Lithium titanate powder and active material ingredient for electrode of power storage device, and electrode sheet and power storage device using same

1. A lithium titanate powder, comprising Li 4 Ti 5 O 12 as a main component,

having a specific surface area of 4 m 2 /g or more and 25 m 2 /g or less, and

comprising at least one localized element selected from the group consisting of M1 where M1 is at least one metal element selected from W and Mo,

wherein M1 as the localized element are localized on or near surfaces of lithium titanate particles forming the lithium titanate powder.

2. The lithium titanate powder according to claim 1 ,

wherein boron (B) is contained as the localized element,

B B (mass %) is 0.05 or more and 1.0 or less where B B is defined as the content of boron (B) determined by inductively coupled plasma atomic emission spectroscopy (ICP-AES),

a peak attributed to B—O bond is observed in a spectrum of B1s in surface analysis by X-ray photoelectron spectroscopy (XPS), and

a relation represented by the following expression (I) is satisfied:

10≤(B S ×S)≤100  (I)

wherein B S (atm %) is the concentration of boron (B) determined based on a peak area in the spectrum of B1s in surface analysis by X-ray photoelectron spectroscopy (XPS) and S (m 2 /g) is the specific surface area.

3. The lithium titanate powder according to claim 1 ,

wherein Ln is contained as the localized element,

C Ln (mass %) is 0.1 or more and 5 or less, where C Ln is the content of Ln determined by inductively coupled plasma atomic emission spectroscopy (ICP-AES), and

a relation represented by the following expression (II) is satisfied:

1≤(C S1 ×S)≤100  (II)

wherein C S1 (atm %) is the concentration of Ln determined based on a peak area of a spectrum of Ln3d, Ln3d5/2, Ln4d, Ln4d5/2, Ln2p, or Ln2p3/2 in surface analysis by X-ray photoelectron spectroscopy (XPS) and S (m 2 /g) is the specific surface area.

4. The lithium titanate powder according to claim 1 ,

C M1 (mol %) is 0.01 or more and 0.9 or less, where C M1 is the content of M1 determined by inductively coupled plasma atomic emission spectroscopy (ICP-AES), and

a relation represented by the following expression (III) is satisfied:

1≤(C S2 ×S)≤100  (III)

wherein C S2 (atm %) is the concentration of M1 determined based on a peak area of a spectrum of W4d5/2 and/or Mo3d in surface analysis by X-ray photoelectron spectroscopy (XPS) and S (m 2 /g) is the specific surface area.

5. The lithium titanate powder for an electrode of an energy storage device according to claim 1 ,

wherein Ln is contained in the localized element,

C Ln (mass %) is 0.1 or more and 5 or less, where C Ln is the content of Ln determined by inductively coupled plasma atomic emission spectroscopy (ICP-AES), and

relations represented by the following expressions (IV) and (V) are satisfied:

D1>D2  (IV)

0.20≤D1/Dti≤2.0  (V)

wherein D1 (atm %) is the elemental concentration of Ln at a depth position of 1 nm from the surface of each lithium titanate particle, Dti (atm %) is the atomic concentration of titanium at a depth position of 1 nm therefrom, and D2 (atm %) is the elemental concentration of Ln at a depth position of 100 nm from the surface of each lithium titanate particle, the elemental concentrations and the atomic concentration being measured by energy dispersive X-ray spectroscopy in cross-sectional analysis of the lithium titanate particles forming the lithium titanate powder using a scanning transmission electron microscope.

6. The lithium titanate powder according to claim 1 ,

C M1 (mol %) is 0.01 or more and 0.9 or less, where C M1 is the content of M1 determined by inductively coupled plasma atomic emission spectroscopy (ICP-AES), and

relations represented by the following expressions (VI) and (VII) are satisfied:

E1>E2  (VI)

0.05≤E1/Eti≤6  (VII)

wherein E1 (atm %) is the elemental concentration of M1 at a depth position of 1 nm from the surface of each lithium titanate particle, Eti (atm %) is the atomic concentration of titanium at a depth position of 1 nm therefrom, and E2 (atm %) is the elemental concentration of M1 at a depth position of 100 nm from the surface of each lithium titanate particle, the elemental concentrations and the atomic concentration being measured by energy dispersive X-ray spectroscopy in cross-sectional analysis of the lithium titanate particles forming the lithium titanate powder using a scanning transmission electron microscope.

7. The lithium titanate powder according to claim 6 , wherein C M1 is 0.02 or more and 0.9 or less.

8. The lithium titanate powder according to claim 5 , wherein in the cross-sectional analysis of the lithium titanate particles forming the lithium titanate powder using the scanning transmission electron microscope, Ln is not detected at a position of 100 nm from the surfaces of the lithium titanate particles measured by energy dispersive X-ray spectroscopy.

9. The lithium titanate powder according to claim 6 , wherein in the cross-sectional analysis of the lithium titanate particles forming the lithium titanate powder using the scanning transmission electron microscope, M1 is not detected at a position of 100 nm from the surfaces of the lithium titanate particles measured by energy dispersive X-ray spectroscopy.

10. The lithium titanate powder for an electrode of an energy storage device according to claim 1 , wherein M2, where M2 is at least one element selected from the group consisting of elements of Groups 2, 12, and 13, is contained.

11. The lithium titanate powder according to claim 10 , wherein M2 is at least one element selected from the group consisting of B, Mg, Zn, Al, Ga, and In.

12. The lithium titanate powder according to claim 11 , wherein M2 is Al.

13. The lithium titanate powder according to claim 12 , wherein boron (B) is contained as the localized element, and

a ratio of A S to B S (A S /B S (atm %/atm %)) is 0.06 or more and 3 or less, where B S (atm %) is the concentration of boron (B) determined based on a peak area in a spectrum of B1s in surface analysis by X-ray photoelectron spectroscopy (XPS), and A S (atm %) is the concentration of Al determined based on a peak area in a spectrum of Al2s in surface analysis by X-ray photoelectron spectroscopy (XPS).

14. The lithium titanate powder for an electrode of an energy storage device according to claim 10 , wherein a relation represented by the following expression (VIII) is satisfied:

F1/F2≥5  (VIII)

wherein F1 (atm %) is the elemental concentration of M2 at an inner position of 1 nm from the surface of each lithium titanate particle, the inner position being located on a straight line which extends from the surface of each lithium titanate particle and is drawn orthogonal to a tangent of the surface of the lithium titanate particle, and F2 (atm %) is the elemental concentration of M2 at a depth position of 100 nm from the surface of the lithium titanate particle, the inner position being located on a straight line which extends from the surface of the lithium titanate particle and is drawn orthogonal to a tangent of the surface of the lithium titanate particle, the elemental concentrations being measured by energy dispersive X-ray spectroscopy in cross-sectional analysis of the lithium titanate particles forming the lithium titanate powder using a scanning transmission electron microscope.

15. The lithium titanate powder of claim 10 , wherein C M2 (mass %) is 0.01 or more and 1.0 or less, where C M2 is the content of M2 determined by inductively coupled plasma atomic emission spectroscopy (ICP-AES).

16. The lithium titanate powder according to claim 15 ,

wherein boron (B) is contained as the localized element, and

a ratio of C M2 to B B (C M2 /B B (mass %/mass %)) is 0.07 or more and 15 or less, where B B (mass %) is the content of boron (B) determined by inductively coupled plasma atomic emission spectroscopy (ICP-AES).

17. The lithium titanate powder according to claim 15 ,

wherein Ln is contained as the localized element, and

a ratio of C M2 to C Ln (C M2 /C Ln (mass %/mass %)) is 0.05 or more and 5.0 or less, where C Ln (mass %) is the content of Ln determined by inductively coupled plasma atomic emission spectroscopy (ICP-AES).

18. The lithium titanate powder according to claim 15 ,

wherein M1 is contained as the localized element,

a ratio of C M2 to C M1 (C M2 /C M1 (mol %/mol %)) is 0.3 or more and 30 or less, where C M i (mol %) is the content of M1 determined by inductively coupled plasma atomic emission spectroscopy (ICP-AES).

19. An active material comprising the lithium titanate powder according to claim 1 .

20. An electrode sheet, comprising the active material according to claim 19 .

21. An energy storage device comprising the active material according to claim 19 .

22. A lithium ion secondary battery comprising the active material according to claim 19 .

23. A hybrid capacitor comprising the active material according to claim 19 .