Adhesive film and optical member comprising same
Provided are an adhesive film and an optical member comprising same, the adhesive film comprising at least two types of (meth)acrylic monomers for a (meth)acrylic prepolymer, and (meth)acrylate containing silicon, wherein the release force of the adhesive film with respect to a polyimide film is approximately 0.5 gf/in to 5 gf/in.
1. An adhesive film formed of at least two kinds of (meth)acrylic monomers for a (meth)acrylic prepolymer and a silicon-containing (meth)acrylate,
the adhesive film having a peel strength of about 0.5 gf/in to about 5 gf/in with respect to a polyimide film at 25° C.
2. The adhesive film according to claim 1 , wherein the silicon-containing (meth)acrylate comprises a siloxane-modified monofunctional (meth)acrylate.
3. The adhesive film according to claim 2 , wherein the siloxane-modified monofunctional (meth)acrylate is represented by Formula 1:
where R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , and R 7 are each independently a hydrogen, a C 1 to C 10 alkyl group, a C 3 to C 10 cycloalkyl group, or a C 6 to C 10 aryl group; R 8 is a C 1 to C 10 alkylene group or a C 6 to C 10 arylene group; R 9 is a hydrogen or a methyl group; and n is an integer of 10 to 100.
4. The adhesive film according to claim 2 , wherein the adhesive film is formed of an adhesive composition comprising a monomer mixture comprising the at least two kinds of (meth)acrylic monomers for the (meth)acrylic prepolymer and the silicon-containing (meth)acrylate.
5. The adhesive film according to claim 4 , wherein the adhesive film has a transfer peel strength change rate of about 85% or more, as calculated by Equation 2:
Transfer peel strength change rate= D/C× 100, <Equation 2>
where C is a peel strength (unit: gf/in) of an adhesive tape with respect to a glass substrate; and
D is a peel strength (unit: gf/in) of the adhesive tape with respect to a portion of the glass substrate from which the adhesive film is removed, after the adhesive film is laminated onto the glass substrate and is left in an oven at 40° C. for 10 days.
6. The adhesive film according to claim 4 , wherein the silicon-containing (meth)acrylate is present in an amount of about 6 wt % to about 80 wt % in the monomer mixture.
7. The adhesive film according to claim 4 , wherein the at least two kinds of (meth)acrylic monomers for the (meth)acrylic prepolymer comprises an alkyl group-containing (meth)acrylate and a hydroxyl group-containing (meth)acrylate,
the monomer mixture comprising about 5 wt % to about 90 wt % of the alkyl group containing (meth)acrylate, about 1 wt % to about 15 wt % of the hydroxyl group-containing (meth)acrylate, and about 6 wt % to about 80 wt % of the silicon-containing (meth)acrylate.
8. The adhesive film according to claim 4 , wherein the monomer mixture further comprises a cyclic functional group-containing (meth)acrylic monomer.
9. The adhesive film according to claim 8 , wherein the cyclic functional group-containing (meth)acrylic monomer comprises a C 3 to C 15 alicyclic group-containing (meth)acrylate and a C 3 to C 15 hetero-alicyclic group-containing (meth)acrylic monomer having at least one of oxygen, nitrogen, and sulfur.
10. The adhesive film according to claim 8 , wherein the cyclic functional group-containing (meth)acrylic monomer is present in an amount of about 1 wt % to about 10 wt % in the monomer mixture.
11. The adhesive film according to claim 1 , wherein the adhesive film is formed of an adhesive composition comprising the at least two kinds of (meth)acrylic monomers for the (meth)acrylic prepolymer and a siloxane-modified monofunctional (meth)acrylate and a siloxane-modified bifunctional (meth)acrylate as the silicon-containing (meth)acrylate,
the siloxane-modified monofunctional (meth)acrylate and the siloxane-modified bifunctional (meth)acrylate being present in a total amount of about 3 wt % to about 40 wt % based on a total amount of the at least two kinds of (meth)acrylic monomers for the (meth)acrylic prepolymer, the siloxane-modified monofunctional (meth)acrylate, and the siloxane-modified bifunctional (meth)acrylate.
12. The adhesive film according to claim 11 , wherein the adhesive film has a residue ratio of about 25% or less, as calculated by Equation 3:
Residue ratio=| B−A|/A× 100, <Equation 3>
where A is a peel strength (unit: gf/in) of an adhesive tape with respect to a glass substrate, and
B is a peel strength (unit: gf/in) of the adhesive tape with respect to a portion of the glass substrate from which the adhesive film is removed, after the adhesive film is laminated onto the glass substrate and is left at 50° C. for 10 days.
13. The adhesive film according to claim 11 , wherein the adhesive film has a weight change rate of about 2% or less, as calculated by Equation 4:
Weight change ratio=| F−E|/E× 100, <Equation 4>
where E is an initial weight (unit: g) of the adhesive film, and
F is a weight (unit: g) of the adhesive film after the adhesive film is left at 150° C. for 90 minutes and left at 25° C. for 15 minutes.
14. The adhesive film according to claim 11 , wherein the siloxane-modified bifunctional (meth)acrylate is represented by Formula 5:
where R 11 , R 12 , R 13 , R 14 , R 15 , and R 16 are each independently a hydrogen, a C 1 to C 10 alkyl group, a C 3 to C 10 cycloalkyl group, or a C 6 to C 10 aryl group; R 17 and R 18 are each independently a C 1 to C 10 alkylene group or a C 6 to C 10 arylene group; R 19 and R 20 are each independently a hydrogen or a methyl group; and n is an integer of 10 to 100.
15. The adhesive film according to claim 11 , wherein the at least two kinds of (meth)acrylic monomers for the (meth)acrylic prepolymer comprise an alkyl group-containing (meth)acrylate and a hydroxyl group-containing (meth)acrylate.
16. The adhesive film according to claim 11 , wherein the siloxane-modified bifunctional (meth)acrylate is present in an amount of about 2 wt % to about 25 wt % based on the total amount of the at least two kinds of (meth)acrylic monomers for the (meth)acrylic prepolymer, the siloxane-modified monofunctional (meth)acrylate, and the siloxane-modified bifunctional (meth)acrylate.
17. The adhesive film according to claim 11 , wherein the adhesive film is formed of an adhesive composition comprising: a monomer mixture for the (meth)acrylic prepolymer comprising the at least two kinds of (meth)acrylic monomers and the siloxane-modified monofunctional (meth)acrylate; and the siloxane-modified bifunctional (meth)acrylate.
18. The adhesive film according to claim 17 , wherein the siloxane-modified monofunctional (meth)acrylate and the siloxane-modified bifunctional (meth)acrylate are present in a total amount of about 4 parts by weight to about 40 parts by weight relative to a total amount of 100 parts by weight of the monomer mixture for the (meth)acrylic prepolymer and about 3 parts by weight to about 25 parts by weight of the siloxane-modified bifunctional (meth)acrylate.
19. The adhesive film according to claim 17 , wherein the siloxane-modified monofunctional (meth)acrylate is present in an amount of about 1 wt % to about 15 wt % in the monomer mixture.
20. The adhesive film according to claim 17 , wherein the siloxane-modified bifunctional (meth)acrylate is present in an amount of about 3 parts by weight to about 25 parts by weight relative to 100 parts by weight of the monomer mixture.
21. The adhesive film according to claim 11 , wherein the adhesive film is formed of an adhesive composition comprising: a monomer mixture for the (meth)acrylic prepolymer comprising the at least two kinds of (meth)acrylic monomers, the siloxane-modified monofunctional (meth)acrylate, and the siloxane-modified bifunctional (meth)acrylate.
22. The adhesive film according to claim 21 , wherein the siloxane-modified monofunctional (meth)acrylate and the siloxane-modified bifunctional (meth)acrylate are present in a total amount of about 4 wt % to about 40 wt % in the monomer mixture for the (meth)acrylic prepolymer.
23. The adhesive film according to claim 21 , wherein the siloxane-modified monofunctional (meth)acrylate is present in an amount of about 1 wt % to about 15 wt % in the monomer mixture.
24. The adhesive film according to claim 21 , wherein the siloxane-modified bifunctional (meth)acrylate is present in an amount of about 3 wt % to about 25 wt % in the monomer mixture.
25. The adhesive film according to claim 1 , further comprising: an antistatic agent.
26. The adhesive film according to claim 25 , wherein the adhesive film has a surface resistance of about 6.5×10 9 Ω/□ or less.
27. The adhesive film according to claim 21 , wherein the adhesive composition further comprises a crosslinking agent.
28. The adhesive film according to claim 27 , wherein the crosslinking agent is present in an amount of about 0.5 parts by weight or more relative to 100 parts by weight of the monomer mixture.
29. An optical member comprising:
an optical film; and
the adhesive film according to claim 1 , the adhesive film being formed on at least one surface of the optical film.