Method for the pneumatic delivery of superabsorbent particles
A method of pneumatically conveying superabsorbent particles, wherein the superabsorbent particles have been admixed with an aqueous wax dispersion prior to the pneumatic conveying, the wax has a glass transition temperature of at least 65° C. and, based on the untreated superabsorbent particles, from 0.020% to 0.20% by weight of wax has been used.
1. A method of pneumatically conveying superabsorbent particles comprising admixing the superabsorbent particles with an aqueous wax dispersion prior to pneumatic conveying, wherein the wax has a glass transition temperature of at least 65° C. and, based on the untreated superabsorbent particles, from 0.020% to 0.20% by weight of wax is admixed.
2. The method according to claim 1 , wherein the wax has a glass transition temperature of at least 80° C.
3. The method according to claim 1 , wherein, based on the superabsorbent particles, from 0.035% to 0.08% by weight of wax is admixed.
4. The method according to claim 1 , wherein the wax is a copolymer of 70 to 95 mol % of at least one ethylenically unsaturated hydrocarbon and 5 to 30 mol % of at least one ethylenically unsaturated carboxylic acid.
5. The method according to claim 1 , wherein the superabsorbent particles have an average particle size of 250 to 500 μm.
6. The method according to claim 1 , wherein the superabsorbent particles have an average sphericity (ASPHT) of greater than 0.72.
7. The method according to claim 1 , wherein a temperature of the superabsorbent particles during the pneumatic conveying is at least 40° C., and at least 20° C. less than the glass transition temperature of the wax.
8. The method according to claim 1 , wherein an initial gas velocity in the pneumatic conveying corresponds to a Froude number of 2 to 40.
9. The method according to claim 1 , wherein a conveying material load in the pneumatic conveying is from 1 to 30 kg/kg and the conveying material load is the quotient of conveying material mass flow rate and gas mass flow rate.
10. A composition comprising superabsorbent particles and wax particles, wherein the wax particles are on the surface of the superabsorbent particles, the wax particles are dispersible in water and have a glass transition temperature of at least 65° C., a proportion of the wax particles based on the superabsorbent particles is from 0.02% to 0.2% by weight, and the composition has an absorption under a pressure of 4.83 kPa (AUL0.7 psi) of at least 10 g/g.
11. The composition according to claim 10 , wherein the wax has a glass transition temperature of at least 80° C.
12. The composition according to claim 10 , wherein, based on the superabsorbent particles, the proportion of wax particles is from 0.035% to 0.08% by weight of wax.
13. The composition according to claim 10 , wherein the wax is a copolymer of 5 to 30 mol % of at least one ethylenically unsaturated carboxylic acid and 70 to 95 mol % of at least one ethylenically unsaturated hydrocarbon.
14. The composition according to claim 10 , wherein the superabsorbent particles have an average particle size of 250 to 500 μm.
15. The composition according to claim 10 , wherein the superabsorbent particles have an average sphericity (ASPHT) of greater than 0.72.