Multi-layer structures prepared by layer-by-layer assembly
A protective layer can be deposited on a surface of an porous polymer separator placing on a Li-metal electrode to protect against adverse electrochemical activity in a battery. The protective layer can be a multilayered structure including graphene oxide.
1. A multi-layer structure comprising a tetralayer on a substrate, the tetralayer including an ion-conductive polymer and a barrier layer, the tetralayer on the substrate positioned between a surface of a separator and a surface of a Li-metal electrode in a battery, wherein the tetralayer includes a first polyethylene oxide layer, a graphene oxide layer adjacent to the first polyethylene oxide layer, a second polyethylene oxide layer adjacent to the graphene oxide layer and opposite the first polyethylene oxide layer, and a polyacrylic acid layer adjacent to the second polyethylene oxide layer.
2. The structure of claim 1 , wherein the substrate includes a polymer membrane.
3. The structure of claim 2 , wherein the polymer membrane includes polypropylene.
4. The structure of claim 1 , wherein the tetralayer includes graphene oxide, polyethylene oxide or polyacrylic acid.
5. The structure of claim 1 , wherein the tetralayer is on a polypropylene membrane.
6. The structure of claim 2 , wherein the surface of the tetralayer is more hydrophilic than a surface of the substrate.
7. The structure of claim 1 , wherein the thickness of the structure increases as the number of tetralayers increases.
8. The structure of claim 1 , wherein increasing the thickness of the tetralayer changes the ionic conductivities of the structure.
9. The structure of claim 1 , wherein electrolyte permeability of the tetralayer are repressed with increasing thickness of the tetralayer.
10. The structure of claim 1 , wherein the tetralayer includes graphene oxide which lowers the permeability of the tetralayer.
11. A battery device comprising an electrode protective structure, wherein the electrode protective structure includes graphene oxide in a tetralayer on a substrate positioned between a surface of a separator and a surface of a Li-metal electrode, wherein the tetralayer includes a first polyethylene oxide layer, a graphene oxide layer adjacent to the first polyethylene oxide layer, a second polyethylene oxide layer adjacent to the graphene oxide layer and opposite the first polyethylene oxide layer, and a polyacrylic acid layer adjacent to the second Polyethylene oxide layer.
12. The device of claim 11 , wherein the electrode protective structure contacts a surface of an anode.
13. The device of claim 11 , wherein the electrode protective structure includes ion-conductive polymer, a barrier layer, polyethylene oxide, or polyacrylic acid.
14. The device of claim 11 , wherein the electrode protective structure includes a first polyethylene oxide layer, a graphene oxide layer adjacent to the first polyethylene oxide layer, a second polyethylene oxide layer adjacent to the graphene oxide layer and opposite the first polyethylene oxide layer, and a polyacrylic acid layer adjacent to the second polyethylene oxide layer.
15. The device of claim 14 , wherein the electrode protective structure includes layers formed on a polypropylene membrane.
16. The device of claim 14 , wherein the electrode protective structure includes layers that suppress dendritic growth on an electrode.
17. The device of claim 14 , wherein the electrode protective structure includes layers that suppress dendritic growth on a lithium anode.