1
R B4
NCH 3
L A2522
H
R B1
S
L A2582
R B1
R B5
NCH 3
L A2523
H
R B2
S
L A2583
R B1
R A34
NCH 3
L A2524
H
R B3
S
L A2584
R B1
R A52
NCH 3
L A2525
H
R B4
S
L A2585
R B1
H
C(CH 3 ) 2
L A2526
H
R B5
S
L A2586
R B1
R B1
C(CH 3 ) 2
L A2527
H
R A34
S
L A2587
R B1
R B2
C(CH 3 ) 2
L A2528
H
R A52
S
L A2588
R B1
R B3
C(CH 3 ) 2
L A2529
H
H
O
L A2589
R B1
R B4
C(CH 3 ) 2
L A2530
H
R B1
O
L A2590
R B1
R B5
C(CH 3 ) 2
L A2531
H
R B2
O
L A2591
R B1
R A34
C(CH 3 ) 2
L A2532
H
R B3
O
L A2592
R B1
R A52
C(CH 3 ) 2
L A2533
H
R B4
O
L A2593
R B1
H
Si(CH 3 ) 2
L A2534
H
R B5
O
L A2594
R B1
R B1
Si(CH 3 ) 2
L A2535
H
R A34
O
L A2595
R B1
R B2
Si(CH 3 ) 2
L A2536
H
R A52
O
L A2596
R B1
R B3
Si(CH 3 ) 2
L A2537
H
H
NCH 3
L A2597
R B1
R B4
Si(CH 3 ) 2
L A2538
H
R B1
NCH 3
L A2598
R B1
R B5
Si(CH 3 ) 2
L A2539
H
R B2
NCH 3
L A2599
R B1
R A34
Si(CH 3 ) 2
L A2540
H
R B3
NCH 3
L A2600
R B1
R A52
Si(CH 3 ) 2
L A2541
H
R B4
NCH 3
L A2601
R B6
H
S
L A2542
H
R B5
NCH 3
L A2602
R B6
R B1
S
L A2543
H
R A34
NCH 3
L A2603
R B6
R B2
S
L A2544
H
R A52
NCH 3
L A2604
R B6
R B3
S
L A2545
H
H
C(CH 3 ) 2
L A2605
R B6
R B4
S
L A2546
H
R B1
C(CH 3 ) 2
L A2606
R B6
R B5
S
L A2547
H
R B2
C(CH 3 ) 2
L A2607
R B6
R A34
S
L A2548
H
R B3
C(CH 3 ) 2
L A2608
R B6
R A52
S
L A2549
H
R B4
C(CH 3 ) 2
L A2609
R B6
H
O
L A2550
H
R B5
C(CH 3 ) 2
L A2610
R B6
R B1
O
L A2551
H
R A34
C(CH 3 ) 2
L A2611
R B6
R B2
O
L A2552
H
R A52
C(CH 3 ) 2
L A2612
R B6
R B3
O
L A2553
H
H
Si(CH 3 ) 2
L A2613
R B6
R B4
O
L A2554
H
R B1
Si(CH 3 ) 2
L A2614
R B6
R B5
O
L A2555
H
R B2
Si(CH 3 ) 2
L A2615
R B6
R A34
O
L A2556
H
R B3
Si(CH 3 ) 2
L A2616
R B6
R A52
O
L A2557
H
R B4
Si(CH 3 ) 2
L A2617
R B6
H
NCH 3
L A2558
H
R B5
Si(CH 3 ) 2
L A2618
R B6
R B1
NCH 3
L A2559
H
R A34
Si(CH 3 ) 2
L A2619
R B6
R B2
NCH 3
L A2560
H
R A52
Si(CH 3 ) 2
L A2620
R B6
R B3
NCH 3
L A2561
R B1
H
S
L A2621
R B6
R B4
NCH 3
L A2562
R B1
R B1
S
L A2622
R B6
R B5
NCH 3
L A2563
R B1
R B2
S
L A2623
R B6
R A34
NCH 3
L A2564
R B1
R B3
S
L A2624
R B6
R A52
NCH 3
L A2565
R B1
R B4
S
L A2625
R B6
H
C(CH 3 ) 2
L A2566
R B1
R B5
S
L A2626
R B6
R B1
C(CH 3 ) 2
L A2567
R B1
R A34
S
L A2627
R B6
R B2
C(CH 3 ) 2
L A2568
R B1
R A52
S
L A2628
R B6
R B3
C(CH 3 ) 2
L A2569
R B1
H
O
L A2629
R B6
R B4
C(CH 3 ) 2
L A2570
R B1
R B1
O
L A2630
R B6
R B5
C(CH 3 ) 2
L A2571
R B1
R B2
O
L A2631
R B6
R A34
C(CH 3 ) 2
L A2572
R B1
R B3
O
L A2632
R B6
R A52
C(CH 3 ) 2
L A2573
R B1
R B4
O
L A2633
R B6
H
Si(CH 3 )
L A2574
R B1
R B5
O
L A2634
R B6
R B1
Si(CH 3 )
L A2575
R B1
R A34
O
L A2635
R B6
R B2
Si(CH 3 )
L A2576
R B1
R A52
O
L A2636
R B6
R B3
Si(CH 3 )
L A2577
R B1
H
NCH 3
L A2637
R B6
R B4
Si(CH 3 )
L A2578
R B1
R B1
NCH 3
L A2638
R B6
R B5
Si(CH 3 )
L A2579
R B1
R B2
NCH 3
L A2639
R B6
R A34
Si(CH 3 )
L A2580
R B1
R B3
NCH 3
L A2640
R B6
R A52
Si(CH 3 )
wherein L A2641 through L A2736 have a structure of Formula XIX:
wherein R 4 , R 5 , Y, and Z are defined as provided below:
Ligand
R 5
R 4
Y
Z
Ligand
R 5
R 4
Y
Z
L A2641
H
H
S
S
L A2689
R B6
H
S
S
L A2642
H
R B1
S
S
L A2690
R B6
R B1
S
S
L A2643
H
R B3
S
S
L A2691
R B6
R B3
S
S
L A2644
H
R B4
S
S
L A2692
R B6
R B4
S
S
L A2645
H
R B7
S
S
L A2693
R B6
R B7
S
S
L A2646
H
R B10
S
S
L A2694
R B6
R B10
S
S
L A2647
H
R A3
S
S
L A2695
R B6
R A3
S
S
L A2648
H
R A34
S
S
L A2696
R B6
R A34
S
S
L A2649
H
H
S
O
L A2697
R B6
H
S
O
L A2650
H
R B1
S
O
L A2698
R B6
R B1
S
O
L A2651
H
R B3
S
O
L A2699
R B6
R B3
S
O
L A2652
H
R B4
S
O
L A2700
R B6
R B4
S
O
L A2653
H
R B7
S
O
L A2701
R B6
R B7
S
O
L A2654
H
R B10
S
O
L A2702
R B6
R B10
S
O
L A2655
H
R A3
S
O
L A2703
R B6
R A3
S
O
L A2656
H
R A34
S
O
L A2704
R B6
R A34
S
O
L A2657
H
H
S
NCH 3
L A2705
R B6
H
S
NCH 3
L A2658
H
R B1
S
NCH 3
L A2706
R B6
R B1
S
NCH 3
L A2659
H
R B3
S
NCH 3
L A2707
R B6
R B3
S
NCH 3
L A2660
H
R B4
S
NCH 3
L A2708
R B6
R B4
S
NCH 3
L A2661
H
R B7
S
NCH 3
L A2709
R B6
R B7
S
NCH 3
L A2662
H
R B10
S
NCH 3
L A2710
R B6
R B10
S
NCH 3
L A2663
H
R A3
S
NCH 3
L A2711
R B6
R A3
S
NCH 3
L A2664
H
R A34
S
NCH 3
L A2712
R B6
R A34
S
NCH 3
L A2665
H
H
O
S
L A2713
R B6
H
O
S
L A2666
H
R B1
O
S
L A2714
R B6
R B1
O
S
L A2667
H
R B3
O
S
L A2715
R B6
R B3
O
S
L A2668
H
R B4
O
S
L A2716
R B6
R B4
O
S
L A2669
H
R B7
O
S
L A2717
R B6
R B7
O
S
L A2670
H
R B10
O
S
L A2718
R B6
R B10
O
S
L A2671
H
R A3
O
S
L A2719
R B6
R A3
O
S
L A2672
H
R A34
O
S
L A2720
R B6
R A34
O
S
L A2673
H
H
O
O
L A2721
R B6
H
O
O
L A2674
H
R B1
O
O
L A2722
R B6
R B1
O
O
L A2675
H
R B3
O
O
L A2723
R B6
R B3
O
O
L A2676
H
R B4
O
O
L A2724
R B6
R B4
O
O
L A2677
H
R B7
O
O
L A2725
R B6
R B7
O
O
L A2678
H
R B10
O
O
L A2726
R B6
R B10
O
O
L A2679
H
R A3
O
O
L A2727
R B6
R A3
O
O
L A2680
H
R A34
O
O
L A2728
R B6
R A34
O
O
L A2681
H
H
O
NCH 3
L A2729
R B6
H
O
NCH 3
L A2682
H
R B1
O
NCH 3
L A2730
R B6
R B1
O
NCH 3
L A2683
H
R B3
O
NCH 3
L A2731
R B6
R B3
O
NCH 3
L A2684
H
R B4
O
NCH 3
L A2732
R B6
R B4
O
NCH 3
L A2685
H
R B7
O
NCH 3
L A2733
R B6
R B7
O
NCH 3
L A2686
H
R B10
O
NCH 3
L A2734
R B6
R B10
O
NCH 3
L A2687
H
R A3
O
NCH 3
L A2735
R B6
R A3
O
NCH 3
L A2688
H
R A34
O
NCH 3
L A2736
R B6
R A34
O
NCH 3
wherein L A2857 through L A2976 have a structure of Formula XX:
wherein R 1 , R 5 , Y, and X are defined as provided below:
Ligand
R 1
R 5
X
Y
L A2857
H
H
N
S
L A2858
R B1
H
N
S
L A2859
R B3
H
N
S
L A2860
R B4
H
N
S
L A2861
R B7
H
N
S
L A2862
R B10
H
N
S
L A2863
R A3
H
N
S
L A2864
R A34
H
N
S
L A2865
H
H
N
O
L A2866
R B1
H
N
O
L A2867
R B3
H
N
O
L A2868
R B4
H
N
O
L A2869
R B7
H
N
O
L A2870
R B10
H
N
O
L A2871
R A3
H
N
O
L A2872
R A34
H
N
O
L A2873
H
H
N
NCH 3
L A2874
R B1
H
N
NCH 3
L A2875
R B3
H
N
NCH 3
L A2876
R B4
H
N
NCH 3
L A2877
R B7
H
N
NCH 3
L A2878
R B10
H
N
NCH 3
L A2879
R A3
H
N
NCH 3
L A2880
R A34
H
N
NCH 3
L A2881
H
H
N
C(CH 3 ) 2
L A2882
R B1
H
N
C(CH 3 ) 2
L A2883
R B3
H
N
C(CH 3 ) 2
L A2884
R B4
H
N
C(CH 3 ) 2
L A2885
R B7
H
N
C(CH 3 ) 2
L A2886
R B10
H
N
C(CH 3 ) 2
L A2887
R A3
H
N
C(CH 3 ) 2
L A2888
R A34
H
N
C(CH 3 ) 2
L A2889
H
H
N
Si(CH 3 ) 2
L A2890
R B1
H
N
Si(CH 3 ) 2
L A2891
R B3
H
N
Si(CH 3 ) 2
L A2892
R B4
H
N
Si(CH 3 ) 2
L A2893
R B7
H
N
Si(CH 3 ) 2
L A2894
R B10
H
N
Si(CH 3 ) 2
L A2895
R A3
H
N
Si(CH 3 ) 2
L A2896
R A34
H
N
Si(CH 3 ) 2
L A2897
H
R B1
N
S
L A2898
R B1
R B1
N
S
L A2899
R B3
R B1
N
S
L A2900
R B4
R B1
N
S
L A2901
R B7
R B1
N
S
L A2902
R B10
R B1
N
S
L A2903
R A3
R B1
N
S
L A2904
R A34
R B1
N
S
L A2905
H
R B1
N
O
L A2906
R B1
R B1
N
O
L A2907
R B3
R B1
N
O
L A2908
R B4
R B1
N
O
L A2909
R B7
R B1
N
O
L A2910
R B10
R B1
N
O
L A2911
R A3
R B1
N
O
L A2912
R A34
R B1
N
O
L A2913
H
R B1
N
NCH 3
L A2914
R B1
R B1
N
NCH 3
L A2915
R B3
R B1
N
NCH 3
L A2916
R B4
R B1
N
NCH 3
L A2917
R B7
R B1
N
NCH 3
L A2918
R B10
R B1
N
NCH 3
L A2919
R A3
R B1
N
NCH 3
L A2920
R A34
R B1
N
NCH 3
L A2921
H
R B1
N
C(CH 3 ) 2
L A2922
R B1
R B1
N
C(CH 3 ) 2
L A2923
R B3
R B1
N
C(CH 3 ) 2
L A2924
R B4
R B1
N
C(CH 3 ) 2
L A2925
R B7
R B1
N
C(CH 3 ) 2
L A2926
R B10
R B1
N
C(CH 3 ) 2
L A2927
R A3
R B1
N
C(CH 3 ) 2
L A2928
R A34
R B1
N
C(CH 3 ) 2
L A2929
H
R B1
N
Si(CH 3 ) 2
L A2930
R B1
R B1
N
Si(CH 3 ) 2
L A2931
R B3
R B1
N
Si(CH 3 ) 2
L A2932
R B4
R B1
N
Si(CH 3 ) 2
L A2933
R B7
R B1
N
Si(CH 3 ) 2
L A2934
R B10
R B1
N
Si(CH 3 ) 2
L A2935
R A3
R B1
N
Si(CH 3 ) 2
L A2936
R A34
R B1
N
Si(CH 3 ) 2
L A2937
H
R B6
N
S
L A2938
R B1
R B6
N
S
L A2939
R B3
R B6
N
S
L A2940
R B4
R B6
N
S
L A2941
R B7
R B6
N
S
L A2942
R B10
R B6
N
S
L A2943
R A3
R B6
N
S
L A2944
R A34
R B6
N
S
L A2945
H
R B6
N
O
L A2946
R B1
R B6
N
O
L A2947
R B3
R B6
N
O
L A2948
R B4
R B6
N
O
L A2949
R B7
R B6
N
O
L A2950
R B10
R B6
N
O
L A2951
R A3
R B6
N
O
L A2952
R A34
R B6
N
O
L A2953
H
R B6
N
NCH 3
L A2954
R B1
R B6
N
NCH 3
L A2955
R B3
R B6
N
NCH 3
L A2956
R B4
R B6
N
NCH 3
L A2957
R B7
R B6
N
NCH 3
L A2958
R B10
R B6
N
NCH 3
L A2959
R A3
R B6
N
NCH 3
L A2960
R A34
R B6
N
NCH 3
L A2961
H
R B6
N
C(CH 3 ) 2
L A2962
R B1
R B6
N
C(CH 3 ) 2
L A2963
R B3
R B6
N
C(CH 3 ) 2
L A2964
R B4
R B6
N
C(CH 3 ) 2
L A2965
R B7
R B6
N
C(CH 3 ) 2
L A2966
R B10
R B6
N
C(CH 3 ) 2
L A2967
R A3
R B6
N
C(CH 3 ) 2
L A2968
R A34
R B6
N
C(CH 3 ) 2
L A2969
H
R B6
N
Si(CH 3 ) 2
L A2970
R B1
R B6
N
Si(CH 3 ) 2
L A2971
R B3
R B6
N
Si(CH 3 ) 2
L A2972
R B4
R B6
N
Si(CH 3 ) 2
L A2973
R B7
R B6
N
Si(CH 3 ) 2
L A2974
R B10
R B6
N
Si(CH 3 ) 2
L A2975
R A3
R B6
N
Si(CH 3 ) 2
L A2976
R A34
R B6
N
Si(CH 3 ) 2
wherein L A2977 through L A3096 have a structure of Formula XXI:
wherein R 3 , R 5 , and Y are defined as provided below:
Ligand
R 5
R 3
Y
Ligand
R 5
R 3
Y
L A2977
H
H
S
L A3037
R B1
R B4
NCH 3
L A2978
H
R B1
S
L A3038
R B1
R B5
NCH 3
L A2979
H
R B2
S
L A3039
R B1
R A34
NCH 3
L A2980
H
R B3
S
L A3040
R B1
R A52
NCH 3
L A2981
H
R B4
S
L A3041
R B1
H
C(CH 3 ) 2
L A2982
H
R B5
S
L A3042
R B1
R B1
C(CH 3 ) 2
L A2983
H
R A34
S
L A3043
R B1
R B2
C(CH 3 ) 2
L A2984
H
R A52
S
L A3044
R B1
R B3
C(CH 3 ) 2
L A2985
H
H
O
L A3045
R B1
R B4
C(CH 3 ) 2
L A2986
H
R B1
O
L A3046
R B1
R B5
C(CH 3 ) 2
L A2987
H
R B2
O
L A3047
R B1
R A34
C(CH 3 ) 2
L A2988
H
R B3
O
L A3048
R B1
R A52
C(CH 3 ) 2
L A2989
H
R B4
O
L A3049
R B1
H
Si(CH 3 ) 2
L A2990
H
R B5
O
L A3050
R B1
R B1
Si(CH 3 ) 2
L A2991
H
R A34
O
L A3051
R B1
R B2
Si(CH 3 ) 2
L A2992
H
R A52
O
L A3052
R B1
R B3
Si(CH 3 ) 2
L A2993
H
H
NCH 3
L A3053
R B1
R B4
Si(CH 3 ) 2
L A2994
H
R B1
NCH 3
L A3054
R B1
R B5
Si(CH 3 ) 2
L A2995
H
R B2
NCH 3
L A3055
R B1
R A34
Si(CH 3 ) 2
L A2996
H
R B3
NCH 3
L A3056
R B1
R A52
Si(CH 3 ) 2
L A2997
H
R B4
NCH 3
L A3057
R B6
H
S
L A2998
H
R B5
NCH 3
L A3058
R B6
R B1
S
L A2999
H
R A34
NCH 3
L A3059
R B6
R B2
S
L A3000
H
R A52
NCH 3
L A3060
R B6
R B3
S
L A3001
H
H
C(CH 3 ) 2
L A3061
R B6
R B4
S
L A3002
H
R B1
C(CH 3 ) 2
L A3062
R B6
R B5
S
L A3003
H
R B2
C(CH 3 ) 2
L A3063
R B6
R A34
S
L A3004
H
R B3
C(CH 3 ) 2
L A3064
R B6
R A52
S
L A3005
H
R B4
C(CH 3 ) 2
L A3065
R B6
H
O
L A3006
H
R B5
C(CH 3 ) 2
L A3066
R B6
R B1
O
L A3007
H
R A34
C(CH 3 ) 2
L A3067
R B6
R B2
O
L A3008
H
R A52
C(CH 3 ) 2
L A3068
R B6
R B3
O
L A3009
H
H
Si(CH 3 ) 2
L A3069
R B6
R B4
O
L A3010
H
R B1
Si(CH 3 ) 2
L A3070
R B6
R B5
O
L A3011
H
R B2
Si(CH 3 ) 2
L A3071
R B6
R A34
O
L A3012
H
R B3
Si(CH 3 ) 2
L A3072
R B6
R A52
O
L A3013
H
R B4
Si(CH 3 ) 2
L A3073
R B6
H
NCH 3
L A3014
H
R B5
Si(CH 3 ) 2
L A3074
R B6
R B1
NCH 3
L A3015
H
R A34
Si(CH 3 ) 2
L A3075
R B6
R B2
NCH 3
L A3016
H
R A52
Si(CH 3 ) 2
L A3076
R B6
R B3
NCH 3
L A3017
R B1
H
S
L A3077
R B6
R B4
NCH 3
L A3018
R B1
R B1
S
L A3078
R B6
R B5
NCH 3
L A3019
R B1
R B2
S
L A3079
R B6
R A34
NCH 3
L A3020
R B1
R B3
S
L A3080
R B6
R A52
NCH 3
L A3021
R B1
R B4
S
L A3081
R B6
H
C(CH 3 ) 2
L A3022
R B1
R B5
S
L A3082
R B6
R B1
C(CH 3 ) 2
L A3023
R B1
R A34
S
L A3083
R B6
R B2
C(CH 3 ) 2
L A3024
R B1
R A52
S
L A3084
R B6
R B3
C(CH 3 ) 2
L A3025
R B1
H
O
L A3085
R B6
R B4
C(CH 3 ) 2
L A3026
R B1
R B1
O
L A3086
R B6
R B5
C(CH 3 ) 2
L A3027
R B1
R B2
O
L A3087
R B6
R A34
C(CH 3 ) 2
L A3028
R B1
R B3
O
L A3088
R B6
R A52
C(CH 3 ) 2
L A3029
R B1
R B4
O
L A3089
R B6
H
Si(CH 3 ) 2
L A3030
R B1
R B5
O
L A3090
R B6
R B1
Si(CH 3 ) 2
L A3031
R B1
R A34
O
L A3091
R B6
R B2
Si(CH 3 ) 2
L A3032
R B1
R A52
O
L A3092
R B6
R B3
Si(CH 3 ) 2
L A3033
R B1
H
NCH 3
L A3093
R B6
R B4
Si(CH 3 ) 2
L A3034
R B1
R B1
NCH 3
L A3094
R B6
R B5
Si(CH 3 ) 2
L A3035
R B1
R B2
NCH 3
L A3095
R B6
R A34
Si(CH 3 ) 2
L A3036
R B1
R B3
NCH 3
L A3096
R B6
R A52
Si(CH 3 ) 2
wherein L A3097 through L A3192 have a structure of Formula XXII:
wherein R 4 , R 5 , Y, and Z are defined as provided below:
Ligand
R 5
R 4
Y
Z
Ligand
R 5
R 4
Y
Z
L A3097
H
H
S
S
L A3145
R B6
H
S
S
L A3098
H
R B1
S
S
L A3146
R B6
R B1
S
S
L A3099
H
R B3
S
S
L A3147
R B6
R B3
S
S
L A3100
H
R B4
S
S
L A3148
R B6
R B4
S
S
L A3101
H
R B7
S
S
L A3149
R B6
R B7
S
S
L A3102
H
R B10
S
S
L A3150
R B6
R B10
S
S
L A3103
H
R A3
S
S
L A3151
R B6
R A3
S
S
L A3104
H
R A34
S
S
L A3152
R B6
R A34
S
S
L A3105
H
H
S
O
L A3153
R B6
H
S
O
L A3106
H
R B1
S
O
L A3154
R B6
R B1
S
O
L A3107
H
R B3
S
O
L A3155
R B6
R B3
S
O
L A3108
H
R B4
S
O
L A3156
R B6
R B4
S
O
L A3109
H
R B7
S
O
L A3157
R B6
R B7
S
O
L A3110
H
R B10
S
O
L A3158
R B6
R B10
S
O
L A3111
H
R A3
S
O
L A3159
R B6
R A3
S
O
L A3112
H
R A34
S
O
L A3160
R B6
R A34
S
O
L A3113
H
H
S
NCH 3
L A3161
R B6
H
S
NCH 3
L A3114
H
R B1
S
NCH 3
L A3162
R B6
R B1
S
NCH 3
L A3115
H
R B3
S
NCH 3
L A3163
R B6
R B3
S
NCH 3
L A3116
H
R B4
S
NCH 3
L A3164
R B6
R B4
S
NCH 3
L A3117
H
R B7
S
NCH 3
L A3165
R B6
R B7
S
NCH 3
L A3118
H
R B10
S
NCH 3
L A3166
R B6
R B10
S
NCH 3
L A3119
H
R A3
S
NCH 3
L A3167
R B6
R A3
S
NCH 3
L A3120
H
R A34
S
NCH 3
L A3168
R B6
R A34
S
NCH 3
L A3121
H
H
O
S
L A3169
R B6
H
O
S
L A3122
H
R B1
O
S
L A3170
R B6
R B1
O
S
L A3123
H
R B3
O
S
L A3171
R B6
R B3
O
S
L A3124
H
R B4
O
S
L A3172
R B6
R B4
O
S
L A3125
H
R B7
O
S
L A3173
R B6
R B7
O
S
L A3126
H
R B10
O
S
L A3174
R B6
R B10
O
S
L A3127
H
R A3
O
S
L A3175
R B6
R A3
O
S
L A3128
H
R A34
O
S
L A3176
R B6
R A34
O
S
L A3129
H
H
O
O
L A3177
R B6
H
O
O
L A3130
H
R B1
O
O
L A3178
R B6
R B1
O
O
L A3131
H
R B3
O
O
L A3179
R B6
R B3
O
O
L A3132
H
R B4
O
O
L A3180
R B6
R B4
O
O
L A3133
H
R B7
O
O
L A3181
R B6
R B7
O
O
L A3134
H
R B10
O
O
L A3182
R B6
R B10
O
O
L A3135
H
R A3
O
O
L A3183
R B6
R A3
O
O
L A3136
H
R A34
O
O
L A3184
R B6
R A34
O
O
L A3137
H
H
O
NCH 3
L A3185
R B6
H
O
NCH 3
L A3138
H
R B1
O
NCH 3
L A3186
R B6
R B1
O
NCH 3
L A3139
H
R B3
O
NCH 3
L A3187
R B6
R B3
O
NCH 3
L A3140
H
R B4
O
NCH 3
L A3188
R B6
R B4
O
NCH 3
L A3141
H
R B7
O
NCH 3
L A3189
R B6
R B7
O
NCH 3
L A3142
H
R B10
O
NCH 3
L A3190
R B6
R B10
O
NCH 3
L A3143
H
R A3
O
NCH 3
L A3191
R B6
R A3
O
NCH 3
L A3144
H
R A34
O
NCH 3
L A3192
R B6
R A34
O
NCH 3
wherein L A3193 through L A3432 have a structure of Formula XXIII:
wherein R 1 , R 5 , X, and Y are defined as provided below:
Ligand
R 1
R 5
X
Y
Ligand
R 1
R 5
X
Y
L A3193
H
H
C
S
L A3313
H
H
N
S
L A3194
R B1
H
C
S
L A3314
R B1
H
N
S
L A3195
R B3
H
C
S
L A3315
R B3
H
N
S
L A3196
R B4
H
C
S
L A3316
R B4
H
N
S
L A3197
R B7
H
C
S
L A3317
R B7
H
N
S
L A3198
R B10
H
C
S
L A3318
R B10
H
N
S
L A3199
R A3
H
C
S
L A3319
R A3
H
N
S
L A3200
R A34
H
C
S
L A3320
R A34
H
N
S
L A3201
H
H
C
O
L A3321
H
H
N
O
L A3202
R B1
H
C
O
L A3322
R B1
H
N
O
L A3203
R B3
H
C
O
L A3323
R B3
H
N
O
L A3204
R B4
H
C
O
L A3324
R B4
H
N
O
L A3205
R B7
H
C
O
L A3325
R B7
H
N
O
L A3206
R B10
H
C
O
L A3326
R B10
H
N
O
L A3207
R A3
H
C
O
L A3327
R A3
H
N
O
L A3208
R A34
H
C
O
L A3328
R A34
H
N
O
L A3209
H
H
C
NCH 3
L A3329
H
H
N
NCH 3
L A3210
R B1
H
C
NCH 3
L A3330
R B1
H
N
NCH 3
L A3211
R B3
H
C
NCH 3
L A3331
R B3
H
N
NCH 3
L A3212
R B4
H
C
NCH 3
L A3332
R B4
H
N
NCH 3
L A3213
R B7
H
C
NCH 3
L A3333
R B7
H
N
NCH 3
L A3214
R B10
H
C
NCH 3
L A3334
R B10
H
N
NCH 3
L A3215
R A3
H
C
NCH 3
L A3335
R A3
H
N
NCH 3
L A3216
R A34
H
C
NCH 3
L A3336
R A34
H
N
NCH 3
L A3217
H
H
C
C(CH 3 ) 2
L A3337
H
H
N
C(CH 3 ) 2
L A3218
R B1
H
C
C(CH 3 ) 2
L A3338
R B1
H
N
C(CH 3 ) 2
L A3219
R B3
H
C
C(CH 3 ) 2
L A3339
R B3
H
N
C(CH 3 ) 2
L A3220
R B4
H
C
C(CH 3 ) 2
L A3340
R B4
H
N
C(CH 3 ) 2
L A3221
R B7
H
C
C(CH 3 ) 2
L A3341
R B7
H
N
C(CH 3 ) 2
L A3222
R B10
H
C
C(CH 3 ) 2
L A3342
R B10
H
N
C(CH 3 ) 2
L A3223
R A3
H
C
C(CH 3 ) 2
L A3343
R A3
H
N
C(CH 3 ) 2
L A3224
R A34
H
C
C(CH 3 ) 2
L A3344
R A34
H
N
C(CH 3 ) 2
L A3225
H
H
C
Si(CH 3 ) 2
L A3345
H
H
N
Si(CH 3 ) 2
L A3226
R B1
H
C
Si(CH 3 ) 2
L A3346
R B1
H
N
Si(CH 3 ) 2
L A3227
R B3
H
C
Si(CH 3 ) 2
L A3347
R B3
H
N
Si(CH 3 ) 2
L A3228
R B4
H
C
Si(CH 3 ) 2
L A3348
R B4
H
N
Si(CH 3 ) 2
L A3229
R B7
H
C
Si(CH 3 ) 2
L A3349
R B7
H
N
Si(CH 3 ) 2
L A3230
R B10
H
C
Si(CH 3 ) 2
L A3350
R B10
H
N
Si(CH 3 ) 2
L A3231
R A3
H
C
Si(CH 3 ) 2
L A3351
R A3
H
N
Si(CH 3 ) 2
L A3232
R A34
H
C
Si(CH 3 ) 2
L A3352
R A34
H
N
Si(CH 3 ) 2
L A3233
H
R B1
C
S
L A3353
H
R B1
N
S
L A3234
R B1
R B1
C
S
L A3354
R B1
R B1
N
S
L A3235
R B3
R B1
C
S
L A3355
R B3
R B1
N
S
L A3236
R B4
R B1
C
S
L A3356
R B4
R B1
N
S
L A3237
R B7
R B1
C
S
L A3357
R B7
R B1
N
S
L A3238
R B10
R B1
C
S
L A3358
R B10
R B1
N
S
L A3239
R A3
R B1
C
S
L A3359
R A3
R B1
N
S
L A3240
R A34
R B1
C
S
L A3360
R A34
R B1
N
S
L A3241
H
R B1
C
O
L A3361
H
R B1
N
O
L A3242
R B1
R B1
C
O
L A3362
R B1
R B1
N
O
L A3243
R B3
R B1
C
O
L A3363
R B3
R B1
N
O
L A3244
R B4
R B1
C
O
L A3364
R B4
R B1
N
O
L A3245
R B7
R B1
C
O
L A3365
R B7
R B1
N
O
L A3246
R B10
R B1
C
O
L A3366
R B10
R B1
N
O
L A3247
R A3
R B1
C
O
L A3367
R A3
R B1
N
O
L A3248
R A34
R B1
C
O
L A3368
R A34
R B1
N
O
L A3249
H
R B1
C
NCH 3
L A3369
H
R B1
N
NCH 3
L A3250
R B1
R B1
C
NCH 3
L A3370
R B1
R B1
N
NCH 3
L A3251
R B3
R B1
C
NCH 3
L A3371
R B3
R B1
N
NCH 3
L A3252
R B4
R B1
C
NCH 3
L A3372
R B4
R B1
N
NCH 3
L A3253
R B7
R B1
C
NCH 3
L A3373
R B7
R B1
N
NCH 3
L A3254
R B10
R B1
C
NCH 3
L A3374
R B10
R B1
N
NCH 3
L A3255
R A3
R B1
C
NCH 3
L A3375
R A3
R B1
N
NCH 3
L A3256
R A34
R B1
C
NCH 3
L A3376
R A34
R B1
N
NCH 3
L A3257
H
R B1
C
C(CH 3 ) 2
L A3377
H
R B1
N
C(CH 3 ) 2
L A3258
R B1
R B1
C
C(CH 3 ) 2
L A3378
R B1
R B1
N
C(CH 3 ) 2
L A3259
R B3
R B1
C
C(CH 3 ) 2
L A3379
R B3
R B1
N
C(CH 3 ) 2
L A3260
R B4
R B1
C
C(CH 3 ) 2
L A3380
R B4
R B1
N
C(CH 3 ) 2
L A3261
R B7
R B1
C
C(CH 3 ) 2
L A3381
R B7
R B1
N
C(CH 3 ) 2
L A3262
R B10
R B1
C
C(CH 3 ) 2
L A3382
R B10
R B1
N
C(CH 3 ) 2
L A3263
R A3
R B1
C
C(CH 3 ) 2
L A3383
R A3
R B1
N
C(CH 3 ) 2
L A3264
R A34
R B1
C
C(CH 3 ) 2
L A3384
R A34
R B1
N
C(CH 3 ) 2
L A3265
H
R B1
C
Si(CH 3 ) 2
L A3385
H
R B1
N
Si(CH 3 ) 2
L A3266
R B1
R B1
C
Si(CH 3 ) 2
L A3386
R B1
R B1
N
Si(CH 3 ) 2
L A3267
R B3
R B1
C
Si(CH 3 ) 2
L A3387
R B3
R B1
N
Si(CH 3 ) 2
L A3268
R B4
R B1
C
Si(CH 3 ) 2
L A3388
R B4
R B1
N
Si(CH 3 ) 2
L A3269
R B7
R B1
C
Si(CH 3 ) 2
L A3389
R B7
R B1
N
Si(CH 3 ) 2
L A3270
R B10
R B1
C
Si(CH 3 ) 2
L A3390
R B10
R B1
N
Si(CH 3 ) 2
L A3271
R A3
R B1
C
Si(CH 3 ) 2
L A3391
R A3
R B1
N
Si(CH 3 ) 2
L A3272
R A34
R B1
C
Si(CH 3 ) 2
L A3392
R A34
R B1
N
Si(CH 3 ) 2
L A3273
H
R B6
C
S
L A3393
H
R B6
N
S
L A3274
R B1
R B6
C
S
L A3394
R B1
R B6
N
S
L A3275
R B3
R B6
C
S
L A3395
R B3
R B6
N
S
L A3276
R B4
R B6
C
S
L A3396
R B4
R B6
N
S
L A3277
R B7
R B6
C
S
L A3397
R B7
R B6
N
S
L A3278
R B10
R B6
C
S
L A3398
R B10
R B6
N
S
L A3279
R A3
R B6
C
S
L A3399
R A3
R B6
N
S
L A3280
R A34
R B6
C
S
L A3400
R A34
R B6
N
S
L A3281
H
R B6
C
O
L A3401
H
R B6
N
O
L A3282
R B1
R B6
C
O
L A3402
R B1
R B6
N
O
L A3283
R B3
R B6
C
O
L A3403
R B3
R B6
N
O
L A3284
R B4
R B6
C
O
L A3404
R B4
R B6
N
O
L A3285
R B7
R B6
C
O
L A3405
R B7
R B6
N
O
L A3286
R B10
R B6
C
O
L A3406
R B10
R B6
N
O
L A3287
R A3
R B6
C
O
L A3407
R A3
R B6
N
O
L A3288
R A34
R B6
C
O
L A3408
R A34
R B6
N
O
L A3289
H
R B6
C
NCH 3
L A3409
H
R B6
N
NCH 3
L A3290
R B1
R B6
C
NCH 3
L A3410
R B1
R B6
N
NCH 3
L A3291
R B3
R B6
C
NCH 3
L A3411
R B3
R B6
N
NCH 3
L A3292
R B4
R B6
C
NCH 3
L A3412
R B4
R B6
N
NCH 3
L A3293
R B7
R B6
C
NCH 3
L A3413
R B7
R B6
N
NCH 3
L A3294
R B10
R B6
C
NCH 3
L A3414
R B10
R B6
N
NCH 3
L A3295
R A3
R B6
C
NCH 3
L A3415
R A3
R B6
N
NCH 3
L A3296
R A34
R B6
C
NCH 3
L A3416
R A34
R B6
N
NCH 3
L A3297
H
R B6
C
C(CH 3 ) 2
L A3417
H
R B6
N
C(CH 3 ) 2
L A3298
R B1
R B6
C
C(CH 3 ) 2
L A3418
R B1
R B6
N
C(CH 3 ) 2
L A3299
R B3
R B6
C
C(CH 3 ) 2
L A3419
R B3
R B6
N
C(CH 3 ) 2
L A3300
R B4
R B6
C
C(CH 3 ) 2
L A3420
R B4
R B6
N
C(CH 3 ) 2
L A3301
R B7
R B6
C
C(CH 3 ) 2
L A3421
R B7
R B6
N
C(CH 3 ) 2
L A3302
R B10
R B6
C
C(CH 3 ) 2
L A3422
R B10
R B6
N
C(CH 3 ) 2
L A3303
R A3
R B6
C
C(CH 3 ) 2
L A3423
R A3
R B6
N
C(CH 3 ) 2
L A3304
R A34
R B6
C
C(CH 3 ) 2
L A3424
R A34
R B6
N
C(CH 3 ) 2
L A3305
H
R B6
C
Si(CH 3 ) 2
L A3425
H
R B6
N
Si(CH 3 ) 2
L A3306
R B1
R B6
C
Si(CH 3 ) 2
L A3426
R B1
R B6
N
Si(CH 3 ) 2
L A3307
R B3
R B6
C
Si(CH 3 ) 2
L A3427
R B3
R B6
N
Si(CH 3 ) 2
L A3308
R B4
R B6
C
Si(CH 3 ) 2
L A3428
R B4
R B6
N
Si(CH 3 ) 2
L A3309
R B7
R B6
C
Si(CH 3 ) 2
L A3429
R B7
R B6
N
Si(CH 3 ) 2
L A3310
R B10
R B6
C
Si(CH 3 ) 2
L A3430
R B10
R B6
N
Si(CH 3 ) 2
L A3311
R A3
R B6
C
Si(CH 3 ) 2
L A3431
R A3
R B6
N
Si(CH 3 ) 2
L A3312
R A34
R B6
C
Si(CH 3 ) 2
L A3432
R A34
R B6
N
wherein L A3433 through L A3552 have a structure of Formula XXIV:
wherein R 3 , R 5 , and Y are defined as provided below:
Ligand
R 5
R 3
Y
Ligand
R 5
R 3
Y
L A3433
H
H
S
L A3493
R B1
R B4
NCH 3
L A3434
H
R B1
S
L A3494
R B1
R B5
NCH 3
L A3435
H
R B2
S
L A3495
R B1
R A34
NCH 3
L A3436
H
R B3
S
L A3496
R B1
R A52
NCH 3
L A3437
H
R B4
S
L A3497
R B1
H
C(CH 3 ) 2
L A3438
H
R B5
S
L A3498
R B1
R B1
C(CH 3 ) 2
L A3439
H
R A34
S
L A3499
R B1
R B2
C(CH 3 ) 2
L A3440
H
R A52
S
L A3500
R B1
R B3
C(CH 3 ) 2
L A3441
H
H
O
L A3501
R B1
R B4
C(CH 3 ) 2
L A3442
H
R B1
O
L A3502
R B1
R B5
C(CH 3 ) 2
L A3443
H
R B2
O
L A3503
R B1
R A34
C(CH 3 ) 2
L A3444
H
R B3
O
L A3504
R B1
R A52
C(CH 3 ) 2
L A3445
H
R B4
O
L A3505
R B1
H
Si(CH 3 ) 2
L A3446
H
R B5
O
L A3506
R B1
R B1
Si(CH 3 ) 2
L A3447
H
R A34
O
L A3507
R B1
R B2
Si(CH 3 ) 2
L A3448
H
R A52
O
L A3508
R B1
R B3
Si(CH 3 ) 2
L A3449
H
H
NCH 3
L A3509
R B1
R B4
Si(CH 3 ) 2
L A3450
H
R B1
NCH 3
L A3510
R B1
R B5
Si(CH 3 ) 2
L A3451
H
R B2
NCH 3
L A3511
R B1
R A34
Si(CH 3 ) 2
L A3452
H
R B3
NCH 3
L A3512
R B1
R A52
Si(CH 3 ) 2
L A3453
H
R B4
NCH 3
L A3513
R B6
H
S
L A3454
H
R B5
NCH 3
L A3514
R B6
R B1
S
L A3455
H
R A34
NCH 3
L A3515
R B6
R B2
S
L A3456
H
R A52
NCH 3
L A3516
R B6
R B3
S
L A3457
H
H
C(CH 3 ) 2
L A3517
R B6
R B4
S
L A3458
H
R B1
C(CH 3 ) 2
L A3518
R B6
R B5
S
L A3459
H
R B2
C(CH 3 ) 2
L A3519
R B6
R A34
S
L A3460
H
R B3
C(CH 3 ) 2
L A3520
R B6
R A52
S
L A3461
H
R B4
C(CH 3 ) 2
L A3521
R B6
H
O
L A3462
H
R B5
C(CH 3 ) 2
L A3522
R B6
R B1
O
L A3463
H
R A34
C(CH 3 ) 2
L A3523
R B6
R B2
O
L A3464
H
R A52
C(CH 3 ) 2
L A3524
R B6
R B3
O
L A3465
H
H
Si(CH 3 ) 2
L A3525
R B6
R B4
O
L A3466
H
R B1
Si(CH 3 ) 2
L A3526
R B6
R B5
O
L A3467
H
R B2
Si(CH 3 ) 2
L A3527
R B6
R A34
O
L A3468
H
R B3
Si(CH 3 ) 2
L A3528
R B6
R A52
O
L A3469
H
R B4
Si(CH 3 ) 2
L A3529
R B6
H
NCH 3
L A3470
H
R B5
Si(CH 3 ) 2
L A3530
R B6
R B1
NCH 3
L A3471
H
R A34
Si(CH 3 ) 2
L A3531
R B6
R B2
NCH 3
L A3472
H
R A52
Si(CH 3 ) 2
L A3532
R B6
R B3
NCH 3
L A3473
R B1
H
S
L A3533
R B6
R B4
NCH 3
L A3474
R B1
R B1
S
L A3534
R B6
R B5
NCH 3
L A3475
R B1
R B2
S
L A3535
R B6
R A34
NCH 3
L A3476
R B1
R B3
S
L A3536
R B6
R A52
NCH 3
L A3477
R B1
R B4
S
L A3537
R B6
H
C(CH 3 ) 2
L A3478
R B1
R B5
S
L A3538
R B6
R B1
C(CH 3 ) 2
L A3479
R B1
R A34
S
L A3539
R B6
R B2
C(CH 3 ) 2
L A3480
R B1
R A52
S
L A3540
R B6
R B3
C(CH 3 ) 2
L A3481
R B1
H
O
L A3541
R B6
R B4
C(CH 3 ) 2
L A3482
R B1
R B1
O
L A3542
R B6
R B5
C(CH 3 ) 2
L A3483
R B1
R B2
O
L A3543
R B6
R A34
C(CH 3 ) 2
L A3484
R B1
R B3
O
L A3544
R B6
R A52
C(CH 3 ) 2
L A3485
R B1
R B4
O
L A3545
R B6
H
Si(CH 3 ) 2
L A3486
R B1
R B5
O
L A3546
R B6
R B1
Si(CH 3 ) 2
L A3487
R B1
R A34
O
L A3547
R B6
R B2
Si(CH 3 ) 2
L A3488
R B1
R A52
O
L A3548
R B6
R B3
Si(CH 3 ) 2
L A3489
R B1
H
NCH 3
L A3549
R B6
R B4
Si(CH 3 ) 2
L A3490
R B1
R B1
NCH 3
L A3550
R B6
R B5
Si(CH 3 ) 2
L A3491
R B1
R B2
NCH 3
L A3551
R B6
R A34
Si(CH 3 ) 2
L A3492
R B1
R B3
NCH 3
L A3552
R B6
R A52
Si(CH 3 ) 2
wherein L A3553 through L A3648 have a structure of Formula XXV:
wherein R 4 , R 5 , Y, and Z are defined as provided below:
Ligand
R 5
R 4
Y
Z
Ligand
R 5
R 4
Y
Z
L A3553
H
H
S
S
L A3601
R B6
H
S
S
L A3554
H
R B1
S
S
L A3602
R B6
R B1
S
S
L A3555
H
R B3
S
S
L A3603
R B6
R B3
S
S
L A3556
H
R B4
S
S
L A3604
R B6
R B4
S
S
L A3557
H
R B7
S
S
L A3605
R B6
R B7
S
S
L A3558
H
R B10
S
S
L A3606
R B6
R B10
S
S
L A3559
H
R A3
S
S
L A3607
R B6
R A3
S
S
L A3560
H
R A34
S
S
L A3608
R B6
R A34
S
S
L A3561
H
H
S
O
L A3609
R B6
H
S
O
L A3562
H
R B1
S
O
L A3610
R B6
R B1
S
O
L A3563
H
R B3
S
O
L A3611
R B6
R B3
S
O
L A3564
H
R B4
S
O
L A3612
R B6
R B4
S
O
L A3565
H
R B7
S
O
L A3613
R B6
R B7
S
O
L A3566
H
R B10
S
O
L A3614
R B6
R B10
S
O
L A3567
H
R A3
S
O
L A3615
R B6
R A3
S
O
L A3568
H
R A34
S
O
L A3616
R B6
R A34
S
O
L A3569
H
H
S
NCH 3
L A3617
R B6
H
S
NCH 3
L A3570
H
R B1
S
NCH 3
L A3618
R B6
R B1
S
NCH 3
L A3571
H
R B3
S
NCH 3
L A3619
R B6
R B3
S
NCH 3
L A3572
H
R B4
S
NCH 3
L A3620
R B6
R B4
S
NCH 3
L A3573
H
R B7
S
NCH 3
L A3621
R B6
R B7
S
NCH 3
L A3574
H
R B10
S
NCH 3
L A3622
R B6
R B10
S
NCH 3
L A3575
H
R A3
S
NCH 3
L A3623
R B6
R A3
S
NCH 3
L A3576
H
R A34
S
NCH 3
L A3624
R B6
R A34
S
NCH 3
L A3577
H
H
O
S
L A3625
R B6
H
O
S
L A3578
H
R B1
O
S
L A3626
R B6
R B1
O
S
L A3579
H
R B3
O
S
L A3627
R B6
R B3
O
S
L A3580
H
R B4
O
S
L A3628
R B6
R B4
O
S
L A3581
H
R B7
O
S
L A3629
R B6
R B7
O
S
L A3582
H
R B10
O
S
L A3630
R B6
R B10
O
S
L A3583
H
R A3
O
S
L A3631
R B6
R A3
O
S
L A3584
H
R A34
O
S
L A3632
R B6
R A34
O
S
L A3585
H
H
O
O
L A3633
R B6
H
O
O
L A3586
H
R B1
O
O
L A3634
R B6
R B1
O
O
L A3587
H
R B3
O
O
L A3635
R B6
R B3
O
O
L A3588
H
R B4
O
O
L A3636
R B6
R B4
O
O
L A3589
H
R B7
O
O
L A3637
R B6
R B7
O
O
L A3590
H
R B10
O
O
L A3638
R B6
R B10
O
O
L A3591
H
R A3
O
O
L A3639
R B6
R A3
O
O
L A3592
H
R A34
O
O
L A3640
R B6
R A34
O
O
L A3593
H
H
O
NCH 3
L A3641
R B6
H
O
NCH 3
L A3594
H
R B1
O
NCH 3
L A3642
R B6
R B1
O
NCH 3
L A3595
H
R B3
O
NCH 3
L A3643
R B6
R B3
O
NCH 3
L A3596
H
R B4
O
NCH 3
L A3644
R B6
R B4
O
NCH 3
L A3597
H
R B7
O
NCH 3
L A3645
R B6
R B7
O
NCH 3
L A3598
H
R B10
O
NCH 3
L A3646
R B6
R B10
O
NCH 3
L A3599
H
R A3
O
NCH 3
L A3647
R B6
R A3
O
NCH 3
L A3600
H
R A34
O
NCH 3
L A3648
R B6
R A34
O
NCH 3
wherein L A3649 through L A3888 have a structure of Formula XXVI:
wherein R 1 , R 5 , X, and Y are defined as provided below:
Ligand
R 1
R 5
X
Y
Ligand
R 1
R 5
X
Y
L A3649
H
H
C
S
L A3769
H
H
N
S
L A3650
R B1
H
C
S
L A3770
R B1
H
N
S
L A3651
R B3
H
C
S
L A3771
R B3
H
N
S
L A3652
R B4
H
C
S
L A3772
R B4
H
N
S
L A3653
R B7
H
C
S
L A3773
R B7
H
N
S
L A3654
R B10
H
C
S
L A3774
R B10
H
N
S
L A3655
R A3
H
C
S
L A3775
R A3
H
N
S
L A3656
R A34
H
C
S
L A3776
R A34
H
N
S
L A3657
H
H
C
O
L A3777
H
H
N
O
L A3658
R B1
H
C
O
L A3778
R B1
H
N
O
L A3659
R B3
H
C
O
L A3779
R B3
H
N
O
L A3660
R B4
H
C
O
L A3780
R B4
H
N
O
L A3661
R B7
H
C
O
L A3781
R B7
H
N
O
L A3662
R B10
H
C
O
L A3782
R B10
H
N
O
L A3663
R A3
H
C
O
L A3783
R A3
H
N
O
L A3664
R A34
H
C
O
L A3784
R A34
H
N
O
L A3665
H
H
C
NCH 3
L A3785
H
H
N
NCH 3
L A3666
R B1
H
C
NCH 3
L A3786
R B1
H
N
NCH 3
L A3667
R B3
H
C
NCH 3
L A3787
R B3
H
N
NCH 3
L A3668
R B4
H
C
NCH 3
L A3788
R B4
H
N
NCH 3
L A3669
R B7
H
C
NCH 3
L A3789
R B7
H
N
NCH 3
L A3670
R B10
H
C
NCH 3
L A3790
R B10
H
N
NCH 3
L A3671
R A3
H
C
NCH 3
L A3791
R A3
H
N
NCH 3
L A3672
R A34
H
C
NCH 3
L A3792
R A34
H
N
NCH 3
L A3673
H
H
C
C(CH 3 ) 2
L A3793
H
H
N
C(CH 3 ) 2
L A3674
R B1
H
C
C(CH 3 ) 2
L A3794
R B1
H
N
C(CH 3 ) 2
L A3675
R B3
H
C
C(CH 3 ) 2
L A3795
R B3
H
N
C(CH 3 ) 2
L A3676
R B4
H
C
C(CH 3 ) 2
L A3796
R B4
H
N
C(CH 3 ) 2
L A3677
R B7
H
C
C(CH 3 ) 2
L A3797
R B7
H
N
C(CH 3 ) 2
L A3678
R B10
H
C
C(CH 3 ) 2
L A3798
R B10
H
N
C(CH 3 ) 2
L A3679
R A3
H
C
C(CH 3 ) 2
L A3799
R A3
H
N
C(CH 3 ) 2
L A3680
R A34
H
C
C(CH 3 ) 2
L A3800
R A34
H
N
C(CH 3 ) 2
L A3681
H
H
C
Si(CH 3 ) 2
L A3801
H
H
N
Si(CH 3 ) 2
L A3682
R B1
H
C
Si(CH 3 ) 2
L A3802
R B1
H
N
Si(CH 3 ) 2
L A3683
R B3
H
C
Si(CH 3 ) 2
L A3803
R B3
H
N
Si(CH 3 ) 2
L A3684
R B4
H
C
Si(CH 3 ) 2
L A3804
R B4
H
N
Si(CH 3 ) 2
L A3685
R B7
H
C
Si(CH 3 ) 2
L A3805
R B7
H
N
Si(CH 3 ) 2
L A3686
R B10
H
C
Si(CH 3 ) 2
L A3806
R B10
H
N
Si(CH 3 ) 2
L A3687
R A3
H
C
Si(CH 3 ) 2
L A3807
R A3
H
N
Si(CH 3 ) 2
L A3688
R A34
H
C
Si(CH 3 ) 2
L A3808
R A34
H
N
Si(CH 3 ) 2
L A3689
H
R B1
C
S
L A3809
H
R B1
N
S
L A3690
R B1
R B1
C
S
L A3810
R B1
R B1
N
S
L A3691
R B3
R B1
C
S
L A3811
R B3
R B1
N
S
L A3692
R B4
R B1
C
S
L A3812
R B4
R B1
N
S
L A3693
R B7
R B1
C
S
L A3813
R B7
R B1
N
S
L A3694
R B10
R B1
C
S
L A3814
R B10
R B1
N
S
L A3695
R A3
R B1
C
S
L A3815
R A3
R B1
N
S
L A3696
R A34
R B1
C
S
L A3816
R A34
R B1
N
S
L A3697
H
R B1
C
O
L A3817
H
R B1
N
O
L A3698
R B1
R B1
C
O
L A3818
R B1
R B1
N
O
L A3699
R B3
R B1
C
O
L A3819
R B3
R B1
N
O
L A3700
R B4
R B1
C
O
L A3820
R B4
R B1
N
O
L A3701
R B7
R B1
C
O
L A3821
R B7
R B1
N
O
L A3702
R B10
R B1
C
O
L A3822
R B10
R B1
N
O
L A3703
R A3
R B1
C
O
L A3823
R A3
R B1
N
O
L A3704
R A34
R B1
C
O
L A3824
R A34
R B1
N
O
L A3705
H
R B1
C
NCH 3
L A3825
H
R B1
N
NCH 3
L A3706
R B1
R B1
C
NCH 3
L A3826
R B1
R B1
N
NCH 3
L A3707
R B3
R B1
C
NCH 3
L A3827
R B3
R B1
N
NCH 3
L A3708
R B4
R B1
C
NCH 3
L A3828
R B4
R B1
N
NCH 3
L A3709
R B7
R B1
C
NCH 3
L A3829
R B7
R B1
N
NCH 3
L A3710
R B10
R B1
C
NCH 3
L A3830
R B10
R B1
N
NCH 3
L A3711
R A3
R B1
C
NCH 3
L A3831
R A3
R B1
N
NCH 3
L A3712
R A34
R B1
C
NCH 3
L A3832
R A34
R B1
N
NCH 3
L A3713
H
R B1
C
C(CH 3 ) 2
L A3833
H
R B1
N
C(CH 3 ) 2
L A3714
R B1
R B1
C
C(CH 3 ) 2
L A3834
R B1
R B1
N
C(CH 3 ) 2
L A3715
R B3
R B1
C
C(CH 3 ) 2
L A3835
R B3
R B1
N
C(CH 3 ) 2
L A3716
R B4
R B1
C
C(CH 3 ) 2
L A3836
R B4
R B1
N
C(CH 3 ) 2
L A3717
R B7
R B1
C
C(CH 3 ) 2
L A3837
R B7
R B1
N
C(CH 3 ) 2
L A3718
R B10
R B1
C
C(CH 3 ) 2
L A3838
R B10
R B1
N
C(CH 3 ) 2
L A3719
R A3
R B1
C
C(CH 3 ) 2
L A3839
R A3
R B1
N
C(CH 3 ) 2
L A3720
R A34
R B1
C
C(CH 3 ) 2
L A3840
R A34
R B1
N
C(CH 3 ) 2
L A3721
H
R B1
C
Si(CH 3 ) 2
L A3841
H
R B1
N
Si(CH 3 ) 2
L A3722
R B1
R B1
C
Si(CH 3 ) 2
L A3842
R B1
R B1
N
Si(CH 3 ) 2
L A3723
R B3
R B1
C
Si(CH 3 ) 2
L A3843
R B3
R B1
N
Si(CH 3 ) 2
L A3724
R B4
R B1
C
Si(CH 3 ) 2
L A3844
R B4
R B1
N
Si(CH 3 ) 2
L A3725
R B7
R B1
C
Si(CH 3 ) 2
L A3845
R B7
R B1
N
Si(CH 3 ) 2
L A3726
R B10
R B1
C
Si(CH 3 ) 2
L A3846
R B10
R B1
N
Si(CH 3 ) 2
L A3727
R A3
R B1
C
Si(CH 3 ) 2
L A3847
R A3
R B1
N
Si(CH 3 ) 2
L A3728
R A34
R B1
C
Si(CH 3 ) 2
L A3848
R A34
R B1
N
Si(CH 3 ) 2
L A3729
H
R B6
C
S
L A3849
H
R B6
N
S
L A3730
R B1
R B6
C
S
L A3850
R B1
R B6
N
S
L A3731
R B3
R B6
C
S
L A3851
R B3
R B6
N
S
L A3732
R B4
R B6
C
S
L A3852
R B4
R B6
N
S
L A3733
R B7
R B6
C
S
L A3853
R B7
R B6
N
S
L A3734
R B10
R B6
C
S
L A3854
R B10
R B6
N
S
L A3735
R A3
R B6
C
S
L A3855
R A3
R B6
N
S
L A3736
R A34
R B6
C
S
L A3856
R A34
R B6
N
S
L A3737
H
R B6
C
O
L A3857
H
R B6
N
O
L A3738
R B1
R B6
C
O
L A3858
R B1
R B6
N
O
L A3739
R B3
R B6
C
O
L A3859
R B3
R B6
N
O
L A3740
R B4
R B6
C
O
L A3860
R B4
R B6
N
O
L A3741
R B7
R B6
C
O
L A3861
R B7
R B6
N
O
L A3742
R B10
R B6
C
O
L A3862
R B10
R B6
N
O
L A3743
R A3
R B6
C
O
L A3863
R A3
R B6
N
O
L A3744
R A34
R B6
C
O
L A3864
R A34
R B6
N
O
L A3745
H
R B6
C
NCH 3
L A3865
H
R B6
N
NCH 3
L A3746
R B1
R B6
C
NCH 3
L A3866
R B1
R B6
N
NCH 3
L A3747
R B3
R B6
C
NCH 3
L A3867
R B3
R B6
N
NCH 3
L A3748
R B4
R B6
C
NCH 3
L A3868
R B4
R B6
N
NCH 3
L A3749
R B7
R B6
C
NCH 3
L A3869
R B7
R B6
N
NCH 3
L A3750
R B10
R B6
C
NCH 3
L A3870
R B10
R B6
N
NCH 3
L A3751
R A3
R B6
C
NCH 3
L A3871
R A3
R B6
N
NCH 3
L A3752
R A34
R B6
C
NCH 3
L A3872
R A34
R B6
N
NCH 3
L A3753
H
R B6
C
C(CH 3 ) 2
L A3873
H
R B6
N
C(CH 3 ) 2
L A3754
R B1
R B6
C
C(CH 3 ) 2
L A3874
R B1
R B6
N
C(CH 3 ) 2
L A3755
R B3
R B6
C
C(CH 3 ) 2
L A3875
R B3
R B6
N
C(CH 3 ) 2
L A3756
R B4
R B6
C
C(CH 3 ) 2
L A3876
R B4
R B6
N
C(CH 3 ) 2
L A3757
R B7
R B6
C
C(CH 3 ) 2
L A3877
R B7
R B6
N
C(CH 3 ) 2
L A3758
R B10
R B6
C
C(CH 3 ) 2
L A3878
R B10
R B6
N
C(CH 3 ) 2
L A3759
R A3
R B6
C
C(CH 3 ) 2
L A3879
R A3
R B6
N
C(CH 3 ) 2
L A3760
R A34
R B6
C
C(CH 3 ) 2
L A3880
R A34
R B6
N
C(CH 3 ) 2
L A3761
H
R B6
C
Si(CH 3 ) 2
L A3881
H
R B6
N
Si(CH 3 ) 2
L A3762
R B1
R B6
C
Si(CH 3 ) 2
L A3882
R B1
R B6
N
Si(CH 3 ) 2
L A3763
R B3
R B6
C
Si(CH 3 ) 2
L A3883
R B3
R B6
N
Si(CH 3 ) 2
L A3764
R B4
R B6
C
Si(CH 3 ) 2
L A3884
R B4
R B6
N
Si(CH 3 ) 2
L A3765
R B7
R B6
C
Si(CH 3 ) 2
L A3885
R B7
R B6
N
Si(CH 3 ) 2
L A3766
R B10
R B6
C
Si(CH 3 ) 2
L A3886
R B10
R B6
N
Si(CH 3 ) 2
L A3767
R A3
R B6
C
Si(CH 3 ) 2
L A3887
R A3
R B6
N
Si(CH 3 ) 2
L A3768
R A34
R B6
C
Si(CH 3 ) 2
L A3888
R A34
R B6
N
Si(CH 3 ) 2
wherein L A3889 through L A4008 have a structure of Formula XXVII:
wherein R 3 , R 5 , and Y are defined as provided below:
Ligand
R 5
R 3
Y
Ligand
R 5
R 3
Y
L A3889
H
H
S
L A3949
R B1
R B4
NCH 3
L A3890
H
R B1
S
L A3950
R B1
R B5
NCH 3
L A3891
H
R B2
S
L A3951
R B1
R A34
NCH 3
L A3892
H
R B3
S
L A3952
R B1
R A52
NCH 3
L A3893
H
R B4
S
L A3953
R B1
H
C(CH 3 ) 2
L A3894
H
R B5
S
L A3954
R B1
R B1
C(CH 3 ) 2
L A3895
H
R A34
S
L A3955
R B1
R B2
C(CH 3 ) 2
L A3896
H
R A52
S
L A3956
R B1
R B3
C(CH 3 ) 2
L A3897
H
H
O
L A3957
R B1
R B4
C(CH 3 ) 2
L A3898
H
R B1
O
L A3958
R B1
R B5
C(CH 3 ) 2
L A3899
H
R B2
O
L A3959
R B1
R A34
C(CH 3 ) 2
L A3900
H
R B3
O
L A3960
R B1
R A52
C(CH 3 ) 2
L A3901
H
R B4
O
L A3961
R B1
H
Si(CH 3 ) 2
L A3902
H
R B5
O
L A3962
R B1
R B1
Si(CH 3 ) 2
L A3903
H
R A34
O
L A3963
R B1
R B2
Si(CH 3 ) 2
L A3904
H
R A52
O
L A3964
R B1
R B3
Si(CH 3 ) 2
L A3905
H
H
NCH 3
L A3965
R B1
R B4
Si(CH 3 ) 2
L A3906
H
R B1
NCH 3
L A3966
R B1
R B5
Si(CH 3 ) 2
L A3907
H
R B2
NCH 3
L A3967
R B1
R A34
Si(CH 3 ) 2
L A3908
H
R B3
NCH 3
L A3968
R B1
R A52
Si(CH 3 ) 2
L A3909
H
R B4
NCH 3
L A3969
R B6
H
S
L A3910
H
R B5
NCH 3
L A3970
R B6
R B1
S
L A3911
H
R A34
NCH 3
L A3971
R B6
R B2
S
L A3912
H
R A52
NCH 3
L A3972
R B6
R B3
S
L A3913
H
H
C(CH 3 ) 2
L A3973
R B6
R B4
S
L A3914
H
R B1
C(CH 3 ) 2
L A3974
R B6
R B5
S
L A3915
H
R B2
C(CH 3 ) 2
L A3975
R B6
R A34
S
L A3916
H
R B3
C(CH 3 ) 2
L A3976
R B6
R A52
S
L A3917
H
R B4
C(CH 3 ) 2
L A3977
R B6
H
O
L A3918
H
R B5
C(CH 3 ) 2
L A3978
R B6
R B1
O
L A3919
H
R A34
C(CH 3 ) 2
L A3979
R B6
R B2
O
L A3920
H
R A52
C(CH 3 ) 2
L A3980
R B6
R B3
O
L A3921
H
H
Si(CH 3 ) 2
L A3981
R B6
R B4
O
L A3922
H
R B1
Si(CH 3 ) 2
L A3982
R B6
R B5
O
L A3923
H
R B2
Si(CH 3 ) 2
L A3983
R B6
R A34
O
L A3924
H
R B3
Si(CH 3 ) 2
L A3984
R B6
R A52
O
L A3925
H
R B4
Si(CH 3 ) 2
L A3985
R B6
H
NCH 3
L A3926
H
R B5
Si(CH 3 ) 2
L A3986
R B6
R B1
NCH 3
L A3927
H
R A34
Si(CH 3 ) 2
L A3987
R B6
R B2
NCH 3
L A3928
H
R A52
Si(CH 3 ) 2
L A3988
R B6
R B3
NCH 3
L A3929
R B1
H
S
L A3989
R B6
R B4
NCH 3
L A3930
R B1
R B1
S
L A3990
R B6
R B5
NCH 3
L A3931
R B1
R B2
S
L A3991
R B6
R A34
NCH 3
L A3932
R B1
R B3
S
L A3992
R B6
R A52
NCH 3
L A3933
R B1
R B4
S
L A3993
R B6
H
C(CH 3 ) 2
L A3934
R B1
R B5
S
L A3994
R B6
R B1
C(CH 3 ) 2
L A3935
R B1
R A34
S
L A3995
R B6
R B2
C(CH 3 ) 2
L A3936
R B1
R A52
S
L A3996
R B6
R B3
C(CH 3 ) 2
L A3937
R B1
H
O
L A3997
R B6
R B4
C(CH 3 ) 2
L A3938
R B1
R B1
O
L A3998
R B6
R B5
C(CH 3 ) 2
L A3939
R B1
R B2
O
L A3999
R B6
R A34
C(CH 3 ) 2
L A3940
R B1
R B3
O
L A4000
R B6
R A52
C(CH 3 ) 2
L A3941
R B1
R B4
O
L A4001
R B6
H
Si(CH 3 ) 2
L A3942
R B1
R B5
O
L A4002
R B6
R B1
Si(CH 3 ) 2
L A3943
R B1
R A34
O
L A4003
R B6
R B2
Si(CH 3 ) 2
L A3944
R B1
R A52
O
L A4004
R B6
R B3
Si(CH 3 ) 2
L A3945
R B1
H
NCH 3
L A4005
R B6
R B4
Si(CH 3 ) 2
L A3946
R B1
R B1
NCH 3
L A4006
R B6
R B5
Si(CH 3 ) 2
L A3947
R B1
R B2
NCH 3
L A4007
R B6
R A34
Si(CH 3 ) 2
L A3948
R B1
R B3
NCH 3
L A4008
R B6
R A52
Si(CH 3 ) 2
wherein L A4009 through L A4104 have a structure of Formula XXVIII:
wherein R 4 , R 5 , Y, and Z are defined as provided below:
Ligand
R 5
R 4
Y
Z
Ligand
R 5
R 4
Y
Z
L A4009
H
H
S
S
L A4057
R B6
H
S
S
L A4010
H
R B1
S
S
L A4058
R B6
R B1
S
S
L A4011
H
R B3
S
S
L A4059
R B6
R B3
S
S
L A4012
H
R B4
S
S
L A4060
R B6
R B4
S
S
L A4013
H
R B7
S
S
L A4061
R B6
R B7
S
S
L A4014
H
R B10
S
S
L A4062
R B6
R B10
S
S
L A4015
H
R A3
S
S
L A4063
R B6
R A3
S
S
L A4016
H
R A34
S
S
L A4064
R B6
R A34
S
S
L A4017
H
H
S
O
L A4065
R B6
H
S
O
L A4018
H
R B1
S
O
L A4066
R B6
R B1
S
O
L A4019
H
R B3
S
O
L A4067
R B6
R B3
S
O
L A4020
H
R B4
S
O
L A4068
R B6
R B4
S
O
L A4021
H
R B7
S
O
L A4069
R B6
R B7
S
O
L A4022
H
R B10
S
O
L A4070
R B6
R B10
S
O
L A4023
H
R A3
S
O
L A4071
R B6
R A3
S
O
L A4024
H
R A34
S
O
L A4072
R B6
R A34
S
O
L A4025
H
H
S
NCH 3
L A4073
R B6
H
S
NCH 3
L A4026
H
R B1
S
NCH 3
L A4074
R B6
R B1
S
NCH 3
L A4027
H
R B3
S
NCH 3
L A4075
R B6
R B3
S
NCH 3
L A4028
H
R B4
S
NCH 3
L A4076
R B6
R B4
S
NCH 3
L A4029
H
R B7
S
NCH 3
L A4077
R B6
R B7
S
NCH 3
L A4030
H
R B10
S
NCH 3
L A4078
R B6
R B10
S
NCH 3
L A4031
H
R A3
S
NCH 3
L A4079
R B6
R A3
S
NCH 3
L A4032
H
R A34
S
NCH 3
L A4080
R B6
R A34
S
NCH 3
L A4033
H
H
O
S
L A4081
R B6
H
O
S
L A4034
H
R B1
O
S
L A4082
R B6
R B1
O
S
L A4035
H
R B3
O
S
L A4083
R B6
R B3
O
S
L A4036
H
R B4
O
S
L A4084
R B6
R B4
O
S
L A4037
H
R B7
O
S
L A4085
R B6
R B7
O
S
L A4038
H
R B10
O
S
L A4086
R B6
R B10
O
S
L A4039
H
R A3
O
S
L A4087
R B6
R A3
O
S
L A4040
H
R A34
O
S
L A4088
R B6
R A34
O
S
L A4041
H
H
O
O
L A4089
R B6
H
O
O
L A4042
H
R B1
O
O
L A4090
R B6
R B1
O
O
L A4043
H
R B3
O
O
L A4091
R B6
R B3
O
O
L A4044
H
R B4
O
O
L A4092
R B6
R B4
O
O
L A4045
H
R B7
O
O
L A4093
R B6
R B7
O
O
L A4046
H
R B10
O
O
L A4094
R B6
R B10
O
O
L A4047
H
R A3
O
O
L A4095
R B6
R A3
O
O
L A4048
H
R A34
O
O
L A4096
R B6
R A34
O
O
L A4049
H
H
O
NCH 3
L A4097
R B6
H
O
NCH 3
L A4050
H
R B1
O
NCH 3
L A4098
R B6
R B1
O
NCH 3
L A4051
H
R B3
O
NCH 3
L A4099
R B6
R B3
O
NCH 3
L A4052
H
R B4
O
NCH 3
L A4100
R B6
R B4
O
NCH 3
L A4053
H
R B7
O
NCH 3
L A4101
R B6
R B7
O
NCH 3
L A4054
H
R B10
O
NCH 3
L A4102
R B6
R B10
O
NCH 3
L A4055
H
R A3
O
NCH 3
L A4103
R B6
R A3
O
NCH 3
L A4056
H
R A34
O
NCH 3
L A4104
R B6
R A34
O
NCH 3
wherein L A4225 through L A4344 have a structure of Formula XXIX:
wherein R 1 , R 5 , X, and Y are defined as provided below:
Ligand
R 1
R 5
X
Y
L A4225
H
H
N
S
L A4226
R B1
H
N
S
L A4227
R B3
H
N
S
L A4228
R B4
H
N
S
L A4229
R B7
H
N
S
L A4230
R B10
H
N
S
L A4231
R A3
H
N
S
L A4232
R A34
H
N
S
L A4233
H
H
N
O
L A4234
R B1
H
N
O
L A4235
R B3
H
N
O
L A4236
R B4
H
N
O
L A4237
R B7
H
N
O
L A4238
R B10
H
N
O
L A4239
R A3
H
N
O
L A4240
R A34
H
N
O
L A4241
H
H
N
NCH 3
L A4242
R B1
H
N
NCH 3
L A4243
R B3
H
N
NCH 3
L A4244
R B4
H
N
NCH 3
L A4245
R B7
H
N
NCH 3
L A4246
R B10
H
N
NCH 3
L A4247
R A3
H
N
NCH 3
L A4248
R A34
H
N
NCH 3
L A4249
H
H
N
C(CH 3 ) 2
L A4250
R B1
H
N
C(CH 3 ) 2
L A4251
R B3
H
N
C(CH 3 ) 2
L A4252
R B4
H
N
C(CH 3 ) 2
L A4253
R B7
H
N
C(CH 3 ) 2
L A4254
R B10
H
N
C(CH 3 ) 2
L A4255
R A3
H
N
C(CH 3 ) 2
L A4256
R A34
H
N
C(CH 3 ) 2
L A4257
H
H
N
Si(CH 3 ) 2
L A4258
R B1
H
N
Si(CH 3 ) 2
L A4259
R B3
H
N
Si(CH 3 ) 2
L A4260
R B4
H
N
Si(CH 3 ) 2
L A4261
R B7
H
N
Si(CH 3 ) 2
L A4262
R B10
H
N
Si(CH 3 ) 2
L A4263
R A3
H
N
Si(CH 3 ) 2
L A4264
R A34
H
N
Si(CH 3 ) 2
L A4265
H
R B1
N
S
L A4266
R B1
R B1
N
S
L A4267
R B3
R B1
N
S
L A4268
R B4
R B1
N
S
L A4269
R B7
R B1
N
S
L A4270
R B10
R B1
N
S
L A4271
R A3
R B1
N
S
L A4272
R A34
R B1
N
S
L A4273
H
R B1
N
O
L A4274
R B1
R B1
N
O
L A4275
R B3
R B1
N
O
L A4276
R B4
R B1
N
O
L A4277
R B7
R B1
N
O
L A4278
R B10
R B1
N
O
L A4279
R A3
R B1
N
O
L A4280
R A34
R B1
N
O
L A4281
H
R B1
N
NCH 3
L A4282
R B1
R B1
N
NCH 3
L A4283
R B3
R B1
N
NCH 3
L A4284
R B4
R B1
N
NCH 3
L A4285
R B7
R B1
N
NCH 3
L A4286
R B10
R B1
N
NCH 3
L A4287
R A3
R B1
N
NCH 3
L A4288
R A34
R B1
N
NCH 3
L A4289
H
R B1
N
C(CH 3 ) 2
L A4290
R B1
R B1
N
C(CH 3 ) 2
L A4291
R B3
R B1
N
C(CH 3 ) 2
L A4292
R B4
R B1
N
C(CH 3 ) 2
L A4293
R B7
R B1
N
C(CH 3 ) 2
L A4294
R B10
R B1
N
C(CH 3 ) 2
L A4295
R A3
R B1
N
C(CH 3 ) 2
L A4296
R A34
R B1
N
C(CH 3 ) 2
L A4297
H
R B1
N
Si(CH 3 ) 2
L A4298
R B1
R B1
N
Si(CH 3 ) 2
L A4299
R B3
R B1
N
Si(CH 3 ) 2
L A4300
R B4
R B1
N
Si(CH 3 ) 2
L A4301
R B7
R B1
N
Si(CH 3 ) 2
L A4302
R B10
R B1
N
Si(CH 3 ) 2
L A4303
R A3
R B1
N
Si(CH 3 ) 2
L A4304
R A34
R B1
N
Si(CH 3 ) 2
L A4305
H
R B6
N
S
L A4306
R B1
R B6
N
S
L A4307
R B3
R B6
N
S
L A4308
R B4
R B6
N
S
L A4309
R B7
R B6
N
S
L A4310
R B10
R B6
N
S
L A4311
R A3
R B6
N
S
L A4312
R A34
R B6
N
S
L A4313
H
R B6
N
O
L A4314
R B1
R B6
N
O
L A4315
R B3
R B6
N
O
L A4316
R B4
R B6
N
O
L A4317
R B7
R B6
N
O
L A4318
R B10
R B6
N
O
L A4319
R A3
R B6
N
O
L A4320
R A34
R B6
N
O
L A4321
H
R B6
N
NCH 3
L A4322
R B1
R B6
N
NCH 3
L A4323
R B3
R B6
N
NCH 3
L A4324
R B4
R B6
N
NCH 3
L A4325
R B7
R B6
N
NCH 3
L A4326
R B10
R B6
N
NCH 3
L A4327
R A3
R B6
N
NCH 3
L A4328
R A34
R B6
N
NCH 3
L A4329
H
R B6
N
C(CH 3 ) 2
L A4330
R B1
R B6
N
C(CH 3 ) 2
L A4331
R B3
R B6
N
C(CH 3 ) 2
L A4332
R B4
R B6
N
C(CH 3 ) 2
L A4333
R B7
R B6
N
C(CH 3 ) 2
L A4334
R B10
R B6
N
C(CH 3 ) 2
L A4335
R A3
R B6
N
C(CH 3 ) 2
L A4336
R A34
R B6
N
C(CH 3 ) 2
L A4337
H
R B6
N
Si(CH 3 ) 2
L A4338
R B1
R B6
N
Si(CH 3 ) 2
L A4339
R B3
R B6
N
Si(CH 3 ) 2
L A4340
R B4
R B6
N
Si(CH 3 ) 2
L A4341
R B7
R B6
N
Si(CH 3 ) 2
L A4342
R B10
R B6
N
Si(CH 3 ) 2
L A4343
R A3
R B6
N
Si(CH 3 ) 2
L A4344
R A34
R B6
N
Si(CH 3 ) 2
wherein L A4345 through L A4464 have a structure of Formula XXX:
wherein R 3 , R 5 , and Y are defined as provided below:
Ligand
R 5
R 3
Y
Ligand
R 5
R 3
Y
L A4345
H
H
S
L A4405
R B1
R B4
NCH 3
L A4346
H
R B1
S
L A4406
R B1
R B5
NCH 3
L A4347
H
R B2
S
L A4407
R B1
R A34
NCH 3
L A4348
H
R B3
S
L A4408
R B1
R A52
NCH 3
L A4349
H
R B4
S
L A4409
R B1
H
C(CH 3 ) 2
L A4350
H
R B5
S
L A4410
R B1
R B1
C(CH 3 ) 2
L A4351
H
R A34
S
L A4411
R B1
R B2
C(CH 3 ) 2
L A4352
H
R A52
S
L A4412
R B1
R B3
C(CH 3 ) 2
L A4353
H
H
O
L A4413
R B1
R B4
C(CH 3 ) 2
L A4354
H
R B1
O
L A4414
R B1
R B5
C(CH 3 ) 2
L A4355
H
R B2
O
L A4415
R B1
R A34
C(CH 3 ) 2
L A4356
H
R B3
O
L A4416
R B1
R A52
C(CH 3 ) 2
L A4357
H
R B4
O
L A4417
R B1
H
Si(CH 3 ) 2
L A4358
H
R B5
O
L A4418
R B1
R B1
Si(CH 3 ) 2
L A4359
H
R A34
O
L A4419
R B1
R B2
Si(CH 3 ) 2
L A4360
H
R A52
O
L A4420
R B1
R B3
Si(CH 3 ) 2
L A4361
H
H
NCH 3
L A4421
R B1
R B4
Si(CH 3 ) 2
L A4362
H
R B1
NCH 3
L A4422
R B1
R B5
Si(CH 3 ) 2
L A4363
H
R B2
NCH 3
L A4423
R B1
R A34
Si(CH 3 ) 2
L A4364
H
R B3
NCH 3
L A4424
R B1
R A52
Si(CH 3 ) 2
L A4365
H
R B4
NCH 3
L A4425
R B6
H
S
L A4366
H
R B5
NCH 3
L A4426
R B6
R B1
S
L A4367
H
R A34
NCH 3
L A4427
R B6
R B2
S
L A4368
H
R A52
NCH 3
L A4428
R B6
R B3
S
L A4369
H
H
C(CH 3 ) 2
L A4429
R B6
R B4
S
L A4370
H
R B1
C(CH 3 ) 2
L A4430
R B6
R B5
S
L A4371
H
R B2
C(CH 3 ) 2
L A4431
R B6
R A34
S
L A4372
H
R B3
C(CH 3 ) 2
L A4432
R B6
R A52
S
L A4373
H
R B4
C(CH 3 ) 2
L A4433
R B6
H
O
L A4374
H
R B5
C(CH 3 ) 2
L A4434
R B6
R B1
O
L A4375
H
R A34
C(CH 3 ) 2
L A4435
R B6
R B2
O
L A4376
H
R A52
C(CH 3 ) 2
L A4436
R B6
R B3
O
L A4377
H
H
Si(CH 3 ) 2
L A4437
R B6
R B4
O
L A4378
H
R B1
Si(CH 3 ) 2
L A4438
R B6
R B5
O
L A4379
H
R B2
Si(CH 3 ) 2
L A4439
R B6
R A34
O
L A4380
H
R B3
Si(CH 3 ) 2
L A4440
R B6
R A52
O
L A4381
H
R B4
Si(CH 3 ) 2
L A4441
R B6
H
NCH 3
L A4382
H
R B5
Si(CH 3 ) 2
L A4442
R B6
R B1
NCH 3
L A4383
H
R A34
Si(CH 3 ) 2
L A4443
R B6
R B2
NCH 3
L A4384
H
R A52
Si(CH 3 ) 2
L A4444
R B6
R B3
NCH 3
L A4385
R B1
H
S
L A4445
R B6
R B4
NCH 3
L A4386
R B1
R B1
S
L A4446
R B6
R B5
NCH 3
L A4387
R B1
R B2
S
L A4447
R B6
R A34
NCH 3
L A4388
R B1
R B3
S
L A4448
R B6
R A52
NCH 3
L A4389
R B1
R B4
S
L A4449
R B6
H
C(CH 3 ) 2
L A4390
R B1
R B5
S
L A4450
R B6
R B1
C(CH 3 ) 2
L A4391
R B1
R A34
S
L A4451
R B6
R B2
C(CH 3 ) 2
L A4392
R B1
R A52
S
L A4452
R B6
R B3
C(CH 3 ) 2
L A4393
R B1
H
O
L A4453
R B6
R B4
C(CH 3 ) 2
L A4394
R B1
R B1
O
L A4454
R B6
R B5
C(CH 3 ) 2
L A4395
R B1
R B2
O
L A4455
R B6
R A34
C(CH 3 ) 2
L A4396
R B1
R B3
O
L A4456
R B6
R A52
C(CH 3 ) 2
L A4397
R B1
R B4
O
L A4457
R B6
H
Si(CH 3 ) 2
L A4398
R B1
R B5
O
L A4458
R B6
R B1
Si(CH 3 ) 2
L A4399
R B1
R A34
O
L A4459
R B6
R B2
Si(CH 3 ) 2
L A4400
R B1
R A52
O
L A4460
R B6
R B3
Si(CH 3 ) 2
L A4401
R B1
H
NCH 3
L A4461
R B6
R B4
Si(CH 3 ) 2
L A4402
R B1
R B1
NCH 3
L A4462
R B6
R B5
Si(CH 3 ) 2
L A4403
R B1
R B2
NCH 3
L A4463
R B6
R A34
Si(CH 3 ) 2
L A4404
R B1
R B3
NCH 3
L A4464
R B6
R A52
Si(CH 3 ) 2
wherein L A4465 through L A4560 have a structure of Formula XXXI:
wherein R 4 , R 5 , Y, and Z are defined as provided below:
Ligand
R 5
R 4
Y
Z
Ligand
R 5
R 4
Y
Z
L A4465
H
H
S
S
L A4513
R B6
H
S
S
L A4466
H
R B1
S
S
L A4514
R B6
R B1
S
S
L A4467
H
R B3
S
S
L A4515
R B6
R B3
S
S
L A4468
H
R B4
S
S
L A4516
R B6
R B4
S
S
L A4469
H
R B7
S
S
L A4517
R B6
R B7
S
S
L A4470
H
R B10
S
S
L A4518
R B6
R B10
S
S
L A4471
H
R A3
S
S
L A4519
R B6
R A3
S
S
L A4472
H
R A34
S
S
L A4520
R B6
R A34
S
S
L A4473
H
H
S
O
L A4521
R B6
H
S
O
L A4474
H
R B1
S
O
L A4522
R B6
R B1
S
O
L A4475
H
R B3
S
O
L A4523
R B6
R B3
S
O
L A4476
H
R B4
S
O
L A4524
R B6
R B4
S
O
L A4477
H
R B7
S
O
L A4525
R B6
R B7
S
O
L A4478
H
R B10
S
O
L A4526
R B6
R B10
S
O
L A4479
H
R A3
S
O
L A4527
R B6
R A3
S
O
L A4480
H
R A34
S
O
L A4528
R B6
R A34
S
O
L A4481
H
H
S
NCH 3
L A4529
R B6
H
S
NCH 3
L A4482
H
R B1
S
NCH 3
L A4530
R B6
R B1
S
NCH 3
L A4483
H
R B3
S
NCH 3
L A4531
R B6
R B3
S
NCH 3
L A4484
H
R B4
S
NCH 3
L A4532
R B6
R B4
S
NCH 3
L A4485
H
R B7
S
NCH 3
L A4533
R B6
R B7
S
NCH 3
L A4486
H
R B10
S
NCH 3
L A4534
R B6
R B10
S
NCH 3
L A4487
H
R A3
S
NCH 3
L A4535
R B6
R A3
S
NCH 3
L A4488
H
R A34
S
NCH 3
L A4536
R B6
R A34
S
NCH 3
L A4489
H
H
O
S
L A4537
R B6
H
O
S
L A4490
H
R B1
O
S
L A4538
R B6
R B1
O
S
L A4491
H
R B3
O
S
L A4539
R B6
R B3
O
S
L A4492
H
R B4
O
S
L A4540
R B6
R B4
O
S
L A4493
H
R B7
O
S
L A4541
R B6
R B7
O
S
L A4494
H
R B10
O
S
L A4542
R B6
R B10
O
S
L A4495
H
R A3
O
S
L A4543
R B6
R A3
O
S
L A4496
H
R A34
O
S
L A4544
R B6
R A34
O
S
L A4497
H
H
O
O
L A4545
R B6
H
O
O
L A4498
H
R B1
O
O
L A4546
R B6
R B1
O
O
L A4499
H
R B3
O
O
L A4547
R B6
R B3
O
O
L A4500
H
R B4
O
O
L A4548
R B6
R B4
O
O
L A4501
H
R B7
O
O
L A4549
R B6
R B7
O
O
L A4502
H
R B10
O
O
L A4550
R B6
R B10
O
O
L A4503
H
R A3
O
O
L A4551
R B6
R A3
O
O
L A4504
H
R A34
O
O
L A4552
R B6
R A34
O
O
L A4505
H
H
O
NCH 3
L A4553
R B6
H
O
NCH 3
L A4506
H
R B1
O
NCH 3
L A4554
R B6
R B1
O
NCH 3
L A4507
H
R B3
O
NCH 3
L A4555
R B6
R B3
O
NCH 3
L A4508
H
R B4
O
NCH 3
L A4556
R B6
R B4
O
NCH 3
L A4509
H
R B7
O
NCH 3
L A4557
R B6
R B7
O
NCH 3
L A4510
H
R B10
O
NCH 3
L A4558
R B6
R B10
O
NCH 3
L A4511
H
R A3
O
NCH 3
L A4559
R B6
R A3
O
NCH 3
L A4512
H
R A34
O
NCH 3
L A4560
R B6
R A34
O
NCH 3
wherein L A4561 through L A4780 have a structure of Formula XXXII:
wherein R 1 , R 2 , R 3 , and Y are defined as provided below:
Ligand
R 1
R 3
R 2
Y
Ligand
R 1
R 3
R 2
Y
L A4561
H
H
H
O
L A4671
H
H
R B1
O
L A4562
R B1
R B1
H
O
L A4672
R B1
R B1
R B1
O
L A4563
R B3
R B3
H
O
L A4673
R B3
R B3
R B1
O
L A4564
R B4
R B4
H
O
L A4674
R B4
R B4
R B1
O
L A4565
R B7
R B7
H
O
L A4675
R B7
R B7
R B1
O
L A4566
R B10
R B10
H
O
L A4676
R B10
R B10
R B1
O
L A4567
R A3
R A3
H
O
L A4677
R A3
R A3
R B1
O
L A4568
R A34
R A34
H
O
L A4678
R A34
R A34
R B1
O
L A4569
R B1
H
H
O
L A4679
R B1
H
R B1
O
L A4570
R B3
H
H
O
L A4680
R B3
H
R B1
O
L A4571
R B4
H
H
O
L A4681
R B4
H
R B1
O
L A4572
R B7
H
H
O
L A4682
R B7
H
R B1
O
L A4573
R B10
H
H
O
L A4683
R B10
H
R B1
O
L A4574
R A3
H
H
O
L A4684
R A3
H
R B1
O
L A4575
R A34
H
H
O
L A4685
R A34
H
R B1
O
L A4576
H
R B1
H
O
L A4686
H
R B1
R B1
O
L A4577
H
R B3
H
O
L A4687
H
R B3
R B1
O
L A4578
H
R B4
H
O
L A4688
H
R B4
R B1
O
L A4579
H
R B7
H
O
L A4689
H
R B7
R B1
O
L A4580
H
R B10
H
O
L A4690
H
R B10
R B1
O
L A4581
H
R A3
H
O
L A4691
H
R A3
R B1
O
L A4582
H
R A34
H
O
L A4692
H
R A34
R B1
O
L A4583
H
H
H
S
L A4693
H
H
R B1
S
L A4584
R B1
R B1
H
S
L A4694
R B1
R B1
R B1
S
L A4585
R B3
R B3
H
S
L A4695
R B3
R B3
R B1
S
L A4586
R B4
R B4
H
S
L A4696
R B4
R B4
R B1
S
L A4587
R B7
R B7
H
S
L A4697
R B7
R B7
R B1
S
L A4588
R B10
R B10
H
S
L A4698
R B10
R B10
R B1
S
L A4589
R A3
R A3
H
S
L A4699
R A3
R A3
R B1
S
L A4590
R A34
R A34
H
S
L A4700
R A34
R A34
R B1
S
L A4591
R B1
H
H
S
L A4701
R B1
H
R B1
S
L A4592
R B3
H
H
S
L A4702
R B3
H
R B1
S
L A4593
R B4
H
H
S
L A4703
R B4
H
R B1
S
L A4594
R B7
H
H
S
L A4704
R B7
H
R B1
S
L A4595
R B10
H
H
S
L A4705
R B10
H
R B1
S
L A4596
R A3
H
H
S
L A4706
R A3
H
R B1
S
L A4597
R A34
H
H
S
L A4707
R A34
H
R B1
S
L A4598
H
R B1
H
S
L A4708
H
R B1
R B1
S
L A4599
H
R B3
H
S
L A4709
H
R B3
R B1
S
L A4600
H
R B4
H
S
L A4710
H
R B4
R B1
S
L A4601
H
R B7
H
S
L A4711
H
R B7
R B1
S
L A4602
H
R B10
H
S
L A4712
H
R B10
R B1
S
L A4603
H
R A3
H
S
L A4713
H
R A3
R B1
S
L A4604
H
R A34
H
S
L A4714
H
R A34
R B1
S
L A4605
H
H
H
NCH 3
L A4715
H
H
R B1
NCH 3
L A4606
R B1
R B1
H
NCH 3
L A4716
R B1
R B1
R B1
NCH 3
L A4607
R B3
R B3
H
NCH 3
L A4717
R B3
R B3
R B1
NCH 3
L A4608
R B4
R B4
H
NCH 3
L A4718
R B4
R B4
R B1
NCH 3
L A4609
R B7
R B7
H
NCH 3
L A4719
R B7
R B7
R B1
NCH 3
L A4610
R B10
R B10
H
NCH 3
L A4720
R B10
R B10
R B1
NCH 3
L A4611
R A3
R A3
H
NCH 3
L A4721
R A3
R A3
R B1
NCH 3
L A4612
R A34
R A34
H
NCH 3
L A4722
R A34
R A34
R B1
NCH 3
L A4613
R B1
H
H
NCH 3
L A4723
R B1
H
R B1
NCH 3
L A4614
R B3
H
H
NCH 3
L A4724
R B3
H
R B1
NCH 3
L A4615
R B4
H
H
NCH 3
L A4725
R B4
H
R B1
NCH 3
L A4616
R B7
H
H
NCH 3
L A4726
R B7
H
R B1
NCH 3
L A4617
R B10
H
H
NCH 3
L A4727
R B10
H
R B1
NCH 3
L A4618
R A3
H
H
NCH 3
L A4728
R A3
H
R B1
NCH 3
L A4619
R A34
H
H
NCH 3
L A4729
R A34
H
R B1
NCH 3
L A4620
H
R B1
H
NCH 3
L A4730
H
R B1
R B1
NCH 3
L A4621
H
R B3
H
NCH 3
L A4731
H
R B3
R B1
NCH 3
L A4622
H
R B4
H
NCH 3
L A4732
H
R B4
R B1
NCH 3
L A4623
H
R B7
H
NCH 3
L A4733
H
R B7
R B1
NCH 3
L A4624
H
R B10
H
NCH 3
L A4734
H
R B10
R B1
NCH 3
L A4625
H
R A3
H
NCH 3
L A4735
H
R A3
R B1
NCH 3
L A4626
H
R A34
H
NCH 3
L A4736
H
R A34
R B1
NCH 3
L A4627
H
H
H
C(CH 3 ) 2
L A4737
H
H
R B1
C(CH 3 ) 2
L A4628
R B1
R B1
H
C(CH 3 ) 2
L A4738
R B1
R B1
R B1
C(CH 3 ) 2
L A4629
R B3
R B3
H
C(CH 3 ) 2
L A4739
R B3
R B3
R B1
C(CH 3 ) 2
L A4630
R B4
R B4
H
C(CH 3 ) 2
L A4740
R B4
R B4
R B1
C(CH 3 ) 2
L A4631
R B7
R B7
H
C(CH 3 ) 2
L A4741
R B7
R B7
R B1
C(CH 3 ) 2
L A4632
R B10
R B10
H
C(CH 3 ) 2
L A4742
R B10
R B10
R B1
C(CH 3 ) 2
L A4633
R A3
R A3
H
C(CH 3 ) 2
L A4743
R A3
R A3
R B1
C(CH 3 ) 2
L A4634
R A34
R A34
H
C(CH 3 ) 2
L A4744
R A34
R A34
R B1
C(CH 3 ) 2
L A4635
R B1
H
H
C(CH 3 ) 2
L A4745
R B1
H
R B1
C(CH 3 ) 2
L A4636
R B3
H
H
C(CH 3 ) 2
L A4746
R B3
H
R B1
C(CH 3 ) 2
L A4637
R B4
H
H
C(CH 3 ) 2
L A4747
R B4
H
R B1
C(CH 3 ) 2
L A4638
R B7
H
H
C(CH 3 ) 2
L A4748
R B7
H
R B1
C(CH 3 ) 2
L A4639
R B10
H
H
C(CH 3 ) 2
L A4749
R B10
H
R B1
C(CH 3 ) 2
L A4640
R A3
H
H
C(CH 3 ) 2
L A4750
R A3
H
R B1
C(CH 3 ) 2
L A4641
R A34
H
H
C(CH 3 ) 2
L A4751
R A34
H
R B1
C(CH 3 ) 2
L A4642
H
R B1
H
C(CH 3 ) 2
L A4752
H
R B1
R B1
C(CH 3 ) 2
L A4643
H
R B3
H
C(CH 3 ) 2
L A4753
H
R B3
R B1
C(CH 3 ) 2
L A4644
H
R B4
H
C(CH 3 ) 2
L A4754
H
R B4
R B1
C(CH 3 ) 2
L A4645
H
R B7
H
C(CH 3 ) 2
L A4755
H
R B7
R B1
C(CH 3 ) 2
L A4646
H
R B10
H
C(CH 3 ) 2
L A4756
H
R B10
R B1
C(CH 3 ) 2
L A4647
H
R A3
H
C(CH 3 ) 2
L A4757
H
R A3
R B1
C(CH 3 ) 2
L A4648
H
R A34
H
C(CH 3 ) 2
L A4758
H
R A34
R B1
C(CH 3 ) 2
L A4649
H
H
H
Si(CH 3 ) 2
L A4759
H
H
R B1
Si(CH 3 ) 2
L A4650
R B1
R B1
H
Si(CH 3 ) 2
L A4760
R B1
R B1
R B1
Si(CH 3 ) 2
L A4651
R B3
R B3
H
Si(CH 3 ) 2
L A4761
R B3
R B3
R B1
Si(CH 3 ) 2
L A4652
R B4
R B4
H
Si(CH 3 ) 2
L A4762
R B4
R B4
R B1
Si(CH 3 ) 2
L A4653
R B7
R B7
H
Si(CH 3 ) 2
L A4763
R B7
R B7
R B1
Si(CH 3 ) 2
L A4654
R B10
R B10
H
Si(CH 3 ) 2
L A4764
R B10
R B10
R B1
Si(CH 3 ) 2
L A4655
R A3
R A3
H
Si(CH 3 ) 2
L A4765
R A3
R A3
R B1
Si(CH 3 ) 2
L A4656
R A34
R A34
H
Si(CH 3 ) 2
L A4766
R A34
R A34
R B1
Si(CH 3 ) 2
L A4657
R B1
H
H
Si(CH 3 ) 2
L A4767
R B1
H
R B1
Si(CH 3 ) 2
L A4658
R B3
H
H
Si(CH 3 ) 2
L A4768
R B3
H
R B1
Si(CH 3 ) 2
L A4659
R B4
H
H
Si(CH 3 ) 2
L A4769
R B4
H
R B1
Si(CH 3 ) 2
L A4660
R B7
H
H
Si(CH 3 ) 2
L A4770
R B7
H
R B1
Si(CH 3 ) 2
L A4661
R B10
H
H
Si(CH 3 ) 2
L A4771
R B10
H
R B1
Si(CH 3 ) 2
L A4662
R A3
H
H
Si(CH 3 ) 2
L A4772
R A3
H
R B1
Si(CH 3 ) 2
L A4663
R A34
H
H
Si(CH 3 ) 2
L A4773
R A34
H
R B1
Si(CH 3 ) 2
L A4664
H
R B1
H
Si(CH 3 ) 2
L A4774
H
R B1
R B1
Si(CH 3 ) 2
L A4665
H
R B3
H
Si(CH 3 ) 2
L A4775
H
R B3
R B1
Si(CH 3 ) 2
L A4666
H
R B4
H
Si(CH 3 ) 2
L A4776
H
R B4
R B1
Si(CH 3 ) 2
L A4667
H
R B7
H
Si(CH 3 ) 2
L A4777
H
R B7
R B1
Si(CH 3 ) 2
L A4668
H
R B10
H
Si(CH 3 ) 2
L A4778
H
R B10
R B1
Si(CH 3 ) 2
L A4669
H
R A3
H
Si(CH 3 ) 2
L A4779
H
R A3
R B1
Si(CH 3 ) 2
L A4670
H
R A34
H
Si(CH 3 ) 2
L A4780
H
R A34
R B1
Si(CH 3 ) 2
wherein R B1 to R B23 have the following structures:
and
wherein R A1 to R A51 have the following structures:
10. The compound of claim 9 , wherein the compound has a formula of M(L A ) x (L B ) y (L C ) z wherein L B and L C are each a bidentate ligand; and wherein x is 1, 2, or 3; y is 0, 1, or 2; z is 0, 1, or 2; and x+y+z is the oxidation state of the metal M.
11. The compound of claim 10 , wherein the compound has a formula selected from the group consisting of Ir(L A ) 3 , Ir(L A )(L B ) 2 , Ir(L A ) 2 (L B ), Ir(L A ) 2 (L C ), and Ir(L A )(L B )(L C ); and wherein L A , L B , and L C are different from each other.
12. The compound of claim 10 , wherein L B and L C are each independently selected from the group consisting of:
wherein each Y 1 to Y 13 is independently selected from the group consisting of carbon and nitrogen;
wherein X is selected from the group consisting of BR′, NR′, PR′, O, S, Se, C═O, S═O, SO 2 , CR 1 R 2 , SiR 1 R 2 , and GeR 1 R 2 ;
wherein R 1 and R 2 are optionally fused or joined to form a ring;
wherein each R a , R b , R c , and R d may represent from mono substitution to the possible maximum number of substitution, or no substitution;
wherein R′, R 1 , R 2 , R a , R b , R c , and R d are each independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof; and
wherein any two adjacent substituents of R a , R b , R c , and R d are optionally fused or joined to form a ring or form a multidentate ligand.
13. The compound of claim 11 , wherein the compound is selected from the group consisting of Compound Ax having the formula Ir(L Ai ) 3 , Compound By having the formula Ir(L Ai )(L Bk ) 2 ; and Compound Cz having the formula Ir(L Ai ) 2 (L Cj ); wherein x=i, y=468i+k−468, and z=1260i+j−1260; wherein i is an integer from 121 to 456, 577 to 2736, 2857 to 4104, or 4225 to 4780; wherein k is an integer from 1 to 468; wherein j is an integer from 1 to 1260;
wherein L Bk has the following structures:
and
wherein L Cj is selected from the group consisting of the following structures:
L C1 through L C1260 are based on a structure of Formula X,
in which R 1 , R 2 , and R 3 are defined as:
Ligand
R 1
R 2
R 3
Ligand
R 1
R 2
R 3
Ligand
R 1
R 2
R 3
L C1
R D1
R D1
H
L C421
R D26
R D21
H
L C841
R D7
R D14
R D1
L C2
R D2
R D2
H
L C422
R D26
R D23
H
L C842
R D7
R D15
R D1
L C3
R D3
R D3
H
L C423
R D26
R D24
H
L C843
R D7
R D16
R D1
L C4
R D4
R D4
H
L C424
R D26
R D25
H
L C844
R D7
R D17
R D1
L C5
R D5
R D5
H
L C425
R D26
R D27
H
L C845
R D7
R D18
R D1
L C6
R D6
R D6
H
L C426
R D26
R D28
H
L C846
R D7
R D19
R D1
L C7
R D7
R D7
H
L C427
R D26
R D29
H
L C847
R D7
R D20
R D1
L C8
R D8
R D8
H
L C428
R D26
R D30
H
L C848
R D7
R D21
R D1
L C9
R D9
R D9
H
L C429
R D26
R D31
H
L C849
R D7
R D22
R D1
L C10
R D10
R D10
H
L C430
R D26
R D32
H
L C850
R D7
R D23
R D1
L C11
R D11
R D11
H
L C431
R D26
R D33
H
L C851
R D7
R D24
R D1
L C12
R D12
R D12
H
L C432
R D26
R D34
H
L C852
R D7
R D25
R D1
L C13
R D13
R D13
H
L C433
R D26
R D35
H
L C853
R D7
R D26
R D1
L C14
R D14
R D14
H
L C434
R D26
R D40
H
L C854
R D7
R D27
R D1
L C15
R D15
R D15
H
L C435
R D26
R D41
H
L C855
R D7
R D28
R D1
L C16
R D16
R D16
H
L C436
R D26
R D42
H
L C856
R D7
R D29
R D1
L C17
R D17
R D17
H
L C437
R D26
R D64
H
L C857
R D7
R D30
R D1
L C18
R D18
R D18
H
L C438
R D26
R D66
H
L C858
R D7
R D31
R D1
L C19
R D19
R D19
H
L C439
R D26
R D68
H
L C859
R D7
R D32
R D1
L C20
R D20
R D20
H
L C440
R D26
R D76
H
L C860
R D7
R D33
R D1
L C21
R D21
R D21
H
L C441
R D35
R D5
H
L C861
R D7
R D34
R D1
L C22
R D22
R D22
H
L C442
R D35
R D6
H
L C862
R D7
R D35
R D1
L C23
R D23
R D23
H
L C443
R D35
R D9
H
L C863
R D7
R D40
R D1
L C24
R D24
R D24
H
L C444
R D35
R D10
H
L C864
R D7
R D41
R D1
L C25
R D25
R D25
H
L C445
R D35
R D12
H
L C865
R D7
R D42
R D1
L C26
R D26
R D26
H
L C446
R D35
R D15
H
L C866
R D7
R D64
R D1
L C27
R D27
R D27
H
L C447
R D35
R D16
H
L C867
R D7
R D66
R D1
L C28
R D28
R D28
H
L C448
R D35
R D17
H
L C868
R D7
R D68
R D1
L C29
R D29
R D29
H
L C449
R D35
R D18
H
L C869
R D7
R D76
R D1
L C30
R D30
R D30
H
L C450
R D35
R D19
H
L C870
R D8
R D5
R D1
L C31
R D31
R D31
H
L C451
R D35
R D20
H
L C871
R D8
R D6
R D1
L C32
R D32
R D32
H
L C452
R D35
R D21
H
L C872
R D8
R D9
R D1
L C33
R D33
R D33
H
L C453
R D35
R D23
H
L C873
R D8
R D10
R D1
L C34
R D34
R D34
H
L C454
R D35
R D24
H
L C874
R D8
R D11
R D1
L C35
R D35
R D35
H
L C455
R D35
R D25
H
L C875
R D8
R D12
R D1
L C36
R D40
R D40
H
L C456
R D35
R D27
H
L C876
R D8
R D13
R D1
L C37
R D41
R D41
H
L C457
R D35
R D28
H
L C877
R D8
R D14
R D1
L C38
R D42
R D42
H
L C458
R D35
R D29
H
L C878
R D8
R D15
R D1
L C39
R D64
R D64
H
L C459
R D35
R D30
H
L C879
R D8
R D16
R D1
L C40
R D66
R D66
H
L C460
R D35
R D31
H
L C880
R D8
R D17
R D1
L C41
R D68
R D68
H
L C461
R D35
R D32
H
L C881
R D8
R D18
R D1
L C42
R D76
R D76
H
L C462
R D35
R D33
H
L C882
R D8
R D19
R D1
L C43
R D1
R D2
H
L C463
R D35
R D34
H
L C883
R D8
R D20
R D1
L C44
R D1
R D3
H
L C464
R D35
R D40
H
L C884
R D8
R D21
R D1
L C45
R D1
R D4
H
L C465
R D35
R D41
H
L C885
R D8
R D22
R D1
L C46
R D1
R D5
H
L C466
R D35
R D42
H
L C886
R D8
R D23
R D1
L C47
R D1
R D6
H
L C467
R D35
R D64
H
L C887
R D8
R D24
R D1
L C48
R D1
R D7
H
L C468
R D35
R D66
H
L C888
R D8
R D25
R D1
L C49
R D1
R D8
H
L C469
R D35
R D68
H
L C889
R D8
R D26
R D1
L C50
R D1
R D9
H
L C470
R D35
R D76
H
L C890
R D8
R D27
R D1
L C51
R D1
R D10
H
L C471
R D40
R D5
H
L C891
R D8
R D28
R D1
L C52
R D1
R D11
H
L C472
R D40
R D6
H
L C892
R D8
R D29
R D1
L C53
R D1
R D12
H
L C473
R D40
R D9
H
L C893
R D8
R D30
R D1
L C54
R D1
R D13
H
L C474
R D40
R D10
H
L C894
R D8
R D31
R D1
L C55
R D1
R D14
H
L C475
R D40
R D12
H
L C895
R D8
R D32
R D1
L C56
R D1
R D15
H
L C476
R D40
R D15
H
L C896
R D8
R D33
R D1
L C57
R D1
R D16
H
L C477
R D40
R D16
H
L C897
R D8
R D34
R D1
L C58
R D1
R D17
H
L C478
R D40
R D17
H
L C898
R D8
R D35
R D1
L C59
R D1
R D18
H
L C479
R D40
R D18
H
L C899
R D8
R D40
R D1
L C60
R D1
R D19
H
L C480
R D40
R D19
H
L C900
R D8
R D41
R D1
L C61
R D1
R D20
H
L C481
R D40
R D20
H
L C901
R D8
R D42
R D1
L C62
R D1
R D21
H
L C482
R D40
R D21
H
L C902
R D8
R D64
R D1
L C63
R D1
R D22
H
L C483
R D40
R D23
H
L C903
R D8
R D66
R D1
L C64
R D1
R D23
H
L C484
R D40
R D24
H
L C904
R D8
R D68
R D1
L C65
R D1
R D24
H
L C485
R D40
R D25
H
L C905
R D8
R D76
R D1
L C66
R D1
R D25
H
L C486
R D40
R D27
H
L C906
R D11
R D5
R D1
L C67
R D1
R D26
H
L C487
R D40
R D28
H
L C907
R D11
R D6
R D1
L C68
R D1
R D27
H
L C488
R D40
R D29
H
L C908
R D11
R D9
R D1
L C69
R D1
R D28
H
L C489
R D40
R D30
H
L C909
R D11
R D10
R D1
L C70
R D1
R D29
H
L C490
R D40
R D31
H
L C910
R D11
R D12
R D1
L C71
R D1
R D30
H
L C491
R D40
R D32
H
L C911
R D11
R D13
R D1
L C72
R D1
R D31
H
L C492
R D40
R D33
H
L C912
R D11
R D14
R D1
L C73
R D1
R D32
H
L C493
R D40
R D34
H
L C913
R D11
R D15
R D1
L C74
R D1
R D33
H
L C494
R D40
R D41
H
L C914
R D11
R D16
R D1
L C75
R D1
R D34
H
L C495
R D40
R D42
H
L C915
R D11
R D17
R D1
L C76
R D1
R D35
H
L C496
R D40
R D64
H
L C916
R D11
R D18
R D1
L C77
R D1
R D40
H
L C497
R D40
R D66
H
L C917
R D11
R D19
R D1
L C78
R D1
R D41
H
L C498
R D40
R D68
H
L C918
R D11
R D20
R D1
L C79
R D1
R D42
H
L C499
R D40
R D76
H
L C919
R D11
R D21
R D1
L C80
R D1
R D64
H
L C500
R D41
R D5
H
L C920
R D11
R D22
R D1
L C81
R D1
R D66
H
L C501
R D41
R D6
H
L C921
R D11
R D23
R D1
L C82
R D1
R D68
H
L C502
R D41
R D9
H
L C922
R D11
R D24
R D1
L C83
R D1
R D76
H
L C503
R D41
R D10
H
L C923
R D11
R D25
R D1
L C84
R D2
R D1
H
L C504
R D41
R D12
H
L C924
R D11
R D26
R D1
L C85
R D2
R D3
H
L C505
R D41
R D15
H
L C925
R D11
R D27
R D1
L C86
R D2
R D4
H
L C506
R D41
R D16
H
L C926
R D11
R D28
R D1
L C87
R D2
R D5
H
L C507
R D41
R D17
H
L C927
R D11
R D29
R D1
L C88
R D2
R D6
H
L C508
R D41
R D18
H
L C928
R D11
R D30
R D1
L C89
R D2
R D7
H
L C509
R D41
R D19
H
L C929
R D11
R D31
R D1
L C90
R D2
R D8
H
L C510
R D41
R D20
H
L C930
R D11
R D32
R D1
L C91
R D2
R D9
H
L C511
R D41
R D21
H
L C931
R D11
R D33
R D1
L C92
R D2
R D10
H
L C512
R D41
R D23
H
L C932
R D11
R D34
R D1
L C93
R D2
R D11
H
L C513
R D41
R D24
H
L C933
R D11
R D35
R D1
L C94
R D2
R D12
H
L C514
R D41
R D25
H
L C934
R D11
R D40
R D1
L C95
R D2
R D13
H
L C515
R D41
R D27
H
L C935
R D11
R D41
R D1
L C96
R D2
R D14
H
L C516
R D41
R D28
H
L C936
R D11
R D42
R D1
L C97
R D2
R D15
H
L C517
R D41
R D29
H
L C937
R D11
R D64
R D1
L C98
R D2
R D16
H
L C518
R D41
R D30
H
L C938
R D11
R D66
R D1
L C99
R D2
R D17
H
L C519
R D41
R D31
H
L C939
R D11
R D68
R D1
L C100
R D2
R D18
H
L C520
R D41
R D32
H
L C940
R D11
R D76
R D1
L C101
R D2
R D19
H
L C521
R D41
R D33
H
L C941
R D13
R D5
R D1
L C102
R D2
R D20
H
L C522
R D41
R D34
H
L C942
R D13
R D6
R D1
L C103
R D2
R D21
H
L C523
R D41
R D42
H
L C943
R D13
R D9
R D1
L C104
R D2
R D22
H
L C524
R D41
R D64
H
L C944
R D13
R D10
R D1
L C105
R D2
R D23
H
L C525
R D41
R D66
H
L C945
R D13
R D12
R D1
L C106
R D2
R D24
H
L C526
R D41
R D68
H
L C946
R D13
R D14
R D1
L C107
R D2
R D25
H
L C527
R D41
R D76
H
L C947
R D13
R D15
R D1
L C108
R D2
R D26
H
L C528
R D64
R D5
H
L C948
R D13
R D16
R D1
L C109
R D2
R D27
H
L C529
R D64
R D6
H
L C949
R D13
R D17
R D1
L C110
R D2
R D28
H
L C530
R D64
R D9
H
L C950
R D13
R D18
R D1
L C111
R D2
R D29
H
L C531
R D64
R D10
H
L C951
R D13
R D19
R D1
L C112
R D2
R D30
H
L C532
R D64
R D12
H
L C952
R D13
R D20
R D1
L C113
R D2
R D31
H
L C533
R D64
R D15
H
L C953
R D13
R D21
R D1
L C114
R D2
R D32
H
L C534
R D64
R D16
H
L C954
R D13
R D22
R D1
L C115
R D2
R D33
H
L C535
R D64
R D17
H
L C955
R D13
R D23
R D1
L C116
R D2
R D34
H
L C536
R D64
R D18
H
L C956
R D13
R D24
R D1
L C117
R D2
R D35
H
L C537
R D64
R D19
H
L C957
R D13
R D25
R D1
L C118
R D2
R D40
H
L C538
R D64
R D20
H
L C958
R D13
R D26
R D1
L C119
R D2
R D41
H
L C539
R D64
R D21
H
L C959
R D13
R D27
R D1
L C120
R D2
R D42
H
L C540
R D64
R D23
H
L C960
R D13
R D28
R D1
L C121
R D2
R D64
H
L C541
R D64
R D24
H
L C961
R D13
R D29
R D1
L C122
R D2
R D66
H
L C542
R D64
R D25
H
L C962
R D13
R D30
R D1
L C123
R D2
R D68
H
L C543
R D64
R D27
H
L C963
R D13
R D31
R D1
L C124
R D2
R D76
H
L C544
R D64
R D28
H
L C964
R D13
R D32
R D1
L C125
R D3
R D4
H
L C545
R D64
R D29
H
L C965
R D13
R D33
R D1
L C126
R D3
R D5
H
L C546
R D64
R D30
H
L C966
R D13
R D34
R D1
L C127
R D3
R D6
H
L C547
R D64
R D31
H
L C967
R D13
R D35
R D1
L C128
R D3
R D7
H
L C548
R D64
R D32
H
L C968
R D13
R D40
R D1
L C129
R D3
R D8
H
L C549
R D64
R D33
H
L C969
R D13
R D41
R D1
L C130
R D3
R D9
H
L C550
R D64
R D34
H
L C970
R D13
R D42
R D1
L C131
R D3
R D10
H
L C551
R D64
R D42
H
L C971
R D13
R D64
R D1
L C132
R D3
R D11
H
L C552
R D64
R D64
H
L C972
R D13
R D66
R D1
L C133
R D3
R D12
H
L C553
R D64
R D66
H
L C973
R D13
R D68
R D1
L C134
R D3
R D13
H
L C554
R D64
R D68
H
L C974
R D13
R D76
R D1
L C135
R D3
R D14
H
L C555
R D64
R D76
H
L C975
R D14
R D5
R D1
L C136
R D3
R D15
H
L C556
R D66
R D5
H
L C976
R D14
R D6
R D1
L C137
R D3
R D16
H
L C557
R D66
R D6
H
L C977
R D14
R D9
R D1
L C138
R D3
R D17
H
L C558
R D66
R D9
H
L C978
R D14
R D10
R D1
L C139
R D3
R D18
H
L C559
R D66
R D10
H
L C979
R D14
R D12
R D1
L C140
R D3
R D19
H
L C560
R D66
R D12
H
L C980
R D14
R D15
R D1
L C141
R D3
R D20
H
L C561
R D66
R D15
H
L C981
R D14
R D16
R D1
L C142
R D3
R D21
H
L C562
R D66
R D16
H
L C982
R D14
R D17
R D1
L C143
R D3
R D22
H
L C563
R D66
R D17
H
L C983
R D14
R D18
R D1
L C144
R D3
R D23
H
L C564
R D66
R D18
H
L C984
R D14
R D19
R D1
L C145
R D3
R D24
H
L C565
R D66
R D19
H
L C985
R D14
R D20
R D1
L C146
R D3
R D25
H
L C566
R D66
R D20
H
L C986
R D14
R D21
R D1
L C147
R D3
R D26
H
L C567
R D66
R D21
H
L C987
R D14
R D22
R D1
L C148
R D3
R D27
H
L C568
R D66
R D23
H
L C988
R D14
R D23
R D1
L C149
R D3
R D28
H
L C569
R D66
R D24
H
L C989
R D14
R D24
R D1
L C150
R D3
R D29
H
L C570
R D66
R D25
H
L C990
R D14
R D25
R D1
L C151
R D3
R D30
H
L C571
R D66
R D27
H
L C991
R D14
R D26
R D1
L C152
R D3
R D31
H
L C572
R D66
R D28
H
L C992
R D14
R D27
R D1
L C153
R D3
R D32
H
L C573
R D66
R D29
H
L C993
R D14
R D28
R D1
L C154
R D3
R D33
H
L C574
R D66
R D30
H
L C994
R D14
R D29
R D1
L C155
R D3
R D34
H
L C575
R D66
R D31
H
L C995
R D14
R D30
R D1
L C156
R D3
R D35
H
L C576
R D66
R D32
H
L C996
R D14
R D31
R D1
L C157
R D3
R D40
H
L C577
R D66
R D33
H
L C997
R D14
R D32
R D1
L C158
R D3
R D41
H
L C578
R D66
R D34
H
L C998
R D14
R D33
R D1
L C159
R D3
R D42
H
L C579
R D66
R D42
H
L C999
R D14
R D34
R D1
L C160
R D3
R D64
H
L C580
R D66
R D64
H
L C1000
R D14
R D35
R D1
L C161
R D3
R D66
H
L C581
R D66
R D66
H
L C1001
R D14
R D40
R D1
L C162
R D3
R D68
H
L C582
R D68
R D5
H
L C1002
R D14
R D41
R D1
L C163
R D3
R D76
H
L C583
R D68
R D6
H
L C1003
R D14
R D42
R D1
L C164
R D4
R D5
H
L C584
R D68
R D9
H
L C1004
R D14
R D64
R D1
L C165
R D4
R D6
H
L C585
R D68
R D10
H
L C1005
R D14
R D66
R D1
L C166
R D4
R D7
H
L C586
R D68
R D12
H
L C1006
R D14
R D68
R D1
L C167
R D4
R D8
H
L C587
R D68
R D15
H
L C1007
R D14
R D76
R D1
L C168
R D4
R D9
H
L C588
R D68
R D16
H
L C1008
R D22
R D5
R D1
L C169
R D4
R D10
H
L C589
R D68
R D17
H
L C1009
R D22
R D6
R D1
L C170
R D4
R D11
H
L C590
R D68
R D18
H
L C1010
R D22
R D9
R D1
L C171
R D4
R D12
H
L C591
R D68
R D19
H
L C1011
R D22
R D10
R D1
L C172
R D4
R D13
H
L C592
R D68
R D20
H
L C1012
R D22
R D12
R D1
L C173
R D4
R D14
H
L C593
R D68
R D21
H
L C1013
R D22
R D15
R D1
L C174
R D4
R D15
H
L C594
R D68
R D23
H
L C1014
R D22
R D16
R D1
L C175
R D4
R D16
H
L C595
R D68
R D24
H
L C1015
R D22
R D17
R D1
L C176
R D4
R D17
H
L C596
R D68
R D25
H
L C1016
R D22
R D18
R D1
L C177
R D4
R D18
H
L C597
R D68
R D27
H
L C1017
R D22
R D19
R D1
L C178
R D4
R D19
H
L C598
R D68
R D28
H
L C1018
R D22
R D20
R D1
L C179
R D4
R D20
H
L C599
R D68
R D29
H
L C1019
R D22
R D21
R D1
L C180
R D4
R D21
H
L C600
R D68
R D30
H
L C1020
R D22
R D23
R D1
L C181
R D4
R D22
H
L C601
R D68
R D31
H
L C1021
R D22
R D24
R D1
L C182
R D4
R D23
H
L C602
R D68
R D32
H
L C1022
R D22
R D25
R D1
L C183
R D4
R D24
H
L C603
R D68
R D33
H
L C1023
R D22
R D26
R D1
L C184
R D4
R D25
H
L C604
R D68
R D34
H
L C1024
R D22
R D27
R D1
L C185
R D4
R D26
H
L C605
R D68
R D42
H
L C1025
R D22
R D28
R D1
L C186
R D4
R D27
H
L C606
R D68
R D76
H
L C1026
R D22
R D29
R D1
L C187
R D4
R D28
H
L C607
R D68
R D5
H
L C1027
R D22
R D30
R D1
L C188
R D4
R D29
H
L C608
R D76
R D6
H
L C1028
R D22
R D31
R D1
L C189
R D4
R D30
H
L C609
R D76
R D9
H
L C1029
R D22
R D32
R D1
L C190
R D4
R D31
H
L C610
R D76
R D10
H
L C1030
R D22
R D33
R D1
L C191
R D4
R D32
H
L C611
R D76
R D12
H
L C1031
R D22
R D34
R D1
L C192
R D4
R D33
H
L C612
R D76
R D15
H
L C1032
R D22
R D35
R D1
L C193
R D4
R D34
H
L C613
R D76
R D16
H
L C1033
R D22
R D40
R D1
L C194
R D4
R D35
H
L C614
R D76
R D17
H
L C1034
R D22
R D41
R D1
L C195
R D4
R D40
H
L C615
R D76
R D18
H
L C1035
R D22
R D42
R D1
L C196
R D4
R D41
H
L C616
R D76
R D19
H
L C1036
R D22
R D64
R D1
L C197
R D4
R D42
H
L C617
R D76
R D20
H
L C1037
R D22
R D66
R D1
L C198
R D4
R D64
H
L C618
R D76
R D21
H
L C1038
R D22
R D68
R D1
L C199
R D4
R D66
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L C619
R D76
R D23
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L C1039
R D22
R D76
R D1
L C200
R D4
R D68
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L C620
R D76
R D24
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L C1040
R D26
R D5
R D1
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R D4
R D76
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L C621
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R D25
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L C1041
R D26
R D6
R D1
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R D1
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R D76
R D27
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R D26
R D9
R D1
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R D5
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R D28
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R D26
R D10
R D1
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R D7
R D6
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L C624
R D76
R D29
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L C1044
R D26
R D12
R D1
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R D7
R D8
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L C625
R D76
R D30
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L C1045
R D26
R D15
R D1
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R D7
R D9
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L C626
R D76
R D31
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L C1046
R D26
R D16
R D1
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R D7
R D10
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L C627
R D76
R D32
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L C1047
R D26
R D17
R D1
L C208
R D7
R D11
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L C628
R D76
R D33
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L C1048
R D26
R D18
R D1
L C209
R D7
R D12
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L C629
R D76
R D34
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L C1049
R D26
R D19
R D1
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R D7
R D13
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L C630
R D76
R D42
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L C1050
R D26
R D20
R D1
L C211
R D7
R D14
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L C631
R D1
R D1
R D1
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R D26
R D21
R D1
L C212
R D7
R D15
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L C632
R D2
R D2
R D1
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R D26
R D23
R D1
L C213
R D7
R D16
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R D3
R D3
R D1
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R D26
R D24
R D1
L C214
R D7
R D17
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R D4
R D4
R D1
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R D26
R D25
R D1
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R D7
R D18
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R D5
R D5
R D1
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R D26
R D27
R D1
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R D7
R D19
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R D6
R D6
R D1
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R D26
R D28
R D1
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R D7
R D20
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R D7
R D7
R D1
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R D26
R D29
R D1
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R D7
R D21
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R D8
R D8
R D1
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R D26
R D30
R D1
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R D7
R D22
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R D9
R D9
R D1
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R D26
R D31
R D1
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R D23
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R D10
R D10
R D1
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R D26
R D32
R D1
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R D7
R D24
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R D11
R D11
R D1
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R D26
R D33
R D1
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R D7
R D25
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R D12
R D12
R D1
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R D26
R D34
R D1
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R D7
R D26
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R D13
R D13
R D1
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R D26
R D35
R D1
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R D27
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R D14
R D14
R D1
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R D26
R D40
R D1
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R D28
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R D15
R D15
R D1
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R D26
R D41
R D1
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R D7
R D29
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R D16
R D16
R D1
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R D26
R D42
R D1
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R D7
R D30
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R D17
R D17
R D1
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R D26
R D64
R D1
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R D31
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R D18
R D18
R D1
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R D26
R D66
R D1
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R D7
R D32
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R D19
R D19
R D1
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R D26
R D68
R D1
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R D7
R D33
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R D20
R D20
R D1
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R D26
R D76
R D1
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R D7
R D34
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R D21
R D21
R D1
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R D35
R D5
R D1
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R D7
R D35
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L C652
R D22
R D22
R D1
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R D35
R D6
R D1
L C233
R D7
R D40
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L C653
R D23
R D23
R D1
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R D35
R D9
R D1
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R D7
R D41
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L C654
R D24
R D24
R D1
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R D35
R D10
R D1
L C235
R D7
R D42
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L C655
R D25
R D25
R D1
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R D35
R D12
R D1
L C236
R D7
R D64
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L C656
R D26
R D26
R D1
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R D35
R D15
R D1
L C237
R D7
R D66
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L C657
R D27
R D27
R D1
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R D35
R D16
R D1
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R D7
R D68
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L C658
R D28
R D28
R D1
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R D35
R D17
R D1
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R D7
R D76
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R D29
R D29
R D1
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R D35
R D18
R D1
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R D8
R D5
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R D30
R D30
R D1
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R D35
R D19
R D1
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R D8
R D6
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R D31
R D31
R D1
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R D35
R D20
R D1
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R D8
R D9
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R D32
R D32
R D1
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R D35
R D21
R D1
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R D8
R D10
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R D33
R D33
R D1
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R D35
R D23
R D1
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R D8
R D11
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R D34
R D34
R D1
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R D35
R D24
R D1
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R D8
R D12
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L C665
R D35
R D35
R D1
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R D35
R D25
R D1
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R D8
R D13
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R D40
R D40
R D1
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R D35
R D27
R D1
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R D8
R D14
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L C667
R D41
R D41
R D1
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R D35
R D28
R D1
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R D8
R D15
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L C668
R D42
R D42
R D1
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R D35
R D29
R D1
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R D8
R D16
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L C669
R D64
R D64
R D1
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R D35
R D30
R D1
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R D8
R D17
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L C670
R D66
R D66
R D1
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R D35
R D31
R D1
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R D8
R D18
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R D68
R D68
R D1
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R D35
R D32
R D1
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R D8
R D19
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R D76
R D76
R D1
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R D35
R D33
R D1
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R D8
R D20
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R D1
R D2
R D1
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R D35
R D34
R D1
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R D8
R D21
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R D1
R D3
R D1
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R D35
R D40
R D1
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R D8
R D22
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R D1
R D4
R D1
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R D35
R D41
R D1
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R D8
R D23
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R D1
R D5
R D1
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R D35
R D42
R D1
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R D8
R D24
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R D1
R D6
R D1
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R D35
R D64
R D1
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R D8
R D25
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R D7
R D1
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R D35
R D66
R D1
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R D8
R D26
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R D8
R D1
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R D35
R D68
R D1
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R D8
R D27
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R D1
R D9
R D1
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R D35
R D76
R D1
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R D8
R D28
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R D1
R D10
R D1
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R D40
R D5
R D1
L C262
R D8
R D29
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R D1
R D11
R D1
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R D40
R D6
R D1
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R D8
R D30
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R D1
R D12
R D1
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R D40
R D9
R D1
L C264
R D8
R D31
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R D1
R D13
R D1
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R D40
R D10
R D1
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R D8
R D32
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R D1
R D14
R D1
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R D40
R D12
R D1
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R D8
R D33
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R D1
R D15
R D1
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R D40
R D15
R D1
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R D8
R D34
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R D1
R D16
R D1
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R D40
R D16
R D1
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R D8
R D35
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L C688
R D1
R D17
R D1
L C1108
R D40
R D17
R D1
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R D8
R D40
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R D1
R D18
R D1
L C1109
R D40
R D18
R D1
L C270
R D8
R D41
H
L C690
R D1
R D19
R D1
L C1110
R D40
R D19
R D1
L C271
R D8
R D42
H
L C691
R D1
R D20
R D1
L C1111
R D40
R D20
R D1
L C272
R D8
R D64
H
L C692
R D1
R D21
R D1
L C1112
R D40
R D21
R D1
L C273
R D8
R D66
H
L C693
R D1
R D22
R D1
L C1113
R D40
R D23
R D1
L C274
R D8
R D68
H
L C694
R D1
R D23
R D1
L C1114
R D40
R D24
R D1
L C275
R D8
R D76
H
L C695
R D1
R D24
R D1
L C1115
R D40
R D25
R D1
L C276
R D11
R D5
H
L C696
R D1
R D25
R D1
L C1116
R D40
R D27
R D1
L C277
R D11
R D6
H
L C697
R D1
R D26
R D1
L C1117
R D40
R D28
R D1
L C278
R D11
R D9
H
L C698
R D1
R D27
R D1
L C1118
R D40
R D29
R D1
L C279
R D11
R D10
H
L C699
R D1
R D28
R D1
L C1119
R D40
R D30
R D1
L C280
R D11
R D12
H
L C700
R D1
R D29
R D1
L C1120
R D40
R D31
R D1
L C281
R D11
R D13
H
L C701
R D1
R D30
R D1
L C1121
R D40
R D32
R D1
L C282
R D11
R D14
H
L C702
R D1
R D31
R D1
L C1122
R D40
R D33
R D1
L C283
R D11
R D15
H
L C703
R D1
R D32
R D1
L C1123
R D40
R D34
R D1
L C284
R D11
R D16
H
L C704
R D1
R D33
R D1
L C1124
R D40
R D41
R D1
L C285
R D11
R D17
H
L C705
R D1
R D34
R D1
L C1125
R D40
R D42
R D1
L C286
R D11
R D18
H
L C706
R D1
R D35
R D1
L C1126
R D40
R D64
R D1
L C287
R D11
R D19
H
L C707
R D1
R D40
R D1
L C1127
R D40
R D66
R D1
L C288
R D11
R D20
H
L C708
R D1
R D41
R D1
L C1128
R D40
R D68
R D1
L C289
R D11
R D21
H
L C709
R D1
R D42
R D1
L C1129
R D40
R D76
R D1
L C290
R D11
R D22
H
L C710
R D1
R D64
R D1
L C1130
R D41
R D5
R D1
L C291
R D11
R D23
H
L C711
R D1
R D66
R D1
L C1131
R D41
R D6
R D1
L C292
R D11
R D24
H
L C712
R D1
R D68
R D1
L C1132
R D41
R D9
R D1
L C293
R D11
R D25
H
L C713
R D1
R D76
R D1
L C1133
R D41
R D10
R D1
L C294
R D11
R D26
H
L C714
R D2
R D1
R D1
L C1134
R D41
R D12
R D1
L C295
R D11
R D27
H
L C715
R D2
R D3
R D1
L C1135
R D41
R D15
R D1
L C296
R D11
R D28
H
L C716
R D2
R D4
R D1
L C1136
R D41
R D16
R D1
L C297
R D11
R D29
H
L C717
R D2
R D5
R D1
L C1137
R D41
R D17
R D1
L C298
R D11
R D30
H
L C718
R D2
R D6
R D1
L C1138
R D41
R D18
R D1
L C299
R D11
R D31
H
L C719
R D2
R D7
R D1
L C1139
R D41
R D19
R D1
L C300
R D11
R D32
H
L C720
R D2
R D8
R D1
L C1140
R D41
R D20
R D1
L C301
R D11
R D33
H
L C721
R D2
R D9
R D1
L C1141
R D41
R D21
R D1
L C302
R D11
R D34
H
L C722
R D2
R D10
R D1
L C1142
R D41
R D23
R D1
L C303
R D11
R D35
H
L C723
R D2
R D11
R D1
L C1143
R D41
R D24
R D1
L C304
R D11
R D40
H
L C724
R D2
R D12
R D1
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R D41
R D25
R D1
L C305
R D11
R D41
H
L C725
R D2
R D13
R D1
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R D41
R D27
R D1
L C306
R D11
R D42
H
L C726
R D2
R D14
R D1
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R D41
R D28
R D1
L C307
R D11
R D64
H
L C727
R D2
R D15
R D1
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R D41
R D29
R D1
L C308
R D11
R D66
H
L C728
R D2
R D16
R D1
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R D41
R D30
R D1
L C309
R D11
R D68
H
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R D2
R D17
R D1
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R D41
R D31
R D1
L C310
R D11
R D76
H
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R D2
R D18
R D1
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R D41
R D32
R D1
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R D13
R D5
H
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R D2
R D19
R D1
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R D33
R D1
L C312
R D13
R D6
H
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R D2
R D20
R D1
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R D34
R D1
L C313
R D13
R D9
H
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R D2
R D21
R D1
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R D41
R D42
R D1
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R D13
R D10
H
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R D2
R D22
R D1
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R D41
R D64
R D1
L C315
R D13
R D12
H
L C735
R D2
R D23
R D1
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R D41
R D66
R D1
L C316
R D13
R D14
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R D2
R D24
R D1
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R D41
R D68
R D1
L C317
R D13
R D15
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L C737
R D2
R D25
R D1
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R D41
R D76
R D1
L C318
R D13
R D16
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R D26
R D1
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R D64
R D5
R D1
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R D13
R D17
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R D27
R D1
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R D64
R D6
R D1
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R D13
R D18
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R D2
R D28
R D1
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R D64
R D9
R D1
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R D13
R D19
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R D29
R D1
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R D64
R D10
R D1
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R D20
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R D30
R D1
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R D64
R D12
R D1
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R D21
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R D31
R D1
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R D64
R D15
R D1
L C324
R D13
R D22
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R D2
R D32
R D1
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R D64
R D16
R D1
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R D13
R D23
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R D2
R D33
R D1
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R D64
R D17
R D1
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R D13
R D24
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R D2
R D34
R D1
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R D64
R D18
R D1
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R D13
R D25
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R D2
R D35
R D1
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R D64
R D19
R D1
L C328
R D13
R D26
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R D2
R D40
R D1
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R D64
R D20
R D1
L C329
R D13
R D27
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R D2
R D41
R D1
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R D64
R D21
R D1
L C330
R D13
R D28
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L C750
R D2
R D42
R D1
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R D64
R D23
R D1
L C331
R D13
R D29
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R D2
R D64
R D1
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R D64
R D24
R D1
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R D13
R D30
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R D2
R D66
R D1
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R D64
R D25
R D1
L C333
R D13
R D31
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L C753
R D2
R D68
R D1
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R D64
R D27
R D1
L C334
R D13
R D32
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R D2
R D76
R D1
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R D64
R D28
R D1
L C335
R D13
R D33
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R D3
R D4
R D1
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R D64
R D29
R D1
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R D13
R D34
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R D3
R D5
R D1
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R D64
R D30
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R D35
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R D6
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R D64
R D31
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R D32
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R D64
R D1
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R D3
R D12
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R D66
R D1
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R D76
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R D13
R D1
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R D64
R D68
R D1
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R D5
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R D3
R D14
R D1
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R D64
R D76
R D1
L C346
R D14
R D6
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R D3
R D15
R D1
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R D66
R D5
R D1
L C347
R D14
R D9
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R D3
R D16
R D1
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R D66
R D6
R D1
L C348
R D14
R D10
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R D3
R D17
R D1
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R D66
R D9
R D1
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R D14
R D12
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R D3
R D18
R D1
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R D66
R D10
R D1
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R D14
R D15
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L C770
R D3
R D19
R D1
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R D66
R D12
R D1
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R D14
R D16
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R D3
R D20
R D1
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R D66
R D15
R D1
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R D14
R D17
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R D3
R D21
R D1
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R D66
R D16
R D1
L C353
R D14
R D18
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R D3
R D22
R D1
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R D66
R D17
R D1
L C354
R D14
R D19
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R D3
R D23
R D1
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R D66
R D18
R D1
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R D14
R D20
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R D3
R D24
R D1
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R D66
R D19
R D1
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R D14
R D21
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R D3
R D25
R D1
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R D66
R D20
R D1
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R D14
R D22
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R D3
R D26
R D1
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R D66
R D21
R D1
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R D23
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R D3
R D27
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R D66
R D23
R D1
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R D14
R D24
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R D3
R D28
R D1
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R D66
R D24
R D1
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R D14
R D25
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R D3
R D29
R D1
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R D66
R D25
R D1
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R D26
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R D3
R D30
R D1
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R D66
R D27
R D1
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R D14
R D27
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R D3
R D31
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R D66
R D28
R D1
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R D28
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R D32
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R D29
R D1
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R D29
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R D33
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R D66
R D30
R D1
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R D30
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R D34
R D1
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R D66
R D31
R D1
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R D35
R D1
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R D32
R D1
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R D32
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R D40
R D1
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R D33
R D1
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R D33
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R D41
R D1
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R D66
R D34
R D1
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R D14
R D34
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R D3
R D42
R D1
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R D66
R D42
R D1
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R D14
R D35
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L C790
R D3
R D64
R D1
L C1210
R D66
R D68
R D1
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R D14
R D40
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L C791
R D3
R D66
R D1
L C1211
R D66
R D76
R D1
L C372
R D14
R D41
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L C792
R D3
R D68
R D1
L C1212
R D68
R D5
R D1
L C373
R D14
R D42
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L C793
R D3
R D76
R D1
L C1213
R D68
R D6
R D1
L C374
R D14
R D64
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L C794
R D4
R D5
R D1
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R D68
R D9
R D1
L C375
R D14
R D66
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L C795
R D4
R D6
R D1
L C1215
R D68
R D10
R D1
L C376
R D14
R D68
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R D4
R D7
R D1
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R D68
R D12
R D1
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R D14
R D76
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R D4
R D8
R D1
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R D68
R D15
R D1
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R D5
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R D4
R D9
R D1
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R D16
R D1
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R D6
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R D10
R D1
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R D68
R D17
R D1
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R D9
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R D4
R D11
R D1
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R D68
R D18
R D1
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R D22
R D10
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R D12
R D1
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R D19
R D1
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R D22
R D12
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R D4
R D13
R D1
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R D20
R D1
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R D22
R D15
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R D4
R D14
R D1
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R D68
R D21
R D1
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R D22
R D16
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R D4
R D15
R D1
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R D68
R D23
R D1
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R D22
R D17
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R D4
R D16
R D1
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R D68
R D24
R D1
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R D22
R D18
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L C806
R D4
R D17
R D1
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R D68
R D25
R D1
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R D22
R D19
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R D4
R D18
R D1
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R D68
R D27
R D1
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R D22
R D20
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L C808
R D4
R D19
R D1
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R D68
R D28
R D1
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R D22
R D21
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R D4
R D20
R D1
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R D68
R D29
R D1
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R D22
R D23
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R D4
R D21
R D1
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R D68
R D30
R D1
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R D22
R D24
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R D4
R D22
R D1
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R D68
R D31
R D1
L C392
R D22
R D25
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R D4
R D23
R D1
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R D68
R D32
R D1
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R D22
R D26
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R D4
R D24
R D1
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R D68
R D33
R D1
L C394
R D22
R D27
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L C814
R D4
R D25
R D1
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R D68
R D34
R D1
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R D22
R D28
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L C815
R D4
R D26
R D1
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R D68
R D42
R D1
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R D22
R D29
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R D4
R D27
R D1
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R D68
R D76
R D1
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R D22
R D30
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R D4
R D28
R D1
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R D76
R D5
R D1
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R D22
R D31
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R D4
R D29
R D1
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R D76
R D6
R D1
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R D32
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R D4
R D30
R D1
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R D76
R D9
R D1
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R D22
R D33
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R D4
R D31
R D1
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R D76
R D10
R D1
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R D22
R D34
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R D4
R D32
R D1
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R D12
R D1
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R D22
R D35
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R D33
R D1
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R D15
R D1
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R D22
R D40
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R D4
R D34
R D1
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R D76
R D16
R D1
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R D22
R D41
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R D4
R D35
R D1
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R D76
R D17
R D1
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R D22
R D42
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R D4
R D40
R D1
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R D76
R D18
R D1
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R D22
R D64
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R D4
R D41
R D1
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R D76
R D19
R D1
L C407
R D22
R D66
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L C827
R D4
R D42
R D1
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R D76
R D20
R D1
L C408
R D22
R D68
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L C828
R D4
R D64
R D1
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R D76
R D21
R D1
L C409
R D22
R D76
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L C829
R D4
R D66
R D1
L C1249
R D76
R D23
R D1
L C410
R D26
R D5
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L C830
R D4
R D68
R D1
L C1250
R D76
R D24
R D1
L C411
R D26
R D6
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L C831
R D4
R D76
R D1
L C1251
R D76
R D25
R D1
L C412
R D26
R D9
H
L C832
R D4
R D1
R D1
L C1252
R D76
R D27
R D1
L C413
R D26
R D10
H
L C833
R D7
R D5
R D1
L C1253
R D76
R D28
R D1
L C414
R D26
R D12
H
L C834
R D7
R D6
R D1
L C1254
R D76
R D29
R D1
L C415
R D26
R D15
H
L C835
R D7
R D8
R D1
L C1255
R D76
R D30
R D1
L C416
R D26
R D16
H
L C836
R D7
R D9
R D1
L C1256
R D76
R D31
R D1
L C417
R D26
R D17
H
L C837
R D7
R D10
R D1
L C1257
R D76
R D32
R D1
L C418
R D26
R D18
H
L C838
R D7
R D11
R D1
L C1258
R D76
R D33
R D1
L C419
R D26
R D19
H
L C839
R D7
R D12
R D1
L C1259
R D76
R D34
R D1
L C420
R D26
R D20
H
L C840
R D7
R D13
R D1
L C1260
R D76
R D42
R D1
and wherein R D1 to R D81 has the following structures:
14. An organic light emitting device (OLED) comprising:
an anode;
a cathode; and
an organic layer, disposed between the anode and the cathode, comprising a compound comprising a first ligand L A having the Formula selected from the group consisting of:
wherein ring B and C are each independently a 5-membered or 6-membered aromatic or heteroaromatic ring;
wherein R A , R B , R C , and R D each independently represent mono to the maximum possible number of substituents, or no substituent;
wherein Z 1 and Z 2 are each independently selected from the group consisting of C and N;
wherein X 1 , X 2 , X 3 , X 4 , X 5 , and X 6 are each C;
wherein when the first ligand L A has the Formula of Formula IA, ring B is a 5-membered ring or ring B contains two nitrogen atoms;
wherein Y is selected from the group consisting of CRR′, NR′, O, S, SiRR′, and Se;
wherein when ring B is phenyl in Formula IB, Y is selected from the group consisting of NR′, S, SiRR′, and Se;
wherein R, R′, R A , R B , R C , and R D are each independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof;
wherein any two substituents are optionally joined or fused into a ring;
wherein the ligand L A is coordinated to a metal M by the dashed lines to form a 5-membered chelate ring;
wherein M does not form a direct bond to X 1 in Formula IB;
wherein M does not form a direct bond to X 4 in Formula IC;
wherein the metal M can be coordinated to other ligands; and
wherein the ligand L A is optionally linked with other ligands to comprise a tridentate, tetradentate, pentadentate or hexadentate ligand.
15. The OLED of claim 14 , wherein the organic layer is an emissive layer and the compound is an emissive dopant or a non-emissive dopant.
16. The OLED of claim 14 , wherein the organic layer further comprises a host, wherein host comprises at least one chemical group selected from the group consisting of a metal complex, triphenylene, carbazole, dibenzothiophene, dibenzofuran, dibenzoselenophene, azatriphenylene, azacarbazole, aza-dibenzothiophene, aza-dibenzofuran, and aza-dibenzoselenophene.
17. The OLED of claim 16 , wherein the host is selected from the group consisting of:
and combinations thereof.
18. A consumer product comprising an organic light-emitting device (OLED) comprising:
an anode;
a cathode; and
an organic layer, disposed between the anode and the cathode, comprising a compound comprising a first ligand L A having the Formula selected from the group consisting of:
wherein ring B and C are each independently a 5-membered or 6-membered aromatic or heteroaromatic ring;
wherein R A , R B , R C , and R D each independently represent mono to the maximum possible number of substituents, or no substituent;
wherein Z 1 and Z 2 are each independently selected from the group consisting of C and N;
wherein X 1 , X 2 , X 3 , X 4 , X 5 , and X 6 are each C;
wherein when the first ligand L A has the Formula of Formula IA, ring B is a 5-membered ring or ring B contains two nitrogen atoms;
wherein Y is selected from the group consisting of CRR′, NR′, O, S, SiRR′, and Se;
wherein when ring B is phenyl in Formula IB, Y is selected from the group consisting of NR′, S, SiRR′, and Se;
wherein R, R′, R A , R B , R C , and R D are each independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof;
wherein any two substituents are optionally joined or fused into a ring;
wherein the ligand L A is coordinated to a metal M by the dashed lines to form a 5-membered chelate ring;
wherein M does not form a direct bond to X 1 in Formula IB;
wherein M does not form a direct bond to X 4 in Formula IC;
wherein the metal M can be coordinated to other ligands;
wherein the ligand L A is optionally linked with other ligands to comprise a tridentate, tetradentate, pentadentate or hexadentate ligand; and
wherein the consumer product is one of a flat panel display, a curved display, a computer monitor, a medical monitor, a television, a billboard, a light for interior or exterior illumination and/or signaling, a heads-up display, a fully or partially transparent display, a flexible display, a rollable display, a foldable display, a stretchable display, a laser printer, a telephone, a cell phone, tablet, a phablet, a personal digital assistant (PDA), a wearable device, a laptop computer, a digital camera, a camcorder, a viewfinder, a micro-display that is less than 2 inches diagonal, a 3-D display, a virtual reality or augmented reality display, a vehicle, a video wall comprising multiple displays tiled together, a theater or stadium screen, a light therapy device, or a sign.
19. A formulation comprising the compound of claim 1 .