Organic electroluminescence device and polycyclic compound for organic electroluminescence device

1. An organic electroluminescence device comprising:

a first electrode;

a hole transport region on the first electrode;

an emission layer on the hole transport region;

an electron transport region on the emission layer; and

a second electrode on the electron transport region,

wherein the first electrode and the second electrode each independently comprise at least one selected from the group consisting of Ag, Mg, Cu, Al, Pt, Pd, Au, Ni, Nd, Ir, Cr, Li, Ca, LiF/Ca, LiF/AI, Mo, Ti, In, Sn, and Zn, a compound of two or more thereof, a mixture of two or more thereof, and an oxide thereof, and

wherein the emission layer comprises a polycyclic compound represented by Formula 3:

in Formula 3,

Ring A and Ring B are each independently a substituted or unsubstituted aryl group having 6 to 30 carbon atoms for forming a ring, or a substituted or unsubstituted heteroaryl group having 2 to 30 carbon atoms for forming a ring, and at least one selected from Ring A or Ring B is represented by Formula 2,

wherein when Ring A is Formula 2, R 1 and R 2 are combined to form a ring:

in Formula 2,

X and Y are O, X and Y are S, X is O and Y is S, X is S and Y is O, or

X and Y are each independently a direct bond, SO, SO 2 , Se, PR 4 , POR 5 , PSR 6 , SiR 7 F 8 , GeR 9 R 10 or BR 11 , provided that X and Y are not both a direct bond at the same time, and

R 1 and R 2 are each independently a hydrogen atom, a deuterium atom, a halogen atom, a cyano group, a substituted or unsubstituted oxy group, a substituted or unsubstituted thiol group, a substituted or unsubstituted amine group, a phosphine oxide group, a phosphine sulfide group, a silyl group, a carbonyl group, a boron group, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms for forming a ring, or a substituted or unsubstituted heteroaryl group having 2 to 30 carbon atoms for forming a ring,

R 4 to R 11 are each independently a hydrogen atom, a deuterium atom, a halogen atom, a cyano group, a substituted or unsubstituted oxy group, a substituted or unsubstituted thiol group, a substituted or unsubstituted amine group, a phosphine oxide group, a phosphine sulfide group, a silyl group, a carbonyl group, a boron group, a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms, a substituted or unsubstituted aralkyl group having 7 to 30 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms for forming a ring, or a substituted or unsubstituted heteroaryl group having 2 to 30 carbon atoms for forming a ring,

wherein one or more selected from R 1 , R 2 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 , or R 11 are optionally combined with an adjacent group to form a ring,

Ring L is a substituted or unsubstituted aryl group having 6 to 30 carbon atoms for forming a ring, or a substituted or unsubstituted heteroaryl group having 2 to 30 carbon atoms for forming a ring,

Z and Z′ are each independently selected from BAr 2 , POAr 3 , PSAr 4 , SiAr 5 Ar 6 , or GeAr 7 Ar 8 ,

and

Ar 2 to Ar 8 are each independently a substituted or unsubstituted amino group, a substituted or unsubstituted oxy group, a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms for forming a ring, a substituted or unsubstituted aralkyl group having 7 to 30 carbon atoms, or a substituted or unsubstituted heteroaryl group having 2 to 30 carbon atoms for forming a ring, wherein Z and Z′ in Formula 3 are the same.

2. The organic electroluminescence device of claim 1 , wherein the emission layer is configured to emit delayed fluorescence.

3. The organic electroluminescence device of claim 1 , wherein the emission layer is a thermally activated delayed fluorescence emission layer configured to emit blue light.

4. The organic electroluminescence device of claim 1 , wherein Z is BAr 2 .

5. The organic electroluminescence device of claim 4 , wherein Z is represented by Formula 5:

in Formula 5,

V 1 to V 5 are each independently CR 12 or N, and

R 12 is a hydrogen atom, a deuterium atom, a halogen atom, a cyano group, a substituted or unsubstituted oxy group, a substituted or unsubstituted thiol group, a substituted or unsubstituted amine group, a phosphine oxide group, a phosphine sulfide group, a silyl group, a carbonyl group, a boron group, a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms, a substituted or unsubstituted aralkyl group having 7 to 30 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms for forming a ring, or a substituted or unsubstituted heteroaryl group having 2 to 30 carbon atoms for forming a ring, wherein R 12 is optionally bonded to adjacent group to form a ring.

6. The organic electroluminescence device of claim 5 ,

wherein V 1 to V 5 are each independently CR 12 , and

R 12 is a hydrogen atom, a deuterium atom, or a substituted or unsubstituted alkyl group having 2 to 10 carbon atoms.

7. A polycyclic compound represented by Formula 3:

in Formula 3,

Ring A and Ring B are each independently a substituted or unsubstituted aryl group having 6 to 30 carbon atoms for forming a ring, or a substituted or unsubstituted heteroaryl group having 2 to 30 carbon atoms for forming a ring, and at least one selected from Ring A or Ring B is represented by Formula 2,

wherein when Rind A is Formula 2, R 1 and R 2 are combined to form a ring:

in Formula 2,

X and Y are O, X and Y are S, X is O and Y is S, X is S and Y is O, or

X and Y are each independently a direct bond, SO, SO 2 , Se, PR 4 , POR 5 , PSR 6 , SiR 7 R 8 , GeR 9 R 10 or BR 11 , provided that X and Y are not both a direct bond at the same time, and

R 1 and R 2 are each independently a hydrogen atom, a deuterium atom, a halogen atom, a cyano group, a substituted or unsubstituted oxy group, a substituted or unsubstituted thiol group, a substituted or unsubstituted amine group, a phosphine oxide group, a phosphine sulfide group, a silyl group, a carbonyl group, a boron group, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms for forming a ring, or a substituted or unsubstituted heteroaryl group having 2 to 30 carbon atoms for forming a ring,

R 4 to R 11 are each independently a hydrogen atom, a deuterium atom, a halogen atom, a cyano group, a substituted or unsubstituted oxy group, a substituted or unsubstituted thiol group, a substituted or unsubstituted amine group, a phosphine oxide group, a phosphine sulfide group, a silyl group, a carbonyl group, a boron group, a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms, a substituted or unsubstituted aralkyl group having 7 to 30 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms for forming a ring, or a substituted or unsubstituted heteroaryl group having 2 to 30 carbon atoms for forming a ring,

wherein one or more selected from R 1 , R 2 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 , or R 11 are optionally combined with an adjacent group to form a ring,

Ring L is a substituted or unsubstituted aryl group having 6 to 30 carbon atoms for forming a ring, or a substituted or unsubstituted heteroaryl group having 2 to 30 carbon atoms for forming a ring,

Z and Z′ are each independently selected from BAr 2 , POAr 3 , PSAr 4 , SiAr 5 Ar 6 , or GeAr 7 Ar 8 , and

Ar 2 to Ar 8 are each independently a substituted or unsubstituted amino group, a substituted or unsubstituted oxy group, a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms for forming a ring, a substituted or unsubstituted aralkyl group having 7 to 30 carbon atoms, or a substituted or unsubstituted heteroaryl group having 2 to 30 carbon atoms for forming a ring, wherein Z and Z′ in Formula 3 are the same.

8. The polycyclic compound of claim 7 , wherein Z is BAr 2 .

9. The polycyclic compound of claim 8 , wherein Z is represented by Formula 5:

in Formula 5,

V 1 to V 5 are each independently CR 12 or N, and

R 12 is a hydrogen atom, a deuterium atom, a halogen atom, a cyano group, a substituted or unsubstituted oxy group, a substituted or unsubstituted thiol group, a substituted or unsubstituted amine group, a phosphine oxide group, a phosphine sulfide group, a silyl group, a carbonyl group, a boron group, a substituted or unsubstituted alkyl group having 1 to 10 carbon atoms, a substituted or unsubstituted aralkyl group having 7 to 30 carbon atoms, a substituted or unsubstituted aryl group having 6 to 30 carbon atoms for forming a ring, or a substituted or unsubstituted heteroaryl group having 2 to 30 carbon atoms for forming a ring, wherein R 12 is optionally bonded to adjacent group to form a ring.

10. The polycyclic compound of claim 9 ,

wherein V 1 to V 5 are each independently CR 12 , and

R 12 is a hydrogen atom, a deuterium atom, or a substituted or unsubstituted alkyl group having 2 to 10 carbon atoms.

11. An organic electroluminescence device comprising:

a first electrode;

a hole transport region on the first electrode;

an emission layer on the hole transport region;

an electron transport region on the emission layer; and

a second electrode on the electron transport region,

wherein the first electrode and the second electrode each independently comprise at least one selected from the group consisting of Ag, Mg, Cu, Al, Pt, Pd, Au, Ni, Nd, Ir, Cr, Li, Ca, LiF/Ca, LiF/AI, Mo, Ti, In, Sn, and Zn, a compound of two or more thereof, a mixture of two or more thereof, and an oxide thereof, and

wherein the emission layer comprises the polycyclic compound of claim 7 .

12. The organic electroluminescence device of claim 11 , wherein the emission layer is configured to emit delayed fluorescence.

13. The organic electroluminescence device of claim 11 ,

wherein the emission layer is a delayed fluorescence emission layer comprising a host and a dopant,

wherein the dopant is the polycyclic compound.

14. The organic electroluminescence device of claim 11 , wherein the emission layer is a thermally activated delayed fluorescence emission layer configured to emit blue light.