Lubricating compositions and methods of operating an internal combustion engine
The instant disclosure generally relates to lubricating compositions having an oil of lubricating viscosity, a mixture of boron-containing and boron-free dispersants, an overbased magnesium-based detergent, an overbased calcium-based detergent, a molybdenum-containing material, and, optionally, other performance additives. The instant lubricating compositions may improve one or more of cleanliness, TBN retention, fuel economy and low-speed preignition (“LSPI”).
1. An internal combustion engine lubricating composition comprising:
oil of lubricating viscosity comprising at least 50 weight percent of a Group III base oil, a Group IV base oil, or combinations thereof;
a boron-containing polyisobutenyl succinimide dispersant, wherein the boron-containing succinimide dispersant is derived from a polyisobutylene having a vinylidene content of greater than 70 mol % where the dispersant has a number average molecular weight of from 1750 to 2200 and wherein the boron-containing succinimide dispersant is present in the lubricating composition in an amount of 0.2 to 2.1 wt %;
a boron-free polyisobutenyl succinimide dispersant wherein the boron-free polyisobutenyl succinimide dispersant includes a combination of a first boron-free polyisobutenyl succinimide dispersant having a number average molecular weight of from 1150 to 1650 and a second boron-free polyisobutenyl succinimide dispersant having a number average molecular weight of from 1950 to 2500, wherein the first boron-free polyisobutylene succinimide dispersant is present in an amount of 60% to 90% by weight of the total combination of the first boron-free polyisobutenyl succinimide dispersant and the second boron-free polyisobutenyl succinimide dispersant and wherein the boron-free polyisobutenyl succinimide dispersant is present in the lubricating composition in an amount of 0.5 to 6.5 wt. %;
an overbased magnesium-based detergent in an amount to deliver at least 400 ppm magnesium to the lubricating composition;
an overbased calcium-based detergent in an amount to deliver at least 400 ppm calcium to the lubricating composition; and
a molybdenum-containing material.
2. The lubricating composition according to claim 1 , wherein the boron-free polyisobutenyl succinimide dispersant includes a first boron-free polyisobutenyl succinimide dispersant is present in the lubricating composition in an amount of from 1.8 to 2.5 wt % and a second boron-free polyisobutenyl succinimide dispersant having a number average molecular weight of from 1950 to 2500 and is present in the lubricating composition an amount of from 0.5 to 0.8 wt %.
3. The lubricating composition according to claim 1 , wherein the overbased magnesium-based detergent is present in the lubricating composition in an amount of from 0.1 to 1.5 wt %.
4. The lubricating composition according to claim 1 , wherein the overbased magnesium-based detergent is an overbased alkylbenzene sulfonate detergent having a metal ratio of at least 8.
5. The lubricating composition according to claim 1 , wherein the overbased magnesium-based detergent has a TBN (KOH/g) greater than 500.
6. The lubricating composition according to claim 1 , wherein the overbased magnesium-based detergent has a TBN (KOH/g) of from 500 to 850.
7. The lubricating composition according to claim 1 , wherein the overbased magnesium-based detergent delivers from 400 to 700 ppm magnesium to the lubricating composition.
8. The lubricating composition according to claim 1 , wherein the overbased calcium-based detergent is present in the lubricating composition in an amount of from 0.1 to 2.5 wt %.
9. The lubricating composition according to claim 1 , wherein the overbased calcium-based detergent has a metal ratio of at least 5.
10. The lubricating composition according to claim 1 , wherein the overbased calcium-based detergent has a TBN (KOH/g) from 450 to 850.
11. The lubricating composition according to claim 1 , wherein the overbased calcium-based detergent delivers from 400 to 1200 ppm calcium to the lubricating composition.
12. The lubricating composition according to claim 1 , wherein the overbased calcium-based detergent is selected from an overbased calcium salixarate detergent, an overbased calcium salicylate detergent, and mixtures thereof.
13. The lubricating composition according to claim 1 , wherein the overbased calcium-based detergent is an overbased calcium salicylate detergent.
14. The lubricating composition according to claim 1 , wherein the overbased calcium-based detergent includes a mixture of an overbased calcium salixarate detergent and an overbased calcium salicylate detergent.
15. The lubricating composition according to claim 1 , further comprising an ashless antioxidant present in an amount of at least 0.9 weight percent of the lubricating composition.
16. The lubricating composition according to claim 1 , further comprising an ashless friction modifier selected from one or more of an ester, an amide, or an imide of an alpha-hydroxy carbonyl compound, and mixtures thereof present in the lubricating composition in an amount of from 0.01 to 1.1 wt %.
17. The lubricating composition according to claim 1 , further comprising a zinc dialkyldithiophosphate anti-wear agent in an amount to deliver 200 ppm up to 1000 ppm phosphorus to the lubricating composition.
18. The lubricating composition according to claim 1 , wherein the lubricating composition is free of or substantially free of tetrapropenylphenol (pddp) and derivatives thereof.
19. The lubricating composition according to claim 1 , wherein the molybdenum-containing material is selected from a molybdenum dithiocarbamate complex, a molybdenum dithiocarbamate dimer complex, and a tri-nuclear molybdenum compound.
20. The lubricating composition according to claim 1 , wherein the molybdenum-containing material is present in an amount to provide 40 to 1200 ppm by weight molybdenum to the lubricating composition.
21. The lubricating composition according to claim 1 , wherein the molybdenum-containing material is present in an amount to provide 60 to 200 ppm by weight molybdenum to the lubricating composition.
22. A method of operating a gasoline-fueled internal combustion engine comprising supplying to an internal combustion engine a lubricating composition according to claim 1 .
23. A method for reducing low speed preignition in a gasoline-fueled internal combustion engine operating at a brake mean effective pressure (BMEP) of greater than 12 bars and at a speed of less than 3,000 RPMs comprising: supplying to said engine a lubricating composition according to claim 1 .
24. The method of claim 23 where the gasoline-fueled internal combustion engine further comprises a turbo charger.