Heat exchanger integration with membrane system for evaporator pre-concentration
A system for processing a feed includes a membrane system configured to receive the feed and produce a concentrate and a permeate, wherein the membrane system includes an active cooling system, a passive cooling system, or a combination thereof. Further, the system includes a heat exchanger in fluid communication with the membrane system and disposed upstream of the membrane system, such that the feed enters the heat exchanger prior to entering the membrane system, wherein the heat exchanger is configured to cool the feed and heat the concentrate by transferring heat from the feed to the concentrate.
1. A system for concentrating a liquid feed, the system comprising:
a membrane system configured to receive the liquid feed and produce a concentrate and a permeate, the membrane system including:
a graphene oxide membrane configured to operate at a membrane temperature of at least 60° C.;
a passive cooling system, the passive cooling system including uninsulated piping, a membrane housing, or a combination thereof; and
an active cooling system;
a heat exchanger in fluid communication with the membrane system and disposed upstream of the membrane system such that the liquid feed enters the membrane system immediately after exiting the heat exchanger, the heat exchanger configured to cool the liquid feed and heat the concentrate by transferring heat from the liquid feed to the concentrate; and
a controller configured to:
determine performance of the passive cooling system; and
adjust an operation of the active cooling system based on the determined performance of the passive cooling system, such that the cooling of the membrane system is at a target cooling level.
2. The system of claim 1 , wherein the liquid feed comprises black liquor.
3. The system of claim 1 , wherein the heat exchanger operates at about atmospheric pressure.
4. The system of claim 1 , wherein the heat exchanger is configured to transfer about 0.24 to about 0.39 BTU/gallon from the liquid feed to the concentrate.
5. The system of claim 1 , wherein the heat exchanger is configured to have a heat transfer coefficient in a range of about 100 to about 500 BTU per hour-square feet-Fahrenheit.
6. The system of claim 1 , wherein the heat exchanger is configured to have about 900 to about 1,000 square feet of effective heat transfer area.
7. The system of claim 1 , wherein the active cooling system includes at least one of a water sprayer, a heat sink with cooling fins, or a membrane system heat exchanger.
8. The system of claim 1 , wherein the controller is further configured to control an operation of the heat exchanger to control a temperature of the liquid feed based on the determined performance of the passive cooling.
9. The system of claim 1 , wherein the controller is further configured to:
determine a temperature of the concentrate before the concentrate enters the heat exchanger or after the concentrate leaves the heat exchanger; and
adjust a heat transfer rate between the liquid feed and the concentrate based on the determined temperature of the concentrate.
10. The system of claim 9 , wherein adjusting the heat transfer rate includes reducing or increasing an effective heat transfer area of the heat exchanger.
11. The system of claim 9 , wherein adjusting the heat transfer rate includes:
separating a flow of the liquid feed into a first flow and a second flow, wherein:
the first flow is configured to pass through the heat exchanger;
the second flow is configured to bypass the heat exchanger; and
the controller is configured to determine a magnitude of the first flow and/or second flow; and
recombining the first and the second flow after the first flow passes through the heat exchanger.
12. The system of claim 1 , wherein the controller is further configured to:
determine the membrane temperature and adjust a heat transfer rate between the liquid feed and the concentrate based on the determined membrane temperature.
13. The system of claim 12 , wherein the controller is configured to:
increase a temperature of the liquid feed if the membrane temperature is below a target temperature value; and
decrease the temperature of the liquid feed if the membrane temperature is above the target temperature value.
14. The system of claim 1 , wherein a temperature difference between the concentrate prior to entering the heat exchanger and the liquid feed prior to entering the heat exchanger is between about 10-40 degrees Celsius.
15. The system of claim 1 , wherein the system includes a controller is further configured to:
determine a temperature (T c ) of the concentrate;
determine a temperature (T f ) of the liquid feed; and
adjust a heat transfer rate between the liquid feed and the concentrate based on the determined T c and T f to minimize a system objective function F.
16. The system of claim 15 , wherein the system objective function F is F=w 1 (T c −T c ref ) 2 +w 2 (T f −T f ref ) 2 , wherein T c ref is a concentrate reference temperature, and T f ref is a liquid feed reference temperature, and w 1 and w 2 are weights ranging between zero and one.
17. The system of claim 1 , wherein the controller is further configured to:
determine a change in a flow rate of the liquid feed; and
adjust a heat transfer rate in the heat exchanger based on the determined change in the flow rate of the liquid feed.
18. The system of claim 1 , wherein the controller is further configured to:
determine a change in a flow rate of the liquid feed;
adjust a heat transfer rate in the heat exchanger based on the determined change in the flow rate of the liquid feed; and
adjust an operation of the active cooling system based on the determined change in the flow rate of the liquid feed.
19. The system of claim 1 , wherein the liquid feed enters the heat exchanger at a flow rate of about 165 to about 220 klb/hr.
20. The system of claim 1 , wherein the concentrate enters the heat exchanger at a flow rate of about 110 to about 165 klb/hr.
21. A system for concentrating a liquid feed, the system comprising:
a membrane system configured to receive the liquid feed and produce a concentrate and a permeate, the membrane system including:
an active cooling system, a passive cooling system, or a combination thereof; and
a graphene oxide membrane configured to operate at a membrane temperature of at least 60° C.;
a first heat exchanger in fluid communication with the membrane system and disposed upstream of the membrane system;
a second heat exchanger in fluid communication with both the first heat exchanger and the membrane system and disposed between the first heat exchanger and the membrane system, such that the liquid feed enters the first heat exchanger, the second heat exchanger, and the membrane system sequentially; and
a controller configured to:
determine the membrane temperature;
adjust a heat transfer rate in the first heat exchanger based on the determined membrane temperature; and
adjust a heat transfer rate in the second heat exchanger based on the determined membrane temperature;
wherein:
the first heat exchanger is configured to cool the liquid feed and heat the concentrate by transferring heat from the liquid feed to the concentrate; and
the second heat exchanger is configured to cool the liquid feed and heat the permeate by transferring heat from the liquid feed to the permeate.
22. The system of claim 21 , wherein the liquid feed includes black liquor.
23. The system of claim 21 , wherein the controller is further configured to:
determine a temperature of the concentrate before the concentrate enters the first heat exchanger or after the concentrate leaves the first heat exchanger; and
adjust the heat transfer rate in the first heat exchanger based on at least one of the determined temperature of the concentrate, or the membrane temperature.
24. The system of claim 21 , wherein the controller is further configured to:
determine a change in a flow rate of the liquid feed; and
adjust the heat transfer rate in the first heat exchanger or the second heat exchanger based on at least one of the determined change in the flow rate of the liquid feed or the membrane temperature.
25. The system of claim 21 , wherein the controller is further configured to:
determine a temperature (T c ) of the concentrate;
determine a temperature (T f ) of the liquid feed;
determine a temperature (T p ) of the permeate; and
adjust a heat flow between the liquid feed and the concentrate and between the liquid feed and the permeate based on the determined T c , T f , and T p to minimize a system objective function F.
26. The system of claim 25 , wherein the system objective function F is F=w 1 (T c −T c ref ) 2 +w 2 (T f −T f ref ) 2 , wherein T c ref is a concentrate reference temperature, and T f ref is a feed reference temperature, and w 1 and w 2 are weights ranging between zero and one.
27. The system of claim 25 , wherein the system objective function F is F=w 1 (T c −T c ref ) 2 +w 2 (T f −T f ref ) 2 +w 3 (T p −T p ref ), wherein T c ref is a concentrate reference temperature, T f ref is a feed reference temperature, and T p ref is a permeate reference temperature, and w 1 , w 2 , and w 3 are weights ranging between zero and one.
28. A system for concentrating a liquid feed, the system comprising:
a membrane system configured to receive the liquid feed and produce a concentrate and a permeate, the membrane system including:
a graphene oxide membrane configured to operate at a membrane temperature of at least 60° C.; and
an active cooling system;
a heat exchanger in fluid communication with the membrane system and disposed upstream of the membrane system such that the liquid feed enters the membrane system immediately after exiting the heat exchanger, the heat exchanger configured to cool the liquid feed and heat the concentrate by transferring heat from the liquid feed to the concentrate; and
a controller configured to:
determine a temperature of the concentrate before the concentrate enters the heat exchanger or after the concentrate leaves the heat exchanger; and
adjust a heat transfer rate between the liquid feed and the concentrate based on the determined temperature of the concentrate.
29. The system of claim 28 , wherein the liquid feed comprises black liquor.
30. The system of claim 28 , wherein the active cooling system includes at least one of a water sprayer, a heat sink with cooling fins, or a membrane system heat exchanger.
31. The system of claim 28 , wherein adjusting the heat transfer rate includes reducing or increasing an effective heat transfer area of the heat exchanger.
32. A system for concentrating a liquid feed, the system comprising:
a membrane system configured to receive the liquid feed and produce a concentrate and a permeate, the membrane system including:
a graphene oxide membrane configured to operate at a membrane temperature of at least 60° C.; and
an active cooling system;
a heat exchanger in fluid communication with the membrane system and disposed upstream of the membrane system such that the liquid feed enters the membrane system immediately after exiting the heat exchanger, the heat exchanger configured to cool the liquid feed and heat the concentrate by transferring heat from the liquid feed to the concentrate; and
a controller configured to determine the membrane temperature and adjust a heat transfer rate between the liquid feed and the concentrate based on the determined membrane temperature.
33. The system of claim 32 , wherein the controller is further configured to:
increase a temperature of the liquid feed if the membrane temperature is below a target temperature value; and
decrease the temperature of the liquid feed if the membrane temperature is above the target temperature value.
34. The system of claim 32 , wherein a temperature difference between the concentrate prior to entering the heat exchanger and the liquid feed prior to entering the heat exchanger is between about 10-40 degrees Celsius.
35. A system for concentrating a liquid feed, the system comprising:
a membrane system configured to receive the liquid feed and produce a concentrate and a permeate, the membrane system including:
a graphene oxide membrane configured to operate at a membrane temperature of at least 60° C.; and
an active cooling system;
a heat exchanger in fluid communication with the membrane system and disposed upstream of the membrane system such that the liquid feed enters the membrane system immediately after exiting the heat exchanger, the heat exchanger configured to cool the liquid feed and heat the concentrate by transferring heat from the liquid feed to the concentrate; and
a controller configured to:
determine a temperature (T c ) of the concentrate;
determine a temperature (T f ) of the liquid feed; and
adjust a heat transfer rate between the liquid feed and the concentrate based on the determined T c and T f to minimize a system objective function F.
36. The system of claim 35 , wherein the system objective function F is F=w 1 (T c −T c ref ) 2 +w 2 (T f −T f ref ) 2 , wherein T c ref is a concentrate reference temperature, and T f ref is a liquid feed reference temperature, and w 1 and w 2 are weights ranging between zero and one.
37. A system for concentrating a liquid feed, the system comprising:
a membrane system configured to receive the liquid feed and produce a concentrate and a permeate, the membrane system including:
a graphene oxide membrane configured to operate at a membrane temperature of at least 60° C.; and
an active cooling system;
a heat exchanger in fluid communication with the membrane system and disposed upstream of the membrane system such that the liquid feed enters the membrane system immediately after exiting the heat exchanger, the heat exchanger configured to cool the liquid feed and heat the concentrate by transferring heat from the liquid feed to the concentrate; and
a controller configured to:
determine a change in a flow rate of the liquid feed; and
adjust a heat transfer rate in the heat exchanger based on the determined change in the flow rate of the liquid feed.
38. The system of claim 37 , wherein the membrane system further includes a passive cooling, the controller being further configured to:
adjust an operation of the active cooling system based on the determined change in the flow rate of the liquid feed.
39. A system for concentrating a liquid feed, the system comprising:
a membrane system configured to receive the liquid feed and produce a concentrate and a permeate, the membrane system including:
an active cooling system, a passive cooling system, or a combination thereof; and
a graphene oxide membrane configured to operate at a membrane temperature of at least 60° C.;
a first heat exchanger in fluid communication with the membrane system and disposed upstream of the membrane system;
a second heat exchanger in fluid communication with both the first heat exchanger and the membrane system and disposed between the first heat exchanger and the membrane system, such that the liquid feed enters the first heat exchanger, the second heat exchanger, and the membrane system sequentially; and
a controller configured to:
determine a change in a flow rate of the liquid feed; and
adjust a heat transfer rate in the first heat exchanger or the second heat exchanger based on the determined change in the flow rate of the liquid feed;
wherein:
the first heat exchanger is configured to cool the liquid feed and heat the concentrate by transferring heat from the liquid feed to the concentrate; and
the second heat exchanger is configured to cool the liquid feed and heat the permeate by transferring heat from the liquid feed to the permeate.
40. The system of claim 39 , wherein the liquid feed includes black liquor.
41. The system of claim 39 , wherein adjusting the heat transfer rate in the first heat exchanger or the second heat exchanger includes reducing or increasing an effective heat transfer area of the first heat exchanger or the second heat exchanger.
42. A system for concentrating a liquid feed, the system comprising:
a membrane system configured to receive the liquid feed and produce a concentrate and a permeate, the membrane system including:
an active cooling system, a passive cooling system, or a combination thereof; and
a graphene oxide membrane configured to operate at a membrane temperature of at least 60° C.;
a first heat exchanger in fluid communication with the membrane system and disposed upstream of the membrane system;
a second heat exchanger in fluid communication with both the first heat exchanger and the membrane system and disposed between the first heat exchanger and the membrane system, such that the liquid feed enters the first heat exchanger, the second heat exchanger, and the membrane system sequentially; and
a controller configured to:
determine a temperature (T c ) of the concentrate;
determine a temperature (T f ) of the liquid feed;
determine a temperature (T p ) of the permeate; and
adjust a heat flow between the liquid feed and the concentrate and between the liquid feed and the permeate based on the determined T c , T f , and T p to minimize a system objective function F;
wherein:
the first heat exchanger is configured to cool the liquid feed and heat the concentrate by transferring heat from the liquid feed to the concentrate; and
the second heat exchanger is configured to cool the liquid feed and heat the permeate by transferring heat from the liquid feed to the permeate.
43. The system of claim 42 , wherein the system objective function F is F=w 1 (T c −T c ref ) 2 +w 2 (T f −T f ref ) 2 +w 3 (T p −T p ref ), wherein T c ref is a concentrate reference temperature, T f ref is a feed reference temperature, and T p ref is a permeate reference temperature, and w 1 , w 2 , and w 3 are weights ranging between zero and one.