Sealant film, multilayer film including same and packaging bag
A sealant film including a polyolefin layer containing polyolefin as a main ingredient, and a polycycloolefin layer as an outermost layer containing polycycloolefin as a main ingredient. The polycycloolefin contains two or more kinds of structural units selected from a structural unit (A) derived from a dicyclopentadiene compound, a structural unit (B) derived from a tetracyclododecene compound, and a structural unit (C) derived from a norbornene compound, and the polycycloolefin has a glass transition temperature less than or equal to 80° C.
1. A sealant film comprising:
a polyolefin layer containing greater than or equal to 90 mass % of polyolefin; and
a polycycloolefin layer as an outermost layer containing greater than or equal to 90 mass % of polycycloolefin,
wherein the polycycloolefin of the polycycloolefin layer is a ternary copolymer made of structural units selected from a structural unit (A) derived from a dicyclopentadiene compound, a structural unit (B) derived from a tetracyclododecene compound, and a structural unit (C) derived from a norbornene compound,
wherein the dicyclopentadiene compound is tricyclo [5.2.1.0 2,6 ] deca-3,8-diene, the tetracyclododecene compound is tetracyclo [4.4.0.1 2,5 0.1 7,10 ]-3-dodecene, and the norbornene compound is bicyclo [2.2.1] hept-2-ene.
2. The sealant film according to claim 1 , wherein the polycycloolefin of the polycycloolefin layer is a ring-opening metathesis polymer of the ternary copolymer made of tricyclo [5.2.1.0 2,6 ] deca-3,8-diene, tetracyclo [4.4.0.1 2,5 0.1 7,10 ]-3-dodecene, and bicyclo [2.2.1] hept-2-ene, and carbon-carbon double bonds are hydrogenated.
3. A multilayer film comprising:
a base sheet; and
the sealant film according to claim 1 ,
the sealant film being stacked on the base sheet.
4. The multilayer film according to claim 3 , further comprising a gas barrier film stacked between the base sheet and the sealant film.
5. The multilayer film according to claim 3 having a thickness less than or equal to 100 μm.
6. A packaging bag comprising two of the multilayer films according to claim 3 sealed such that the sealant films of said multilayer films are fused to each other.
7. The sealant film of claim 1 , wherein
the polyolefin layer has a thickness greater than or equal to 10 μm and less than or equal to 40 μm, and
the polycycloolefin layer has a thickness greater than or equal to 5 μm and less than or equal to 20 μm.
8. The sealant film of claim 1 , wherein
the polycycloolefin layer has a thickness (T2) greater than or equal to 5 μm and less than or equal to 10 μm, and
a ratio (a) of a thickness (T1) of the polyolefin layer to the thickness (T2) of the polycycloolefin layer is greater than or equal to 3 and less than or equal to 9.
9. The sealant film according to claim 1 , wherein the polycycloolefin of the polycycloolefin layer contains 5 to 80 mol % of the structural unit (A) derived from a dicyclopentadiene compound, 10-90 mol % of the structural unit (B) derived from a tetracyclododecene compound and 5 to 50 mol % the structural unit (C) derived from a norbornene compound, and wherein the structural units (A), (B) and (C) together form 100 mol %.