IP Library › Granted Patent US 11,840,775
Granted Patent B2
US 11,840,775 · App. 17/617,325 · Granted Dec 12, 2023

Fiber comprising propylene ethylene random copolymer

Inventors: Roberto De Palo (Ferrara, IT); Davide Tartari (Ferrara, IT); Monica Galvan (Ferrara, IT); Claudio Cavalieri (Ferrara, IT); Isabella Maria Vittoria Camurati (Ferrara, IT)
Assignee: Basell Poliolefine Italia S.r.l.
D01F6/30C08F210/06D01F8/06C08F2800/20
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Quick Facts
Patent No.
US 11,840,775
App. No.
17/617,325
Granted
Dec 12, 2023
Kind
B2
Abstract

A fiber of a propylene ethylene copolymer having: i) xylene soluble fraction at 25° C. ranging from 14 wt % to 27 wt %; ii) intrinsic viscosity of the fraction soluble in xylene at 25° C. ranging from 1.0 to 2.4 dl/g; iii) melt flow rate, MFR, ranging from 12 g/10 min to 60 g/10 min; iv) an ethylene derived units content ranging from 5.0 wt % to 12.0 wt %; v) the ethylene derived units content of the fraction insoluble in xylene at 25° C. ranging from 2.5 wt % to 6.0 wt %; vi) the ethylene derived units content of the fraction soluble in xylene at 25° C. ranging from 15.2. wt % to 30.2 wt % vii) C 13 NMR sequences PEP measured on the fraction insoluble in xylene at 25° C. ranging from 3.5 mol % to 5.5 mol %; and viii) the C 13 NMR sequences PEP measured on the fraction soluble in xylene at 25° C. ranging from 11.0 mol % to 14.2 mol %.

Claims (24)

1. A fiber comprising:

a propylene ethylene copolymer having:

i) a xylene soluble fraction at 25° C. ranging from 14 wt % to 27 wt %, based upon the total weight of the propylene ethylene copolymer;

ii) an intrinsic viscosity of the fraction soluble in xylene at 25° C. ranging from 1.0 to 2.4 dl/g;

iii) a melt flow rate, MFR, measured according to ISO 1133 at 230 ° C. with a load of 2.16 kg, ranging from 12 g/10 min to 60.0 g/10 min;

iv) an ethylene derived units content ranging from 5.0 wt % to 12.0 wt %, based upon the total weight of the propylene ethylene copolymer;

v) the ethylene derived units content of the fraction insoluble in xylene at 25° C. ranging from 2.5 wt % to 6.0 wt %;

vi) the ethylene derived units content on the fraction soluble in xylene at 25° C. ranging from 15.2 wt % to 30.2 wt %;

vii) C 13 NMR sequences PEP measured on the fraction insoluble in xylene at 25° C. ranging from 3.5 mol % to 5.5 mol %; and

viii) C 13 NMR sequences PEP measured on the fraction soluble in xylene at 25° C. ranging from 11.0 mol % to 14.2 mol %.

2. The fiber according claim 1 , wherein, in the propylene ethylene copolymer, the melt flow rate, MFR, measured according to ISO 1133 at 230° C. with a load of 2.16 kg, ranges from 15.0 g/10 min to 50.0 g/10 min.

3. The fiber according to claim 1 , wherein, in the propylene ethylene copolymer, the xylene soluble fraction at 25° C. ranges from 17 wt % to 25 wt %.

4. The fiber according to claim 1 , wherein, in the propylene ethylene copolymer, the intrinsic viscosity of the fraction soluble in xylene at 25° C. ranges from 1.5 to 2.2 dl/g.

5. The fiber according to claim 1 , wherein, in the propylene ethylene copolymer, the melt flow rate, MFR, measured according to ISO 1133 at 230° C. with a load of 2.16 kg, ranges from 18.6 g/10 min to 30.0 g/10 min.

6. The fiber according to claim 1 , wherein, in the propylene ethylene copolymer, the C 13 NMR sequences PEP measured on the fraction insoluble in xylene at 25° C. ranges from 3.8 mol % to 5.2 mol %; and the C 13 NMR sequences PEP measured on the fraction soluble in xylene at 25° C. ranges from 11.5 mol % to 13.8 mol %.

7. The fiber according to claim 1 , wherein, in the propylene ethylene copolymer, the C 13 NMR sequences PEP measured on the fraction insoluble in xylene at 25° C. ranges from 3.9 mol % to 4.8 mol %; and the C 13 NMR sequences PEP measured on the fraction soluble in xylene at 25° C. ranges from 12.3 mol % to 13.5 mol %.

8. The fiber according to claim 1 , wherein, in the propylene ethylene copolymer, the ethylene derived units content of the fraction insoluble in xylene at 25° C. ranges from 3.2 wt % to 5.2 wt %.

9. The fiber according to claim 1 , wherein, in the propylene ethylene copolymer, the ethylene derived units content of the fraction soluble in xylene at 25° C. ranges from 17.2 wt % to 24.8 wt %.

10. The fiber according to claim 1 , wherein, in the propylene ethylene copolymer, the C 13 NMR sequences PEE measured on the fraction soluble in xylene at 25° C. range from 7.2 mol % to 12.0 mol %.

11. The fiber according to claim 1 , wherein, in the propylene ethylene copolymer, the C 13 NMR sequences EEE measured on the fraction soluble in xylene at 25° C. are lower than 6.5 mol %.

12. The fiber according to claim 1 , wherein, in the propylene ethylene copolymer, the product of reactivity ratio r1r2 of the fraction insoluble in xylene at 25° C. measured with C 13 NMR is between 2.4 and 4.6.

13. The fiber according to claim 1 comprising a skin-core structure wherein the skin, the core, or both of the fiber comprise the propylene ethylene copolymer.

14. The fiber according to claim 13 , wherein both the skin and core of the fiber comprise the propylene ethylene copolymer .

15. Non-woven fabrics comprising a fiber according to claim 1 .

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 25, 2022
From: DE PALO, ROBERTO; TARTARI, DAVIDE; GALVAN, MONICA; CAVALIERI, CLAUDIO; CAMURATI, ISABELLA MARIA VITTORIA
To: BASELL POLIOLEFINE ITALIA, S.R.L.
Reel/Frame 060604/0163 →
Priority Claims (1)
EP 19179504 · Jun 11, 2019 · regional
Continuity (1)
Related Publication 20220228298A1 · Jul 21, 2022