IP Library Granted Patent US 11,965,128
Granted Patent B2
US 11,965,128 · App. 17/631,335 · Granted Apr 23, 2024

Polymeric gels for oil and gas conformance control applications and methods of making same

Inventors: Ahmed Hamza (Doha, QA); Ibnelwaleed Ali Hussein (Doha, QA); Mohamed Shamlooh (Doha, QA); Mustafa Nasser (Doha, QA); Musaab Magzoub (Doha, QA); Saeed Salehi (Doha, QA)
Assignees: QATAR FOUNDATION FOR EDUCATION, SCIENCE AND COMMUNITY DEVELOPMENT; QATAR UNIVERSITY
C09K8/035C08J3/11E21B21/003E21B33/138C08J2333/26
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Quick Facts
Patent No.
US 11,965,128
App. No.
17/631,335
Granted
Apr 23, 2024
Kind
B2
Abstract

A gel material for oil and gas conformance control operations is provided. The gel material includes a plurality of gel material components including polyacrylamide, triamine silica, and nanosilica which are added in suitable amounts to form the gel material under a gel formation condition. The present technology replaces and/or supplements conventional crosslinkers and provides enhanced polymeric gels, such as, for oil and gas field applications including wellbore strengthening, loss circulation materials, and water shut-off applications, at high temperatures. The present technology is compatible with fresh and high salinity water.

Claims (16)

1. A method of preventing or reducing loss circulation during drilling operations in an oil and gas well, the method comprising:

mixing a plurality of gel material components comprising polyacrylamide (PAM), triamine silica (TAS), and nanosilica (NS) at a surface temperature of an oil and gas well to form a mixture;

injecting the mixture through a tubing in the oil and gas well; and

allowing the mixture to form a gel material in the oil and gas well.

2. The method of claim 1 wherein a concentration of the polyacrylamide (PAM) is 9 wt. %.

3. The method of claim 1 further comprising providing to the mixture a chelating agent comprising at least one of diethylenetriamine pentaacetic acid (DTPA), hydroxy ethylethylenediaminetriacetic acid (HEDTA), or ethylene diamine tetra acetic acid (EDTA).

4. The method of claim 3 , wherein the chelating agent comprises ethylene diamine tetra acetic acid (EDTA) in a concentration of up to 1 wt. %.

5. A method of wellbore strengthening, LCMs, and/or water shut-off applications at high temperatures in oil and gas well drilling operations, the method comprising:

mixing a plurality of gel material components comprising polyacrylamide (PAM), triamine silica (TAS), and nanosilica (NS) at a surface temperature of an oil and gas well to form a mixture;

injecting the mixture through a tubing in the oil and gas well; and

allowing the mixture to form a gel material in the oil and gas well.

6. The method of claim 5 further comprising adding polyethyleneimine (PEI) to the mixture.

7. The method of claim 5 further comprising polyacrylamide tert-butyl (PAtBA).

8. The method of claim 5 , wherein a concentration of the polyacrylamide (PAM) is 9 wt. %.

9. The method of claim 5 further comprising providing to the mixture a chelating agent comprising at least one of diethylenetriamine pentaacetic acid (DTPA), hydroxy ethylethylenediaminetriacetic acid (HEDTA), or ethylene diamine tetra acetic acid (EDTA).

10. The method of claim 9 , wherein the chelating agent comprises ethylene diamine tetra acetic acid (EDTA) in a concentration of up to 1 wt. %.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 13, 2023
From: HAMZA, AHMED; HUSSEIN, IBNELWALEED ALI; SHAMLOOH, MOHAMED; NASSER, MUSTAFA; MAGZOUB, MUSAAB; SALEHI, SAEED
To: QATAR FOUNDATION FOR EDUCATION, SCIENCE AND COMMUNITY DEVELOPMENT; QATAR UNIVERSITY
Reel/Frame 065855/0362 →
Continuity (2)
Provisional Application 62880845 · Jul 31, 2019
Related Publication 20220363970A1 · Nov 17, 2022