Tape-shaped prepreg and a method for production thereof
The invention aims to provide a tape-shaped prepreg including unidirectionally oriented reinforcing fibers and a thermoplastic resin composition and being high in handleability during molding and high in adhesiveness to other members. The tape-shaped prepreg includes unidirectionally oriented reinforcing fibers and a thermoplastic resin composition and has an arithmetic average roughness (Ra) of 0.1 to 10 μm in a direction perpendicular to the orientation direction of the reinforcing fibers, as measured according to JIS B 0601: 2013, and a warpage rate of 5% or less as determined by the procedure specified in (i) to (iii) below: (i) place a test piece of the above tape-shaped prepreg having a length of 100 mm in the fiber orientation direction on a plane in such manner that the end portions curl upward, (ii) measure the vertical distance from the highest position at the right end of the curled tape to the plane, which is denoted by a, and the vertical distance from the highest position at the left end to the plane, which is denoted by b, and calculate the arithmetic average of a and b, which is defined as the warpage distance, and (iii) calculate the warpage rate by the following equation: warpage rate (%)=warpage distance (mm)/100 (mm)×100.
1. A tape-shaped prepreg comprising unidirectionally oriented reinforcing fibers and a thermoplastic resin composition, wherein the tape-shaped prepreg has
an arithmetic average roughness (Ra) of 0.1 to 10 μm in a direction perpendicular to the orientation direction of the reinforcing fibers, as measured according to JIS B 0601: 2013, and
a warpage rate of 5% or less as determined by the procedure specified in (i) to (iii) below:
(i) a test piece of the above tape-shaped prepreg having a length of 100 mm is placed in the fiber orientation direction on a plane in such manner that the end portions curl upward,
(ii) the vertical distance from the highest position at the right end of the curled tape to the plane, which is denoted by a, and the vertical distance from the highest position at the left end to the plane, which is denoted by b, are measured and the arithmetic average of a and b is calculated, which is defined as the warpage distance, and
(iii) the warpage rate is calculated based on the following equation:
warpage rate (%)=warpage distance (mm)/100 (mm)×100,
wherein
the tape-shaped prepreg has a thickness of 0.20 to 15 mm and
the tape-shaped prepreg exhibits a waviness curve having a maximum cross-sectional height (Wt) of 80 μm or less in a direction perpendicular to the orientation direction of the reinforcing fibers, as measured according to JIS B 0601: 2013.
2. A tape-shaped prepreg according to claim 1 , wherein the reinforcing fiber accounts for a fiber volume content of 30% to 70%.
3. A tape-shaped prepreg according to claim 1 having a void content of 5 vol % or less.
4. A tape-shaped prepreg according to claim 1 , wherein the thermoplastic resin composition is a polyamide resin composition.
5. A tape-shaped prepreg according to claim 1 , wherein the reinforcing fiber is carbon fiber.
6. A tape-shaped prepreg according to claim 1 , wherein the tape-shaped prepreg has a width of 50 mm or more.
7. A method for producing the tape-shaped prepreg according to claim 1 which comprises:
putting a thermoplastic resin composition in a molten state into a tank having an inlet portion and an outlet portion,
introducing a plurality of continuous reinforcing fibers from the inlet portion of the tank so that they are impregnated with the resin composition, and
causing the thermoplastic resin composition and the plurality of continuous reinforcing fibers to exit through the outlet portion of the tank and then pass through a cooling mechanism to produce a tape-shaped prepreg,
wherein the following relation (A) holds between Pc and Qp, wherein Pc [W] is the heat absorbing capacity of the cooling mechanism and Qp [m 3 /s] is the volume of the tape-shaped prepreg passing through the cooling mechanism in one second:
2.8×10 8 ≤Pc/Qp≤23.2×10 8 (A).
8. A method for producing a tape-shaped prepreg according to claim 7 , wherein one or a plurality of roller-shaped cooling members are included in the cooling mechanism.
9. A method for producing a tape-shaped prepreg according to claim 7 , wherein one or a plurality of plate-shaped cooling members are included in the cooling mechanism.
10. A method for producing a tape-shaped prepreg according to claim 7 , wherein both one or a plurality of roller-shaped cooling members and one or a plurality of plate-shaped cooling members are included in the cooling mechanism.
11. A method for producing a tape-shaped prepreg according to claim 7 , wherein the temperature of the cooling members of the cooling mechanism can be controlled.
12. A method for producing a tape-shaped prepreg according to claim 10 , wherein:
a plurality of cooling members are included in the cooling mechanism, and
the temperature of each cooling member of the cooling mechanism can be controlled independently.
13. A method for producing a tape-shaped prepreg according to claim 7 , wherein at least two cooling members located opposite to each other are included in the cooling mechanism to allow the tape-shaped prepreg to travel therebetween.
14. A method for producing a tape-shaped prepreg according to claim 13 , wherein the distance between the two cooling members can be adjusted as desired.
15. A method for producing a tape-shaped prepreg according to claim 13 , wherein the force exerted for fixing the two cooling members at specific positions can be adjusted as desired.
16. A method for producing a tape-shaped prepreg according to claim 7 , wherein the tape-shaped prepreg solidified while passing through the cooling mechanism is wound up.
17. A method for producing a tape-shaped prepreg according to claim 7 , wherein a plurality of parallel strips of a tape-shaped prepreg are allowed travel simultaneously.
18. A method for producing a tape-shaped prepreg according to claim 7 , wherein the plurality of continuous reinforcing fibers impregnated with a thermoplastic resin composition are oriented in the traveling direction as they pass through the outlet portion of the tank.
19. A method for producing a tape-shaped prepreg according to claim 7 , wherein the thermoplastic resin composition is a polyamide resin composition.
20. A method for producing a tape-shaped prepreg according to claim 7 , wherein the continuous reinforcing fiber is carbon fiber.