BCDA-based semi-alicyclic homo- or co-polyimide membrane materials for gas separation and the preparation method thereof
The present invention relates to a BCDA-based semi-alicyclic homo- or co-polyimide membrane material for gas separation and a preparation method thereof. The polyimide material prepared according to the present invention has high solubility in casting solvents, particularly in polar organic solvents, by interrupting asymmetry in the polyimide chain structure and formation of polyimide complexes compared with aromatic polyimides, and has higher heat resistance than the conventional aromatic polyimides and aliphatic polyimides, so that it is useful for the process of a high-selective permeable composite membrane or a asymmetric hollow fiber membrane used for commercial purposes, suggesting that it can be effectively used as a membrane for gas separation in various fields. In addition, the polyimide material membrane for gas separation of the present invention is useful because it has superior gas separation properties to the conventional commercialized aromatic polyimides or semi-alicyclic polyimides.
1. A homo- or co-polyimide material comprising a compound of Formula 1′:
wherein
is at least one compound selected from the group consisting of
wherein n is greater than or equal to 10.
2. The homo- or co-polyimide material according to claim 1 , wherein the homo- or co-polyimide material has an intrinsic viscosity (η int ) of 0.9-1.7 dL/g.
3. The homo- or co-polyimide material according to claim 1 , wherein the homo- or co-polyimide material is soluble in N-methyl-2-pyrrolidone (NMP), dimethylacetamide (DMAc), dimethylformamide (DMF), dimethylsulfoxide (DMSO), tetrahydrofuran (THF), acetone (AC), chloroform (CF), diethylacetate, y-butyrolactone, or a mixed solvent thereof.
4. A gas separation membrane comprising the homo- or co-polyimide material of claim 1 .
5. The gas separation membrane according to claim 4 , wherein the gas separation membrane is for the separation of one or more gases selected from the group consisting of hydrogen, methane, nitrogen, nitrous oxide, oxygen, carbon monoxide and carbon dioxide.
6. The gas separation membrane according to claim 4 , wherein the gas separation membrane is used for the purpose of obtaining high purity methane by eliminating carbon dioxide and moisture from natural gas; eliminating carbon dioxide from by-product gas in steel works and separating and concentrating hydrogen; separating and concentrating carbon dioxide and hydrogen in the course of methane reforming; and separating and concentrating nitrous oxide in the process of preparing adipic acid.
7. The gas separation membrane according to claim 4 , wherein the gas separation membrane is a gas separation membrane in which the homo- or co-polyimide material of claim 5 is processed into a membrane in the form of an asymmetric hollow fiber membrane through a phase-change process in the course of dry-jet wet spinning, or in the form of a composite membrane by coating a porous polyether or polypropylene support with the homo- or co-polyimide material.
8. A method for separating one or more gas from mixed gas using the gas separation membrane of claim 4 .
9. The method according to claim 8 , wherein the mixed gas is a mixture of one or more gas selected from the group consisting of H 2 , CO, CO 2 , CH 4 , N 2 , N 2 O and O 2 .
10. The method according to claim 8 , wherein the separated gas is H 2 if the mixed gas comprises H 2 /CH 4 ;
wherein the separated gas is CO 2 if the mixed gas comprises CO 2 /CH 4 or CO 2 /CO; or
wherein the separated gas is O 2 if the mixed gas comprises O 2 /N 2 .