IP Library › Granted Patent US 11,939,651
Granted Patent B2
US 11,939,651 · App. 17/059,641 · Granted Mar 26, 2024

Al—Fe-alloy plated steel sheet for hot forming, having excellent TWB welding characteristics, hot forming member, and manufacturing methods therefor

Inventors: Seong-Woo Kim (Gwangyang-si, KR); Jin-Keun Oh (Gwangyang-si, KR); Yeol-Rae Cho (Gwangyang-si, KR); Hyeon-Jeong Shin (Incheon, KR)
Assignee: POSCO CO., LTD
C22C38/32B23K35/0238B23K35/3086C21D8/0205C21D8/0226C21D8/0236C21D9/46C22C38/02C22C38/04C22C38/06C23C2/02C23C2/0224C23C2/12C23C2/261C23C2/28C23C2/29C23C2/40B23K2103/166B23K2103/20C21D2211/001C21D2211/002C21D2211/005C21D2211/008
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Quick Facts
Patent No.
US 11,939,651
App. No.
17/059,641
Granted
Mar 26, 2024
Kind
B2
Abstract

Provided is an Al—Fe-alloy plated steel sheet for hot forming, having excellent TWB welding characteristics since excellent hardness uniformity of a TWB weld zone after hot forming is obtained by suitably controlling a batch annealing condition, after plating Al, such that an Al—Fe-alloy layer is formed; a hot forming member; and manufacturing methods therefor.

Claims (22)

1. An Al—Fe alloy plated steel sheet for hot press forming, the Al—Fe alloy plated steel sheet comprising:

a base steel sheet comprising, by weight percentage (wt %), carbon (C): 0.1 to 0.5%, silicon (Si): 0.01 to 2.0%, manganese (Mn): 0.1 to 10%, phosphorus (P): 0.001 to 0.05%, sulfur (S): 0.0001 to 0.02%, aluminum (Al): 0.001 to 1.0%, nitrogen (N): 0.001 to 0.02%, and a balance of iron (Fe) and unavoidable impurities;

an Al—Fe alloy layer disposed on the base steel sheet; and

an oxide layer formed on the Al—Fe alloy layer, the oxide layer having a thickness of 2 μm or less, wherein the thickness of 2 μm or less refers to a thickness to a point having 10 wt % of oxygen concentration in an oxygen concentration profile obtained through glow discharge spectrometer (GDS) analysis,

wherein the Al—Fe alloy layer comprises, by wt %, aluminum (Al): 40 to 60%, silicon (Si): 2 to 10%, and a balance of iron (Fe) and unavoidable impurities, and a fraction of an unalloyed phase is 1 area % or less, and

wherein the Al—Fe alloy layer comprises:

a diffusion layer disposed on the base steel sheet and constituting a layer while including Si in an amount of 0.5 to 12.0 wt %; and

an intermediate layer disposed in the Al—Fe alloy layer and constituting a layer while including Si in an amount of 3.0 to 20.0 wt %, and

wherein a sum of average thicknesses of the diffusion layer and the intermediate layer is 1.0 to 10 μm.

2. The Al—Fe alloy plated steel sheet of claim 1 , wherein the base steel sheet further comprises one or more of chromium (Cr) and molybdenum (Mo) in a total amount of 0.01 to 4.0 wt %.

3. The Al—Fe alloy plated steel sheet of claim 1 , wherein the base steel sheet further comprises one or more of titanium (Ti), niobium (Nb), and vanadium (V) in a total amount of 0.001 to 0.4 wt %.

4. The Al—Fe alloy plated steel sheet of claim 1 , wherein the base steel sheet further comprises boron (B) in an amount of 0.0001 to 0.01 wt %.

5. The Al—Fe alloy plated steel sheet of claim 1 , wherein the base steel sheet has a microstructure comprising, by an area fraction, 20% or less of pearlite, 10% or less of martensite, 10% or less of spheroidized carbide, and a balance of ferrite.

6. The Al—Fe alloy plated steel sheet of claim 1 , wherein the Al—Fe alloy layer has a thickness of 10 to 60 μm.

7. A hot press formed part manufactured by hot press forming a tailer welded blank, the tailer welded blank being manufactured by welding an Al—Fe alloy plated steel sheet of claim 1 to a steel sheet having a thickness or a strength different from a thickness or a strength of the Al—Fe alloyed plate steel sheet,

wherein the hot press formed part has a tensile strength of 1300 MPa or more and a welding zone hardness deviation of 100Hv or less.

8. The hot press formed part of claim 7 , wherein a portion corresponding to the Al—Fe alloy plated steel sheet has a microstructure comprising martensite or bainite as a main phase, 30 area % or less of retained austenite, and 5 area % or less of ferrite.

9. A method of manufacturing a hot press formed part, the method comprising:

welding an Al—Fe alloy plated steel sheet of claim 1 to a steel sheet having a thickness or a strength different from a thickness or a strength of the Al—Fe alloy plated steel sheet to form a tailer welded blank;

heating the tailer welded blank to a temperate within a range of (Ae3+30° C.) to (Ae3+150° C.) at a heating rate of 1 to 1000° C./sec and then maintained for 1 to 1000 seconds to form a heated tailer welded blank; and

hot press forming the heated tailer welded blank while simultaneously cooling at a cooling rate of 1 to 1000° C./sec.

10. The method of claim 9 , wherein the steel sheet having the strength different from that of the Al—Fe alloy plated steel sheet comprises carbon (C): 0.05 to 0.08%, silicon (Si): 0.01 to 0.4%, manganese (Mn): 0.08 to 1.7%, aluminum (Al): 0.01 to 0.07%, Ti: 0.09% or less, and a balance of iron (Fe) and unavoidable impurities.

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 26, 2022
From: POSCO HOLDINGS INC.
To: POSCO CO., LTD
Reel/Frame 061773/0658 →
CHANGE OF NAME Recorded Sep 19, 2022
From: POSCO
To: POSCO HOLDINGS INC.
Reel/Frame 061476/0736 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 30, 2020
From: KIM, SEONG-WOO; OH, JIN-KEUN; CHO, YEOL-RAE; SHIN, HYEON-JEONG
To: POSCO
Reel/Frame 054543/0580 →
Continuity (1)
Related Publication 20210222276A1 · Jul 22, 2021
Cited By (3)
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