Water-repellent member and method for manufacturing water-repellent member
Provided is a water-repellent member in which a silica layer having a specific thickness and mainly composed of silica nanoparticles is provided on the outer surfaces of various substrates, and then a water- and oil-repellent layer having a specific thickness and containing a cured product of a fluorine-containing organosilicon compound as a main component is provided on the outer surface of the silica layer. The water-repellent member is obtained by a method comprising: a step for wet coating a dispersion containing silica nanoparticles and a solvent onto the outer surface of a substrate; a step for drying and removing the solvent from the dispersion; a step for wet coating a solution containing a fluorine-containing organosilicon compound and a solvent onto the outer surface of a silica layer formed by drying and removing the solvent; and a step for drying and removing the solvent from the solution to cure the fluorine-containing organosilicon compound. According to the water-repellent member, a water- and oil-repellent coating having excellent abrasion resistance can be reliably and easily applied to various substrates.
1. A water repellent member comprising:
a substrate having an outer surface, wherein the substrate is of aluminum or alloy thereof,
a silica layer disposed on the substrate outer surface, wherein the silica layer consists of (i) 100% by weight of silica nanoparticles having an average particle size of 0.1 nm to 10 nm, or (ii) at least 50% by weight of silica nanoparticles having an average particle size of 0.1 nm to 10 nm and 0.1 to 50% by weight of nanoparticles having an average particle size of 1 nm to 10 nm and selected from titanium oxide, tin oxide, silver, platinum, copper, alumina, calcium oxide, magnesium oxide, manganese oxide, nickel oxide, zirconium oxide and multi-component oxides,
wherein in (ii), the sum of the silica nanoparticles and the nanoparticles is equal to 100% by weight;
wherein the silica layer is formed by wet coating and has a thickness of 1 nm to 5 μm, and
a water/oil repellent layer disposed on an outer surface of the silica layer, wherein the water/oil repellent layer is composed mainly of a cured product of a fluorinated organosilicon compound, and wherein the water/oil repellent layer has a thickness of 0.5 to 30 nm, and
wherein the fluorinated organosilicon compound is at least one compound selected from the following hydrolyzable organosilicon compounds:
wherein Me is methyl, p1, q1, r1, s1, and t1 are each independently an integer of 1 to 200, wherein the sum of p1, q1, r1, s1, and t1 is 3 to 500, each unit in parentheses may be randomly arranged,
wherein the cured product has a water contact angle from 102-113° after an abrasion test.
2. The water repellent member of claim 1 wherein the silica layer consists of (ii) at least 50% by weight of silica nanoparticles having an average particle size of 0.1 nm to 10 nm and 0.1 to 50% by weight of nanoparticles having an average particle size of 1 nm to 10 nm, and further wherein the nanoparticles are of at least one type selected from titanium oxide nanoparticles, platinum nanoparticles, and tin oxide nanoparticles.
3. The water repellent member of claim 1 wherein the silica layer of clause (i) is formed by wet coating a dispersion of the silica nanoparticles of clause (i) in a solvent onto the substrate outer surface, and drying off the solvent.
4. The water repellent member of claim 1 wherein the silica layer of clause (ii) is formed by wet coating a dispersion of the silica nanoparticles and the nanoparticles of titanium oxide, tin oxide, silver, platinum, copper, alumina, calcium oxide, magnesium oxide, manganese oxide, nickel oxide, zirconium oxide or multi-component oxides of clause (ii) in a solvent onto the substrate outer surface, and drying off the solvent.
5. A method for preparing the water/oil repellent layer-bearing water repellent member of claim 1 , the method comprising the steps of:
wet coating a dispersion of silica nanoparticles in a solvent onto an outer surface of a substrate,
drying the dispersion to remove the solvent and to form a silica layer,
wet coating a solution of a fluorinated organosilicon compound in a solvent onto an outer surface of the silica layer, and
drying the solution to remove the solvent and to cure the fluorinated organosilicon compound.