Quantum dot dispersed resin molded body, quantum dot dispersed colloid, and light emitting device
Disclosed in the present disclosure are a quantum dot dispersed resin molded body, a quantum dot dispersed colloid, and a light emitting device. The quantum dot dispersed resin molded body includes quantum dots dispersed in an acrylate polymer, at least a portion of repeating units of the acrylate polymer comprise a C═C double bond, and the degree of polymerization n of the repeating units is greater than or equal to 2, the quantum dot dispersed resin molded body is formed by cross-linking and curing the quantum dot dispersed colloid.
1. A quantum dot dispersed colloid, comprising a dispersion medium and quantum dots dispersed in said dispersion medium, wherein said dispersion medium comprises: a functional acrylate resin, a non-functional acrylate prepolymer and a non-functional acrylate monomer; said functional acrylate resin is selected from at least one of a functional acrylate prepolymer and a functional acrylate monomer; a molecular chain of said functional acrylate prepolymer further comprises at least one C═C double bond in addition to an active functional allyl group; a molecular structure of said functional acrylate monomer further comprises at least one C═C double bond in addition to an active functional allyl group, said functional acrylate monomer is selected from one or more of dicyclopentadiene acrylate, dicyclopentadiene ethoxy acrylate, dicyclopentadiene methacrylate, and dicyclopentadiene ethoxy methacrylate.
2. The quantum dot dispersed colloid according to claim 1 , wherein said non-functional acrylate monomer comprises at least one of a monofunctional acrylate and a multifunctional acrylate;
said monofunctional acrylate is selected from one or more of isobornyl (meth)acrylate, methyl (meth)acrylate, ethyl (meth)acrylate, n-butyl (meth)acrylate, cyclohexyl (meth)acrylate, isooctyl (meth)acrylate, isodecyl (meth)acrylate, lauryl (meth)acrylate, 3,3,5-trimethylcyclohexyl acrylate, hydroxyethyl (meth)acrylate, hydroxypropyl (meth)acrylate, 2-phenoxyethyl (meth)acrylate, tetrahydrofurfuryl (meth)acrylate, glycidyl (meth)acrylate, acryloylmorpholine, and 2-ethylhexyl (meth)acrylate;
said multifunctional acrylate is selected from one or more of trimethylolpropane tri(meth)acrylate, ethoxylated trimethylolpropane tri(meth)acrylate, propoxylated trimethylolpropane triacrylate, 1,3-butanediol diacrylate, 1,6-hexanediol di(meth)acrylate, dipropylene glycol diacrylate, tripropylene glycol diacrylate, neopentyl glycol diacrylate, polyethylene glycol diacrylate, tricyclodecane dimethanol diacrylate, pentaerythritol triacrylate, tris(2-hydroxyethyl)isocyanurate triacrylate, pentaerythritol tetraacrylate, and dipentaerythritol hexaacrylate.
3. The quantum dot dispersed colloid according to claim 1 , wherein said non-functional acrylate prepolymer is selected from one or more of urethane acrylate, polyester acrylate, epoxy acrylate resin, and silicone modified acrylate.
4. The quantum dot dispersed colloid according to claim 1 , wherein said functional acrylate prepolymer is selected from one or more of unsaturated polyester modified acrylate, polybutadiene modified acrylate, and polyisoprene modified acrylate.
5. The quantum dot dispersed colloid according to claim 1 , wherein further comprising one or more of the following substances dispersed in said dispersion medium: a light diffusion particle, a photoinitiator, and an antioxidant.
6. The quantum dot dispersed colloid according to claim 1 , wherein an addition amount of said functional acrylate resin is 5%-50% of a total mass of said dispersion medium.
7. The quantum dot dispersed colloid according to claim 2 , wherein further comprising one or more of the following substances dispersed in said dispersion medium: a light diffusion particle, a photoinitiator, and an antioxidant.
8. The quantum dot dispersed colloid according to claim 3 , wherein further comprising one or more of the following substances dispersed in said dispersion medium: a light diffusion particle, a photoinitiator, and an antioxidant.
9. The quantum dot dispersed colloid according to claim 4 , wherein further comprising one or more of the following substances dispersed in said dispersion medium: a light diffusion particle, a photoinitiator, and an antioxidant.
10. The quantum dot dispersed colloid according to claim 2 , wherein an addition amount of said functional acrylate resin is 5%-50% of a total mass of said dispersion medium.
11. The quantum dot dispersed colloid according to claim 3 , wherein an addition amount of said functional acrylate resin is 5%-50% of a total mass of said dispersion medium.
12. The quantum dot dispersed colloid according to claim 4 , wherein an addition amount of said functional acrylate resin is 5%-50% of a total mass of said dispersion medium.
13. A light emitting device, comprising a primary light source, wherein further comprising a quantum dot dispersed resin molded body prepared from said quantum dot dispersed colloid according to claim 1 , wherein said primary light source is provided in contact with or not in contact with said quantum dot dispersed resin molded body.
14. The light emitting device according to claim 13 , wherein a shape of said quantum dot dispersed resin molded body is lamellar or tubular or fibrous or lenticular or dome-shaped.