IP Library › Granted Patent US 11,926,699
Granted Patent B2
US 11,926,699 · App. 17/577,514 · Granted Mar 12, 2024

Aliphatic polyester composition

Inventors: Jie-Cheng Li (Taipei, TW); Te-Shun Lin (Taipei, TW)
Assignee: CHANG CHUN PLASTICS CO., LTD.
C08G63/16C08G2230/00
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Quick Facts
Patent No.
US 11,926,699
App. No.
17/577,514
Granted
Mar 12, 2024
Kind
B2
Abstract

Provided is an aliphatic polyester composition. The aliphatic polyester composition comprises a polybutylene succinate, wherein the proton nuclear magnetic resonance of the aliphatic polyester composition has a first characteristic peak and a second characteristic peak. The first characteristic peak is located between 3.84 ppm and 4.32 ppm, and the second characteristic peak is located between 5.65 ppm and 5.85 ppm. The integral value of the first characteristic peak is set to be 100 and the integral value of the second characteristic peak is less than 0.10. By controlling the integral value of the second characteristic peak in H 1 -NMR of the aliphatic polyester composition, the aliphatic polyester composition has good appearance and low concentration of carboxylic acid end group and thereby the product value thereof is increased.

Claims (20)

1. An aliphatic polyester composition comprising polybutylene succinate; wherein the proton nuclear magnetic resonance of the aliphatic polyester composition has a first characteristic peak and a second characteristic peak, the first characteristic peak is at 3.84 ppm to 4.32 ppm, the second characteristic peak is at 5.65 ppm to 5.85 ppm, and the integral value of the second characteristic peak is less than 0.10 based on the integral value of the first characteristic peak as 100.

2. The aliphatic polyester composition as claimed in claim 1 , wherein the proton nuclear magnetic resonance of the aliphatic polyester composition has a third characteristic peak, the third characteristic peak is at 3.30 ppm to 3.42 ppm, and the integral value of the third characteristic peak is 0.001 to 2.0 based on the integral value of the first characteristic peak as 100.

3. The aliphatic polyester composition as claimed in claim 1 , wherein the proton nuclear magnetic resonance of the aliphatic polyester composition has a fourth characteristic peak, the fourth characteristic peak is at 3.55 ppm to 3.70 ppm, and the integral value of the fourth characteristic peak is 0.01 to 0.50 based on the integral value of the first characteristic peak as 100.

4. The aliphatic polyester composition as claimed in claim 1 , wherein the proton nuclear magnetic resonance of the aliphatic polyester composition has a fifth characteristic peak, the fifth characteristic peak is at 4.72 ppm to 4.90 ppm, and the integral value of the fifth characteristic peak is 0.15 to 0.50 based on the integral value of the first characteristic peak as 100.

5. The aliphatic polyester composition as claimed in claim 1 , wherein the proton nuclear magnetic resonance of the aliphatic polyester composition has a sixth characteristic peak, the sixth characteristic peak is at 4.97 ppm to 5.15 ppm, and the integral value of the sixth characteristic peak is less than 0.21 based on the integral value of the first characteristic peak as 100.

6. The aliphatic polyester composition as claimed in claim 1 , wherein the content of sulfur of the aliphatic polyester composition is less than 100 ppm.

7. The aliphatic polyester composition as claimed in claim 1 , wherein the content of phosphorous of the aliphatic polyester composition is less than 50 ppm.

8. The aliphatic polyester composition as claimed in claim 1 , wherein the content of titanium of the aliphatic polyester composition is 20 ppm to 100 ppm.

9. The aliphatic polyester composition as claimed in claim 1 , wherein the melt flow index of the aliphatic polyester composition is less than 40.0 g/10 min.

10. The aliphatic polyester composition as claimed in claim 6 , wherein the melt flow index of the aliphatic polyester composition is less than 40.0 g/10 min.

11. The aliphatic polyester composition as claimed in claim 7 , wherein the melt flow index of the aliphatic polyester composition is less than 40.0 g/10 min.

12. The aliphatic polyester composition as claimed in claim 1 , wherein the concentration of carboxylic acid end group of the aliphatic polyester composition is less than 30.0 meq COOH/kg.

13. The aliphatic polyester composition as claimed in claim 6 , wherein the concentration of carboxylic acid end group of the aliphatic polyester composition is less than 30.0 meq COOH/kg.

14. The aliphatic polyester composition as claimed in claim 7 , wherein the concentration of carboxylic acid end group of the aliphatic polyester composition is less than 30.0 meq COOH/kg.

15. The aliphatic polyester composition as claimed in claim 1 , wherein the chromaticity b of the aliphatic polyester composition is less than 15.0.

16. The aliphatic polyester composition as claimed in claim 6 , wherein the chromaticity b of the aliphatic polyester composition is less than 15.0.

17. The aliphatic polyester composition as claimed in claim 7 , wherein the chromaticity b of the aliphatic polyester composition is less than 15.0.

18. The aliphatic polyester composition as claimed in claim 1 , wherein the yellowness index of the aliphatic polyester composition is less than 30.0.

19. The aliphatic polyester composition as claimed in claim 6 , wherein the yellowness index of the aliphatic polyester composition is less than 30.0.

20. The aliphatic polyester composition as claimed in claim 7 , wherein the yellowness index of the aliphatic polyester composition is less than 30.0.

Assignments (2)
CORRECTIVE ASSIGNMENT TO CORRECT THE THE ASSIGNEE NAME PREVIOUSLY RECORDED AT REEL: 058728 FRAME: 0848. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Mar 30, 2022
From: LI, JIE-CHENG; LIN, TE-SHUN
To: CHANG CHUN PLASTICS CO., LTD.
Reel/Frame 059547/0084 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 21, 2022
From: LI, JIE-CHENG; LIN, TE-SHUN
To: CHUNG CHUN PLASTICS CO., LTD.
Reel/Frame 058728/0848 →
Priority Claims (2)
CN 202111508210.8 · Dec 10, 2021 · national
TW 110146326 · Dec 10, 2021 · national
Continuity (1)
Related Publication 20230183420A1 · Jun 15, 2023
Cited By (1)
US 12,570,796