IP Library › Granted Patent US 11,831,038
Granted Patent B2
US 11,831,038 · App. 16/960,086 · Granted Nov 28, 2023

Composition for lithium ion secondary battery separator, two-part composition for lithium ion secondary battery separator, method of producing separator for lithium ion secondary battery, and method of producing lithium ion secondary battery

Inventor: Kazuki Asai (Tokyo, JP)
Assignee: ZEON CORPORATION
H01M50/403H01M10/0525H01M50/411H01M50/414H01M50/42H01M50/489
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Quick Facts
Patent No.
US 11,831,038
App. No.
16/960,086
Granted
Nov 28, 2023
Kind
B2
Abstract

Provided are a composition for a lithium ion secondary battery separator containing: a liquid medium; and 40 mass % or less of a first compound including a function-displaying functional group and having a molecular weight of 50,000 or less, and having a surface tension of 15 mN/m to 30 mN/m, and a two-part composition for a lithium ion secondary battery separator including: a first liquid containing a first compound and first liquid medium; and a second liquid containing a second compound and second liquid medium, wherein the first compound includes a function-displaying functional group and has a molecular weight of 50,000 or less, the second compound is reactive with the first compound and has a molecular weight of 50,000 or less, and the first and second liquids each contain the corresponding compound in a proportion of 40 mass % or less and have a surface tension of 15 mN/m to 30 mN/m.

Claims (34)

1. A composition for a lithium ion secondary battery separator comprising:

a first compound including a function-displaying functional group and having a molecular weight of 50,000 or less; and

a liquid medium, wherein

the function-displaying functional group includes at least one type of acidic functional group,

the first compound is at least one compound selected from the group consisting of polyacrylic acid having a molecular weight of 3,000 or more, a copolymer of acrylic acid and a sulfo group-containing monomer having a molecular weight of 3,000 or more, allyl sulfonic acid, 2-acrylamido-2-methylpropane sulfonic acid, 2-hydroxy-2-allyloxypropane sulfonic acid, styrene sulfonic acid, isoprene sulfonic acid, dodecylbenzenesulfonic acid, dioctyl sulfosuccinic acid, and a salt of either of the preceding compounds, and contained in a proportion of 3 mass % or more and 40 mass % or less, and

the composition for a lithium ion secondary battery separator has a surface tension of not less than 15 mN/m and not more than 30 mN/m.

2. The composition for a lithium ion secondary battery separator according to claim 1 , wherein the liquid medium includes water.

3. The composition for a lithium ion secondary battery separator according to claim 1 , further comprising a second compound that has a molecular weight of 50,000 or less and that is reactive with the first compound, wherein

the first compound and the second compound are contained in a total proportion of 40 mass % or less.

4. The composition for a lithium ion secondary battery separator according to claim 3 , wherein the second compound includes at least one type of basic functional group.

5. The composition for a lithium ion secondary battery separator according to claim 3 , wherein

the second compound is a cross-linker that cross-links molecules of the macromolecular compound.

6. A method of producing a separator for a lithium ion secondary battery comprising:

a step of impregnating a separator substrate comprising a microporous membrane made from a resin with the composition for a lithium ion secondary battery separator according to claim 1 ; and

a step of drying the separator substrate that has been impregnated with the composition for a lithium ion secondary battery separator.

7. The method of producing a separator for a lithium ion secondary battery according to claim 6 , wherein the separator substrate has an air resistance of not less than 10 s/100 cc-air and not more than 1,000 s/100 cc-air.

8. A method of producing a lithium ion secondary battery that includes a positive electrode, a negative electrode, a separator, and an electrolyte solution, comprising a step of producing a separator using the method of producing a separator for a lithium ion secondary battery according to claim 6 .

9. A two-part composition for a lithium ion secondary battery separator comprising:

a first liquid containing a first compound and a first liquid medium; and

a second liquid containing a second compound and a second liquid medium, wherein

the first compound includes a function-displaying functional group and has a molecular weight of 50,000 or less,

the function-displaying functional group includes at least one type of acidic functional group,

the second compound is reactive with the first compound and has a molecular weight of 50,000 or less,

the first compound is at least one compound selected from the group consisting of polyacrylic acid having a molecular weight of 3,000 or more, a copolymer of acrylic acid and a sulfo group-containing monomer having a molecular weight of 3,000 or more, allyl sulfonic acid, 2-acrylamido-2-methylpropane sulfonic acid, 2-hydroxy-2-allyloxypropane sulfonic acid, styrene sulfonic acid, isoprene sulfonic acid, dodecylbenzenesulfonic acid, dioctyl sulfosuccinic acid, and a salt of either of the preceding compounds,

the first liquid contains the first compound in a proportion of 3 mass % or more and 40 mass % or less and has a surface tension of not less than 15 mN/m and not more than 30 mN/m, and

the second liquid contains the second compound in a proportion of 40 mass % or less and has a surface tension of not less than 15 mN/m and not more than 30 mN/m.

10. The two-part composition for a lithium ion secondary battery separator according to claim 9 , wherein

the second compound includes at least one type of basic functional group.

11. The two-part composition for a lithium ion secondary battery separator according to claim 9 , wherein the first liquid medium and the second liquid medium include water.

12. A method of producing a separator for a lithium ion secondary battery using the two-part composition for a lithium ion secondary battery separator according to claim 9 , comprising:

a first step of impregnating a separator substrate comprising a microporous membrane made from a resin with one of the first liquid and the second liquid;

a second step of drying the separator substrate that has been impregnated with one of the first liquid and the second liquid;

a third step of impregnating the separator substrate that has been dried with the other of the first liquid and the second liquid after the second step; and

a fourth step of drying the separator substrate that has been impregnated with the other of the first liquid and the second liquid.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 6, 2020
From: ASAI, KAZUKI
To: ZEON CORPORATION
Reel/Frame 053123/0740 →
Priority Claims (1)
JP 2018-015694 · Jan 31, 2018 · national
Continuity (1)
Related Publication 20210066691A1 · Mar 4, 2021