Flexible abrasive article
The disclosure relates to a curable composition comprising: a polymerizable epoxy-acrylate resin composition having a complex viscosity at 25° C. and 1 Hz frequency of at least about 4500 Pa-s and a probe tack peak force of at least about 300 kPa; and abrasive particles partially or fully embedded in the polymerizable epoxy-acrylate resin composition. The disclosure also relates to cured compositions formed from such curable compositions, wherein the abrasive particles are partially or fully embedded in the cured composition. In addition, the disclosure relates to abrasive articles made from such cured compositions as well as methods for making abrasive articles.
1. A curable composition comprising:
a polymerizable epoxy-acrylate resin composition comprising from about 15 to about 50 parts by weight of an acrylate copolymer relative to 100 parts of the curable composition and having a complex viscosity at 25° C. and 1 Hz frequency of at least about 4500 Pa-s and a probe tack peak force of at least about 300 kPa; and
abrasive particles partially or fully embedded in the polymerizable epoxy-acrylate resin component.
2. The curable composition of claim 1 , wherein the polymerizable epoxy-acrylate resin composition has an aligned mineral retention after coating of at least about 95%.
3. The curable composition as in claim 1 , wherein the acrylate copolymer comprises a tetrahydrofurfuryl (THF) (meth)acrylate copolymer component, and the polymerizable epoxy-acrylate resin composition further comprises one or more epoxy resins and one or more hydroxy-functional polyethers.
4. The curable composition as in claim 1 , wherein the polymerizable epoxy-acrylate resin composition further comprises one or more hydroxyl-containing film-forming polymers.
5. The curable composition as in claim 1 , further comprising one or more photoinitiators.
6. The curable composition as in claim 3 , wherein the THF (meth)acrylate copolymer component comprises one or more THF (meth)acrylate monomers, one or more C 1 -C 8 (meth)acrylate ester monomers, and one or more optional cationically reactive functional (meth)acrylate monomers.
7. The curable composition as in claim 3 , wherein the THF (meth)acrylate copolymer component comprises polymerized monomer units of: (A) 40-60 wt % of tetrahydrofurfuryl (meth)acrylate; (B) 40-60 wt % of C 1 -C 8 alkyl (meth)acrylate ester monomers; and (C) 0-10 wt % of cationically reactive functional monomers, wherein the sum of A)-C) is 100 wt % of the THFA copolymer.
8. The curable composition as in claim 3 , wherein the curable composition comprises: i) the acrylate copolymer; ii) from about 25 to about 50 parts by weight of the one or more epoxy resins; iii) from about 5 to about 15 parts by weight of the one or more hydroxy-functional polyethers; iv) in the range of from about 10 to about 25 parts by weight of one or more hydroxyl-containing film-forming polymers; where the sum of i) to iv) is 100 parts by weight; and v) from about 0.1 to about 5 parts by weight of a photoinitiator, relative to the 100 parts of i) to iv).
9. The curable composition as in claim 3 , wherein the one or more hydroxy-functional polyethers is a liquid.
10. The curable composition as in claim 5 , wherein the photoinitiator is a cationic photoinitiator.
11. The curable composition as in claim 1 , wherein the abrasive particles comprise formed abrasive particles.
12. A cured composition formed from the curable composition of claim 1 , wherein the abrasive particles are partially or fully embedded in the cured composition.
13. An abrasive article comprising the cured composition of claim 12 as an abrasive layer.
14. The abrasive article of claim 13 , further comprising at least one of a size coat, a supersize coat, and a backing.
15. The abrasive article of claim 13 , further comprising a size coat having a size coat first major surface and a size coat second major surface and the abrasive layer has an abrasive layer first major surface and an abrasive layer second major surface, wherein the abrasive layer first major surface is in direct contact with the size coat second major surface.
16. The abrasive article of claim 15 , wherein substantially the entire abrasive layer first major surface is in direct contact with substantially the entire size coat second major surface.
17. The abrasive article of claim 13 , further comprising a backing having a backing first major surface and a backing second major surface, wherein the backing first major surface is in direct contact with the abrasive layer second major surface.
18. The abrasive article of claim 17 , wherein substantially the entire backing first major surface is in direct contact with substantially the entire abrasive layer second major surface.
19. The abrasive article of claim 13 , further comprising a supersize coat having a supersize coat first major surface and a supersize coat second major surface, wherein the supersize coat second major surface is in direct contact with the size coat first major surface.
20. The abrasive article of claim 19 , wherein substantially the entire supersize coat second major surface is in direct contact with substantially the entire size coat first major surface.
21. The abrasive article of claim 13 , further comprising a backing having a backing first major surface and a backing second major surface, wherein the backing first major surface is in direct contact with the abrasive layer second major surface.
22. The abrasive article of claim 21 , wherein substantially the entire backing first major surface is in direct contact with substantially the entire abrasive layer second major surface.