Method of treating a mining insert
A method of treating a sintered mining insert including cemented carbide includes the step of subjecting the mining insert to a surface hardening process. The surface hardening process is executed at an elevated temperature of or above 100° C. A mining insert is also provided, wherein the HV1 Vickers hardness measurement increase (HV1%) from the surface region, measured as an average of HV1 measurements taken at 100 μm, 200 μm and 300 μm below the surface, compared to the HV1 Vickers hardness measured in the bulk (HV1bulk), is at least 8.05-0.00350×HV1bulk.
1. A method of treating a sintered mining insert including cemented carbide, wherein the cemented carbide comprises hard constituents in a metallic binder phase, and wherein the metallic binder phase content in the cemented carbide is 4 to 30 wt %, wherein the metallic binder phase comprises at least 80 wt % of one or more metallic elements selected from Co, Ni and Fe; wherein the hard phase comprises at least 80 wt % WC, the method comprising:
subjecting the mining insert to a surface hardening process, wherein the surface hardening process is tumbling, wherein the tumbling process is conducted in dry conditions, wherein the tumbling process is a High Energy Tumbling process, wherein post tumbling a homogenous cemented carbide mining insert has been deformation hardened such that ΔHV3%>9.72-0.00543*HV3 bulk , wherein the ΔHV3% is a percentage difference between a HV3 measurement at 0.3 mm from a surface of the insert compared a HV3 measurement in a bulk of the insert, and wherein the surface hardening process is executed at an elevated temperature of or above 100° C.
2. The method according to claim 1 , wherein the metallic binder phase content in the cemented is 5 to 15 wt %.
3. The method according to claim 1 , wherein the cemented carbide additionally includes Cr in an amount such that the mass ratio of Cr/binder is of 0.043-0.19.
4. The method according to claim 1 , wherein the cemented carbide includes M 7 C 3 carbides.
5. The method according to claim 1 , wherein the cemented carbide has a Com/Co ratio: >0.75 and ≤0.98, wherein Com is a magnetic saturation in weight % and Co is a weight percentage of cobalt in the cemented carbide, Com being related to a magnetic saturation 4πσ 1 [μTm 3 /kg] of the cemented carbide to a magnetic saturation for pure metallic Co binder 4πσ 0 =201.9 [μTm 3 /kg] through the equation:
Com (%)=4πσ 1 *(100/201.9).
6. The method according to claim 1 , wherein the cemented carbide has a Com/Co ratio ≤0.69 and at least 2% volume eta phase, wherein Com is a magnetic saturation in weight % and Co is a weight percentage of cobalt in the cemented carbide, Com being related to a magnetic saturation 4πσ 1 [μTm 3 /kg] of the cemented carbide to a magnetic saturation for pure metallic Co binder 4πσ 0 =201.9 [μTm 3 /kg] through the equation:
Com (%)=4πσ 1 *(100/201.9).
7. The method according to claim 1 , wherein prior to sintering a liquid dispersion or slurry having a grain refiner compound including a grain refiner and carbon and/or nitrogen, and a grain growth promoter being carbon, is applied to least one portion of a surface of a compact of the cemented carbide, the grain refiner compound and the grain growth promoter both being provided onto the surface or surfaces in an amount of from 0.1 to 100 mg/cm 2 .
8. The method according to claim 1 , wherein the method further comprises a step of heating the mining inserts and tumbling media prior to the surface hardening process and the surface hardening process is performed on the heated mining inserts.
9. The method according to claim 8 , wherein the mining inserts are kept heated during the surface hardening process.
10. The method according to claim 1 , wherein after the mining inserts have been subjected to the surface hardening process at an elevated temperature, the mining inserts are subjected to a second surface hardening process at room temperature.
11. The method according to claim 1 , wherein part of the heat is generated by friction between the insert and any media added in the tumbling process.
12. A mining insert produced according to the method of claim 1 .