Organic electroluminescent devices
The present disclosure relates to the field of display technologies, and particularly discloses an organic electroluminescent device. The organic electroluminescent device has a first electrode, a second electrode, and an organic functional layer. The organic functional layer comprises a light-emitting layer. The light-emitting layer comprises at least a host material and a guest material. The host material comprises an exciplex composed of a donor molecule and a receptor molecule, wherein the donor molecule and/or the receptor molecule contains a large steric hindrance substituent group X for increasing an inter-molecular distance between the donor molecule and the receptor molecule, which enables to enhance Foster energy transfer to the guest material molecule, improve device efficiency, inhibit Triplet-Polaron Annihilate Annihilation (TPA), and prolong the device lifetime.
1. An organic electroluminescent device, the organic electroluminescent device comprising an organic functional layer, the organic functional layer comprising a light-emitting layer; the light-emitting layer comprising a host material and a guest material; the host material being an exciplex composed of a donor molecule and a receptor molecule; the donor molecule and/or the receptor molecule containing a plurality of steric hindrance groups, wherein the steric hindrance groups are groups each independently containing substituted or unsubstituted cycloalkyl, silyl, boryl and borosilicate,
wherein the donor molecule employs any one of the following structures:
2. The organic electroluminescent device according to claim 1 , wherein the receptor molecule is a compound containing at least one of pyrimidinyl, triazinyl, oxadiazolyl, pyridyl, carbazolyl, aryl, cyano, acridinyl, dibenzothiophenyl, triphenylphosphonyl, and triphenylboryl.
3. The organic electroluminescent device according to claim 2 , wherein the receptor molecule employs any one of the following molecular structures:
wherein X in the molecular structures is hydrogen or a steric hindrance group, and at least one X is a steric hindrance group.
4. The organic electroluminescent device according to claim 3 ,
wherein the receptor molecule employs any one of the following structures:
5. The organic electroluminescent device according to claim 1 , wherein a number of steric hindrance groups on the donor molecule structure or the receptor molecule structure is less than or equal to six.
6. The organic electroluminescent device according to claim 1 , wherein a mass ratio of the donor molecule to the receptor molecule in the exciplex is 1:9 to 9:1.
7. The organic electroluminescent device according to claim 6 , wherein the mass ratio of the donor molecular material to the receptor molecular material is 1:2 to 1:5, or the mass ratio of the donor molecular material to the receptor molecular material is 2:1 to 5:1.
8. The organic electroluminescent device according to claim 1 , wherein a mass ratio of the host material to the guest material is 1000:1 to 2:1.
9. The organic electroluminescent device according to claim 8 , wherein the mass ratio of the host material to the guest material is 200:1 to 5:1.
10. The organic electroluminescent device according to claim 1 , wherein the steric hindrance groups comprise:
11. The organic electroluminescent device according to claim 1 , wherein the steric hindrance groups are only selected from:
12. The organic electroluminescent device according to claim 1 , wherein the steric hindrance groups are only selected from:
13. The organic electroluminescent device according to claim 1 , wherein the steric hindrance groups comprise:
14. An organic electroluminescent device, the organic electroluminescent device comprising an organic functional layer, the organic functional layer comprising a light-emitting layer; the light-emitting layer comprising a host material and a guest material; the host material being an exciplex composed of a donor molecule and a receptor molecule; the donor molecule and/or the receptor molecule containing a plurality of steric hindrance groups, wherein the steric hindrance groups are groups each independently containing substituted or unsubstituted cycloalkyl, silyl, boryl, and borosilicate,
wherein the donor molecule employs any one of the following structures:
15. An organic electroluminescent device, the organic electroluminescent device comprising an organic functional layer, the organic functional layer comprising a light-emitting layer; the light-emitting layer comprising a host material and a guest material; the host material being an exciplex composed of a donor molecule and a receptor molecule; the donor molecule and/or the receptor molecule containing a plurality of steric hindrance groups, wherein the steric hindrance groups are groups each independently containing substituted or unsubstituted cycloalkyl, silyl, boryl, and borosilicate, and wherein the receptor molecule employs any one of the following molecular structures:
wherein X in the molecular structures is hydrogen or a steric hindrance group, and at least one X is a steric hindrance group,
wherein the donor molecule employs any one of the following structures:
16. The organic electroluminescent device according to claim 15 , wherein the receptor molecule employs any one of the following structures: