IP Library › Granted Patent US 11,926,782
Granted Patent B2
US 11,926,782 · App. 17/754,654 · Granted Mar 12, 2024

Magnetizable abrasive particle and method of making the same

Inventors: Sergei A. Manuilov (Bayport, MN); Adam D. Milller (Vadnais Heights, MN); Laura M. Lara Rodriguez (Woodbury, MN); Dwight D. Erickson (Woodbury, MN); Anatoly Z. Rosenflanz (Maplewood, MN)
Assignee: 3M Innovative Property Company
C09K3/1436H01F1/11
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Quick Facts
Patent No.
US 11,926,782
App. No.
17/754,654
Granted
Mar 12, 2024
Kind
B2
Abstract

A magnetizable abrasive particle is presented. The magnetizable abrasive particle has a ceramic particle having an outer surface. The magnetizable abrasive particle also has a magnetic coating layer applied to the outer surface of the ceramic particle prior to sintering. The sintered magnetizable particle is responsive to a magnetic field.

Claims (21)

1. A method of making magnetizable abrasive particles, comprising:

forming a ceramic particle precursor from a sol-gel precursor material, the sol-gel precursor material comprising alpha-alumina, wherein forming comprises drying the sol-gel precursor material in a shaped mold cavity;

applying a coating directly to a surface of the ceramic particle precursor, wherein the, coating comprises a magnetically responsive material; and

firing the coated ceramic particle precursor to create a sintered ceramic particle and wherein, after firing, the magnetically responsive material is responsive to a magnetic field.

2. The method of claim 1 , and further comprising:

removing solvent from the ceramic particle precursor.

3. The method of claim 2 , wherein removing solvent comprises a pre-firing process.

4. The method of claim 1 , wherein firing the magnetic coated ceramic particle causes a reaction layer to form between the applied coating layer and a ceramic particle layer.

5. The method of claim 4 , wherein the reaction layer comprises alumina, zinc, iron or nickel.

6. The method of claim 1 , wherein the magnetically responsive coating comprises ferrite.

7. The method of claim 1 , wherein the magnetic coating is a unitary coating.

8. The method of claim 1 , wherein the magnetically responsive coating is substantially limited to a single side of the ceramic particle precursor.

9. The method of claim 1 , wherein the magnetically responsive coating comprises a soft magnetic material.

10. The method of claim 1 , wherein coating comprises applying a slurry of the magnetically responsive material.

11. The method of claim 10 , wherein the ferrite magnetically responsive material comprises a nickel zinc ferrite material.

12. The method of claim 1 , wherein the ceramic particle precursor is formed within a tool having a mold cavity, such that the ceramic particle precursor has a shape that is a negative image of the mold cavity.

13. The method of claim 1 , wherein the ceramic particle precursor is a fully dense ceramic particle.

14. The method of claim 13 , wherein coating comprises applying the magnetic coating as a slurry while the ceramic particle precursor is in the mold cavity.

15. The method of claim 1 , wherein firing comprises sintering the ceramic particle precursors at a temperature above 1250° C.

16. The method of claim 1 , wherein the magnetically responsive material cannot be converted into a non-magnetic state during firing; wherein firing comprises heating the coated ceramic particle precursor in an oven to temperatures above 1250° C.

17. The method of claim 16 , wherein the magnetically responsive material has a formula of: XO·M m Fe 2-m O 3 (m<1) where X is a divalent cation and M is a trivalent cation, or a formula of X 3 A 5 O 12 , where X and A are metals.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 8, 2022
From: MANUILOV, SERGEI A.; MILLER, ADAM D.; LARA RODRIQUEZ, LAURA M.; ERICKSON, DWIGHT D.; ROSENFLANZ, ANATOLY Z.
To: 3M INNOVATIVE PROPERTIES COMPANY
Reel/Frame 059538/0601 →
Continuity (2)
Provisional Application 62914778 · Oct 14, 2019
Related Publication 20230193101A1 · Jun 22, 2023