Method for preparing a foam control composition in a granular or a powder form
The present disclosure generally relates to a method for preparing a powder or granular foam control compositions and methods for reducing or preventing or breaking foam in various applications such as powder detergents as well as coatings, cementing, concrete, gypsum board and other construction type applications or in some agricultural formulations like fertilizers, herbicides and pesticides.
1. A method for preparing a foam control composition X in a granular or a powder form, said process comprising the steps of:
a) providing an aqueous dispersion, an aqueous solution or an aqueous concentrate in a liquid form comprising at least one water-soluble or water-dispersible organic polymer A bearing polyacid groups or polyamino groups which is partially salified, or fully salified;
b) mixing said aqueous dispersion, said aqueous solution or said aqueous concentrate comprising said water-soluble or water-dispersible organic polymer A with a foam control agent B which is provided either as a liquid concentrate, as an aqueous dispersion or as an emulsion to form a liquid mixture, and wherein said components are added so that the water-soluble or water-dispersible organic polymer A to foam control agent B weight percent ratio is from 99.9:0.1 to 55:45, and
c) drying the resulting liquid mixture to recover the granular or powder foam control composition X comprising the polymer A and the foam control agent B wherein the water-soluble or water-dispersible organic polymer A to foam control agent B weight percent ratio is from 99.9:0.1 to 55:45,
wherein the polymer A is selected from the group consisting of lignosulfonate salts, copolymers of acrylic acid and 2-acrylamido-2-methylpropanesulfonic acid in their corresponding partially or fully salified forms, copolymers of acrylic acid and styrene sulfonate in their corresponding partially or fully salified forms, and mixtures thereof.
2. The method according to claim 1 wherein said foam control agent B is free of said polymer A.
3. The method according to claim 1 wherein the foam control agent B is selected from the group consisting of silicone antifoaming agents; alkoxylated alcohols; ethylene oxide/propylene oxide block copolymers; organic esters of ethylene oxide/propylene oxide block copolymers; organic esters of polyethylene glycol; polypropylene glycol; mixtures of organic esters of polyethylene glycol and polypropylene glycol; hydrophobic silica; and mixtures thereof.
4. The method according to claim 1 wherein the foam control agent B is a silicone defoaming agent in combination with a hydrophobic silica.
5. The method according to claim 1 wherein in step b) a surfactant is mixed with said aqueous dispersion, said aqueous solution or said aqueous concentrate comprising polymer A and foam control agent B to form the liquid mixture.
6. The method according to claim 1 wherein a spray dryer is used in step c) for drying the resulting mixture.