Compositions and methods for carbon fiber-metal and other composites
The present disclosure generally relates to systems and methods for composites, including carbon fiber-metal composites. In some cases, the composites may be formed from one, two, or more layers of metals or other substrates, sandwiching a plurality of aligned fibers. The fibers may be substantially aligned, and may be present at relatively high densities within the composite. The composites may be prepared, in some aspects, by dispersing fibers by neutralizing the electrostatic interactions between the fibers, for example using aqueous liquids containing the fibers that are able to neutralize the electrostatic interactions that typically occur between the fibers. In some cases, the fibers may be aligned using techniques such as shear flow and/or magnetism. Other aspects are generally directed to methods of using such composites, kits including such composites, or the like.
1. An article, comprising:
a composite comprising a first substantially metallic layer and a second substantially metallic layer, a core layer positioned between the first substantially metallic layer and the second substantially metallic layer, and a first polymer layer and a second polymer layer sandwiching the core layer,
wherein the core layer comprises a plurality of discontinuous fibers substantially transversely aligned in parallel at a fiber volume fraction of between 5 vol % and 91 vol % within the composite, wherein the discontinuous fibers have an average diameter of at least 10 micrometers and consist essentially of one material, wherein the material is carbon.
2. The article of claim 1 , wherein the first substantially metallic layer comprises steel.
3. The article of claim 1 , wherein the first substantially metallic layer comprises an alloy of steel.
4. The article of claim 1 , wherein the first substantially metallic layer comprises at least 80 wt % steel.
5. The article of claim 1 , wherein the discontinuous fibers are aligned substantially orthogonally to the first substantially metallic layer.
6. The article of claim 1 , wherein the composite further comprises a third substantially metallic layer, and a second core layer positioned between the second substantially metallic layer and the third substantially metallic layer.
7. The article of claim 6 , wherein the second core layer comprises a plurality of discontinuous fibers substantially transversely aligned at a fiber volume fraction of at least 30 vol % within the second core layer.
8. The article of claim 1 , wherein the discontinuous fibers have a carbon content greater than 94% and a modulus of at least 200 GPa.
9. The article of claim 1 , wherein the discontinuous fibers are coated with a coating.
10. The article of claim 1 , wherein the discontinuous fibers are coated with sizing.
11. The article of claim 1 , wherein the discontinuous fibers have an anisotropic diamagnetic response in response to a magnetic field.
12. The article of claim 1 , wherein the discontinuous fibers exhibit a physical response to a magnetic field strength of 10 T.
13. The article of claim 1 , wherein at least 50 vol % and no more than 91 vol % of the plurality of discontinuous fibers are substantially transversely aligned.
14. The article of claim 1 , wherein at least some of the plurality of discontinuous fibers have a plurality of magnetic particles adsorbed thereto.
15. The article of claim 1 , wherein the plurality of discontinuous fibers are free of magnetic particles.
16. The article of claim 1 , wherein the composite is substantially free of paramagnetic or ferromagnetic materials.
17. The article of claim 1 , wherein the discontinuous fibers comprise at least 20 vol % and no more than 91 vol % of the volume of the composite.
18. The article of claim 1 , wherein the composite further comprises a binder binding the first substantially metallic layer and the second substantially metallic layer, and the plurality of discontinuous fibers.
19. The article of claim 1 , wherein the plurality of discontinuous fibers are substantially transversely aligned in parallel such that the plurality of discontinuous fibers exhibit an alignment such that at least 50% of the fibers exhibit an alignment that is within 20° of the average alignment of the plurality of the fibers.
20. An article, comprising:
a composite comprising a first polymer layer and a second polymer layer, and a core layer positioned between the first layer and the second layer, wherein the core layer comprises a plurality of discontinuous fibers substantially transversely aligned in parallel at a fiber volume fraction of between 5 vol % and 91 vol % within the composite, wherein the discontinuous fibers have an average diameter of at least 10 micrometers and consist essentially of one material, wherein the material is carbon.
21. The article of claim 20 , wherein the discontinuous fibers are aligned substantially orthogonally to the first polymer layer.
22. The article of claim 20 , wherein the composite further comprises a third polymer layer, and a second core layer positioned between the second polymer layer and the third polymer layer.
23. The article of claim 22 , wherein the second core layer comprises a plurality of discontinuous fibers substantially transversely aligned at a fiber volume fraction of at least 30 vol% within the second core layer.
24. The article of claim 20 , wherein the discontinuous fibers have a carbon content greater than 94% and a modulus of at least 200 GPa.
25. The article of claim 20 , wherein the discontinuous fibers are coated with a coating.
26. The article of claim 20 , wherein the discontinuous fibers are coated with sizing.
27. The article of claim 20 , wherein the discontinuous fibers have an anisotropic diamagnetic response in response to a magnetic field.
28. The article of claim 20 , wherein the discontinuous fibers exhibit a physical response to a magnetic field strength of 10 T.
29. The article of claim 20 , wherein at least 50 vol% and no more than 91 vol% of the plurality of discontinuous fibers are substantially transversely aligned.
30. The article of claim 20 , wherein at least some of the plurality of discontinuous fibers have a plurality of magnetic particles adsorbed thereto.
31. The article of claim 20 , wherein the plurality of discontinuous fibers are free of magnetic particles.
32. The article of claim 20 , wherein the composite is substantially free of paramagnetic or ferromagnetic materials.
33. The article of claim 20 , wherein the discontinuous fibers comprise at least 20 vol% and no more than 91 vol% of the volume of the composite.
34. The article of claim 20 , wherein the composite further comprises a binder binding the first polymer layer and the second polymer layer, and the plurality of discontinuous fibers.
35. The article of claim 20 , wherein the plurality of discontinuous fibers are substantially transversely aligned in parallel such that the plurality of discontinuous fibers exhibit an alignment such that at least 50% of the fibers exhibit an alignment that is within 20° of the average alignment of the plurality of the fibers.