Low reflectance, anti-reflective film structures with controlled color and articles with the same

1. An article, comprising:

a substrate having a major surface; and

an anti-reflective coating disposed on the major surface of the substrate and forming an anti-reflective surface,

wherein the article exhibits a single side average photopic light reflectance at the anti-reflective surface of less than 0.35%,

wherein the article exhibits a single side color shift (ΔC) of less than 6 under an International Commission on Illumination illuminant over an incident angle range from 0 degrees to 60 degrees incidence at the anti-reflective surface, wherein ΔC=√((a* max −a* min ) 2 +(b* max −b* min ) 2 ) with a* max , a* min , b* max , and b* min as the maximum and minimum color coordinates in the (L*, a*, b*) colorimetery system for the respective a* and b* coordinates,

wherein the anti-reflective coating comprises a physical thickness from about 50 nm to less than 450 nm,

wherein the anti-reflective coating comprises a plurality of layers,

wherein the anti-reflective coating comprises a capping layer and a plurality of periods such that each period comprises an alternating low refractive index layer and one or more high refractive index layers, wherein one of the low refractive index layers is in direct contact with the major surface of the substrate, wherein the capping layer comprises a low refractive index layer over the plurality of periods,

wherein at least one of the one or more high refractive index layers has a refractive index of greater than 2.0 and each low refractive index layer has a refractive index of less than 1.7,

wherein at least one of the plurality of periods comprises at least two high refractive index layers, the at least two high refractive index layers comprise a first layer comprising SiN x and a second layer comprising Nb 2 O 5 , TiO 2 , Ta 2 O 3 , or HfO 2 , and further wherein the first layer is thicker than the second layer, and

wherein a combined physical thickness of the high refractive index layers of the anti-reflective coating is about 40% or greater of a total physical thickness of the anti-reflective coating.

2. The article according to claim 1 , wherein the article exhibits single side color coordinates in the (L*, a*, b*) colorimetry system within the range of −2<a*<+1 and −4<b*<+1 under an International Commission on Illumination illuminant over an incident angle range from 0 degrees to 10 degrees at the anti-reflective surface.

3. The article according to claim 1 , wherein the article exhibits single side color coordinates in the (L*, a*, b*) colorimetry system within the range of −2<a*<+2 and −6<b*<+2 under an International Commission on Illumination illuminant over an incident angle range from 0 degrees to 60 degrees at the anti-reflective surface.

4. The article according to claim 1 , wherein the article exhibits a single side color shift (ΔC) of less than 5 under an International Commission on Illumination illuminant over an incident angle range from 0 degrees to 60 degrees at the anti-reflective surface, wherein ΔC=√((a* max −a* min ) 2 +(b* max −b* min ) 2 ) with a* max , a* min , b* max , and b* min as the maximum and minimum color coordinates in the (L*, a*, b*) colorimetery system for the respective a* and b* coordinates.

5. The article according to claim 1 , wherein the article exhibits a single side color shift (ΔC) of less than 2.5 under an International Commission on Illumination illuminant over an incident angle range from 0 degrees to 60 degrees at the anti-reflective surface, wherein ΔC=√((a* max −a* min ) 2 +(b* max −b* min ) 2 ) with a* max , a* min , b* max , and b* min as the maximum and minimum color coordinates in the (L*, a*, b*) colorimetery system for the respective a* and b* coordinates.

6. The article according to claim 1 , wherein the article exhibits a single side average photopic light reflectance of less than 0.25%.

7. The article according to claim 1 , wherein the article exhibits a single side average photopic light reflectance of less than 0.15%.

8. The article according to claim 1 , wherein the substrate is a translucent substrate.

9. The article according to claim 1 , wherein the substrate is a transparent substrate.

10. A consumer electronic product, comprising:

a housing having a front surface, a back surface and side surfaces;

electrical components provided at least partially within the housing, the electrical components including at least a controller, a memory, and a display, the display being provided at or adjacent the front surface of the housing; and

a cover glass disposed over the display, wherein at least one of a portion of the housing or the cover glass comprises the article of claim 1 .

11. An article, comprising:

a substrate having a major surface; and

an anti-reflective coating disposed on the major surface of the substrate and forming an anti-reflective surface,

wherein the article exhibits a single side average photopic light reflectance at the anti-reflective surface of less than 0.5%,

wherein the article exhibits a single side color shift (ΔC) of less than 8 under an International Commission on Illumination illuminant over an incident angle range from 0 degrees to 60 degrees incidence at the anti-reflective surface, wherein ΔC=√((a* max −a* min ) 2 +(b* max −b* min ) 2 ) with a* max , a* min , b* max , and b* min as the maximum and minimum color coordinates in the (L*, a*, b*) colorimetery system for the respective a* and b* coordinates,

wherein the anti-reflective coating comprises a physical thickness from about 50 nm to less than 450 nm,

wherein the anti-reflective coating comprises a maximum hardness of greater than 7 GPa as measured on the anti-reflective surface by a Berkovich Indenter Hardness Test along an indentation depth of about 100 nm and greater,

wherein the anti-reflective coating comprises a plurality of layers,

wherein the anti-reflective coating comprises a capping layer and a plurality of periods such that each period comprises an alternating low refractive index layer and one or more high refractive index layers, wherein one of the low refractive index layers is in direct contact with the major surface of the substrate, wherein the capping layer comprises a low refractive index layer over the plurality of periods,

wherein at least one of the one or more high refractive index layers has a refractive index of greater than 2.0 and each low refractive index layer has a refractive index of less than 1.7,

wherein at least one of the plurality of periods comprises at least two high refractive index layers, the at least two high refractive index layers comprise a first layer comprising SiN x and a second layer comprising Nb 2 O 5 , TiO 2 , Ta 2 O 3 , or HfO 2 , and further wherein the first layer is thicker than the second layer, and

wherein a combined physical thickness of the high refractive index layers of the anti-reflective coating is about 40% or greater of a total physical thickness of the anti-reflective coating.

12. The article according to claim 11 , wherein the article exhibits single side color coordinates in the (L*, a*, b*) colorimetry system within the range of −2<a*<+1 and −4<b*<+1 under an International Commission on Illumination illuminant over an incident angle range from 0 degrees to 10 degrees at the anti-reflective surface.

13. The article according to claim 11 , wherein the article exhibits single side color coordinates in the (L*, a*, b*) colorimetry system within the range of −2<a*<+2 and −6<b*<+2 under an International Commission on Illumination illuminant over an incident angle range from 0 degrees to 60 degrees at the anti-reflective surface.

14. The article according to claim 11 , wherein the anti-reflective coating comprises a maximum hardness of 8 GPa or greater as measured on the anti-reflective surface by a Berkovich Indenter Hardness Test along an indentation depth of about 100 nm and greater.

15. The article according to claim 11 , wherein the article exhibits a single side average photopic light reflectance of less than 0.35%.

16. The article according to claim 11 , wherein the article exhibits a single side average photopic light reflectance of less than 0.25%.

17. The article according to claim 11 , wherein the article exhibits a single side average photopic light reflectance of less than 0.15%.

18. A consumer electronic product, comprising:

a housing having a front surface, a back surface and side surfaces;

electrical components provided at least partially within the housing, the electrical components including at least a controller, a memory, and a display, the display being provided at or adjacent the front surface of the housing; and

a cover glass disposed over the display, wherein at least one of a portion of the housing or the cover glass comprises the article of claim 11 .

19. An article, comprising:

a substrate having a major surface; and

an anti-reflective coating disposed on the major surface of the substrate and forming an anti-reflective surface,

wherein the article exhibits a single side average photopic light reflectance at the anti-reflective surface of less than 0.5%,

wherein the anti-reflective coating comprises a physical thickness from about 50 nm to less than 500 nm,

wherein the anti-reflective coating comprises a maximum hardness of greater than 7 GPa as measured on the anti-reflective surface by a Berkovich Indenter Hardness Test along an indentation depth of about 100 nm and greater,

wherein the anti-reflective coating comprises a plurality of layers,

wherein the anti-reflective coating comprises a capping layer and a plurality of periods such that each period comprises an alternating low refractive index layer and one or more high refractive index layers, wherein one of the low refractive index layers is in direct contact with the major surface of the substrate, and wherein the capping layer comprises a low refractive index layer over the plurality of periods,

wherein at least one of the plurality of periods comprises at least two high refractive index layers, each of the at least two high refractive index layers comprising Nb 2 O 5 , TiO 2 , Ta 2 O 3 , HfO 2 , or SiN x ,

wherein at least one of the one or more high refractive index layers has a refractive index of greater than 2.0 and each low refractive index layer has a refractive index of less than 1.7,

wherein the at least two high refractive index layers comprise a first layer comprising SiN x and a second layer comprising Nb 2 O 5 , TiO 2 , Ta 2 O 3 , or HfO 2 , and further wherein the first layer is thicker than the second layer, and

wherein a combined physical thickness of the high refractive index layers of the anti-reflective coating is about 40% or greater of a total physical thickness of the anti-reflective coating.

20. The article according to claim 19 , wherein the article further exhibits a reflected haze of less than 2% after being subjected to 500 abrasion cycles with a 350 g load in the Alumina SCE Test or less than 2.5% after being subjected to 1500 abrasion cycles with a 350 g load in the Alumina SCE Test.

21. The article according to claim 19 , wherein the anti-reflective coating comprises a maximum hardness of greater than 8 GPa as measured on the anti-reflective surface by a Berkovich Indenter Hardness Test along an indentation depth of about 100 nm and greater.

22. The article according to claim 19 , wherein the article exhibits a single side average photopic light reflectance of less than 0.25%.