Accelerator comprising starch, and related board, slurries, and methods
An accelerator for accelerating the rate of hydration of calcined gypsum is disclosed. The accelerator comprises calcium sulfate dihydrate particles and a starch. The starch has a cold water solubility of at least about 25% (e.g., at least about 35%) and a viscosity of about 25 Brabender Units (BU) or less when the starch is in a 30% aqueous slurry at 92° C. Also disclosed are a method of preparing an accelerator, method of hydrating stucco to form set gypsum, slurry, and method of making gypsum board.
1. An accelerator for use in accelerating the rate of hydration of calcined gypsum to set gypsum in gypsum slurries for producing gypsum wallboard panels, said accelerator comprising: particles of calcium sulfate dihydrate having an average particle size of from 20 μm to 50 μm, and starch having a cold water solubility of at least about 25% and a viscosity of 25 Brabender Units (BU) or less when the starch is in a 30% solids aqueous slurry at 92° C., wherein the starch is an acid-hydrolyzed starch, and wherein said accelerator has a time to 50% hydration of between 2.42 and 3.83 minutes.
2. The accelerator of claim 1 , wherein the starch has a cold water solubility of at least about 35%.
3. The accelerator of claim 2 , wherein the accelerator is prepared by co-grinding the calcium sulfate dihydrate in the presence of the starch.
4. The accelerator of claim 3 , wherein the starch has an average particle size of from about 20 μm to about 100 μm prior to co-grinding.
5. The accelerator of claim 3 , wherein the starch is present in an amount from about 1% to about 10% by weight of the accelerator.
6. The accelerator of claim 3 , wherein the co-grinding occurs in a ball mill.
7. The accelerator of claim 3 , wherein the co-grinding occurs for a period of from about 10 minutes to about 90 minutes.
8. A method of preparing gypsum board comprising: (a) providing a first cover sheet; (b) mixing a first slurry comprising stucco, water, and an accelerator comprising calcium sulfate dihydrate particles having an average particle size of from 20 μm to 50 μm and starch having a cold water solubility of at least about 25%, and a viscosity of about 25 Brabender Units (BU) or less when the starch is in a 30% solids aqueous starch slurry at 92° C., wherein the starch is an acid-hydrolyzed starch, and wherein said accelerator has a time to 50% hydration of between 2.42 and 3.83 minutes; (c) disposing the first μslurry between the first cover sheet and a second cover sheet to form an assembly; (d) cutting the assembly into a board; and (e) drying the board.
9. The method of claim 8 , wherein the first slurry further comprises polyphosphate.
10. The method of claim 8 , wherein the first slurry further includes a pregelatinized starch.
11. The method of claim 10 , wherein the pregelatinized starch has a viscosity of from about 20 centipoise to about 500 centipoise, as measured according to the VMA method.
12. The method of claim 8 , wherein the first slurry further includes uncooked starch having a peak viscosity of from about 100 Brabender Units to about 900 Brabender units when the viscosity is measured by putting the uncooked starch in a second slurry with water at an uncooked starch concentration of 15% solids, and using a Viscograph-E instrument set at 75 rpm and 700 cmg, where the uncooked starch is heated from 25° C. to 95° C. at a rate of 3° C./minute, the second slurry is held at 95° C. for ten minutes, and the starch in the second slurry is cooled to 50° C. at a rate of −3° C./minute.